EP2906876A2 - Verfahren zum betrieb eines dampferzeugers - Google Patents
Verfahren zum betrieb eines dampferzeugersInfo
- Publication number
- EP2906876A2 EP2906876A2 EP13777007.9A EP13777007A EP2906876A2 EP 2906876 A2 EP2906876 A2 EP 2906876A2 EP 13777007 A EP13777007 A EP 13777007A EP 2906876 A2 EP2906876 A2 EP 2906876A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- lignite
- mill
- drying
- flue gas
- dry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 49
- 239000003077 lignite Substances 0.000 claims abstract description 162
- 238000001035 drying Methods 0.000 claims abstract description 70
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000003546 flue gas Substances 0.000 claims abstract description 58
- 238000000227 grinding Methods 0.000 claims abstract description 13
- 238000007664 blowing Methods 0.000 claims abstract description 3
- 238000003801 milling Methods 0.000 claims abstract description 3
- 238000002485 combustion reaction Methods 0.000 claims description 26
- 239000003245 coal Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 abstract 1
- 239000000446 fuel Substances 0.000 description 20
- 239000000203 mixture Substances 0.000 description 8
- 238000010304 firing Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 239000012159 carrier gas Substances 0.000 description 6
- 230000002349 favourable effect Effects 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001599 direct drying Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K1/00—Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
- F23K1/04—Heating fuel prior to delivery to combustion apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2201/00—Pretreatment of solid fuel
- F23K2201/20—Drying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2201/00—Pretreatment of solid fuel
- F23K2201/50—Blending
- F23K2201/501—Blending with other fuels or combustible waste
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2203/00—Feeding arrangements
- F23K2203/002—Feeding devices for steam boilers, e.g. in locomotives
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2203/00—Feeding arrangements
- F23K2203/20—Feeding/conveying devices
- F23K2203/202—Feeding/conveying devices using screws
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23K—FEEDING FUEL TO COMBUSTION APPARATUS
- F23K2900/00—Special features of, or arrangements for fuel supplies
- F23K2900/01041—Heating by using exhaust gas heat
Definitions
- the invention relates to a method for operating a steam generator with a lignite-fired boiler, with at least one mill for grinding the brown coal.
- the mill is connected via a flue gas recirculation to the end of the combustion chamber, where the drying flue gas stream required for drying the lignite coal is removed at a temperature between about 800 ° C and about 1200 ° C.
- a method of the type mentioned is known for example from DE 42 03 713 C2.
- the process involves the milling of brown coal wet lignite in at least one mill, which is supplied with a drying flue gas stream, which is branched off from the boiler behind the convection train and is introduced into the mill at a temperature of about 350 ° C.
- the brown coal is comminuted to the grain band required for combustion in the boiler and at the same time dried in the inert flue gas atmosphere.
- Part of the drying flue gas stream is used as a carrier gas for transporting the dried fuel to the burners of the boiler.
- Another variant of the drying of lignite which has a favorable effect in terms of an increase in efficiency, is the drying of lignite in a separate drying unit in the form of a fluidized bed dryer.
- a separate drying unit in the form of a fluidized bed dryer.
- Such a method is known for example from DE 196 20 047 A1. It is known that by drying the brown coal before the increase in price in the Steam generator of a power plant, a significant increase in efficiency can be achieved.
- the lignite brown coal has a water content of 45% to 65%, which is reduced by drying to 10% to 25%. From DE 195 18 644 C2 it is known to use the emerging from the drying plant high-energy vapors in the dryer itself.
- the dry lignite from the fluidized bed drying usually has a maximum water content of 25 percent by mass and a medium
- the combustion temperature of pre-dried lignite hereinafter referred to as dry lignite (TBK) is about 500 ° C higher than that of lignite.
- Co-incineration for example, has a proportion of 25% dry lignite from a separate drying unit based on the calorific value of the
- the dry lignite can be introduced into the steam generator, for example, via so-called swirl burners, which are also used in hard coal firing.
- Ash softening or ash melting processes and thus can lead to slagging. This in turn reduces the availability of the steam generator.
- the invention is therefore based on the object, a method for
- the object is achieved by a method for operating a steam generator with a lignite-fired boiler, with at least one first mill for grinding the lignite, the method comprising the following method steps: - grinding of pit-wet raw lignite in the first mill,
- Dry lignite in the context of the invention is to be understood as meaning lignite which has dried from the mined mining product to a dried finished product having a moisture content of 10 to 30% by mass, preferably between 10 and 25% by mass and a mean grain diameter D50 of 0.4 to 10 mm in a drying unit was produced.
- Mine-wet crude lignite refers to the untreated crushed and optionally pre-shred mined lignite that has a moisture content of between 45 and 65% by mass.
- Under ground-dried raw lignite is to be understood in a mill with simultaneous drying to a ready-to-burn finished product lignite, of which about 85 to 95 percent by mass has a particle size of less than 1 mm.
- Under a burner allocation in the context of the invention is a
- Burner allocation ends where the fuel is ignited by supplying combustion air. Burner allocation may include classifiers and distributors.
- the process of the invention can be summarized in that in the boiler of the steam generator in addition to meal-dried raw lignite dry brown coal is mitverbrannt, the dry lignite coal
- Suspension gas / fuel mixture from the mill is given prior to allocation or in the allocation to the individual coal burners.
- the dry lignite is not burned through separate swirl burner in the boiler, but the dry lignite is added to the flue gas lignite stream of the mill before the boiler.
- Carrying gas in the context of the invention is to be understood as meaning a mixture of flue gas, evaporated water and combustion air.
- Raw lignite operated first mill to be diverted as soon as a starting and support firing is no longer needed.
- Drying flue gas stream inertized atmosphere means that the oxygen content in the flue gas drying stream is adjusted to an oxygen content of ⁇ 12% by volume.
- Drying unit is fed into the first mill and there with the
- Crude lignite is subjected to a subsequent grinding.
- Crude lignite is subjected to a subsequent grinding.
- Drying unit is not essential.
- the influence of a The fluctuating moisture content of the dry brown coal is thereby eliminated.
- Another advantage is that the controllability of the furnace is improved. If the amount of raw lignite is increased, the first mill reacts only with a longer dead time, because the mill for the higher amount of coal has to be moved to another operating point, or an additional mill must be put into operation. By contrast, stands by an increase in the
- Fuel quantity available This improves the controllability of the entire steam generator system.
- At least one indirectly heated dryer is provided as a separate drying unit. This can be for example
- a drying unit can find application in which the lignite is subjected to direct drying in direct contact with flue gas.
- the dried lignite from the second mill is fed as dry lignite in the flue gas brown waste stream of the first mill. It can be provided, for example, that the dried lignite from the second mill is completely fed as a dry lignite in the flue gas lignite stream of the first mill, so that the second mill is not charged in the usual way unmitelbar the boiler with a flue gas lignite stream.
- the inventive method is characterized in particular by the fact that the boiler is fired with a tangential firing with jet burners to which the flue gas brown coal stream is allocated. Jet burners are in operation much less susceptible to interference than omnidirectional burners or swirl burners. Jet burners are also structurally much simpler. These are based on the principle that the BrennstoffVTraggaskanal is substantially formed as a rectangular shaft, each of corresponding
- Drying unit is fed into a Traggasrezirkulationstechnisch the first mill. This makes it possible to carry out the inventive method substantially without constructive adjustment of existing mills.
- Carrying gas recirculation lines are commonly used to control the performance of the mill by, if appropriate, diverting a portion of the carrier gas behind the mill and recirculating it through the mill.
- Dry lignite are fed into a solids return of a mill classifier. Even such a procedure requires hardly constructive
- Screw conveyor is entered into an inlet region of the first mill.
- an injection of dry brown coal into the first mill with inert gas for example low-pressure steam, or, for example, dry lignite mixed with recirculated carrier gas as the pumped medium. It is expedient to blow dry brown coal in such a way that rapid mixing of the dry brown coal with the raw lignite takes place.
- the entry point for the dry brown coal may also be provided after the first mill in the burner allocation.
- Flue gas lignite stream feed directly behind the first mill may also be desirable to set a different fuel concentration at firing above the height of the steam generator.
- impact wheel mills can be used in which takes place in a known manner an impact stress of the ground material.
- wet fan mills or
- Blower Mills find application. When using a
- the dry brown coal can be added for example in the proposal part of the mill.
- the indirect drying of the brown coal is carried out in at least one fluidized bed dryer.
- roller bowl mill special explosion protection measures are to be observed, so that an approximately forgiven remilling a special
- the energy of the resulting in the indirect drying vapor is at least partially used for preheating the combustion air and / or the boiler feed water.
- the amount of dry brown coal fed in is regulated as a function of the load of the steam generator.
- Dry lignite be increased. As this dry lignite is under
- the brown coal has a mineralogical composition which comprises slag-forming mineral constituents which lead to the formation of deposits in the boiler, especially at relatively high temperatures.
- Dry lignite are due to the mill drying in mixture with the
- the process flow diagram shown in the figure shows a boiler 1 with a combustion chamber 2 and a convection part 3.
- the convection part 3 comprises in a known manner heating surfaces, by means of which a convective
- Within the combustion chamber 2 is dried over dust burner, which are designed as a jet burner
- Water vapor can be vented in a steam turbine to generate electrical energy, alternatively, the steam can also be used as process heat in other coupled processes.
- 4 denotes a suction, via which the flue gas is conveyed from the boiler 1 via a flue gas cleaning device to a chimney.
- the fuel in the form of dry brown coal and raw lignite coal is ground in a beater mill 5 and distributed over a burner allocation 6 on several jet burners.
- the beater wheel mill 5 on the one hand pit-wet raw lignite 7 and on the other hand dry lignite 8 supplied from a drying unit, not shown.
- Dry lignite 8 is added to either a Traggasrezirkulationstechnisch 15 or the beater wheel mill 5 directly.
- Burner allocation 6 supplied behind the flue gas lignite stream 10 combustion air 1 1 is added.
- the combustion air 1 1 is the
- the combustion air preheater 12 is operated with the flue gas stream 13 from the convection part 3 of the boiler 1. Part of the combustion air 1 1 is added to the drying flue gas stream 9 in front of the beater wheel mill 5, a further part is added to the boiler 1 as burnout air 14.
- the raw lignite 7, which comes from a pre-crushing is the
- Dry lignite 8 from a fluidized bed dryer, not shown, is having a water content of
- beater wheel mill 5 for example, between 10 and 30 percent by mass also beater wheel mill 5 abandoned. This is for example in a solids return of a
- Impact wheel mill 5 is the raw lignite 7 together with the Dry lignite 8 reground and after-dried and intimately
- the flue gas lignite stream 10 (carrier gas stream) leaving the impact wheel mill 5 comprises, for example, about 15% to 35%, preferably about 20% to 25% dry lignite 8 based on the calorific value of the total fuel used at full load of the boiler.
- the combustion air 1 1 is preheated by means of the flue gas stream 13 in the combustion air preheater 12.
- the invention is to be understood that instead of a combustion air preheating 12 with flue gas combustion air preheating is used, which is operated with low-temperature heat from the drying of the dry lignite.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Drying Of Solid Materials (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Air Supply (AREA)
- Combustion Of Fluid Fuel (AREA)
Abstract
Description
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL13777007T PL2906876T5 (pl) | 2012-10-11 | 2013-10-10 | Sposób eksploatacji wytwornicy pary |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102012019928.7A DE102012019928A1 (de) | 2012-10-11 | 2012-10-11 | Verfahren zum Betrieb eines Dampferzeugers |
| PCT/EP2013/071139 WO2014057025A2 (de) | 2012-10-11 | 2013-10-10 | Verfahren zum betrieb eines dampferzeugers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP2906876A2 true EP2906876A2 (de) | 2015-08-19 |
| EP2906876B1 EP2906876B1 (de) | 2016-12-28 |
| EP2906876B2 EP2906876B2 (de) | 2020-01-01 |
Family
ID=49378255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP13777007.9A Not-in-force EP2906876B2 (de) | 2012-10-11 | 2013-10-10 | Verfahren zum betrieb eines dampferzeugers |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP2906876B2 (de) |
| CN (1) | CN104781606B (de) |
| AU (2) | AU2013328717A1 (de) |
| CA (1) | CA2887109C (de) |
| DE (1) | DE102012019928A1 (de) |
| PL (1) | PL2906876T5 (de) |
| WO (1) | WO2014057025A2 (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102012019928A1 (de) | 2012-10-11 | 2014-04-30 | Rwe Power Aktiengesellschaft | Verfahren zum Betrieb eines Dampferzeugers |
| DE102015117191A1 (de) * | 2015-10-08 | 2017-04-13 | Mitsubishi Hitachi Power Systems Europe Gmbh | Kohlekraftwerk mit Mühlenluftwärmetauscher |
| CN118935948B (zh) * | 2024-10-14 | 2024-12-17 | 苏能(锡林郭勒)发电有限公司 | 一种褐煤连续干燥装置 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT229803B (de) * | 1960-11-30 | 1963-10-25 | Siemens Ag | Einrichtung zur Vortrocknung von geringwertigen Brennstoffen |
| DE3835428A1 (de) | 1988-10-18 | 1990-04-19 | Saarberg Interplan Gmbh | Verfahren zur erzeugung elektrischer energie und/oder heiz- und prozesswaerme |
| DE3835427A1 (de) | 1988-10-18 | 1990-04-19 | Saarberg Interplan Gmbh | Verfahren zur erzeugung elektrischer energie und/oder heiz- und prozesswaerme |
| DD279937B5 (de) * | 1989-02-06 | 1993-08-19 | Ver Energiewerke Ag | Vorrichtung zur trocknung, mahlung und verbrennung ballastreicher brennstoffe |
| DE4203713C2 (de) * | 1992-02-08 | 1996-01-18 | Rwe Energie Ag | Verfahren zum Betrieb eines mit einem trocknungsbedürftigen Brennstoff befeuerten Kraftwerkes |
| EP0581089A2 (de) † | 1992-07-29 | 1994-02-02 | Dipl.-Ing. SF-Ing. MANFRED BAHNEMANN RECYCLING-SYSTEME GmbH | Verfahren zum Behandeln von Metall-Kunststoff-Verbundstoffen |
| ATE154685T1 (de) | 1993-04-16 | 1997-07-15 | Ver Energiewerke Ag | Verfahren und anlage zur verbrennung von biostoffen und kohlenstaub |
| DE4314010A1 (de) * | 1993-04-23 | 1994-10-27 | Ver Energiewerke Ag | Verfahren und Vorrichtung zur Kohletrocknung in Kraftwerken, insbesondere zur Trocknung wasserhaltiger Braunkohle |
| DE4329773C1 (de) † | 1993-08-14 | 1994-12-22 | Edmund Sorg | Verfahren zur Wiederaufbereitung metallbeschichteter flächiger Substrate |
| DE4418342C2 (de) * | 1994-05-26 | 1997-11-13 | Rwe Energie Ag | Verfahren zum Betrieb eines mit einem trocknungsbedürftigen Brennstoff befeuerten Kraftwerkes |
| DE19518644C2 (de) | 1995-05-20 | 1998-04-16 | Rheinische Braunkohlenw Ag | Verfahren und Einrichtung zum Erzeugen von Dampf durch Verbrennen eines festen getrockneten Brennstoffes |
| JP3626274B2 (ja) † | 1996-04-09 | 2005-03-02 | アイン・エンジニアリング株式会社 | 複合フィルムの再生処理方法及び装置 |
| DE19620047C2 (de) | 1996-05-18 | 2002-06-27 | Rwe Rheinbraun Ag | Verfahren und Vorrichtung zum Trocknen von Braunkohle |
| DE19623209C1 (de) | 1996-06-11 | 1998-02-26 | Rheinische Braunkohlenw Ag | Verfahren zum Betrieb eines mit Braunkohle befeuerten Kraftwerkes sowie ein derartiges Kraftwerk |
| DE19643573A1 (de) | 1996-10-11 | 1998-04-16 | Ver Energiewerke Ag | Verfahren zur Mitverbrennung von Klärschlamm |
| JPH10337536A (ja) † | 1997-06-04 | 1998-12-22 | Takayuki Miyazaki | アルミニウム箔と合紙との選別方法 |
| DE19946517C2 (de) * | 1999-09-28 | 2001-09-06 | Bbp Energy Gmbh | Verfahren zur Zerkleinerung und Trocknung von feuchtem Brennstoff |
| JP2003094031A (ja) † | 2001-09-27 | 2003-04-02 | Fuji Photo Film Co Ltd | スリット屑の回収装置 |
| DE10319477B4 (de) | 2003-04-29 | 2006-11-23 | Rwe Power Ag | Verfahren zum Betreiben eines Dampfturbinenkraftwerks sowie Einrichtung zum Erzeugen von Dampf |
| DE10336802B4 (de) † | 2003-08-11 | 2017-02-16 | Alexander Koslow | Verfahren und Anlage zum Trennen und Sortieren insbesondere von vorzerkleinerten Stoffen |
| DE102008004400C5 (de) * | 2008-01-14 | 2017-01-26 | Babcock Borsig Steinmüller Gmbh | Verfahren zur Dosierung von Kohlenstaub in eine Feuerungseinrichtung |
| US7992310B2 (en) | 2008-08-13 | 2011-08-09 | Trimble Navigation Limited | Reference beam generator and method |
| AU2008364235B2 (en) * | 2008-11-24 | 2013-05-16 | Rwe Power Aktiengesellschaft | Method for generating process steam |
| DE102009035062A1 (de) * | 2009-07-28 | 2011-02-10 | Rwe Power Ag | Verfahren zum Betrieb eines Dampfturbinenkraftwerks sowie Einrichtung zur Erzeugung von Dampf |
| DE102010003612A1 (de) * | 2010-04-01 | 2011-10-06 | Brandenburgische Technische Universität Cottbus | Verfahren und Vorrichtung zum Trocknen von Kohle |
| DE102012108539B4 (de) | 2012-09-12 | 2014-04-03 | Hitachi Power Europe Gmbh | Kohlenstaubmühle mit Biomassevermahlungsbereich |
| DE102012019928A1 (de) | 2012-10-11 | 2014-04-30 | Rwe Power Aktiengesellschaft | Verfahren zum Betrieb eines Dampferzeugers |
-
2012
- 2012-10-11 DE DE102012019928.7A patent/DE102012019928A1/de not_active Withdrawn
-
2013
- 2013-10-10 CA CA2887109A patent/CA2887109C/en not_active Expired - Fee Related
- 2013-10-10 PL PL13777007T patent/PL2906876T5/pl unknown
- 2013-10-10 WO PCT/EP2013/071139 patent/WO2014057025A2/de not_active Ceased
- 2013-10-10 CN CN201380058873.1A patent/CN104781606B/zh not_active Expired - Fee Related
- 2013-10-10 AU AU2013328717A patent/AU2013328717A1/en not_active Abandoned
- 2013-10-10 EP EP13777007.9A patent/EP2906876B2/de not_active Not-in-force
-
2018
- 2018-03-27 AU AU2018202163A patent/AU2018202163B2/en not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2014057025A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2014057025A3 (de) | 2015-01-22 |
| CA2887109C (en) | 2020-09-01 |
| EP2906876B1 (de) | 2016-12-28 |
| WO2014057025A2 (de) | 2014-04-17 |
| EP2906876B2 (de) | 2020-01-01 |
| AU2018202163B2 (en) | 2019-09-19 |
| PL2906876T5 (pl) | 2020-07-13 |
| DE102012019928A1 (de) | 2014-04-30 |
| CN104781606B (zh) | 2017-08-29 |
| CA2887109A1 (en) | 2014-04-17 |
| CN104781606A (zh) | 2015-07-15 |
| AU2013328717A1 (en) | 2015-05-07 |
| PL2906876T3 (pl) | 2017-06-30 |
| AU2018202163A1 (en) | 2018-04-26 |
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