EP2447348A1 - Composition de graisse - Google Patents

Composition de graisse Download PDF

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Publication number
EP2447348A1
EP2447348A1 EP10792044A EP10792044A EP2447348A1 EP 2447348 A1 EP2447348 A1 EP 2447348A1 EP 10792044 A EP10792044 A EP 10792044A EP 10792044 A EP10792044 A EP 10792044A EP 2447348 A1 EP2447348 A1 EP 2447348A1
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EP
European Patent Office
Prior art keywords
mass
grease composition
grease
base oil
thickener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP10792044A
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German (de)
English (en)
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EP2447348A4 (fr
EP2447348B1 (fr
Inventor
Yukitoshi Fujinami
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Idemitsu Kosan Co Ltd
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Idemitsu Kosan Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/02—Mixtures of base-materials and thickeners
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/30—Parts of ball or roller bearings
    • F16C33/66—Special parts or details in view of lubrication
    • F16C33/6603—Special parts or details in view of lubrication with grease as lubricant
    • F16C33/6633—Grease properties or compositions, e.g. rheological properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/003—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022—Ethene
    • C10M2205/0225—Ethene used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/10—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing cycloaliphatic monomers
    • C10M2205/103—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing cycloaliphatic monomers used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/10—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing cycloaliphatic monomers
    • C10M2205/106—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing cycloaliphatic monomers use as thickening agent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • C10M2207/1276—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic used as thickening agent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/128—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof
    • C10M2207/1285—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids containing hydroxy groups; Ethers thereof used as thickening agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/044—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms having cycloaliphatic groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/02—Bearings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/10—Semi-solids; greasy
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2300/00—Application independent of particular apparatuses
    • F16C2300/10—Application independent of particular apparatuses related to size
    • F16C2300/14—Large applications, e.g. bearings having an inner diameter exceeding 500 mm
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2360/00—Engines or pumps
    • F16C2360/31—Wind motors

Definitions

  • the present invention relates to a grease composition.
  • the present invention relates to a grease composition usable for a main bearing that receives a main shaft incorporated in a wind power generator and a pitch bearing that receives a blade shaft.
  • a grease composition is used to lubricate a bearing that receives a large load, such as a main bearing that receives a main shaft incorporated in a wind power generator and a pitch bearing that receives a blade shaft.
  • a main bearing and a pitch bearing are always subjected to fluctuations or slight vibrations due to a change in wind speed or slight control of the blade.
  • a main bearing and a pitch bearing are in conditions that fretting wear thereof easily occurs. Since replacement of a malfunctioned bearing takes a lot of time and costs, what has been sought is a lubricant having an excellent fretting wear resistance and a long-lasting effect in the prevention of damage to a bearing.
  • a grease composition usable for a wind power generator the following compositions have been suggested: a composition containing a base oil, a thickener, and oleoyl sarcosine (see Patent Literature 2); and a composition containing a base oil having a kinematic viscosity of 70 to 250 mm 2 /s at 40 degrees C, a thickener, and a carboxylic antirust additive (see Patent Literature 3).
  • Main bearing and pitch bearing used in a wind power generator simultaneously require reduction in fretting wear due to rotation of main shaft and blade shaft and reduction in bearing wear due to the heavy weights of the main shaft and blade shaft received on the main bearing and pitch bearing, respectively. Even with the grease compositions disclosed in Patent Literatures 1 to 3 and Non-patent Literatures 1 and 2, such bearing wear and fretting wear are unlikely to be simultaneously suppressed. Additionally, using a high viscosity base oil leads to an increase in fretting wear.
  • An object of the invention is to provide a grease composition capable of simultaneously suppressing bearing wear caused under a high-load condition and fretting wear to provide a longer lifetime.
  • the grease composition according to the above aspect of the invention is capable of simultaneously suppressing bearing wear caused under a high-load condition and fretting wear to provide a longer lifetime, and thus is suitably usable for, in particular, a main bearing and a pitch bearing in a wind power generator.
  • a grease composition according to the exemplary embodiment (hereinafter also abbreviated as "grease") includes a base oil and a thickener.
  • the base oil may be a hydrocarbon-based synthetic oil or a combination of hydrocarbon-based synthetic oil and mineral oil.
  • hydrocarbon-based synthetic oil examples thereof include alkylbenzenes such as monoalkylbenzene and dialkylbenzene, and alkylnaphthalenes such as monoalkylnaphthalene, dialkylnaphthalene and polyalkylnaphthalene
  • hydrocarbon-based synthetic oil examples thereof include diester oils such as dibutyl sebacate, di-2-ethylhexyl sebacate, dioctyl adipate, diisodecyl adipate, ditridecyl adipate, ditridecyl glutarate and methyllacetyl ricinoleate, aromatic ester oils such as trioctyl trimellitate, tridecyl trimellitate and tetraoctyl pyromellitate, polyol ester oils such as trimethylol propane caprylate, trimethylol propane peralgonate, pentaerythr
  • hydrocarbon-based synthetic oil is an ether oil
  • examples thereof include polyglycols such as polyethylene glycol, polypropylene glycol, polyethylene glycol monoether and polypropylene glycol monoether, phenyl ether oils such as monoalkyl triphenyl ether, alkyldiphenyl ether, dialkyldiphenyl ether, pentaphenyl ether, tetraphenyl ether, monoalkyl tetraphenyl ether and dialkyl tetraphenyl ether, olefin oligomers such as normal paraffin, isoparafin, polybutene, polyisobutylene, 1-decene oligomer, and co-oligomer of 1-decene and ethylene.
  • polyglycols such as polyethylene glycol, polypropylene glycol, polyethylene glycol monoether and polypropylene glycol monoether
  • phenyl ether oils such as monoalkyl triphenyl ether,
  • Usable mineral oils are ones that have been subjected to an appropriate combination of the following purification processes: vacuum distillation, oil deasphalting, solvent extraction, hydrocracking, solvent dewaxing, sulfate cleaning, clay purification, hydrorefining and the like.
  • the above hydrocarbon-based synthetic oils may be used singularly or in combination.
  • the kinematic viscosity of the base oil is in a range from 200 mm 2 /s to 2000 mm 2 /s at 40 degrees C. When the kinematic viscosity is less than 200 mm 2 /s, fretting wear is reduced but bearing wear is increased, so that load bearing capacity is unlikely to be ensured. On the other hand, when the kinematic viscosity is more than 2000 mm 2 /s, fretting wear is likely to be increased.
  • the kinematic viscosity at 40 degrees C is preferably in a range from 300 mm 2 /s to 1500 mm 2 /s, more preferably in a range from 400 mm 2 /s to 750 mm 2 /s.
  • the blend ratio of the hydrocarbon-based synthetic oil in the base oil is 40 mass% or more. When the blend ratio of the hydrocarbon-based synthetic oil in the base oil is less than 40 mass%, it can be difficult to provide both high viscosity and low-temperature torque performance.
  • the blend ratio of the hydrocarbon-based synthetic oil in the base oil is preferably 60 mass% or more, more preferably 70 mass% or more.
  • the base oil contains a component having a kinematic viscosity of 70 mm 2 /s or less at 40 degrees C (component A).
  • component A a component having a kinematic viscosity of 70 mm 2 /s or less at 40 degrees C.
  • the blend ratio of the component A is in a range from 20 mass% to 70 mass%.
  • the kinematic viscosity of the component A in the base oil is small, a large amount of the base oil is likely to be evaporated during the production process.
  • fretting wear is likely to be increased.
  • the kinematic viscosity of the component A in the base oil at 40 degrees C is preferably in a range from 10 mm 2 /s to 40 mm 2 /s, more preferably in a range from 20 mm 2 /s to 40 mm 2 /s.
  • the blend ratio of the component A in the base oil is less than 20 mass%, fretting wear and pumpability are likely to be worsened.
  • the blend ratio of the component A is more than 70 mass%, the base oil is unlikely to be controlled to have high viscosity.
  • the blend ratio of the component A in the base oil is preferably in a range from 30 mass% to 70 %mass, more preferably in a range from 40 mass% to 65 mass%.
  • Examples of the component A in the base oil include olefin oligomers such as an oligomer of alpha-olefin having 4 to 18, preferably 6 to 14, more preferably 8 to 12 carbon atoms (either singular or combined) and a co-oligomer of 1-decene and ethylene.
  • olefin oligomers such as an oligomer of alpha-olefin having 4 to 18, preferably 6 to 14, more preferably 8 to 12 carbon atoms (either singular or combined) and a co-oligomer of 1-decene and ethylene.
  • One of the above olefin oligomers may be used or, alternatively, a mixture thereof may be used.
  • the above olefin oligomers may be composited in a known method or in a method as disclosed in any one of Japanese Patent Application No. 5-282511 ( JP-A-07-133234 ) and Japanese Patent Application No. 1-269082 ( JP-A-03-131612
  • Either an organic or inorganic thickener is usable as the thickener blended with the base oil, a preferred example of which is a soap thickener.
  • the thickener is preferably any one of Li soap, Li complex soap, Ca sulfonate complex soap and Ca complex soap, more preferably a soap containing a 12-hydroxystearate as a fatty acid.
  • the thickener is preferably a soap containing Li, more preferably a Li complex soap.
  • a Li complex soap is excellent in performance balance from a low temperature to a high temperature.
  • As the thickener urea compound, bentonite, silica, carbon black and the like may also be usable. The above materials may be used singularly or in combination.
  • the blend ratio of the thickener is not limited as long as the thickener and the base oil in combination can form a grease and be kept as the grease, but is preferably a 17 mass% or less of the total amount of the composition.
  • the blend ratio of the thickener is more than 17 mass% or more of the total amount of the composition, fretting wear is likely to be worsened. Additionally, the pumpability is also likely to be lowered.
  • the blend ratio of the thickener relative to the total amount of the composition is more preferably 14 mass% or less, particularly preferably 12 mass% or less.
  • the blend ratio of the thickener is represented as the amount of a carboxylic acid constituting the thickener.
  • the blend ratio of the thickener is represented as the amount of a reactant of isocyanate and amine.
  • the thickener is preferably produced by mixing carboxylic acid and alkali together in the component A of the base oil for saponification.
  • carboxylic acid include wild fatty acids from which glycerin has been removed by hydrolyzing fat and oil, monocarboxylic acids such as a stearic acid, monohydroxy carboxylic acids such as a 12-hydroxy stearic acid, dibasic acids such as an azelaic acid, and aromatic carboxylic acids such as terephthalic acid, salicylic acid and benzoic acid. Carboxylates may also be usable.
  • alkali examples include metal hydroxides such as alkali metals and alkali earth metals.
  • metal examples include sodium, calcium, lithium and aluminum.
  • a sulfur-containing extreme pressure agent is preferably blended at 0.01 mass% to 10 mass% of the total amount of the composition.
  • the blend ratio is less than 0.01 mass% or more than 10 mass%, blend effect such as seizure prevention cannot be expected.
  • the extreme pressure agent include zinc dialkyldithiophosphate (ZnDTP), zinc dithiocarbamate (ZnDTC), dithiocarbamine (DTC), thiophosphate, sulfurized fat and oil, and thiadiazole.
  • ZnDTP zinc dialkyldithiophosphate
  • ZnDTC zinc dithiocarbamate
  • DTC dithiocarbamine
  • thiophosphate sulfurized fat and oil
  • thiadiazole thiadiazole
  • the base oil may be blended with resins or waxes soluble in other base oils such as petroleum resin and polyethylene, among which a petroleum resin is preferable.
  • the blend ratio of the resin is preferably in a range from 0.5 mass% to 30 mass% of the total amount of the composition. When the blend ratio of the resin relative to the total amount of the composition is less than 0.5 mass%, the viscosity is likely to be reduced. When the blend ratio of the resin is more than 30 mass%, the low-temperature torque performance is likely to be lowered.
  • the blend ratio of the resin relative to the total amount of the composition is more preferably in a range from 1 mass% to 25 %mass, particularly preferably in a range from 2 mass% to 20 mass%.
  • the petroleum resin is preferably, for instance, a cyclopentadiene-based petroleum resin.
  • the petroleum resin is preferably provided by thermally copolymerizing a cyclopentadiene material with an alpha-olefin material or a monovinyl aromatic hydrocarbon material, by hydrogenating these materials in a general method as needed, or by mixing these materials.
  • cyclopentadiene material Usable as the cyclopentadiene material are cyclopentadiene, the polymer thereof, the alkyl substitute thereof, and the mixture of these materials. From an industrial point of view, it is advantageous to use a cyclopentadiene fraction (CPD fraction) containing a cyclopentadiene material, which is obtained by steam cracking of naphtha or the like, at approximately 30 mass% or more, preferably at approximately 50 mass% or more.
  • the CPD fraction may contain an olefin monomer copolymerizable with these alicyclic dienes.
  • olefin monomer examples include aliphatic diolefins such as isoprene, piperylene and butadiene, and alicyclic olefins such as cyclopentene. Although the concentration of the above olefins is preferably minimized, a concentration of approximately 10 mass% or less per cyclopentadiene material is acceptable.
  • alpha-olefin material examples include alpha-olefins having 4 to 18, preferably 4 to 12, carbon atoms, and the mixtures thereof, among which a derivative of ethylene, propylene, 1-butene or the like, a paraffin wax resolvent, or the like is preferably used. It is industrially preferable to blend the alpha-olefin material at a ratio of less than approximately 4 mol per 1 mol of the cyclopentadiene material.
  • Examples of the monovinyl aromatic hydrocarbons include styrene, o-, m-, p-vinyltoluene, and alpha-, beta-methylstyrene.
  • the monovinyl aromatic hydrocarbons may contain indenes such as indene methylindene, and ethylindene, and it is industrially advantageous to use a so-called C9 fraction obtained by steam cracking of naphtha.
  • the monovinyl aromatic hydrocarbons are used as a material to be copolymerized, it is industrially preferable to blend the monovinyl aromatic hydrocarbons at a ratio less than approximately 3 mol per 1 mol of the cyclopentadienes.
  • the worked penetration of the grease according to the exemplary embodiment is in a range from 220 to 350, preferably from 250 to 340, more preferably from 265 to 320.
  • the worked penetration is less than 220, the grease becomes harder, so that the low-temperature torque performance is likely to be lowered.
  • the worked penetration is more than 350, the grease becomes sorter, so that shaft wear and fretting wear are likely to occur.
  • the grease according to the exemplary embodiment may be added with additives such as antioxidant, rust inhibitor, solid lubricant, filler, oiliness agent, metal deactivator, water resistant agent, extreme pressure agent, antiwear agent, viscosity index improver and coloring agent if necessary.
  • additives such as antioxidant, rust inhibitor, solid lubricant, filler, oiliness agent, metal deactivator, water resistant agent, extreme pressure agent, antiwear agent, viscosity index improver and coloring agent if necessary.
  • antioxidants examples include aminic antioxidant such as alkylated diphenylamine, phenyl-alpha-naphthylamine and alkylated-alpha-naphthylamine, phenolic antioxidant such as 2,6-di-t-butyl-4-methylphenol and 4,4'-methylenebis(2,6-di-t-butylphenol), and peroxide decomposing agent of sulfur, ZnDTP or the like.
  • the blend ratio thereof is usually in a range from 0.05 mass% to 10 mass%.
  • the rust inhibitor include sodium nitrite, sulfonate, sorbitan monooleate, fatty acid soap, amine compound, succinic acid derivative, thiadiazole, benzotriazole and benzotriazole derivative.
  • solid lubricant examples include polyimide, PTFE, graphite, metal oxide, boron nitride, melamine cyanurate (MCA) and molybdenum disulfide.
  • MCA melamine cyanurate
  • MCA molybdenum disulfide
  • the wind power generator 1 includes a blade 5, a main shaft 4 to which the blade 5 is fixed, an electricity generator 31 being driven by rotation of the main shaft 4, a nacelle 3 in which a main bearing 33 connected to the main shaft 4 and a yaw bearing 32 are housed, and a tower 2 that supports the nacelle 3.
  • a pitch bearing 41 is connected to a blade shaft 51. For instance, by rotating the blade shaft 51, the blade 5 is controlled to receive more wind or less wind to stabilize the rotation of the main shaft 4. This results in stable supply of electricity from the electricity generator 31.
  • the grease according to the exemplary embodiment is preferably used for the main bearing 33 and the pitch bearing 41.
  • the main bearing 33 and the pitch bearing 41 are likely to suffer from shaft wear due to high loads such as the heavy blade 5 and main shaft 4 and fretting wear due to fluctuations or vibrations resulting from the rotation thereof. With the grease according to the exemplary embodiment, it is possible to prevent such shaft wear and fretting wear.
  • the wind power generator 1 is a small-sized wind power generator with an output less than 300 Kw, the invention is not suitably usable because of a small load thereon.
  • the wind power generator 1 is preferably a middle-sized or large-sized wind power generator with an output of preferably 300 Kw or more, more preferably 700 Kw or more.
  • the main bearing 33 and the pitch bearing 41 may be connected to a pump for supplying grease thereto through a pipe (not shown). By driving the pump, it is possible to easily supply grease to the main bearing 33 and the pitch bearing 41. Working at height is thus not required, resulting in improvement of workability.
  • the grease having the above arrangement may be used for high load usage not only in a wind power generator but also in devices that perform rolling motion, such as rolling bearing, ball screw and linear guide.
  • the grease is usable in, for instance, an electrical cylinder, an electrical linear actuator, a jack and a linear operating device.
  • Grease compositions according to Examples and Comparatives were produced as follows. The composition ratio of each grease composition is shown in Tables 1 to 3. Table 4 shows the properties of each material shown in Tables 1 to 3.
  • the mixture was stirred while being heated. After being heated to 165 degrees C, the temperature of the resulting grease composition was maintained for one hour. (4) After being blended with the rest of the base oil, the mixture was cooled down to 80 degrees C at a pace of 50 degrees C per hour, and then antioxidant and extreme pressure agent (the respective amounts thereof are shown in Table 2) were blended therewith. After being naturally cooled down to room temperature, the mixture was subjected to a finishing process using a three-roller device to obtain the grease composition according to Example 11.
  • Example 1 Example 2
  • Example 3 Example 4
  • Example 5 Example 6 Composition Ratio (mass%) Base Oil Hydrocarbon-based Synthetic Oil
  • PAO-A 51.25 52.36 54.21 56.10 30.00 58.02
  • Other Base Oil Petroleum Resin 9.86 10.07 10.43 10.79 - - Thickener 12-Hydroxy Stearic Acid 9.00 7.50 5.00 2.50 6.00 6.00 Azelaic Acid 4.00 4.00 4.00 4.00 4.00 4.00 4.00 Lithium hydroxide (Monohydrate) 3.15 2.95 2.60 2.20 2.70 2.70 Thickener Blend Ratio (Carboxylic Acid Amount Equivalent) 13.00 11.50 9.00 6.50 10.00 10.00 10.00 Additive Antioxidant 1.00 1.00 1.00 1.00 1.00 1.00 Rust Inhibi
  • Example 12 Composition Ratio (mass%) Base Oil Hydrocarbon-based Synthetic Oil PAO-A 54.21 50.90 47.78 48.57 52.65 65.00 PAO-B - - - - - PAO-C Olefin - - - - - - Oligomer 18.77 21.30 16.54 - 18.23 18.40 Other Base Oil Petroleum Resin 10.43 - 9.19 34.83 10.13 - Thickener 12-Hydroxy Stearic Acid 5.00 13.50 13.00 5.00 urea 14% 5.00 Azelaic Acid 4.00 5.00 4.50 4.00 4.00 Lithium hydroxide (Monohydrate) 2.60 4.30 4.00 2.60 2.60 Thickener Blend Ratio (Carboxylic Acid Amount Equivalent) Amount Equivalent) 9.00 18.50 17.50 9.00 14.00 9.00 Additive Antioxidant 1.00 1.00 1.00 1.00 1.00 1.00 Rust Inhibitor 1.00 1.00 1.00 1.00 1.00 1
  • the blend ratio of the thickener has been defined as the amount of the carboxylic acid (12-hydroxy stearic acid + azelaic acid).
  • the invention is suitable as a grease composition usable for a main bearing and a pitch bearing incorporated in a wind power generator or the like.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)
  • Rolling Contact Bearings (AREA)
EP10792044.9A 2009-06-22 2010-06-21 Composition de graisse Active EP2447348B1 (fr)

Applications Claiming Priority (2)

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JP2009147619A JP5604061B2 (ja) 2009-06-22 2009-06-22 グリース組成物
PCT/JP2010/060438 WO2010150726A1 (fr) 2009-06-22 2010-06-21 Composition de graisse

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EP2447348A1 true EP2447348A1 (fr) 2012-05-02
EP2447348A4 EP2447348A4 (fr) 2012-12-26
EP2447348B1 EP2447348B1 (fr) 2018-03-07

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CN (1) CN102803450B (fr)
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ES (1) ES2669556T3 (fr)
WO (1) WO2010150726A1 (fr)

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CN103666657A (zh) * 2013-11-22 2014-03-26 广西大学 重负荷车毂轴承润滑脂
EP2771440A1 (fr) * 2011-10-27 2014-09-03 The Lubrizol Corporation Lubrifiants ayant une compatibilité améliorée avec les joints
WO2015000510A1 (fr) * 2013-07-03 2015-01-08 Aktiebolaget Skf Ensemble palier ayant une cartouche de lubrification
EP3733823A4 (fr) * 2017-12-27 2021-09-15 Idemitsu Kosan Co., Ltd. Composition de graisse et utilisation de celle-ci

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US20130012416A1 (en) * 2010-03-26 2013-01-10 Idemitsu Kosan Co., Ltd. Grease composition
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EP2756059A1 (fr) * 2011-09-15 2014-07-23 Klüber Lubrication München SE & Co. KG Graisse à haute température
CN109937249A (zh) * 2016-11-16 2019-06-25 出光兴产株式会社 用于具有自动供脂装置的机器的润滑脂组合物和其制造方法
CN106947572B (zh) * 2017-03-29 2020-02-07 小松日石润滑油(厦门)有限公司 一种用于全自动泵送润滑系统设备的润滑油及其制备方法
CN108148665B (zh) * 2017-12-30 2021-03-23 深圳市前海龙达新能源有限公司 一种稀油润滑油及其制备方法
CN108626132A (zh) * 2018-04-27 2018-10-09 贝德科技有限公司 一种使用润滑新材料的长轴消防泵
WO2020059346A1 (fr) * 2018-09-21 2020-03-26 ミネベアミツミ株式会社 Palier à roulement dans lequel une composition de graisse est utilisée
DE112020004865T5 (de) * 2019-10-10 2022-07-21 Ntn Corporation Achslager, schmierfettzusammensetzung und wälzkugellager
JP7460445B2 (ja) 2020-05-27 2024-04-02 コスモ石油ルブリカンツ株式会社 潤滑油組成物

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EP2771440A1 (fr) * 2011-10-27 2014-09-03 The Lubrizol Corporation Lubrifiants ayant une compatibilité améliorée avec les joints
WO2015000510A1 (fr) * 2013-07-03 2015-01-08 Aktiebolaget Skf Ensemble palier ayant une cartouche de lubrification
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Also Published As

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WO2010150726A1 (fr) 2010-12-29
JP2011001517A (ja) 2011-01-06
CN102803450B (zh) 2016-08-17
ES2669556T3 (es) 2018-05-28
EP2447348A4 (fr) 2012-12-26
DK2447348T3 (en) 2018-04-16
JP5604061B2 (ja) 2014-10-08
EP2447348B1 (fr) 2018-03-07
US20120098269A1 (en) 2012-04-26
CN102803450A (zh) 2012-11-28

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