EP3086889B1 - Procédé de laminage à chaud, laminoir à chaud et produit programme d'ordinateur pour la mise en oeuvre d'un tel procédé - Google Patents
Procédé de laminage à chaud, laminoir à chaud et produit programme d'ordinateur pour la mise en oeuvre d'un tel procédé Download PDFInfo
- Publication number
- EP3086889B1 EP3086889B1 EP13824153.4A EP13824153A EP3086889B1 EP 3086889 B1 EP3086889 B1 EP 3086889B1 EP 13824153 A EP13824153 A EP 13824153A EP 3086889 B1 EP3086889 B1 EP 3086889B1
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- EP
- European Patent Office
- Prior art keywords
- rolling
- regulating
- réel
- parameters
- sortie
- Prior art date
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- 238000000034 method Methods 0.000 title claims description 45
- 238000005098 hot rolling Methods 0.000 title claims description 18
- 238000005096 rolling process Methods 0.000 claims description 49
- 230000001105 regulatory effect Effects 0.000 claims description 16
- 229910000831 Steel Inorganic materials 0.000 claims description 14
- 239000010959 steel Substances 0.000 claims description 14
- 238000002347 injection Methods 0.000 claims description 11
- 239000007924 injection Substances 0.000 claims description 11
- 238000004364 calculation method Methods 0.000 claims description 9
- 239000000839 emulsion Substances 0.000 claims description 9
- 230000001050 lubricating effect Effects 0.000 claims description 7
- 238000005259 measurement Methods 0.000 claims description 7
- 230000033228 biological regulation Effects 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 238000004590 computer program Methods 0.000 claims description 2
- 239000011265 semifinished product Substances 0.000 claims 7
- 229910000797 Ultra-high-strength steel Inorganic materials 0.000 claims 1
- 239000003921 oil Substances 0.000 description 14
- 238000005461 lubrication Methods 0.000 description 8
- 239000010687 lubricating oil Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000000314 lubricant Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 230000006870 function Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000001427 coherent effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 241001061132 Eutaeniophorus sp. 033-Miya Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
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- 239000002964 rayon Substances 0.000 description 1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B37/00—Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B2001/225—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length by hot-rolling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2265/00—Forming parameters
- B21B2265/12—Rolling load or rolling pressure; roll force
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2265/00—Forming parameters
- B21B2265/20—Slip
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2275/00—Mill drive parameters
- B21B2275/02—Speed
- B21B2275/04—Roll speed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B2275/00—Mill drive parameters
- B21B2275/02—Speed
- B21B2275/06—Product speed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
- B21B27/06—Lubricating, cooling or heating rolls
- B21B27/10—Lubricating, cooling or heating rolls externally
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0239—Lubricating
- B21B45/0245—Lubricating devices
- B21B45/0248—Lubricating devices using liquid lubricants, e.g. for sections, for tubes
- B21B45/0251—Lubricating devices using liquid lubricants, e.g. for sections, for tubes for strips, sheets, or plates
Definitions
- the invention relates to the hot rolling of metallurgical products. More specifically, it relates to a method of controlling at least one parameter of the hot rolling process.
- the hot-rolled strip thus obtained can then be subjected to heat or mechanical treatments which will give it its final properties, or undergo a cold rolling which will further reduce its thickness before the completion of the final heat or mechanical treatments.
- the steel strip is subjected to a specific thermal and mechanical path (reduction, temperature) which is influenced by the friction between the working rolls and the band in the gap between the rollers.
- This path has a major influence on the quality of the band (surface appearance and metallurgical properties).
- the regulation of the coefficient of friction is in particular ensured by the lubrication process.
- lubrication is generally carried out at each roll stand by injecting an emulsion composed of water and a lubricating fluid, usually oil, onto the cylinder at the gap, see for example the document US Patent 3605473 .
- THR Very High Strength, generally between 450 and 900 MPa
- UHR Ultra High Strength, generally greater than 900 MPa
- new formats for example band thicknesses less than 3mm.
- these steels such as USIBOR® or Dual Phase steels are naturally harder and require the application of a greater rolling force, which reduces the capacity of the rolling mill.
- These steels may also have a surface composition such that it has less scale which usually acts as the first lubricating element.
- JP-A-2008264828 discloses a hot rolling method in which the working rolls are coated with a coating layer of specific composition to ensure a certain coefficient of friction value.
- JP-A-2005146094 discloses a hot rolling method wherein slip of the strip would be avoided by using a lubricating oil of particular composition.
- JPH-A-1156410 discloses a method in which the clamping force of the applied rolling rolls would be measured by sensor, then the amount of lubricating oil injected would be adjusted so that the measured rolling force is equal to a target value.
- This solution aims to adjust the coefficient of friction during the process but does not take into account all the parameters on which the coefficient of friction depends, which makes it inefficient.
- this solution involves significant risks of instabilities of the rolling process, such as. variations in speed or traction, if the amount of lubricant to be supplied to achieve the required force is important.
- the object of the invention is therefore to provide a rolling method in which the coefficient of friction is reliably and effectively controlled during production in order to avoid rolling incidents and to obtain optimum performance.
- the object of the invention is also preferably to provide a method reducing the instabilities of the rolling process and allowing lubrication over the entire length of the strip.
- the invention firstly relates to a control method according to claim 1.
- This control method may also include the features of claims 2 to 7, singly or in combination.
- the invention also relates to a rolling method according to claim 8.
- This rolling method may also include the features of claims 9 to 13, taken alone or in combination.
- the invention also relates to a hot rolling mill according to claim 14.
- This mill may also include the features of claim 15.
- the invention also relates to a computer program product according to claim 16.
- the figure 1 shows a metal strip B during rolling in a rolling mill comprising two cages 1, 2 in which the band B is simultaneously under the influence, for example a finishing mill for the hot rolling of the steel strips.
- Rolling mills of this type generally have 5, 6 or 7 cages.
- Each of the cages 1, 2 comprises, conventionally, two working rolls 1a, 1a 'and 2a, 2a' and two support rolls 1b, 1b 'and 2b, 2b'.
- Each cage is activated by a motor torque C 1 , C 2 (not shown).
- the distance between the two working cylinders, respectively 1a -1a 'and 2a-2a' is called the air gap S (not shown) and is adjusted by means of clamping screws 7.
- the lubrication of the cylinders is ensured at each of the cages by an injection device 3, such as for example projection nozzles for projecting an emulsion of oil and water.
- a speed measuring device 4 is disposed at the exit of the first cage in the running direction of the strip, this device 4 makes it possible to measure the speed of the strip at the exit of the strip.
- v- output and v- cage speeds can be expressed in any speed unit, provided they are both expressed in that same unit. In the same way the unit in which the angular velocity ⁇ is expressed must be coherent with that of v cage .
- a device 5 for measuring force to measure in real time the clamping force F of the working rolls is also provided at each cage.
- These devices may for example be strain gauges installed on the cage uprights or under the clamping screws 7.
- the measured tightening force F and the speed of the output band C output are transmitted to a processing unit 6 which can then, according to these measurements and other parameters previously recorded, send instructions by example to the lubricating emulsion injection nozzles 3 or to the clamping screws 7.
- a processing unit 6 for implementing a first embodiment of the regulation method according to the invention is described below with reference to FIG. figure 3 .
- the speed of the output band of the exit v-cage and the angular velocity of the work rolls ⁇ are measured in line and their values are sent to a first computer 8.
- This first computer 8 comprises at least one internal memory on which the value of the radius R of the working rolls is stored, which makes it possible to calculate the linear speed of the working rolls v cage and then the value of the slip ratio.
- forward FWS according to formula 1.
- the calculated value FWS is then transmitted to a second computer 9 which also receives as input the value of the clamping force F measured in real time by the sensor 5.
- This second computer comprises at least one internal memory on which are stored the parameters P 1 . These parameters P 1 depend on the model chosen for the calculation of the real coefficient of friction ⁇ .
- Orowan model As an example we will describe below the use for the purposes of the invention Orowan model, but other models known to those skilled in the art may be used, such as the model of SIMS or Bland & Ford.
- the general theory of each of these three models is described for example in E.Orowan, Proceedings of the Institute of Mechanical Engineers, June 1943, vol.150, No. 1,140-167 for the Orowan model , RB Sims, Proceedings of the Institute of Mechanical Engineers, June 1954, vo1.168, No. 1 191-200 for the Sims Model , " The Calculation of Roll and Torque Force in Cold Strip Rolling with Tensions, "DR Bland and H. Ford, Proceedings of the Institute of Mechanical Engineers, June 1948, vol.149, p.144, for the Bland & Ford model .
- Orowan P 1 To calculate in real time the actual friction coefficient ⁇ using the model Orowan P 1 parameters are input thicknesses e input and output an output of the band, ⁇ entry input and output tractions ⁇ output of the band, these parameters being in the present example fixed at the beginning of rolling but can also be estimated or measured in real time. These parameters are illustrated in figure 2 .
- the second computer 9 thus calculates the real coefficient of friction ⁇ given to a processor 10.
- the computation time of real ⁇ is less than or equal to 100 ms and preferably less than or equal to 50 ms.
- the input data processor 10 are real ⁇ , a target value of target friction coefficient ⁇ determined from graphs or modeling, depending on the steel grade of the rolled strip, the number of kilometers strips laminated on the installation in question, the wear of the rollers, the type of oil used, etc. as well as a parameter ⁇ 0 .
- This parameter is the initial value of the process parameter ⁇ which will be used to regulate the real coefficient of friction ⁇ .
- This parameter may be, for example, the oil injection rate Q of the lubricating oil.
- the initial value can be determined for example using charts or by modeling.
- the value of the actual ⁇ friction coefficient is then compared with the target value of friction coefficient ⁇ target. If the absolute value of the difference between these two values
- the time elapsing between the measurement of the strip exit speed v output and receiving the setpoint ⁇ n is less than or equal to 500 ms and preferably less than or equal to 150 ms.
- the figure 4 represents a control scheme according to a second embodiment of the invention.
- the Orowan model parameters P 2 are the input thicknesses e input and output an output of the band, the input traction ⁇ input and output output ⁇ of the strip, the radius R of the rollers, these parameters being in the present example set at the beginning of rolling, but can also be estimated or measured in real time.
- P2 also includes the milling module M of the mill stand considered. This module, generally expressed in t / mm, characterizes the elastic deformation of the cage related to the rolling force.
- the processor calculates for example the value of rolling force F 'which should be applied to obtain the thickness e output
- the units of these three quantities must be coherent with each other and may for example be in Newton for the forces F and F 'and in N / mm for the curing module M.
- treatment units described above with reference to Figures 3 and 4 contain different elements such as computers or processors but one could consider a single processor for performing the various calculation operations and instructions, or any other possible configuration for calculation steps and instructions.
- a hot rolling method according to the invention was made with a Drawn and Wall Ironed (DWI) steel strip, the lubricating oil used being a commercial standard oil.
- DWI Drawn and Wall Ironed
- the injection rate Q oil is zero during the rolling of the tape head. This is voluntary this test being mainly devoted to the lubrication of the tail of tape.
- the figure 6 represents the thickness of the strip at the output of the cage e output as a function of the rolling time. There is a drop of this thickness e output after 10 seconds, this decrease corresponds to what has been explained above.
- the modification of the injected oil flow rate Q oil causes a change in the force F applied and in this case a significant decrease in the thickness e exit of the strip at the exit of the cage. Thanks to the regulation illustrated in figure 4 a new clamping force F 'is calculated and the air gap S modified accordingly in order to obtain a thickness of output e output according to the expectations of the customer. The increase and the maintenance of the thickness e output are visible on this figure 6 .
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Control Of Metal Rolling (AREA)
- Metal Rolling (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL13824153T PL3086889T3 (pl) | 2013-12-24 | 2013-12-24 | Sposób walcowania na gorąco, walcownia gorąca i program komputerowy do wykonywania takiego sposobu |
HUE13824153 HUE044992T2 (hu) | 2013-12-24 | 2013-12-24 | Meleghengerlési eljárás, meleghengersor és számítógépi program az eljárás végrehajtására |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2013/002865 WO2015097488A1 (fr) | 2013-12-24 | 2013-12-24 | Procede de laminage a chaud |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3086889A1 EP3086889A1 (fr) | 2016-11-02 |
EP3086889B1 true EP3086889B1 (fr) | 2019-02-06 |
Family
ID=50001027
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13824153.4A Active EP3086889B1 (fr) | 2013-12-24 | 2013-12-24 | Procédé de laminage à chaud, laminoir à chaud et produit programme d'ordinateur pour la mise en oeuvre d'un tel procédé |
Country Status (17)
Country | Link |
---|---|
US (1) | US10870138B2 (zh) |
EP (1) | EP3086889B1 (zh) |
JP (1) | JP6342003B2 (zh) |
KR (2) | KR20160101153A (zh) |
CN (1) | CN105916603B (zh) |
AU (1) | AU2013409182B2 (zh) |
BR (1) | BR112016014762B1 (zh) |
CA (1) | CA2935193C (zh) |
ES (1) | ES2724456T3 (zh) |
HU (1) | HUE044992T2 (zh) |
MA (1) | MA39044B1 (zh) |
MX (1) | MX2016008454A (zh) |
PL (1) | PL3086889T3 (zh) |
RU (1) | RU2670630C9 (zh) |
UA (1) | UA117508C2 (zh) |
WO (1) | WO2015097488A1 (zh) |
ZA (1) | ZA201603733B (zh) |
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CN105032949B (zh) * | 2015-07-09 | 2017-02-01 | 首钢总公司 | 一种控制高线盘条尾部圈形的夹持方法 |
JP6638639B2 (ja) * | 2016-12-19 | 2020-01-29 | トヨタ自動車株式会社 | 差厚金属板の製造方法、プレス部品の製造方法及び加工機 |
CN108655176B (zh) * | 2017-03-31 | 2020-05-19 | 上海梅山钢铁股份有限公司 | 用于稳定轧制的冷轧前滑模型自适应计算方法 |
CN107537863B (zh) * | 2017-10-13 | 2019-05-03 | 北京金自天正智能控制股份有限公司 | 一种h型钢开坯机区的全自动控制方法 |
EP3517228A1 (de) * | 2018-01-29 | 2019-07-31 | Primetals Technologies Austria GmbH | Regeln eines walzprozesses |
JP7073983B2 (ja) | 2018-08-21 | 2022-05-24 | 日本製鉄株式会社 | 冷間圧延方法 |
IT201900005442A1 (it) * | 2019-04-09 | 2020-10-09 | Danieli Off Mecc | Processo di laminazione a freddo di un prodotto in alluminio e relativo impianto di laminazione a freddo |
US11617744B2 (en) | 2019-12-09 | 2023-04-04 | Nico Ventures Trading Limited | Moist oral compositions |
US11793230B2 (en) | 2019-12-09 | 2023-10-24 | Nicoventures Trading Limited | Oral products with improved binding of active ingredients |
US11969502B2 (en) | 2019-12-09 | 2024-04-30 | Nicoventures Trading Limited | Oral products |
US11826462B2 (en) | 2019-12-09 | 2023-11-28 | Nicoventures Trading Limited | Oral product with sustained flavor release |
US11872231B2 (en) | 2019-12-09 | 2024-01-16 | Nicoventures Trading Limited | Moist oral product comprising an active ingredient |
CN114850428B (zh) * | 2022-05-09 | 2024-01-16 | 宝信软件(山西)有限公司 | 采用压下力补正立式连铸机拉矫主辊速度的方法 |
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JP4140964B2 (ja) | 2003-11-14 | 2008-08-27 | 大同化学工業株式会社 | アルミニウム及びアルミニウム合金用熱間圧延油および該圧延油を使用するアルミニウム及びアルミニウム合金の熱間圧延方法 |
JP4355279B2 (ja) * | 2004-11-22 | 2009-10-28 | 新日本製鐵株式会社 | 冷間圧延における潤滑油供給方法 |
DE102006002505A1 (de) * | 2005-10-31 | 2007-05-03 | Sms Demag Ag | Verfahren und Fertigwalzstraße zum Warmwalzen von Eingangsmaterial |
FR2898523B1 (fr) * | 2006-03-14 | 2009-02-27 | Alstom Power Conversion Sa | Procede de laminage d'une bande de tole. |
DE102007032485A1 (de) * | 2006-12-15 | 2008-06-19 | Sms Demag Ag | Verfahren und Schmiermittelauftragsvorrichtung zum Regeln der Planheit und/oder der Rauheit eines Metallbandes |
KR101120818B1 (ko) * | 2007-02-02 | 2012-03-26 | 수미도모 메탈 인더스트리즈, 리미티드 | 미세 페라이트 조직을 가지는 열연 강판의 제조 방법, 및 열연 강판 |
JP5025315B2 (ja) | 2007-04-19 | 2012-09-12 | 株式会社フジコー | 熱間圧延用複合ロール、熱間圧延用複合ロールの製造方法及び熱間圧延方法 |
JP4735785B1 (ja) * | 2009-11-24 | 2011-07-27 | 住友金属工業株式会社 | 熱延鋼板の製造方法、および熱延鋼板の製造装置 |
KR101230151B1 (ko) * | 2010-12-28 | 2013-02-15 | 주식회사 포스코 | 열간압연공정에서의 압연유량 제어방법 |
JP5633463B2 (ja) | 2011-04-12 | 2014-12-03 | 新日鐵住金株式会社 | 冷間圧延機の潤滑油供給装置 |
US9095886B2 (en) * | 2011-06-27 | 2015-08-04 | University Of Central Florida Research Foundation, Inc. | Mill control system and method for control of metal strip rolling |
CN105514539A (zh) * | 2016-01-27 | 2016-04-20 | 南京米乐为微电子科技有限公司 | 基于容性负载的超宽带定值移相器 |
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- 2013-12-24 US US15/108,132 patent/US10870138B2/en active Active
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- 2013-12-24 PL PL13824153T patent/PL3086889T3/pl unknown
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- 2013-12-24 CN CN201380081821.6A patent/CN105916603B/zh active Active
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- 2013-12-24 WO PCT/IB2013/002865 patent/WO2015097488A1/fr active Application Filing
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CA2935193A1 (fr) | 2015-07-02 |
JP2017500208A (ja) | 2017-01-05 |
KR102110645B1 (ko) | 2020-05-14 |
RU2670630C9 (ru) | 2018-11-26 |
US20160318080A1 (en) | 2016-11-03 |
KR20180004332A (ko) | 2018-01-10 |
CN105916603A (zh) | 2016-08-31 |
CN105916603B (zh) | 2018-09-07 |
ZA201603733B (en) | 2017-07-26 |
JP6342003B2 (ja) | 2018-06-13 |
BR112016014762A2 (zh) | 2017-08-08 |
MX2016008454A (es) | 2016-10-14 |
MA39044B1 (fr) | 2018-11-30 |
WO2015097488A1 (fr) | 2015-07-02 |
AU2013409182B2 (en) | 2017-08-31 |
CA2935193C (fr) | 2018-12-04 |
AU2013409182A1 (en) | 2016-07-14 |
BR112016014762B1 (pt) | 2022-03-15 |
EP3086889A1 (fr) | 2016-11-02 |
RU2670630C2 (ru) | 2018-10-24 |
US10870138B2 (en) | 2020-12-22 |
PL3086889T3 (pl) | 2019-08-30 |
RU2016130269A (ru) | 2018-01-30 |
ES2724456T3 (es) | 2019-09-11 |
KR20160101153A (ko) | 2016-08-24 |
HUE044992T2 (hu) | 2019-11-28 |
UA117508C2 (uk) | 2018-08-10 |
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