EP2297386A2 - Ein hocheffizientes gasphasenverfahren zur modifizierung und funktionalisierung von kohlenstoff-nanofasern mit salpetersäuredampf - Google Patents
Ein hocheffizientes gasphasenverfahren zur modifizierung und funktionalisierung von kohlenstoff-nanofasern mit salpetersäuredampfInfo
- Publication number
- EP2297386A2 EP2297386A2 EP09772124A EP09772124A EP2297386A2 EP 2297386 A2 EP2297386 A2 EP 2297386A2 EP 09772124 A EP09772124 A EP 09772124A EP 09772124 A EP09772124 A EP 09772124A EP 2297386 A2 EP2297386 A2 EP 2297386A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- carbon
- carbon fibers
- nitric acid
- range
- reactor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 238000000034 method Methods 0.000 title claims abstract description 57
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 47
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910017604 nitric acid Inorganic materials 0.000 title claims abstract description 35
- 238000007306 functionalization reaction Methods 0.000 title claims abstract description 10
- 230000004048 modification Effects 0.000 title description 8
- 238000012986 modification Methods 0.000 title description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 77
- 239000002134 carbon nanofiber Substances 0.000 claims description 73
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 52
- 239000004917 carbon fiber Substances 0.000 claims description 52
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 27
- 229910052760 oxygen Inorganic materials 0.000 claims description 27
- 239000001301 oxygen Substances 0.000 claims description 27
- 230000008569 process Effects 0.000 claims description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000002843 carboxylic acid group Chemical group 0.000 claims description 6
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 6
- 150000001244 carboxylic acid anhydrides Chemical group 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 4
- 238000004458 analytical method Methods 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 239000011149 active material Substances 0.000 claims description 2
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- 239000002638 heterogeneous catalyst Substances 0.000 claims description 2
- 238000011282 treatment Methods 0.000 description 53
- 239000007789 gas Substances 0.000 description 30
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- 239000002041 carbon nanotube Substances 0.000 description 24
- 229910021393 carbon nanotube Inorganic materials 0.000 description 17
- 239000003054 catalyst Substances 0.000 description 16
- 125000000524 functional group Chemical group 0.000 description 15
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 13
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- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 238000001228 spectrum Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000003776 cleavage reaction Methods 0.000 description 4
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- 239000010439 graphite Substances 0.000 description 4
- 239000001307 helium Substances 0.000 description 4
- 229910052734 helium Inorganic materials 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 241000234282 Allium Species 0.000 description 3
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- 150000001299 aldehydes Chemical class 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
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- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- -1 benzene Chemical class 0.000 description 2
- 150000001721 carbon Chemical class 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000000608 laser ablation Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 230000004660 morphological change Effects 0.000 description 2
- 239000002121 nanofiber Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011002 quantification Methods 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000001878 scanning electron micrograph Methods 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- ZPSJGADGUYYRKE-UHFFFAOYSA-N 2H-pyran-2-one Chemical compound O=C1C=CC=CO1 ZPSJGADGUYYRKE-UHFFFAOYSA-N 0.000 description 1
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- 206010001488 Aggression Diseases 0.000 description 1
- 229910002703 Al K Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-NJFSPNSNSA-N Carbon-14 Chemical compound [14C] OKTJSMMVPCPJKN-NJFSPNSNSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 1
- OBOXTJCIIVUZEN-UHFFFAOYSA-N [C].[O] Chemical group [C].[O] OBOXTJCIIVUZEN-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910003481 amorphous carbon Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000012018 catalyst precursor Substances 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
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- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- NQBKFULMFQMZBE-UHFFFAOYSA-N n-bz-3-benzanthronylpyrazolanthron Chemical compound C12=CC=CC(C(=O)C=3C4=CC=CC=3)=C2C4=NN1C1=CC=C2C3=C1C1=CC=CC=C1C(=O)C3=CC=C2 NQBKFULMFQMZBE-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
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- 238000009832 plasma treatment Methods 0.000 description 1
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- 238000007740 vapor deposition Methods 0.000 description 1
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Classifications
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- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
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- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/58—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
- D06M11/64—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with nitrogen oxides; with oxyacids of nitrogen or their salts
- D06M11/65—Salts of oxyacids of nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
Definitions
- the present invention relates to a process for the functionalization of carbon fibers with the vapor of nitric acid, so modified carbon fibers and their use.
- An objective of these treatments may also be the purification, cutting and opening of the carbon nanofibers (Liu, J. et al., 280: 1253-6 (1998)).
- a simple but highly effective method of functionalizing carbon fibers by treatment with nitric acid vapor is provided, thereby avoiding the problematic separation by filtration.
- nitric acid vapor a significantly larger amount of oxygen species on the surface can be detected by X-ray photoelectron spectroscopy (XPS).
- XPS X-ray photoelectron spectroscopy
- Carbon nanofibers more preferred for the invention are obtained by methods basically described in the following references: The production of carbon nanotubes with diameters smaller than 100 nm is described for the first time in EP 205 556 Bl. For the preparation here light (ie, short- and medium-chain aliphatic or mononuclear or dinuclear aromatic) hydrocarbons and an iron-based catalyst are used, are decomposed at the carbon carrier compounds at a temperature above 800-900 0 C.
- the carbon fibers may be positioned in the vapor stream with a fixture 12.
- This holding device may be, for example, a sieve, grid or even rust.
- FIG. 5 shows the comparison of the TPD cleavage profiles of carbon nanofibers during treatment by means of HNO 3 gas phase, NO 2, NO 2: O 2 (1: 1) and HNO 3 liquid. All treatments were carried out for 3 hours each. The graphics are normalized to 1 g carbon fiber.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Textile Engineering (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Composite Materials (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Fibers (AREA)
- Carbon And Carbon Compounds (AREA)
- Catalysts (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102008031579A DE102008031579A1 (de) | 2008-07-03 | 2008-07-03 | Ein hocheffizientes Gasphasenverfahren zur Modifizierung und Funktionalisierung von Kohlenstoff-Nanofasern mit Salpetersäuredampf |
| PCT/EP2009/004664 WO2010000424A2 (de) | 2008-07-03 | 2009-06-27 | Ein hocheffizientes gasphasenverfahren zur modifizierung und funktionalisierung von kohlenstoff-nanofasern mit salpetersäuredampf |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2297386A2 true EP2297386A2 (de) | 2011-03-23 |
Family
ID=41078222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09772124A Withdrawn EP2297386A2 (de) | 2008-07-03 | 2009-06-27 | Ein hocheffizientes gasphasenverfahren zur modifizierung und funktionalisierung von kohlenstoff-nanofasern mit salpetersäuredampf |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20110104492A1 (ru) |
| EP (1) | EP2297386A2 (ru) |
| JP (1) | JP2011526331A (ru) |
| KR (1) | KR20110027723A (ru) |
| CN (1) | CN102099515A (ru) |
| AU (1) | AU2009266063A1 (ru) |
| BR (1) | BRPI0915597A2 (ru) |
| CA (1) | CA2729693A1 (ru) |
| DE (1) | DE102008031579A1 (ru) |
| RU (1) | RU2011103676A (ru) |
| WO (1) | WO2010000424A2 (ru) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8333900B1 (en) * | 2008-06-27 | 2012-12-18 | E I Du Pont De Nemours And Company | Selective etching of single walled carbon nanotubes |
| CN102153069B (zh) * | 2011-02-25 | 2012-12-19 | 中国科学院长春应用化学研究所 | 一种纳米碳材料的处理方法 |
| KR20120105827A (ko) * | 2011-03-16 | 2012-09-26 | 삼성전자주식회사 | 정착장치용 발열체, 이를 구비한 정착장치 및 화상형성장치 |
| CN102424379B (zh) * | 2011-09-20 | 2013-11-20 | 奇瑞汽车股份有限公司 | 一种高分散性碳纳米管的制备方法 |
| CN102424973A (zh) * | 2011-12-26 | 2012-04-25 | 昆山全亚冠环保科技有限公司 | 一种鎳銅合金金相腐蚀剂 |
| CN104018340B (zh) * | 2014-06-12 | 2015-12-09 | 航天精工股份有限公司 | 一种连续碳纤维表面改性方法 |
| CN117385630A (zh) * | 2014-12-09 | 2024-01-12 | 国立大学法人 东京大学 | 表面处理碳纤维、表面处理碳纤维束及它们的制造方法 |
| CN106215949A (zh) * | 2016-08-02 | 2016-12-14 | 上海应用技术学院 | 一种低温选择性催化还原脱硝催化剂及其制备方法 |
| JP6857806B2 (ja) * | 2016-12-05 | 2021-04-14 | パナソニックＩｐマネジメント株式会社 | 燃料電池用の金属粒子担持触媒およびその製造方法、およびその触媒を用いた燃料電池 |
| CN109847706A (zh) * | 2019-02-12 | 2019-06-07 | 广州大学 | 一种表面官能团功能化水热炭吸附剂及其制备方法与应用 |
| CN111139646A (zh) * | 2020-01-14 | 2020-05-12 | 贵州大学 | 一种改性碳纤维及其与尼龙6复合材料的制备 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4729820A (en) * | 1986-05-30 | 1988-03-08 | Amoco Corporation | Multielectrolyte shear treatment of carbon fibers |
| JPH02118121A (ja) * | 1988-10-25 | 1990-05-02 | Osaka Gas Co Ltd | ピッチ系活性炭素繊維およびその製造方法 |
| JPH06166953A (ja) * | 1992-11-25 | 1994-06-14 | Osaka Gas Co Ltd | 炭素繊維の表面処理方法および炭素繊維 |
| EP1061042A1 (en) * | 1999-06-15 | 2000-12-20 | Iljin Nanotech Co., Ltd. | Method for gas phase purification of carbon nanotubes by thermal treatment in diffusion furnace |
| KR100382878B1 (ko) * | 1999-06-15 | 2003-05-09 | 일진나노텍 주식회사 | 고순도 탄소나노튜브의 합성 방법 |
| JP2002177702A (ja) | 2000-12-08 | 2002-06-25 | Sony Corp | カーボンナノ構造体の一段階精製用の超音波還流システム |
| DE50209165D1 (de) * | 2001-02-21 | 2007-02-15 | Basf Ag | Verfahren zur herstellung von d-pantothensäure und/oder salze als zusatz zu tierfuttermitteln |
| WO2003040446A2 (en) * | 2001-06-15 | 2003-05-15 | The Pennsylvania State Research Foundation | Method of purifying nanotubes and nanofibers using electromagnetic radiation |
| JP2005001980A (ja) * | 2003-04-23 | 2005-01-06 | Samsung Corning Co Ltd | 流動化方式を用いた炭素ナノ構造体の処理方法 |
| US7144949B2 (en) * | 2003-12-11 | 2006-12-05 | The Aerospace Corporation | Synthetic method for conducting polymer nanofibers |
| KR100533414B1 (ko) * | 2004-05-12 | 2005-12-02 | 한국전력공사 | 활성탄소섬유의 질산 표면처리장치 및 표면처리방법 |
| KR20070084288A (ko) * | 2004-10-22 | 2007-08-24 | 하이페리온 커탤리시스 인터내셔널 인코포레이티드 | 탄소 나노튜브의 개선된 오존첨가분해 방법 |
| DE102004054959A1 (de) * | 2004-11-13 | 2006-05-18 | Bayer Technology Services Gmbh | Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator |
| DE102006007147A1 (de) * | 2006-02-16 | 2007-08-23 | Bayer Technology Services Gmbh | Verfahren zur kontinuierlichen Herstellung von Katalysatoren |
| DE102007044031A1 (de) * | 2007-09-14 | 2009-03-19 | Bayer Materialscience Ag | Kohlenstoffnanoröhrchenpulver, Kohlenstoffnanoröhrchen und Verfahren zu ihrer Herstellung |
| KR101001385B1 (ko) * | 2008-04-23 | 2010-12-14 | 한화케미칼 주식회사 | 탄소나노튜브의 연속적인 표면처리 방법 및 장치 |
-
2008
- 2008-07-03 DE DE102008031579A patent/DE102008031579A1/de not_active Ceased
-
2009
- 2009-06-27 AU AU2009266063A patent/AU2009266063A1/en not_active Abandoned
- 2009-06-27 US US13/002,396 patent/US20110104492A1/en not_active Abandoned
- 2009-06-27 CA CA2729693A patent/CA2729693A1/en not_active Abandoned
- 2009-06-27 WO PCT/EP2009/004664 patent/WO2010000424A2/de active Application Filing
- 2009-06-27 KR KR1020107029695A patent/KR20110027723A/ko not_active Application Discontinuation
- 2009-06-27 BR BRPI0915597A patent/BRPI0915597A2/pt not_active Application Discontinuation
- 2009-06-27 CN CN2009801252026A patent/CN102099515A/zh active Pending
- 2009-06-27 JP JP2011515218A patent/JP2011526331A/ja not_active Withdrawn
- 2009-06-27 RU RU2011103676/05A patent/RU2011103676A/ru unknown
- 2009-06-27 EP EP09772124A patent/EP2297386A2/de not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2010000424A2 * |
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0915597A2 (pt) | 2019-08-27 |
| DE102008031579A1 (de) | 2010-01-07 |
| CN102099515A (zh) | 2011-06-15 |
| AU2009266063A1 (en) | 2010-01-07 |
| CA2729693A1 (en) | 2010-01-07 |
| US20110104492A1 (en) | 2011-05-05 |
| KR20110027723A (ko) | 2011-03-16 |
| JP2011526331A (ja) | 2011-10-06 |
| WO2010000424A2 (de) | 2010-01-07 |
| RU2011103676A (ru) | 2012-08-10 |
| WO2010000424A3 (de) | 2010-12-29 |
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