EP2450460B1 - Weißgoldlegierung ohne Nickel und Kupfer - Google Patents
Weißgoldlegierung ohne Nickel und Kupfer Download PDFInfo
- Publication number
- EP2450460B1 EP2450460B1 EP11009183.2A EP11009183A EP2450460B1 EP 2450460 B1 EP2450460 B1 EP 2450460B1 EP 11009183 A EP11009183 A EP 11009183A EP 2450460 B1 EP2450460 B1 EP 2450460B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gold alloy
- alloy
- optionally
- gray gold
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C5/00—Alloys based on noble metals
- C22C5/02—Alloys based on gold
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/14—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of noble metals or alloys based thereon
Definitions
- the present invention relates to a nickel-free and copper-free gray gold alloy having a hardness particularly suitable for watchmakers, jewelers and jewelers.
- the invention also relates to a process for preparing this alloy.
- gray gold alloys There are two main types of gray gold alloys on the market, nickel alloys and palladium alloys, in which both are used as whiteners.
- Nickel with its allergenic potential tends to be abandoned.
- its alloys exhibit reduced hardness and deformability that lend themselves poorly to the fields of jewelery and watchmaking.
- the increase in the copper concentration is to the detriment of other elements having whitening effects.
- the Japanese patent application published under the number JP-A-8-003662 discloses white gold alloys of the Au-Pd-In, Au-Pd-Sn or Au-Pd-Bi types. These alloys are intended for the preparation of metal clays, that is to say of clays of precious metals.
- Metal clays are indeed generally defined as being a raw material for the manufacture of jewelery or works of art and comprising a very fine powder of precious metals, an organic binder and water. After forming, they are dried and burned to remove the organic binder, so that only the sintered metals remain.
- This Japanese patent application therefore relates to a white gold alloy powder of Au-Pd-In, Au-Pd-Sn or Au-Pd-Bi type to have excellent sinterability. Concretely, by mixing this powder with water, a binder (plasticizer: di-n-butyl phthalate) and a surfactant (ethyl-cellulose), one should obtain a metal clay with a high degree of sintering.
- the patent DE 3132143 A discloses gold alloys containing Pd, Pt and Nb 2
- a gold alloy In order not to require rhodium-plating, a gold alloy must guarantee, according to ASTM Method D1925, a YI value: D1925 ⁇ 19 (YI: "yellowness index”), regarded as "good white” or "premium” and included in the Grade 1 category (see also http://www.utilisegold.com/jewellery technology / colors / whit e guide and Proceedings of Santa Fe Symposium 2005, pp. 103-120 ).
- the colors of the gold alloys are defined in the tri-chromatic space according to the ISO 8654.
- a YI ⁇ 19 value corresponds in first approximation to [-2 ⁇ a ⁇ 2; b ⁇ 10].
- the object of the present invention is to provide a nickel-free and copper-free gray gold alloy having satisfactory mechanical properties as well as a high whiteness (Grade 1) while not requiring rhodium-plating.
- Elements such as Si and Ti are known to those skilled in the art to improve, when added in small amounts, the surface condition and brightness and reduce the risk of corrosion, without substantially modifying the hardness or affect the colour.
- Elements such as Ir, Re or Ru are known to improve the metallurgical properties, in particular to guarantee the fineness of the grain and to avoid the porosities, without appreciably modifying the hardness or affecting the color.
- Table I groups together 18-carat white gold alloys of the state of the art that are commercially available.
- this table gives indications relating to the Vickers HV hardness index of the alloy in the cast state (HV cast), hardened to 75% (HV 75%) and annealed ( HV annealing), as well as to the color measured in the CIELab system.
- alloy No. 6 has a hardly satisfactory HV value, although it contains copper.
- Alloy No. 9 which is composed only of gold and palladium and is therefore free of copper, has a very low annealed HV value.
- Table II below includes gray gold alloys according to the invention which are ternary. TABLE II (*) Ternary 18-carat gold (% by weight) The at B HV casting HV 75% HV annealing 10 At 75.1 Pd 21.0 In 3.9 78.79 1.49 5.68 80 175 115 11 At 75.1 Pd 22.0 V 2.9 81.04 1.33 5.36 115 195 127 12 At 75.1 Pd 20.0 V 4.9 82.15 1.10 5.03 125 230 157 13 At 75.1 Pd 21.0 Ta 3.9 80.15 1.35 5, 14 135 213 164 14 At 75.1 Pd 23.0 V 1.9 79.34 1.38 5.05 90 182 112 15 At 75.1 Pd 22.0 Sn 2.9 79.54 1.37 5.14 128 202 118 16 At 75.1 Pd 22.0 Zn 2.9 79.36 1.37 4.84 80 156 108 17 At 75.1 Pd 23.5 Zr 1.4 80.06 1.30 4.73 87 179 119 18 At
- Each of the ternary alloys according to the invention thus has satisfactory values L, a, b and HV annealing.
- Quaternary alloys Nos. 33 and 34 and Quaternary No. 36 all have satisfactory L, a, b and HV annealing values.
- the grain index is established according to ASTM E 112. TABLE IV Grain refiner Concentration grain index (Ppm) (ASTM E 112) 39 Iridium 500 2 40 Iridium 1000 3 41 Ruthenium 500 4 42 Ruthenium 1000 7 43 Rhenium 20 5 44 Rhenium 50 6
- the alloys 39 and 40 show a grain structure in columns oriented in the direction of solidification.
- the other alloys exhibit an equiaxed microstructure.
- Ruthenium has the most pronounced grain refining effect, however, there are many inclusions that can penalize polishing.
- Rhenium shows a capacity of refinement of the grain without formation of inclusions. The addition of rhenium at 20 to 60 ppm therefore gives excellent polishing ability.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Adornments (AREA)
Claims (13)
- Weißgoldlegierung ohne Nickel und ohne Kupfer, gebildet aus (in Massenanteilen)- mehr als 75% Au,- mehr als 18% bis weniger als 24% Pd,- mehr als 1 % und weniger als 6% Nb,- gegebenenfalls von mehr als 1 % bis weniger als 6% wenigstens eines aus Mn, Hf, Pt, Ta, V, Zn und Zr ausgewählten Elementes,- gegebenenfalls höchstens 0,5% wenigstens eines aus Si, Ga und Ti ausgewählten Elementes und- gegebenenfalls höchstens 0,2% wenigstens eines aus Ru, Ir und Re ausgewählten Elementes.
- Weißgoldlegierung nach Anspruch 1 gebildet aus (in Massenanteilen)- mehr als 75% Au,- von 19% bis 23,5% Pd,- von 1,4% bis 5,9% Nb,- gegebenenfalls von 1,4% bis 5,9% wenigstens eines aus Mn, Hf, Pt, Ta, V, Zn und Zr ausgewählten Elementes,- gegebenenfalls höchstens 0,5% wenigstens eines aus Si, Ga und Ti ausgewählten Elementes und- gegebenenfalls höchstens 0,1% wenigstens eines aus Ru, Ir und Re ausgewählten Elementes.
- Weißgoldlegierung nach Anspruch 1 oder 2 mit wenigstens 20% Pd.
- Weißgoldlegierung nach einem der Ansprüche 1 bis 3 mit wenigstens 1,5% Zr oder Nb.
- Weißgoldlegierung nach einem der Ansprüche 1 bis 4 mit 0,002% bis 0,006% (20 bis 60 ppm) Re.
- Weißgoldlegierung nach einem der Ansprüche 1 bis 5 mit etwa 75,1 % Au.
- Verfahren zum Herstellen einer Weißgoldlegierung nach einem der Ansprüche 1 bis 6, bei dem- die Bestandteile der Weißgoldlegierung in einen Schmelztiegel eingebracht werden,- der Schmelztiegel bis zum Verflüssigen der Bestandteile erhitzt wird,- die geschmolzene Legierung abgekühlt wird,- sie sich verfestigen gelassen wird,- sie einer Wasserabschreckung unterworfen wird,- sie wenigstens einem Kaltwalzen unterworfen wird und- sie unter Reduzieren der Atmosphäre getempert wird.
- Verfahren nach Anspruch 7, bei dem das Erhitzen durch Induktion in einem dichten Ofen unter Edelgaspartialdruck erfolgt.
- Verfahren nach Anspruch 8, bei dem das Edelgas Ar ist.
- Verfahren nach einem der Ansprüche 7 bis 9, bei dem das Tempern unter einer aus einer Mischung von N2 und H2 gebildeten reduzierenden Atmosphäre durchgeführt wird.
- Verfahren nach Anspruch 10, bei dem die Mischung aus N2 und H2 durch etwa 80% N2 und 20% H2 gebildet ist.
- Verfahren nach einem der Ansprüche 7 bis 11, bei dem das Tempern über etwa 30 Minuten durchgeführt wird.
- Verfahren nach einem der Ansprüche 7 bis 12, bei dem das Tempern bei etwa 850°C durchgeführt wird.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11009183.2A EP2450460B1 (de) | 2009-05-06 | 2010-04-15 | Weißgoldlegierung ohne Nickel und Kupfer |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09405077A EP2251444A1 (de) | 2009-05-06 | 2009-05-06 | Graugoldlegierung ohne Nickel und Kupfer |
EP10716257.0A EP2427582B1 (de) | 2009-05-06 | 2010-04-15 | Graugoldlegierung ohne nickel und ohne kupfer |
EP11009183.2A EP2450460B1 (de) | 2009-05-06 | 2010-04-15 | Weißgoldlegierung ohne Nickel und Kupfer |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10716257.0A Division-Into EP2427582B1 (de) | 2009-05-06 | 2010-04-15 | Graugoldlegierung ohne nickel und ohne kupfer |
EP10716257.0 Division | 2010-04-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2450460A1 EP2450460A1 (de) | 2012-05-09 |
EP2450460B1 true EP2450460B1 (de) | 2013-09-25 |
Family
ID=41127638
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09405077A Withdrawn EP2251444A1 (de) | 2009-05-06 | 2009-05-06 | Graugoldlegierung ohne Nickel und Kupfer |
EP11009183.2A Active EP2450460B1 (de) | 2009-05-06 | 2010-04-15 | Weißgoldlegierung ohne Nickel und Kupfer |
EP10716257.0A Active EP2427582B1 (de) | 2009-05-06 | 2010-04-15 | Graugoldlegierung ohne nickel und ohne kupfer |
EP11009184.0A Active EP2450461B1 (de) | 2009-05-06 | 2010-04-15 | Weißgoldlegierung ohne Nickel und Kupfer |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP09405077A Withdrawn EP2251444A1 (de) | 2009-05-06 | 2009-05-06 | Graugoldlegierung ohne Nickel und Kupfer |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10716257.0A Active EP2427582B1 (de) | 2009-05-06 | 2010-04-15 | Graugoldlegierung ohne nickel und ohne kupfer |
EP11009184.0A Active EP2450461B1 (de) | 2009-05-06 | 2010-04-15 | Weißgoldlegierung ohne Nickel und Kupfer |
Country Status (6)
Country | Link |
---|---|
US (1) | US9650697B2 (de) |
EP (4) | EP2251444A1 (de) |
JP (1) | JP5793136B2 (de) |
CN (1) | CN102549179B (de) |
CH (1) | CH703415B1 (de) |
WO (1) | WO2010127458A1 (de) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014071583A1 (en) * | 2012-11-08 | 2014-05-15 | Heraeus Ltd. | Nickel containing gold alloys having low nickel releasing rate, master alloys for obtaining them and use of metal elements therein |
EP3428295A1 (de) | 2012-12-03 | 2019-01-16 | Argor-Heraeus S.A. | Verfärbungsbeständige goldlegierung |
US20150368756A1 (en) * | 2013-02-06 | 2015-12-24 | Rolex Sa | Timepiece made from rose gold alloy |
EP3020835B1 (de) | 2014-11-17 | 2021-04-21 | Omega SA | Uhr, Schmuckstück oder edler Schmuck, umfassend eine Komponente aus einer Legierung auf Palladiumbasis |
EP3070182B1 (de) | 2015-03-17 | 2017-08-30 | The Swatch Group Research and Development Ltd. | Weissgoldlegierung |
FR3034106B1 (fr) | 2015-03-23 | 2022-07-22 | Centre Nat Rech Scient | Alliage monophasique d'or et de tungstene |
EP3315620B1 (de) * | 2016-10-25 | 2020-06-24 | Nivarox-FAR S.A. | Nichtmagnetische hochwertige legierung für anwendungen in uhren |
EP3339455B1 (de) * | 2016-12-20 | 2020-02-05 | Montres Breguet S.A. | Weissgoldlegierung |
MY192624A (en) * | 2017-03-27 | 2022-08-29 | Subodh Pethe | Hard gold alloy with zirconium, titanium and magnesium for jewelry manufacture |
CH715203B1 (fr) | 2018-07-26 | 2022-03-15 | Px Services Sa | Alliage à base d'or présentant un changement de couleur et son utilisation dans le domaine de la joaillerie et de l'horlogerie. |
CN109136625A (zh) * | 2018-09-14 | 2019-01-04 | 深圳市品越珠宝有限公司 | 一种高硬度合金及其制备方法 |
CN110629062A (zh) * | 2019-05-16 | 2019-12-31 | 杭州辰卓科技有限公司 | 一种具有斯斑效应20k耐腐蚀耐脆断金合金及其工艺 |
JP6789528B1 (ja) * | 2019-09-26 | 2020-11-25 | 田中貴金属工業株式会社 | 医療用Au−Pt−Pd合金 |
EP3808865B1 (de) | 2019-10-17 | 2023-01-18 | Richemont International S.A. | Weissgoldlegierung und ihr herstellungsverfahren |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3374123A (en) * | 1964-03-04 | 1968-03-19 | Foundation | Method of manufacturing non-magnetic, elastic articles having a small change of vibration and deflection for temperature change |
US3716356A (en) * | 1970-09-23 | 1973-02-13 | Ney Co J M | Rhenium containing gold alloys |
DE2136373B2 (de) * | 1971-07-21 | 1972-11-30 | W.C. Heraeus Gmbh, 6450 Hanau | Verwendung einer goldlegierung als werkstoff fuer elektrische widerstaende |
DE3132143C2 (de) * | 1981-08-14 | 1985-07-04 | Degussa Ag, 6000 Frankfurt | Edelmetallegierung zur Herstellung von mit keramischen Massen verblendbaren Kronen und Brücken |
DE3211703C2 (de) * | 1982-03-30 | 1984-01-12 | C. Hafner GmbH + Co., 7530 Pforzheim | Verwendung goldarmer Edelmetallegierungen für Dentalzwecke |
DE3711207A1 (de) * | 1987-04-02 | 1988-10-20 | Kerstin Koerber | Gebrauchsfertige kaeppchen zur zahnstumpfrestauration |
JP2611319B2 (ja) * | 1988-03-28 | 1997-05-21 | 三菱マテリアル株式会社 | 人工ダイヤモンドコート装飾品用金合金 |
JP2922228B2 (ja) * | 1989-10-16 | 1999-07-19 | 株式会社徳力本店 | 装飾用白色金合金 |
JPH0474836A (ja) * | 1990-07-13 | 1992-03-10 | Pilot Corp:The | 金合金細線およびその製造方法 |
JP3130334B2 (ja) | 1991-07-18 | 2001-01-31 | シャープ株式会社 | 耐光性着色薄膜用樹脂組成物 |
CH684616B5 (fr) | 1992-08-17 | 1995-05-15 | Metaux Precieux Sa | Alliage d'or gris et utilisation de cet alliage. |
JPH083663A (ja) * | 1994-06-20 | 1996-01-09 | Mitsubishi Materials Corp | 焼結性に優れたAu−Pd−Ag系白色金合金粉末 |
JPH083662A (ja) * | 1994-06-20 | 1996-01-09 | Mitsubishi Materials Corp | 焼結性に優れたAu−Pd系白色金合金粉末 |
DE19525361A1 (de) * | 1995-02-16 | 1996-08-22 | Herbst Bremer Goldschlaegerei | Edelmetall-Legierung und Verwendung derselben |
US5919320A (en) * | 1997-11-17 | 1999-07-06 | Leach & Garner Company | Nickel-free white gold alloy with reversible hardness characteristics |
ES2195300T3 (es) | 1998-12-14 | 2003-12-01 | Metalor Technologies Int | Aleacion de oro gris sin niquel. |
JP2000336439A (ja) * | 1999-05-27 | 2000-12-05 | Mizuho Kogei:Kk | 白色系金合金 |
US6156266A (en) * | 2000-01-07 | 2000-12-05 | Argen Corporation | Gold alloy for firing on porcelain |
JP2001207226A (ja) * | 2000-01-25 | 2001-07-31 | Kyocera Corp | 18金合金 |
EP1227166B1 (de) | 2001-01-26 | 2010-04-28 | Metalor Technologies International SA | Graue Goldlegierung |
EP1447456A1 (de) * | 2003-02-11 | 2004-08-18 | Metalor Technologies International SA | Dotierte Goldlegierung |
JP3139334U (ja) | 2007-10-31 | 2008-02-14 | 有限会社味 路 | 餃子形パイ菓子 |
-
2009
- 2009-05-06 EP EP09405077A patent/EP2251444A1/de not_active Withdrawn
-
2010
- 2010-04-15 EP EP11009183.2A patent/EP2450460B1/de active Active
- 2010-04-15 CH CH01771/11A patent/CH703415B1/fr unknown
- 2010-04-15 EP EP10716257.0A patent/EP2427582B1/de active Active
- 2010-04-15 EP EP11009184.0A patent/EP2450461B1/de active Active
- 2010-04-15 WO PCT/CH2010/000101 patent/WO2010127458A1/fr active Application Filing
- 2010-04-15 US US13/265,655 patent/US9650697B2/en active Active
- 2010-04-15 CN CN201080019776.8A patent/CN102549179B/zh not_active Expired - Fee Related
- 2010-04-15 JP JP2012508867A patent/JP5793136B2/ja not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2012526192A (ja) | 2012-10-25 |
EP2427582A1 (de) | 2012-03-14 |
EP2450461A1 (de) | 2012-05-09 |
WO2010127458A1 (fr) | 2010-11-11 |
EP2450460A1 (de) | 2012-05-09 |
WO2010127458A8 (fr) | 2011-04-14 |
CN102549179A (zh) | 2012-07-04 |
US20120114522A1 (en) | 2012-05-10 |
EP2450461B1 (de) | 2014-10-29 |
JP5793136B2 (ja) | 2015-10-14 |
CH703415B1 (fr) | 2014-03-14 |
US9650697B2 (en) | 2017-05-16 |
EP2251444A1 (de) | 2010-11-17 |
EP2427582B1 (de) | 2014-03-12 |
CN102549179B (zh) | 2016-03-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2450460B1 (de) | Weißgoldlegierung ohne Nickel und Kupfer | |
EP1010768B1 (de) | Graue Goldlegierung, ohne Nickel | |
JP2019108614A (ja) | 耐変色性金合金 | |
EP3165622B1 (de) | Herstellungsverfahren eines drahtes aus einer goldlegierung | |
US20140003992A1 (en) | Tarnish-resistant sterling silver alloys | |
JP2016505710A5 (de) | ||
US6841012B2 (en) | Anti-tarnish silver alloy | |
JP3173452B2 (ja) | 耐摩耗性被覆部材及びその製造方法 | |
EP2546371B1 (de) | Weißgold, 18 Karat | |
EP3070182A1 (de) | Weissgoldlegierung | |
EP1227166B1 (de) | Graue Goldlegierung | |
EP3020835B1 (de) | Uhr, Schmuckstück oder edler Schmuck, umfassend eine Komponente aus einer Legierung auf Palladiumbasis | |
EP3339455B1 (de) | Weissgoldlegierung | |
EP0008975A1 (de) | Gelbe Goldlegierung, insbesondere für zahnärztliche Zwecke, die gegebenenfalls mit einem keramischen Material überzogen ist, und Verfahren zum Härten einer solchen Legierung | |
FR2764906A1 (fr) | Alliages d'or gris 18 et 14 carats pour bijouterie, sans nickel et sans palladium | |
FR2923492A1 (fr) | Alliages d'or massif, de couleur blanche, eclatante dans toute la masse | |
KR101741681B1 (ko) | 내변색성 및 경도가 우수한 Ag-Cu계 합금 조성물 및 이의 제조방법 | |
CH709923B1 (fr) | Alliage d'or. | |
JP2005307328A (ja) | 装飾用銀合金及び装飾品 | |
JP5727854B2 (ja) | 鋳造用金合金及びその製造方法 | |
CH703143B1 (fr) | Alliage à base de palladium. | |
CN114672691A (zh) | 一种抑菌仿金铜合金及其制备方法和应用 | |
WO2004013363A2 (fr) | Alliage cuivreux, sans nickel, du type cuivre, manganese, silicium | |
JPS6379943A (ja) | Cu合金の製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AC | Divisional application: reference to earlier application |
Ref document number: 2427582 Country of ref document: EP Kind code of ref document: P |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: AL BA ME RS |
|
17P | Request for examination filed |
Effective date: 20121012 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
INTG | Intention to grant announced |
Effective date: 20130417 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AC | Divisional application: reference to earlier application |
Ref document number: 2427582 Country of ref document: EP Kind code of ref document: P |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 633734 Country of ref document: AT Kind code of ref document: T Effective date: 20131015 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: NV Representative=s name: MOINAS AND SAVOYE SA, CH |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602010010604 Country of ref document: DE Effective date: 20131121 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20131225 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 633734 Country of ref document: AT Kind code of ref document: T Effective date: 20130925 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: VDEP Effective date: 20130925 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20131226 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140125 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602010010604 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140127 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 |
|
26N | No opposition filed |
Effective date: 20140626 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602010010604 Country of ref document: DE Effective date: 20140626 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: LU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140415 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140415 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 7 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20100415 Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20140430 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PFA Owner name: ROLEX S.A., CH Free format text: FORMER OWNER: ROLEX S.A., CH |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 8 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 9 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20130925 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20210408 Year of fee payment: 12 Ref country code: FR Payment date: 20210429 Year of fee payment: 12 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20210415 Year of fee payment: 12 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 602010010604 Country of ref document: DE |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20220415 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220415 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20220430 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20221103 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230528 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20230502 Year of fee payment: 14 |