EP2677021A1 - Gleitmaterialzusammensetzung und gleitelement - Google Patents

Gleitmaterialzusammensetzung und gleitelement Download PDF

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Publication number
EP2677021A1
EP2677021A1 EP12747417.9A EP12747417A EP2677021A1 EP 2677021 A1 EP2677021 A1 EP 2677021A1 EP 12747417 A EP12747417 A EP 12747417A EP 2677021 A1 EP2677021 A1 EP 2677021A1
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EP
European Patent Office
Prior art keywords
resin
sliding
sliding member
vol
material composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP12747417.9A
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English (en)
French (fr)
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EP2677021A4 (de
Inventor
Masaru Yoshikawa
Takashi Tomikawa
Toru Kawai
Tasuku Sakurai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Honda Motor Co Ltd
Taiho Kogyo Co Ltd
Original Assignee
Honda Motor Co Ltd
Taiho Kogyo Co Ltd
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Publication date
Application filed by Honda Motor Co Ltd, Taiho Kogyo Co Ltd filed Critical Honda Motor Co Ltd
Publication of EP2677021A1 publication Critical patent/EP2677021A1/de
Publication of EP2677021A4 publication Critical patent/EP2677021A4/de
Withdrawn legal-status Critical Current

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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M157/00—Lubricating compositions characterised by the additive being a mixture of two or more macromolecular compounds covered by more than one of the main groups C10M143/00 - C10M155/00, each of these compounds being essential
    • C10M157/02—Lubricating compositions characterised by the additive being a mixture of two or more macromolecular compounds covered by more than one of the main groups C10M143/00 - C10M155/00, each of these compounds being essential at least one of them being a halogen-containing compound
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
    • C10M103/06—Metal compounds
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/56—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing nitrogen
    • C10M105/58—Amines, e.g. polyalkylene polyamines, quaternary amines
    • C10M105/60—Amines, e.g. polyalkylene polyamines, quaternary amines having amino groups bound to an acyclic or cycloaliphatic carbon atom
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/38—Lubricating compositions characterised by the base-material being a macromolecular compound containing halogen
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    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
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    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/02—Carbon; Graphite
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    • C10M125/10—Metal oxides, hydroxides, carbonates or bicarbonates
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    • C10M169/04—Mixtures of base-materials and additives
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    • C10M2201/041—Carbon; Graphite; Carbon black
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    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
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    • C10M2201/0663—Molybdenum sulfide used as base material
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    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
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    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
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    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C10M2201/103—Clays; Mica; Zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/105—Silica
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/1003—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06—Perfluoro polymers
    • C10M2213/062—Polytetrafluoroethylene [PTFE]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2213/06—Perfluoro polymers
    • C10M2213/062—Polytetrafluoroethylene [PTFE]
    • C10M2213/0623—Polytetrafluoroethylene [PTFE] used as base material
    • C—CHEMISTRY; METALLURGY
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    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C—CHEMISTRY; METALLURGY
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    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/041—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C10M2217/0443—Polyamides used as base material
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/08—Groups 4 or 14
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/02—Bearings
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y10T428/31544—Addition polymer is perhalogenated

Definitions

  • the present invention relates to a sliding material composition and a sliding member and, in particular, relates to a sliding material composition suitable for a sliding member whose counterpart sliding material is configured of rubber.
  • a sliding material composition containing a binder resin, a solid lubricant, and an N ⁇ -monoacyl basic amino acid (refer to patent document 1)
  • a sliding material composition containing a heat resisting resin, a fluorine resin, a solid lubricant, organopolysiloxane, and an organic solvent (refer to patent document 2).
  • the sliding material composition described in patent document 1 is low in friction and excellent in abrasion resistance in the case of sliding under no lubrication condition, i.e., in a dry state where there is no fluid lubrication such as oil and grease.
  • a coefficient of friction is large in the case of sliding under mixed lubrication, i.e., under a condition where each of fluid lubrication (lubrication in an atmosphere where there is oil or grease) and boundary lubrication (lubrication in an atmosphere where there is no oil or grease) may occur, particularly when the counterpart sliding member is a rubber-based material.
  • the present inventors have completed the invention by founding that a low friction effect can be obtained by lowering coefficient of static friction, since the rubber, which is an elastic body, is high in hysteresis in sliding against a rubber-based material and a coefficient of static friction at starting of sliding is high, and by obtaining knowledge on abrasion resistance. That is, the invention relates to a sliding material composition and a sliding member described hereinafter.
  • a sliding material composition and a sliding member capable of achieving a low abrasion property at starting time and during sliding and being excellent in abrasion resistance, especially when the counterpart sliding member is a rubber-based material, can be provided.
  • a sliding material composition according to the invention (hereinafter also referred to as “the composition of the invention”) comprises a binder resin, 5 to 25 vol% of an N ⁇ -monoacyl basic amino acid, 5 to 25 vol% of molybdenum disulfide, and 5 to 20 vol% of polytetrafluoroethylene (PTF).
  • the composition of the invention comprises a binder resin, 5 to 25 vol% of an N ⁇ -monoacyl basic amino acid, 5 to 25 vol% of molybdenum disulfide, and 5 to 20 vol% of polytetrafluoroethylene (PTF).
  • the binder resin is a material having a function of binding the composition of the invention, and the binder resin is preferably at least one kind of resin selected from the group consisting of a polyamideimide (PAI) resin, a polyimide resin, a phenol resin, a polyacetal resin, a polyether ether ketone resin, and a polyphenylene sulfide resin.
  • PAI polyamideimide
  • PAI polyamideimide
  • the composition of the invention contains three kinds of solid lubricants of the N ⁇ -monoacyl basic amino acid, molybdenum disulfide, and PTF, each in a prescribed amount.
  • a coefficient of friction shifts from a coefficient of static friction to a coefficient of dynamic friction when one portion starts to move, and so the sliding is liable to be influenced by a lubricant having a lower coefficient of friction among the lubricants blended.
  • the coefficient of friction does not shift to the coefficient of dynamic friction until the entire starts to move, and so the sliding is liable to be influenced by the lubricant having a higher coefficient of friction among the lubricants blended.
  • the composition of the invention contains three kinds of solid lubricants.
  • the first solid lubricant lowers the coefficient of static friction at starting time.
  • the second solid lubricant lowers the coefficient of dynamic friction and is capable of obtaining abrasion resistance.
  • the third solid lubricant lowers the coefficient of dynamic friction in the case of being out of a grease, i.e., in the case of no lubrication.
  • the invention adopted the N ⁇ -monoacyl basic amino acid, which is an amino acid-based solid lubricant, as the first solid lubricant, molybdenum disulfide (MoS 2 ) as the second solid lubricant, and PTFE as the third solid lubricant.
  • N ⁇ -monoacyl basic amino acid which is an amino acid-based solid lubricant
  • MoS 2 molybdenum disulfide
  • PTFE PTFE
  • N ⁇ -lauroyl-L-lysine As a specific example of the N ⁇ -monoacyl basic amino acid, N ⁇ -lauroyl-L-lysine is exemplified. N ⁇ -Lauroyl-L-lysine is characterized in that it is low in friction property. Accordingly, a low frictional coating composition can be obtained by binding N ⁇ -lauroyI-L-lysine with a binder resin. Since N ⁇ -lauroyl-L-lysine is lower than PTFE and the like in intensity, reduction of abrasion resistance can be suppressed when a solid lubricant such as PTFE coexists.
  • a composite layer of N ⁇ -Lauroyl-L-lysine and the solid lubricant is formed between a counterpart axis and the sliding face during sliding, and therefore, friction is reduced. With the reduction of friction, exothermic temperature of the sliding surface is suppressed, which leads to restraint of damages of the resin composition and composition transferred layer. As a result, excellent abrasion resistance can be obtained.
  • N ⁇ -monoacyl basic amino acid can be easily obtained by introduction of a hydrophobic acyl group into an ⁇ basic amino acid.
  • the examples of the basic amino acids for constituting the N ⁇ -monoacyl basic amino acid for use in the invention include lysine, ornithine and the like, and they may be an optically active substance or a racemic body.
  • the acyl group is preferably a saturated or unsaturated aliphatic acyl group having 8 to 22 carbon atoms.
  • N ⁇ -lauroyl-L-lysine is exemplified.
  • the content of the N ⁇ -monoacyl basic amino acid in the composition is 5 to 25 vol% and preferably 5 to 15 vol%.
  • the content of N ⁇ -monoacyl basic amino acid is in the above range, a good initial low friction effect can be obtained.
  • the content of molybdenum disulfide in the composition of the invention is 5 to 25 vol% and preferably 5 to 15 vol%. When the content of molybdenum disulfide is in the above range, a good abrasion resistance can be obtained.
  • the average particle size of molybdenum disulfide is preferably 0.5 ⁇ m to 20 ⁇ m, and more preferably 1 ⁇ m to 10 ⁇ m.
  • the content of polytetratluoroethylene (PTFE) in the composition of the invention is 5 to 20 vol% and preferably 5%to 15 vol%.
  • PTFE polytetratluoroethylene
  • the average particle size of PTFE is preferably 0.5 ⁇ m to 20 ⁇ m, and more preferably I ⁇ m to 10 ⁇ m.
  • a ratio of a content of PTFE to a content of molybdenum disulfide is preferably 0.5 to 2.0 on a volume basis.
  • the ratio is 2.0 or less, the coefficient of friction is difficult to increase even when the oil in the grease runs out, and is therefore preferable.
  • a ratio of X to Y satisfies a relationship of 2 ⁇ X/Y ⁇ 3 on a volume basis.
  • X/Y is 2 or more, the oil in the grease is sufficiently retained and the coefficient of friction can be lessened, and is therefore preferable.
  • X/Y is 3 or less, the low friction effect of the N ⁇ -monoacyl basic amino acid becomes sufficient and the coefficient of friction can be lessened, and is therefore preferable.
  • the composition of the invention may contain solid lubricants other than the above solid lubricants from the point of imparting a low friction property, and inorganic additives in view of providing abrasion resistance.
  • solid lubricants other than the above solid lubricants at least one kind of solid lubricant selected from a group consisting of graphite, tungsten disulfide, mica, a fluorine resin other than PTFE, boron nitride, graphite fluoride, and fullerene is preferable.
  • the content of the solid lubricant in the composition is preferably 10 vol% or less.
  • the inorganic additive at least one kind of inorganic additive selected from a group consisting of SiC, alumina, Si 3 N 4 , TiO 2 , SiO 2 , calcium carbonate, barium sulfate, and calcium phosphate is preferable. Also, from the viewpoint of abrasion resistance, the content of the inorganic additive in the composition is preferably 1 to 5 vol%.
  • the sliding material composition according to the invention can be used as a coating layer of a base material surface of the sliding member.
  • the sliding material composition of the invention is suitable for coating on the sliding surface in the case where the counterpart sliding member is rubber.
  • a sealing component for a hub bearing part for a vehicle may be specifically exemplified.
  • the material of the base material of the sliding member according to the invention is not especially restricted, but a material selected from a group consisting of iron and steel, stainless steel, cast iron, copper, copper alloy, aluminum, aluminum alloy, rubber, plastics and ceramics is preferable.
  • a shape of the base material is not especially restricted, and may be plate-like or tube-like.
  • the forming method of the coating layer for example, a method of mixing the composition of the invention with a solvent of a resin, forming a film with a known method such as air spray coating or the like, and baking the film at a baking temperature of the resin can be applied. Further, in order to strengthen the coating, surface roughening treatment may be carried out prior to coating of the base material surface, or an adhesive layer may be provided between the base material and the coating layer.
  • a thickness of the coating layer is preferably 5 ⁇ m to 30 ⁇ m.
  • the surface roughness of the coating layer is not especially restricted, but is preferably 0.3 ⁇ m Ra to 3 ⁇ m Ra.
  • the lubrication condition of the sliding member according to the invention is not especially restricted, and can be used in any of oil lubrication, grease lubrication and no lubrication.
  • the SUS base material was spray coated with a composition shown in the following Table I in a thickness of about 15 ⁇ m.
  • Amihope LL registered trademark of Ajinomoto Co., Inc. was used as the N ⁇ -lauroyl-L-lysine
  • HPC-5300 of Hitachi Chemical Co., Ltd. was used as the polyamideimide (PAI) resin.
  • An average particle size of graphite was 1 ⁇ m, and an average particle size of molybdenum disulfide was 1.0 ⁇ m.
  • the obtained film was baked at 200°C to prepare a test specimen.
  • test specimens in the Examples and the Comparative Examples were subjected to a reciprocating sliding test, and the coefficient of friction and abrasion loss of each test specimen were measured.
  • the test specimen in Example 5 was subjected to a friction torque test.
  • the results of the reciprocating sliding test are shown in Table 1 and the results of the friction torque test are shown in Fig. 3 .

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Sliding-Contact Bearings (AREA)
EP20120747417 2011-02-18 2012-02-16 Gleitmaterialzusammensetzung und gleitelement Withdrawn EP2677021A4 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011032811 2011-02-18
PCT/JP2012/053711 WO2012111774A1 (ja) 2011-02-18 2012-02-16 摺動材料組成物及び摺動部材

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EP2677021A1 true EP2677021A1 (de) 2013-12-25
EP2677021A4 EP2677021A4 (de) 2014-08-20

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EP (1) EP2677021A4 (de)
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KR (1) KR20140044778A (de)
CN (1) CN103415604A (de)
WO (1) WO2012111774A1 (de)

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CN106221670A (zh) * 2016-08-27 2016-12-14 明光瑞尔非金属材料有限公司 一种烧结台车间隙密封材料生产工艺
EP3144144A4 (de) * 2014-05-16 2018-01-17 NOK Klueber Co., Ltd. Gleitelement mit beschichtungsfilm und verfahren zur herstellung des beschichtungsfilms
WO2018095986A1 (de) * 2016-11-22 2018-05-31 Ks Gleitlager Gmbh Oberflächenmaterial auf polyamid basis mit füllstoffen für gleitelement
WO2018095982A1 (de) * 2016-11-22 2018-05-31 Ks Gleitlager Gmbh Gleitmaterial auf polyamidbasis
WO2018189318A1 (de) * 2017-04-12 2018-10-18 Ks Gleitlager Gmbh Gleitmaterial auf ptfe-polymerbasis mit die tribologischen eigenschaften verbessernden füllstoffen
EP3543295B1 (de) * 2016-11-17 2022-02-16 Taiho Kogyo Co., Ltd. Harzzusammensetzung und gleitelement

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CN104530695A (zh) * 2014-11-17 2015-04-22 长沙汉韦达新材料科技有限公司 一种耐磨尼龙复合材料及其制备方法
CN105199812A (zh) * 2015-10-26 2015-12-30 胡波 一种纳米磨合剂
CN105291505A (zh) * 2015-11-02 2016-02-03 梅州市星泰环保科技有限公司 一种高强度耐磨金属制品
CN105387078B (zh) * 2015-12-11 2018-02-09 浙江大学 一种用于滚动轴承的复合材料及其应用
JP7390774B2 (ja) 2016-11-17 2023-12-04 大豊工業株式会社 摺動部材
KR102202060B1 (ko) 2018-08-17 2021-01-12 주식회사 엘지화학 저마찰 수지 복합체
JP7216538B2 (ja) * 2018-12-17 2023-02-01 大豊工業株式会社 摺動部材
JP7222690B2 (ja) 2018-12-17 2023-02-15 大豊工業株式会社 摺動部材
CN110791359B (zh) * 2019-11-05 2022-06-28 安徽中天石化股份有限公司 一种基于改性纳米碳酸钙的润滑油及其制备方法
CN111853516B (zh) * 2020-06-15 2021-07-13 中国科学院兰州化学物理研究所 一种在工程基材上获得二维复合超润滑表面的方法
CN114016295B (zh) * 2021-11-11 2022-08-02 中国科学院兰州化学物理研究所 一种具有梯度润滑结构的纤维织物复合材料及其制备方法和应用

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EP3144144A4 (de) * 2014-05-16 2018-01-17 NOK Klueber Co., Ltd. Gleitelement mit beschichtungsfilm und verfahren zur herstellung des beschichtungsfilms
US10760027B2 (en) 2014-05-16 2020-09-01 Nok Klueber Co., Ltd. Sliding member having coating film and method for forming coating film
CN106221670A (zh) * 2016-08-27 2016-12-14 明光瑞尔非金属材料有限公司 一种烧结台车间隙密封材料生产工艺
EP3543295B1 (de) * 2016-11-17 2022-02-16 Taiho Kogyo Co., Ltd. Harzzusammensetzung und gleitelement
WO2018095986A1 (de) * 2016-11-22 2018-05-31 Ks Gleitlager Gmbh Oberflächenmaterial auf polyamid basis mit füllstoffen für gleitelement
WO2018095982A1 (de) * 2016-11-22 2018-05-31 Ks Gleitlager Gmbh Gleitmaterial auf polyamidbasis
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WO2018189318A1 (de) * 2017-04-12 2018-10-18 Ks Gleitlager Gmbh Gleitmaterial auf ptfe-polymerbasis mit die tribologischen eigenschaften verbessernden füllstoffen

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CN103415604A (zh) 2013-11-27
WO2012111774A1 (ja) 2012-08-23
EP2677021A4 (de) 2014-08-20
US20130337271A1 (en) 2013-12-19
JPWO2012111774A1 (ja) 2014-07-07

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