EP3041631A2 - Poudre métallique à base de chrome - Google Patents

Poudre métallique à base de chrome

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Publication number
EP3041631A2
EP3041631A2 EP14789128.7A EP14789128A EP3041631A2 EP 3041631 A2 EP3041631 A2 EP 3041631A2 EP 14789128 A EP14789128 A EP 14789128A EP 3041631 A2 EP3041631 A2 EP 3041631A2
Authority
EP
European Patent Office
Prior art keywords
metal powder
mpa
chromium
powder
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP14789128.7A
Other languages
German (de)
English (en)
Other versions
EP3041631B1 (fr
Inventor
Michael O'sullivan
Lorenz Sigl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Plansee SE
Original Assignee
Plansee SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Plansee SE filed Critical Plansee SE
Publication of EP3041631A2 publication Critical patent/EP3041631A2/fr
Application granted granted Critical
Publication of EP3041631B1 publication Critical patent/EP3041631B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00Obtaining refractory metals
    • C22B34/30Obtaining chromium, molybdenum or tungsten
    • C22B34/32Obtaining chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/045Alloys based on refractory metals
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61HPHYSICAL THERAPY APPARATUS, e.g. DEVICES FOR LOCATING OR STIMULATING REFLEX POINTS IN THE BODY; ARTIFICIAL RESPIRATION; MASSAGE; BATHING DEVICES FOR SPECIAL THERAPEUTIC OR HYGIENIC PURPOSES OR SPECIFIC PARTS OF THE BODY
    • A61H33/00Bathing devices for special therapeutic or hygienic purposes
    • A61H33/06Artificial hot-air or cold-air baths; Steam or gas baths or douches, e.g. sauna or Finnish baths
    • A61H33/063Heaters specifically designed therefor
    • A61H33/065Heaters specifically designed therefor with steam generators
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/16Making metallic powder or suspensions thereof using chemical processes
    • B22F9/18Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
    • B22F9/20Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds
    • B22F9/22Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds using gaseous reductors
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C27/00Alloys based on rhenium or a refractory metal not mentioned in groups C22C14/00 or C22C16/00
    • C22C27/06Alloys based on chromium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2201/00Treatment under specific atmosphere
    • B22F2201/01Reducing atmosphere
    • B22F2201/013Hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2202/00Treatment under specific physical conditions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2301/00Metallic composition of the powder or its coating
    • B22F2301/20Refractory metals

Definitions

  • the present invention relates to a metal powder having a chromium content of at least 90% by mass and a process for its production.
  • the large-scale production of chromium metal powder from chromium oxides is currently only by aluminothermic (powder morphology see Figure 1) and electrolytic (powder morphology see Figure 2) method.
  • powders produced in this way have a poor pressing and sintering behavior.
  • electrolytic processes are environmentally harmful.
  • Increasingly stringent environmental regulations mean that this process is hardly acceptable economically and environmentally.
  • the present invention has therefore set itself the task of providing metal powder having a chromium content of at least 90% by mass, which can be processed well powder metallurgy, in particular by pressing and sintering.
  • a metal powder is to be provided with which complex-shaped and / or thin-walled components can be produced in a simple manner by powder metallurgy.
  • the metal powder should further be produced in a high metallic purity, in particular a metallic purity comparable or better than metal powder, which is obtained by electrolytic route.
  • the object is achieved by metal powder with a chromium content of at least 90% by mass, which is measured by a nanohardness of 0.005 / 5/1/5 EN ISO 14577-1 (2002 edition - Berkovich indenters and Oliver and Pharr's method) of ⁇ 4 GPa.
  • the hardness value refers to a metal powder, which is preferably subjected to no further treatment, such as an annealing.
  • the nanohardness HIT is preferably 0.005 / 5/1/5 ⁇ 3.7 GPa, more preferably ⁇ 3.4 GPa. For very high requirements, for example for very thin-walled components, a nanohardness HIT 0.005 / 5/1/5 of ⁇ 3, 1 GPa has proven itself.
  • a nanohardness of 0.005 / 5/1/5 of about 1.4 GPa can be realized.
  • the nanohardness is determined in the pure chromium phase. If there is no pure chromium phase, the nanohardness is determined in the chromium-rich (phase with the highest chromium content) phase.
  • the metal powder according to the invention thus has a significantly lower nanohardness compared with the nanohards of metal powder according to the prior art. Since the powder according to the invention can be produced without a downstream milling process, the specified nanohardness can be achieved even with very fine-grained powder having a BET surface area of preferably> 0.05 m 2 / g.
  • the information on the BET surface area in the context of this application relates to a BET measurement according to the standard (ISO 9277: 1995, measuring range: 0.01-300 m 2 / g, device: Gemini II 2370, baking temperature: 130 ° C., heating time : 2 hours, adsorptive: nitrogen, volumetric evaluation by five-point determination).
  • the object is further achieved by a metal powder having a chromium content of at least 90% by mass, which is determined by a green strength according to ASTM B 312-09 at a pressure of 550 MPa of at least 7 MPa, preferably at least 10 MPa, more preferably of at least 15 MPa , particularly particularly preferably of at least 20 MPa.
  • a metal powder having a chromium content of at least 90% by mass which is determined by a green strength according to ASTM B 312-09 at a pressure of 550 MPa of at least 7 MPa, preferably at least 10 MPa, more preferably of at least 15 MPa , particularly particularly preferably of at least 20 MPa.
  • metal powders having a green strength of up to about 50 MPa can be produced at a pressure of 550 MPa.
  • the ASTM B 312-09 leaves open whether a wax is used as pressing additive.
  • a wax was used as pressing additive, namely 0.6% by mass of an amide wax, namely LICOWAX® Micropowder
  • the green strength preferably has the following values: at least 8 MPa, preferably at least 13 MPa, at a compression pressure of 450 MPa; at least 6 MPa, preferably at least 1 1 MPa, at a compression pressure of 300 MPa; at least 4 MPa, preferably at least 6 MPa, at one Compressing pressure of 250 MPa and at least 2 MPa, preferably at least 2.5 MPa, at a pressure of 150 MPa.
  • Green strengths could be achieved at pressures of 450, 300 and 250 MPa of 18.5, 13.0 and 7.5 MPa and above.
  • the metal powder according to the invention can be processed in a simple manner by powder metallurgy, for example by pressing and sintering.
  • the metal powder according to the invention enables the simple and cost-effective production of powder metallurgy components with thin-walled areas, complex shape or relatively unfavorable pressing ratio.
  • the properties with regard to nanohardness and green strength can be achieved if the chromium content is at least 90% by mass and thus the content of other substances of 10% by mass is not exceeded.
  • the other substances are present in an advantageous manner separated from the chromium phase.
  • the other substance can be deposited in metallic or non-metallic form, preferably via a diffusion bond. Such powders are referred to as composite powder. Shares (advantageously ⁇ 5% by mass) of the other substance can also be dissolved in the chromium and form a chromium mixed crystal. Such powders are referred to as alloyed powders.
  • the metal powder then comprises a pure chromium phase and / or a chromium mixed crystal phase.
  • La 2 O 3 (up to 5 Ma%) or Cu (up to a maximum of 10 Ma%) may be mentioned, in the case of La 2 0 3 La (OH) 3 and in the case of Cu CuO mixed to form Cr 2 O 3 and the reduction are supplied.
  • La 2 O 3 up to 5 Ma%
  • Cu up to a maximum of 10 Ma%
  • other metals or non-metals are possible.
  • the metal powder preferably has both a green strength at a compacting pressure of 550 MPa of at least 7 MPa, preferably at least 10 MPa, more preferably of at least 15 MPa, particularly preferably of at least 20 MPa, and a nano-hardness HIT of 0.005 / 5/1/5 of ⁇ 4 GPa, preferably ⁇ 3.7 GPa, more preferably ⁇ 3.4 GPa, most preferably ⁇ 3, 1 GPa.
  • the metal powder according to the invention preferably has a sponge-like particle shape Z morphology (division of the particle shape / morphology see Powder Metallurgy Science; Randall M. German; MPIF; Princeton, 1994, second edition, page 63). This has a favorable effect on the green strength.
  • the metal powder has a BET surface without surface enlarging process of> 0.05 m 2 / g.
  • the BET surface area is> 0.07 m 2 / g.
  • BET surfaces of 0.25 m 2 / g and above could be achieved.
  • it without a surface-enlarging process, it can also be called "as produced” and means for the person skilled in the art that the metal powder was obtained directly from the process and, in particular, is no longer subjected to a grinding process Milling process form smooth fracture surfaces, which are not found in unmilled powder. According to the invention, only a deagglomeration is preferably provided.
  • the metal powder according to the invention has a metallic purity, i. a content of chromium based on other metals, of> 99.0 Ma%, preferably> 99.5 Ma%, more preferably ⁇ 99.9 Ma%, particularly preferably of> 99.99 Ma%.
  • Metallic purity here means the purity of the metal powder without consideration of non-metallic constituents such as, for example, O, C, N and H.
  • the oxygen content of metal powder according to the invention is preferably not more than 1500 pg / g of chromium, more preferably not more than 1000 pg / g of chromium. In a particularly preferred embodiment, the oxygen content is not more than 500 pg / g of chromium.
  • the achievable carbon content can be set very low and is preferably not more than 1 50 pg / g of chromium, more preferably not more than 100 pg / g of chromium. In a particularly preferred embodiment, the carbon content is not more than 50 pg / g chromium. In one embodiment, it can be provided that the metal powder is granulated.
  • the granulation can be carried out by customary methods, preferably by spray or build-up granulation (see also Powder Metallurgy Science, Randall M. German, MPIF, Princeton, 1994, second edition, pages 183 to 184). Under granules is the merger of individual powder particles to understand that are connected to each other, for example by means of a binder or by Sinterhals Struktur.
  • the metal powder has a bulk density of ⁇ 2.0 g / cm 3 .
  • the bulk density is preferably 0.1 to 2 g / cm 3 , more preferably 0.5 to 1.5 g / cm 3 . Since a comparatively high bulk density is achieved for the achievable particle size or BET surface area (preferably of> 0.05 m 2 / g), the powder has a good filling behavior during the pressing process.
  • the metal powder preferably has a compact density of> 80% of the theoretical density at 550 MPa compacting pressure. This makes it possible to produce components without high sintering shrinkage near net shape
  • the metal powder according to the invention can be prepared by reducing at least one compound of the group consisting of Cr oxide and Cr hydroxide, optionally with a mixed solid carbon source, under at least temporary exposure to hydrogen and hydrocarbon.
  • Preferred chromium oxide or chromium hydroxide are Cr (III) compounds in powder form, for example Cr 2 O 3 , CrOOH, Cr (OH) 3 or mixtures of chromium oxides and chromium hydroxides.
  • the preferred chromium source is Cr 2 O 3 .
  • the Cr 2 O 3 used has at least pigment quality.
  • the compound of the group consisting of Cr oxide and Cr hydroxide, optionally with a mixed solid carbon source, is preferably heated to a temperature T R of 1100 ° C. ⁇ T R ⁇ 1550 ° C. and optionally maintained at this temperature. Temperatures ⁇ 1 100 ° C or> 1550 ° C lead to deteriorated powder properties, or to a more uneconomical process. The reaction proceeds particularly well for industrial purposes when temperatures T R of about 1200 ° C to 1450 ° C are selected.
  • the degree of reduction R is defined as the ratio of the amount of oxygen in the chromium oxide or chromium hydroxide removed up to the time t, based on the total amount of oxygen present in the unreduced chromium compound:
  • the skilled person can easily determine the optimum combination of temperature and time for his furnace (continuous furnace, batch furnace, maximum achievable furnace temperature, etc.).
  • the reaction over substantially at least 30%, more preferably at least 50% of the reaction time is maintained substantially constant (isothermal) on T R.
  • the presence of hydrocarbon ensures that powder having the properties according to the invention is formed via a chemical transport process.
  • the total pressure of the reaction is advantageously 0.95 to 2 bar. Pressures above 2 bar adversely affect the economics of the process. Pressures below 0.95 bar have an adverse effect on the resulting hydrocarbon partial pressure, which in turn has a very unfavorable effect on the transport processes via the gas phase, which are of great importance for adjusting the powder properties of the invention (for example hardness, green strength, specific surface area) are. In addition, pressures below 0.95 bar adversely affect the process costs.
  • the hydrocarbon is present as CH 4 .
  • the hydrocarbon partial pressure is 5 to 500 mbar.
  • a hydrocarbon partial pressure ⁇ 5 mbar has an unfavorable effect on the powder properties, in particular the green strength.
  • a hydrocarbon partial pressure> 500 mbar leads to a high C content in the reduced powder.
  • the residual gas atmosphere is preferably hydrogen.
  • the action of hydrogen and hydrocarbon preferably takes place at least in the temperature range 800 ° C to 1050 ° C. In this temperature range, the hydrocarbon partial pressure is preferably from 5 to 500 mbar.
  • the reaction mixture forming from the starting materials is preferably at least 45 minutes, particularly preferably at least 60 minutes.
  • the hydrocarbon may be added to the reaction in gaseous form, preferably without admixing a solid carbon source.
  • the at least one compound of the group consisting of Cr oxide and Cr hydroxide is preferably reduced under at least temporary action of an H 2 -CH 4 gas mixture.
  • a H 2 / CH 4 volume ratio in the range 1 to 200, particularly advantageously from 1, 5 to 20 is selected.
  • the action of the H 2 -CH 4 gas mixture is preferably carried out at least temporarily during the heating phase to T R , the influence on the formation of the powder form, in particular in the temperature range 850 to 1000 ° C is very low.
  • T R is preferably switched to a pure hydrogen atmosphere, preferably with a dew point of ⁇ -40 ° C (measured in the gas supply). If T R is less than 1200X, switching to the pure hydrogen atmosphere is preferred when T R is reached .
  • the isothermal phase on T R and cooling to room temperature are advantageously carried out in a Wasserstoffatmosphinre. In particular, when cooling, it is advantageous to use hydrogen with a dew point ⁇ -40 ° C to avoid reoxidation.
  • a solid carbon source is admixed with the Cr oxide and / or Cr hydroxide. Preference is given here per mole of oxygen in the chromium compound between 0.75 and 1.25 mol, preferably between 0.90 and 1.05 moles of carbon used. This refers to the amount of carbon available for reaction with the chromium compound. In a particularly preferred embodiment, the ratio of O to C is slightly substoichiometric at about 0.98. It is preferably provided that the solid carbon source is selected from the group of carbon black, activated carbon, graphite, carbon-releasing compounds or mixtures thereof. As an example of a carbon releasing compound, chromium carbides such as Cr 3 C 2 , Cr 7 C 3 and Cr 2 3C 6 may be mentioned.
  • the powder mixture is heated to T R in an H 2 -containing atmosphere.
  • the H 2 pressure is preferably adjusted so that at least in the temperature range 800 ° to 1050 ° C, a CH 4 partial pressure of 5 to 500 mbar results.
  • the isothermal phase on T R and cooling to room temperature are again advantageously carried out in a hydrogen atmosphere. During these process phases, the presence of hydrocarbon is not required. Hydrogen prevents reoxidation processes during this process phase and during the cooling phase.
  • a hydrogen atmosphere with a dew point ⁇ -40 ° C. is preferably used.
  • FIG. 3 shows an SEM image of Cr 2 O 3 (pigment quality).
  • FIG. 6 shows the green strength of powder according to the invention (CP-181) in comparison with aluminothermically produced chromium powder (Cr-Std).
  • FIG. 7 shows the relative compacted density of powder according to the invention in FIG.
  • Figure 8 shows the time course of the reduction of Cr 2 0 3 to Cr at different temperatures according to the invention.
  • FIG. 9 shows the specific surface of various chromium powders according to the invention.
  • Example 1
  • Heating from 1200 ° C to T R and holding on T R was done by adding dry hydrogen with a dew point ⁇ -40 ° C, the pressure being about 1 bar.
  • the furnace cooling was also carried out under H 2 with a dew point ⁇ -40 ° C.
  • a metallic sponge was obtained, which could easily be deagglomerated to a powder.
  • the chromium metal powder thus produced is shown in FIG. The degree of reduction was> 99.0%, the carbon content 80 g / g and the oxygen content 1020 g / g.
  • An X-ray diffraction analysis provided only peaks for cubic body-centered (BCC) chromium metal.
  • the specific surface area was determined by BET method (according to ISO 9277: 1995, measuring range: 0.01-300 m 2 / g, device: Gemini II 2370, annealing temperature: 130 ° C., heating time: 2 hours, adsorptive: nitrogen, volumetric evaluation via five-point determination) and was 0.14 m 2 / g, the bulk density 1.2 g / cm 3 .
  • the nanohardness HIT 0.005 / 5/1/5 was determined according to EN ISO 14577-1 and was 3 GPa.
  • the green strength was determined according to ASTM B 312-09.
  • the compression additive used was 0.6% by mass LICOWAX® Micropowder PM (supplier Clariant, product number 107075, CAS No. 001 10-30-5). At a compacting pressure of 550 MPa, the green strength was 23.8 MPa, at 450 MPa 18.1 MPa, at 300 MPa 8.5 MPa, at 250 MPa 7.2 MPa and at 150 MPa 3.0 MPa.
  • Pigment-grade Cr 2 O 3 (Lanxess Bayoxide CGN-R) with a mean laser diffraction particle size d 50 of 0.9 ⁇ m was well blended with amorphous carbon black (Thermax ultra-pure N908 - Cancarb).
  • the carbon content of the mixture thus prepared was 0.99 mol / mol of O in Cr 2 O 3 . 12500 g of this mixture were in 80 min. to 800 ° C and then in 125 min. heated to 1050 ° C. The heating was carried out under the action of H 2 , wherein the H 2 pressure was adjusted so that in the temperature range 800 ° C to 1050 ° C, the measured mass spectrometry CH 4 partial pressure> 15 mbar amounted to.
  • the green strength was determined according to ASTM B 312-09.
  • the compression additive used was 0.6% by mass LICOWAX® Micropowder PM (supplier Clariant, product number 107075, CAS No. 001 0-30-5).
  • As pressing pressures 550 MPa, 450 MPa, 350 MPa, 250 MPa and 150 MPa were used.
  • FIG. 6 shows the measured fatigue properties in comparison with samples pressed with aluminothermically produced powder (Cr-Std).
  • the powder according to the invention (CP181) shows a green strength which is at least 5 times higher.
  • FIG. 7 shows the relative densities as a function of the compacting pressure in comparison to standard chromium metal powders (E-Cr: produced by electrolyzing, A-Cr: aluminothermically produced) having different particle sizes.
  • the BET specific surface area (ISO 9277: 1995, measuring range: 0.01-300 m 2 / g, apparatus: Gemini II 2370, baking temperature: 130 ° C., heating time: 2 hours, adsorptive: nitrogen, volumetric evaluation over 5-point determination) and the nanohardness ⁇ ⁇ 0.005 / 5/1/5 according to EN ISO 14577-1. Table 1 lists these characteristics and compares them with the properties of electrolytically produced chromium powders. Striking is the significantly lower nanohardness of the powder according to the invention. The particle size calculated from the BET surface area was 8.3 ⁇ m. Powder Type BET surface area 0 C Nanohardness
  • Chromium powder according to the invention 0,10 1064 114 2,92
  • Electrolytically produced chromium powder 0.1 1 736 87 5.32
  • Table 1 Properties of chromium powder according to the invention in comparison with electrolytically produced chromium powder
  • the holding times on T R were 30 min, 60 min, 90 min, 120 min and 180 min. Heating from 1000 ° C to T R and holding on T R was done by supplying dry hydrogen with a dew point ⁇ -40 ° C, the pressure was about 1 bar. The furnace cooling was also carried out under H 2 with a dew point ⁇ -40 ° C. The degree of reduction was determined as set out in the description. As can be seen from FIG. 8, an advantageous degree of reduction of> 95% at 1400 ° C., 1450 ° C. and 1480 ° C. already occurs with a holding time of 30 min. clearly exceeded. At 1350 ° C it takes about 80 min., At 1300 ° C about 160 min.

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Abstract

Poudre métallique ayant une teneur en chrome d'au moins 90 % en masse, caractérisée en ce qu'elle présente une nanodureté selon EN ISO 14577-1 inférieure ou égale à 4 GPa et/ou une résistance à vert mesurée selon ASTM B312-09 d'au moins 7 MPa pour une pression de compression de 550 MPa.
EP14789128.7A 2013-09-02 2014-08-19 Poudre métallique à base de chrome Active EP3041631B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ATGM283/2013U AT13691U1 (de) 2013-09-02 2013-09-02 Chrommetallpulver
PCT/AT2014/000160 WO2015027256A2 (fr) 2013-09-02 2014-08-19 Poudre métallique à base de chrome

Publications (2)

Publication Number Publication Date
EP3041631A2 true EP3041631A2 (fr) 2016-07-13
EP3041631B1 EP3041631B1 (fr) 2019-02-27

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EP14789128.7A Active EP3041631B1 (fr) 2013-09-02 2014-08-19 Poudre métallique à base de chrome

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Country Link
US (1) US11117188B2 (fr)
EP (1) EP3041631B1 (fr)
JP (1) JP6559134B2 (fr)
KR (1) KR102259464B1 (fr)
CN (1) CN105517736B (fr)
AT (1) AT13691U1 (fr)
CA (1) CA2921068C (fr)
RU (1) RU2662911C2 (fr)
TW (1) TWI636961B (fr)
WO (1) WO2015027256A2 (fr)

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WO2015089534A2 (fr) * 2013-12-20 2015-06-25 Plansee Se Produit de revêtement
CN111886088B (zh) * 2018-03-23 2023-01-17 株式会社村田制作所 铁合金粒子和铁合金粒子的制造方法
CN111922350B (zh) * 2020-09-22 2021-01-01 西安斯瑞先进铜合金科技有限公司 一种低盐酸不溶物金属铬粉的制备方法
CN111922351B (zh) * 2020-09-23 2021-01-01 西安斯瑞先进铜合金科技有限公司 一种高纯低氧金属铬粉的制备方法

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US11117188B2 (en) 2021-09-14
CN105517736B (zh) 2019-08-06
CA2921068A1 (fr) 2015-03-05
EP3041631B1 (fr) 2019-02-27
JP2016532010A (ja) 2016-10-13
AT13691U1 (de) 2014-06-15
TW201512099A (zh) 2015-04-01
WO2015027256A3 (fr) 2015-05-21
CN105517736A (zh) 2016-04-20
US20160199910A1 (en) 2016-07-14
CA2921068C (fr) 2021-03-09
RU2016105215A (ru) 2017-10-09
TWI636961B (zh) 2018-10-01
WO2015027256A2 (fr) 2015-03-05
KR20160051760A (ko) 2016-05-11
JP6559134B2 (ja) 2019-08-14
RU2662911C2 (ru) 2018-07-31
RU2016105215A3 (fr) 2018-04-27
KR102259464B1 (ko) 2021-06-02

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