EP2776600A1 - Procédé et dispositif de revêtement au trempé d'un feuillard métallique avec un revêtement métallique - Google Patents

Procédé et dispositif de revêtement au trempé d'un feuillard métallique avec un revêtement métallique

Info

Publication number
EP2776600A1
EP2776600A1 EP12780134.8A EP12780134A EP2776600A1 EP 2776600 A1 EP2776600 A1 EP 2776600A1 EP 12780134 A EP12780134 A EP 12780134A EP 2776600 A1 EP2776600 A1 EP 2776600A1
Authority
EP
European Patent Office
Prior art keywords
metal strip
melt bath
nozzle
slag
gas flow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP12780134.8A
Other languages
German (de)
English (en)
Other versions
EP2776600B1 (fr
EP2776600B8 (fr
Inventor
Christopher Gusek
Jörg SCHULTE
Marc Blumenau
Fred Jindra
Dirk Czupryna
Rudolf Schönenberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp Steel Europe AG
Original Assignee
ThyssenKrupp Steel Europe AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ThyssenKrupp Steel Europe AG filed Critical ThyssenKrupp Steel Europe AG
Publication of EP2776600A1 publication Critical patent/EP2776600A1/fr
Publication of EP2776600B1 publication Critical patent/EP2776600B1/fr
Application granted granted Critical
Publication of EP2776600B8 publication Critical patent/EP2776600B8/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/50Controlling or regulating the coating processes
    • C23C2/54Controlling or regulating the coating processes of the mixing or stirring the bath
    • C23C2/544Controlling or regulating the coating processes of the mixing or stirring the bath using moving mixing devices separate from the substrate, e.g. an impeller of blade
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/34Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
    • C23C2/36Elongated material
    • C23C2/40Plates; Strips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/02Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
    • B05C11/06Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface with a blast of gas or vapour
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/003Apparatus
    • C23C2/0034Details related to elements immersed in bath
    • C23C2/00342Moving elements, e.g. pumps or mixers
    • C23C2/00344Means for moving substrates, e.g. immersed rollers or immersed bearings
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/16Removing excess of molten coatings; Controlling or regulating the coating thickness using fluids under pressure, e.g. air knives
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/16Removing excess of molten coatings; Controlling or regulating the coating thickness using fluids under pressure, e.g. air knives
    • C23C2/18Removing excess of molten coatings from elongated material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/16Removing excess of molten coatings; Controlling or regulating the coating thickness using fluids under pressure, e.g. air knives
    • C23C2/18Removing excess of molten coatings from elongated material
    • C23C2/20Strips; Plates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/14Removing excess of molten coatings; Controlling or regulating the coating thickness
    • C23C2/22Removing excess of molten coatings; Controlling or regulating the coating thickness by rubbing, e.g. using knives, e.g. rubbing solids
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/325Processes or devices for cleaning the bath
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/02Apparatus for spreading or distributing liquids or other fluent materials already applied to a surface ; Controlling means therefor; Control of the thickness of a coating by spreading or distributing liquids or other fluent materials already applied to the coated surface
    • B05C11/021Apparatus for spreading or distributing liquids or other fluent materials already applied to the surface of an elongated body, e.g. a wire, a tube
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/142Auto-deposited coatings, i.e. autophoretic coatings

Definitions

  • the invention relates to a method for
  • the metal strips coated in this manner are hot or cold rolled steel strips.
  • the invention relates to a device for
  • Hot dip coating a metal strip with a metallic coating said device comprising
  • Melting bath a conveyor for continuously passing the metal strip through the melt bath, a stripping device for adjusting the thickness of the present at its exit from the melt bath on the metal strip metallic coating and at least one nozzle for discharging a gas stream comprising on the
  • the annealed metal strip is passed through a melt bath, which consists of a melt of the metal forming the respective coating or of the respective coating
  • Melting bath is deflected over a roller system at least once and thereby stabilized in its barrel until it emerges from the melt bath. Excess, still molten coating material is stripped off after leaving the coating of wiping nozzles. The stripping is usually done by blowing off by means of a gas stream. But they are also pure
  • Coating quality by the resulting defects are permanently impaired.
  • so-called “smear” or the tape is damaged by indentations when the entrained slag adheres to subsequent roles and cakes. This sometimes creates significant costs due to rework and devaluation of the coated
  • the quality of the coating can be impaired by excessively swirling up the coating bath and by touching the metal strip with the stripping tool.
  • Abschlackeroboter simulate the manual stripping and can not be placed on any hot dip coating plant due to the structural conditions.
  • mirror rollers are used in practice, which are parallel to the width axis of the
  • a third way of preventing the slag from the metal strip emerging from the melt bath is by continuously circulating the coating bath and by establishing cooling zones, by means of which slag formation can be deliberately laid in surface areas of the melt bath which are remote from the strip run. The effectiveness of these measures can thereby be increased by directing the flows within the coating bath so that they act counter to the strip run. As a result, dissolved metal strip components of
  • Hot dip coating equipment can be retrofitted.
  • the object of the invention was to provide a method and an apparatus for hot dip coating of metal strips, which enable the contact of .alpha.
  • the metal strip passed in a continuous pass through a melt bath, then the thickness of the present at its exit from the melt bath on the metal strip metallic coating by means of a
  • a gas flow extending over the width of the metal strip onto the surface of the slag is now carried out by means of at least one nozzle arranged closely adjacent to the metal strip for expelling the slag
  • an apparatus according to the invention for hot dip coating a metal strip with a metallic coating comprises a melt bath, a conveyor for continuously passing the metal strip through the melt bath, a
  • Scraper for adjusting the thickness of the metallic coating present on its exit from the melt bath on the metal strip and at least one nozzle for discharging a gas stream, the slag present on the melt bath from that from the melt bath
  • Coating bath existing surface slag can be kept away from the leaking metal strip.
  • the gas flow can be easily controlled and regulated. In particular, pressure and Einblaswinkel the gas flow to the coating bath, the desired
  • Coating thickness and the belt speed adjusted and always be chosen so that the gas flow acts directly on the coating.
  • the risk of surface defects due to contact of the coating with slag present on the molten bath is effectively minimized by simple means and in a particularly reliable manner.
  • Another advantage of the invention is that existing hot dip coating systems with can be retrofitted with a device according to the invention little effort and can be operated in accordance with the invention.
  • the invention can be independent of the composition of each processed
  • the gas flows are so
  • the gas flow is preferably oriented so that it is largely perpendicular to the respective nozzle
  • the invention for discharging the gas stream
  • provided nozzle is preferably arranged as close as possible to the metal strip, wherein the distance between the nozzle and the band in practice will be chosen in each case so that it is also among those occurring in practice
  • Fluctuations in the tape position to no contact between the nozzle and the tape comes.
  • the distance between nozzle and metal strip in the range of 50 - 500 mm can be adjusted.
  • the nozzle provided for discharging a gas stream according to the invention in the immediate vicinity of the associated surface of the metal strip. Instead, a certain minimum distance must be maintained. In such a case, at least a partial flow of the gas stream discharged from the nozzle is preferably directed against the metal strip. Preference is given to the gas stream so
  • Gas jet could be caused. In addition, it avoids that the gas flow the proper band position of the metal strip on its conveying path through the
  • the respective gas stream may be air, a gas inert with respect to the melt bath, or a gas mixture formed from air and a gas inert to the melt bath. It has been found that pressurization of the gas flow supplied to the nozzles in the range of 1 to 15 bar leads to good results under the conditions prevailing in practice.
  • pressurization of the gas flow supplied to the nozzles in the range of 1 to 15 bar leads to good results under the conditions prevailing in practice.
  • Gas flow can be adjusted by the operator via adjustment
  • the set pressure must be large enough to remove the upper slag from the surface of the
  • the gas pressure should not exceed 15 bar, because if it is too high
  • Coating bath is added by the impulse of the impinging gas in unwanted vibrations.
  • the "blown" upper slag can be skimmed off in a conventional manner at a sufficient distance from the exiting metal strip mechanically from the coating.
  • Metal strips are typically cold or hot rolled steel strips.
  • Hot dip coating applicable metallic melts can be used. These include, for example, zinc or zinc alloy melts and aluminum or
  • Aluminum alloy melts.
  • slot nozzles of known type are suitable. Also can be used as a nozzle acting as a slot nozzle slotted or perforated tube and a nozzle unit, which with two or more
  • nozzle arrangements can also be wider than the metal strip to be coated.
  • nozzle widths of more than 120% of the metal bandwidth would not make economic sense due to the increasing proportion of ineffective gas.
  • the invention is based on
  • Fig. 1 is a device for hot dip coating a
  • Fig. 2 is an enlarged detail A of Fig. 1;
  • Fig. 3 is a corresponding to FIG. 2 representation of
  • Fig. 4 is a representation corresponding to FIG. 2
  • Fig. 5 shows the device according to FIGS. 1 and 2 in one
  • a device 1 for hot dip coating a metal strip M which here for example to cold-rolled, consisting of a corrosion-sensitive steel existing steel strip comprises a filled in a boiler 2 melt bath 3, in which the to be coated, previously in a known manner to a sufficient
  • Proboscis 4 is passed.
  • the metal strip M is deflected at a deflection roller 5 so that it emerges from the melt bath 3 in a vertically oriented conveying direction F.
  • the metal strip M emerging from the melt bath 3 passes through a stripping device 7 arranged at a certain distance above the surface 6 of the melt bath 3. This comprises two here as
  • a nozzle 10, 11 is arranged on each side of the metal strip M at a distance d of 200 mm, each one extending over the width B of the metal strip M extending gas flow G1, G2.
  • the nozzles 10, 11 may be designed as conventional slot nozzles. In practice, however, have been tested as nozzles 10,11 air bars, which consisted of a tube with 20 mm inner diameter, in which at intervals of 25 mm twelve cylindrical Düsenöff ments with a
  • Diameter of each 2 mm were drilled.
  • the gas was supplied centrally.
  • Example was the air bar used approx.
  • the outlet openings of the nozzles 10, 11 are aligned such that a larger partial flow G 11, G 21 of the respective gas flow G 1, G 2 with their central axis Gal in each case relate to the perpendicular to the surface of the melt bath 3 Einblaswinkel ß of about 30 ° directed to the surface of the melt bath 3 and there of the
  • associated surface 01,02 of the metal strip M flows in a direction substantially normal to the respective surface 01,02 pioneering flow direction.
  • a smaller partial flow G12, G22 of the respective gas flow G1, G2 in contrast, against the associated surface 01,02 of the
  • Metal band M associated limit of the impact area X in which the respective gas flow G1, G2 meets the surface 6 of the melt bath 3, with a close distance from the Metal band M ends.
  • the provided with the metallic coating surfaces 01,02 of the metal strip M are not affected in this way by the associated gas flow G1, G2.
  • the nozzles 10, 11 are set in such a way that they do not produce any partial flows G12, G22 directed in the direction of the metal strip M.
  • the nozzles 10, 11 are set in such a way that they do not dispense any partial flows G11, G21 directed away from the metal strip M.
  • the gas streams G1, G2 drive the slag S present on the melt bath 3 away from the metal strip M in a direction oriented transversely to the metal strip M, so that they are in each case in a sufficiently spaced region B1 that is uncritical for the metal strip M, B2 collect and from there mechanically, that is manually or by means of a suitable, motorized
  • Coating bath contained 9.5 wt .-% Si, 2.5 wt .-% Fe and the remainder AI and traces of other elements and unavoidable impurities.
  • the speed of the metal strip emerging from the melt bath was 38 m / min with a coating layer to be applied of min. 75 g / m 2 per side of the metal strip M.
  • Table 1 shows for a slit nozzle arranged in accordance with the invention underneath the wiping nozzles that this good result was not given, if none
  • G11-G22 partial flows of the respective gas jet G1, G2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Abstract

L'invention concerne un dispositif et un procédé de revêtement au trempé d'un feuillard métallique (M) avec un revêtement métallique. Ledit feuillard métallique (M) est acheminé en continu dans un bain de fusion (3), l'épaisseur du revêtement métallique présent sur le feuillard métallique (M) à sa sortie du bain de fusion (3) est ajustée au moyen d'un dispositif racleur (7), et les scories (S) présentes sur le bain de fusion (3) sont retirées du feuillard métallique (M) sortant du bain de fusion (3) au moyen d'un flux de gaz (G1, G2). L'objectif de l'invention est de proposer un procédé de ce type qui permette, à l'aide de moyens simples et économiques, d'éviter un contact entre les scories et le feuillard métallique sortant du bain de fusion et de garantir ainsi une qualité de surface optimale. À cet effet, pour retirer les scories (S) du feuillard métallique (M), au moins une buse (10, 11) agencée à proximité étroite du feuillard métallique (M) est utilisée pour diriger sur la surface (6) du bain de fusion (3) un flux de gaz (G1, G2) s'étendant sur la largeur (B) du feuillard métallique (M).
EP12780134.8A 2011-11-11 2012-10-11 Procédé et dispositif de revêtement au trempé d'un feuillard métallique avec un revêtement métallique Not-in-force EP2776600B8 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011118197A DE102011118197B3 (de) 2011-11-11 2011-11-11 Verfahren und Vorrichtung zum Schmelztauchbeschichten eines Metallbands mit einem metallischen Überzug
PCT/EP2012/070180 WO2013068196A1 (fr) 2011-11-11 2012-10-11 Procédé et dispositif de revêtement au trempé d'un feuillard métallique avec un revêtement métallique

Publications (3)

Publication Number Publication Date
EP2776600A1 true EP2776600A1 (fr) 2014-09-17
EP2776600B1 EP2776600B1 (fr) 2018-08-29
EP2776600B8 EP2776600B8 (fr) 2018-10-17

Family

ID=47115811

Family Applications (1)

Application Number Title Priority Date Filing Date
EP12780134.8A Not-in-force EP2776600B8 (fr) 2011-11-11 2012-10-11 Procédé et dispositif de revêtement au trempé d'un feuillard métallique avec un revêtement métallique

Country Status (8)

Country Link
US (1) US10011897B2 (fr)
EP (1) EP2776600B8 (fr)
JP (1) JP6231485B2 (fr)
KR (1) KR101979399B1 (fr)
CN (1) CN103998641B (fr)
DE (1) DE102011118197B3 (fr)
ES (1) ES2697673T3 (fr)
WO (1) WO2013068196A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9863029B2 (en) * 2012-08-01 2018-01-09 Dongkuk Steel Mill Co., Ltd. Apparatus for forming nitrogen cloud to produce hot dip coated steel sheet
DE102015211489B3 (de) 2015-06-22 2016-06-30 Thyssenkrupp Ag Rolle zur Umlenkung oder Führung eines zu beschichtenden Metallbandes in einem metallischen Schmelzenbad
KR101673546B1 (ko) * 2015-10-02 2016-11-07 주식회사 포스코 도금포트의 상부 드로스 제거장치
CN105349930B (zh) * 2015-11-26 2018-03-27 中冶赛迪工程技术股份有限公司 一种镀层控制方法及其应用
US11384419B2 (en) * 2019-08-30 2022-07-12 Micromaierials Llc Apparatus and methods for depositing molten metal onto a foil substrate
CN110565037A (zh) * 2019-10-19 2019-12-13 广西凯威铁塔有限公司 一种具有表面均匀纹路热浸锌工件的生产方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3667425A (en) * 1971-03-01 1972-06-06 Inland Steel Co Apparatus for controlling coating thickness
JPS5738362Y2 (fr) 1978-10-04 1982-08-24
JPH02156054A (ja) * 1988-12-08 1990-06-15 Sumitomo Metal Ind Ltd 溶融メッキ鋼板へのドロス押込み防止方法
FR2654749B1 (fr) 1989-11-21 1994-03-25 Sollac Procede et dispositif d'epuration d'un bain de metal liquide au temps chaud d'une bande d'acier.
DE4300868C1 (de) 1993-01-15 1994-03-17 Duma Masch Anlagenbau Beschichtungsvorrichtung
DE4223343C1 (de) 1992-07-16 1994-03-17 Duma Masch Anlagenbau Abblasvorrichtung
JPH06256923A (ja) * 1993-03-08 1994-09-13 Kobe Steel Ltd 溶融金属めっきラインにおけるガスワイピング方法お よびその装置
JP2895725B2 (ja) 1993-11-25 1999-05-24 川崎製鉄株式会社 溶融めっきドロス除去方法
JPH0860327A (ja) 1994-08-16 1996-03-05 Nippon Steel Corp 合金化亜鉛めっき鋼板の製造方法
US5683650A (en) * 1995-06-12 1997-11-04 Morando; Jorge A. Bubble apparatus for removing and diluting dross in a steel treating bath
JPH09228016A (ja) * 1996-02-23 1997-09-02 Kawasaki Steel Corp 溶融金属めっき方法及びその装置
JPH10158796A (ja) 1996-11-26 1998-06-16 Nippon Steel Corp スナウト内浴面異物のストリップへの付着防止装置
JP3437731B2 (ja) 1996-11-27 2003-08-18 新日本製鐵株式会社 溶融めっきにおけるスナウト内生成異物の鋼板付着防止装置
US6177140B1 (en) * 1998-01-29 2001-01-23 Ispat Inland, Inc. Method for galvanizing and galvannealing employing a bath of zinc and aluminum
JPH11279730A (ja) 1998-03-27 1999-10-12 Nisshin Steel Co Ltd Znの酸化を抑制した溶融めっき方法
KR100360748B1 (ko) 1998-04-01 2002-11-23 닛폰 고칸 가부시키가이샤 용융아연계 도금방법 및 그 장치
JP3718489B2 (ja) * 2002-07-25 2005-11-24 新日本製鐵株式会社 溶融金属めっきにおけるスナウト内ドロスの除去装置および除去方法
JP3890039B2 (ja) 2003-07-25 2007-03-07 新日本製鐵株式会社 溶融メッキ装置及び溶融メッキ方法
DE102006030914A1 (de) 2006-06-29 2008-01-03 Salzgitter Flachstahl Gmbh Verfahren und Vorrichtung zum kontinuierlichen Feuerverzinken von Stahlband
EP2240620B1 (fr) 2008-02-08 2014-11-26 Siemens VAI Metals Technologies SAS Procédé de galvanisation au trempé d'une bande d'acier
KR101520136B1 (ko) 2008-02-08 2015-05-13 지멘스 바이 메탈스 테크놀로지 에스에이에스 강철 스트립의 경화식 갈바나이징용 장치
PL2100673T3 (pl) * 2008-03-14 2011-06-30 Arcelormittal France Sposób i urządzenie do nadmuchiwania gazu na przemieszczającą się taśmę
JP2011127180A (ja) * 2009-12-18 2011-06-30 Jfe Steel Corp 溶融金属めっき鋼帯の製造設備及び製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2013068196A1 *

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KR101979399B1 (ko) 2019-05-16
WO2013068196A1 (fr) 2013-05-16
ES2697673T3 (es) 2019-01-25
US20150140225A1 (en) 2015-05-21
EP2776600B1 (fr) 2018-08-29
CN103998641A (zh) 2014-08-20
JP6231485B2 (ja) 2017-11-15
DE102011118197B3 (de) 2013-05-08
JP2014532814A (ja) 2014-12-08
CN103998641B (zh) 2017-05-24
EP2776600B8 (fr) 2018-10-17
KR20140101764A (ko) 2014-08-20
US10011897B2 (en) 2018-07-03

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