EP2212466B1 - Verfahren zum einfärben und/oder bedrucken von haftverschlussteilen - Google Patents

Verfahren zum einfärben und/oder bedrucken von haftverschlussteilen Download PDF

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Publication number
EP2212466B1
EP2212466B1 EP08802854A EP08802854A EP2212466B1 EP 2212466 B1 EP2212466 B1 EP 2212466B1 EP 08802854 A EP08802854 A EP 08802854A EP 08802854 A EP08802854 A EP 08802854A EP 2212466 B1 EP2212466 B1 EP 2212466B1
Authority
EP
European Patent Office
Prior art keywords
wax
adhesive closure
application
closure part
color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP08802854A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP2212466A1 (de
Inventor
Jan Tuma
Konstantinos Poulakis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gottlieb Binder GmbH and Co KG
Original Assignee
Gottlieb Binder GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gottlieb Binder GmbH and Co KG filed Critical Gottlieb Binder GmbH and Co KG
Priority to PL08802854T priority Critical patent/PL2212466T3/pl
Publication of EP2212466A1 publication Critical patent/EP2212466A1/de
Application granted granted Critical
Publication of EP2212466B1 publication Critical patent/EP2212466B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0069—Details
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2016—Application of electric energy
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0081—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat

Definitions

  • the invention relates to a method for dyeing and / or printing adhesive closure parts with a plurality of entanglement means connected to a carrier, mainly consisting of a plastic material, wherein a color medium is applied by means of an applicator on the surface of the adhesive closure part or its parts, wherein as a color medium is used on the basis of a solvent-free wax, which is applied melted in droplet, blister or pellet form by means of the applicator and enters the cooled, cured state, a firm connection with the surface of the adhesive closure part and the parts.
  • the known fastening system comprises a male component having a plurality of interlocking elements and a female component having a woven thread structure for releasable attachment to the male component, the female component having at least a first and a second surface modified such that the maximum shearing force for detachment or removal of the male Component 10% less in the first area compared to the second area, and wherein at least a portion of the female component is stretchable.
  • the first area may be modified with ink or a polymeric material.
  • Such an adhesive fastener may be modified, for example, by coating a two-layered backing with hot-melt, phase change waxes.
  • the known adhesive closures consist regularly of two parts in the form of male or female engaging parts, the male engaging parts are formed from a hook or mushroom-shaped closure material as interlocking means, where female engaging parts can be set in the form of a hook or Velcro material, if the two Ein beneficiaeile be joined together to form the actual adhesive closure.
  • the pertinent interlocking means can be separated from each other again and again and connect with each other and main applications for patches are regularly found in the clothing industry; but are also the subject of technical applications, for example as fasteners for wall or panel linings in vehicles and the like.
  • the tape-like adhesive closures mentioned can be obtained in one piece from plastic material by conventional shaping methods; However, it is also possible to obtain at least parts of these adhesive closures by weaving and / or knitting from a plastic fiber material.
  • the plastic material used is usually colorless or has a colored basic shade which originates from the extrusion process, which makes it difficult on a regular basis to adapt the finished adhesive closure products to the color conditions which result, for example, from the fabric colors in the clothing and textile industries.
  • if only small amounts of adhesive closures of a certain color are required, it is difficult for the manufacturer to provide the overall production process for a small batch of this with a predeterminable color of the plastic material.
  • inks in particular reactive inks, acid inks or dispersion inks are used.
  • the pertinent inks are solvent-containing, so that they are not particularly suitable for labeling adhesive fastener parts used in the food, cosmetics and pharmaceutical industries.
  • the ink used bleaches, which reduces the clarity of ink application over time and leads to an ugly appearance.
  • the inks are often not as lightfast and then bleach under the sun exposure accordingly strong.
  • WO 98/39 759 A1 discloses a method in which solvent-based inks, curable inks, and water-based inks are used as the coloring medium for inking and / or printing fastener parts.
  • solvent-based inks, curable inks, and water-based inks are used as the coloring medium for inking and / or printing fastener parts.
  • water-based inks with acrylate binders are used, which are applied by means of flexographic printing processes.
  • solvent-free waxes in the form of hot melt ink compositions for printing on porous substrates for creating so-called barcodes.
  • the object of the invention is a process for dyeing and / or printing of adhesive fastener parts which, while retaining the advantages of the known dyeing solutions, further improves these in such a way that they remain colourfast even in the long-term operation and that also increased environmental and health requirements are taken into account.
  • This object is achieved by a method having the features of claim 1 in its entirety.
  • the adhesive closure parts before the actual dyeing or printing with the wax are subjected to a reactive pretreatment in the sense of a surface coating or a surface functionalization.
  • a fixation or aftertreatment of the wax applied on the surface of the adhesive closure part is carried out by means of a fixing or polishing agent, or by application of intrinsic or actinic energy and by means of UV or IR light.
  • the process according to the invention does not involve any solvents, so that even in critical areas, such as the food industry, the pharmaceutical or cosmetics industry, the wax-colored adhesive closure part can be readily used for special products, such as packaging.
  • the wax application is very reliable and it makes economic sense to treat even small amounts of adhesive closure parts color and design. Leave aside the order of a color design pattern the application waxes also apply in the form of numerical or letter sequences, so that in this respect also manufacturer information, product information od. Like. Can be attached to the adhesive closure part.
  • the application device for the color wax is preferably at least one Wachsubbeddüse, wherein the output of wax is driven by a piezoelectric crystal.
  • very small wax volumes which are in the picoliter range, can be applied drop by drop to the adhesive closure part together with its parts with a very fast application frequency.
  • Another possibility is to provide the color wax in the manner of single wax rods, which are melted in the device interior of the applicator and then fed to a print head of the same. The printheads then inject the application wax, such as pellets, onto the surface of the respective fastener part.
  • the color wax when hitting the adhesive closure part is already almost solid again, which has the advantage that especially in tissue-like adhesive fastener parts made of individual filaments, the wax does not completely penetrate into the tissue to fade in such a way.
  • Another possibility is to heat the color wax abruptly to its evaporation temperature (> 300 ° C), with the result that the wax forms bubbles, which in turn can collapse and thereby be thrown explosively out of an application nozzle.
  • This process can be repeated up to 10,000 times per second and also in such a way can be a high-quality printing process for the respective fastener part reach.
  • the paint application wax dries in fractions of a second on the surface of the adhesive closure part, so that any post-drying or subsequent Curing operations are not necessary, which in turn increases the process speed.
  • each color wax application nozzle used for a particular color or hue is used, with mixed colors can be generated directly on the surface of the fastener part by means of different wax applicator.
  • a plurality of wax application nozzles may be provided, preferably the wax application nozzles are arranged fixed in the applicator and the inked or to be printed adhesive fastener parts are fed at a predeterminable speed through the applicator and by means of wax applicator nozzles with the paint Mistake.
  • Acrylates have proved to be good plastic materials to be colored well as well as customary polyamide, polyester, polyethylene and polypropylene materials from which otherwise the interlocking means of the band-like adhesive closure parts are obtained in one piece as a cast product or by customary knitting weaving methods.
  • the wax application nozzles on both opposite surfaces of the adhesive closure part, so that a dyeing or printing process can take place from two different sides, if necessary with different waxes and colors.
  • the inventive method is used for coloring and / or printing of fastener parts 10, wherein in the figure as a so-called.
  • Male interlocking means 12 mushroom-like hooking heads are shown, which are integral part of the belt-like support 14 for the fastener part 10.
  • the mushroom-like interlocking elements 12 can be connected to a corresponding hook or loop material as a so-called female engaging part to form a Haftverschlußsysterns (not shown), wherein the hook or Velcro material hooks releasably on the edge projections of the interlocking elements 12.
  • a manufacturing method for pertinent engaging parts is exemplary in the EP 1 309 257 B1 the applicant described.
  • the adhesive closure part in this respect consists of a cast in a sieve plastic material, for example in the form of polyethylene in colorless design and thus almost transparent or the plastic material is provided with a base color, as it results from the plastic granules from which the adhesive closure member 10 via said known extrusion process can be produced.
  • the molded in the so-called chill roll adhesive closure member 10 this may also consist of a woven or knitted support base structure, from which the interlocking means (hooks, mushrooms, loops, etc.) with a predetermined projection then protrude (not shown).
  • the method according to the invention provides for the inking and / or printing of the adhesive closure part 10 by means of at least one wax application nozzle 18.
  • the ejection of the wax application nozzle 18 to color wax is controlled by a piezoelectric crystal 20, such an output of color wax per activation cycle of the piezocrystal 20 being in the picoliter range. Since piezocrystals 20 are known to have very high oscillation frequencies, however, the small application rate is sufficient to achieve a rich color wax application, whereby, depending on the plastic material used for the adhesive closure part 10, there is also the possibility that at least partially the applied wax application penetrates slightly into the plastic material on the surface side and thus saturates the open pores of the plastic material with color wax.
  • the inking nozzle 18 shown in the figure is designed overall in the manner of a capillary nozzle and is in fluid communication with a pressure chamber 22 in connection, on the upper side of a vibrating plate 24 acts, which is controlled by the piezoelectric crystal 20. Consequently, positive and negative voltages are applied to the piezocrystal 20 in order to regulate the wax delivery. If there is no voltage at the piezocrystal 20, the color wax flows into the pressure chamber 22 from a storage chamber (Not shown) originating via the supply line 26 into the pressure chamber 22 a.
  • the crystal pushes over the vibrating plate 24 to the wax color in the pressure chamber 22 and hurls the color wax through said capillary nozzle 18 on the rear surface of the adhesive closure part 10.
  • a negative voltage to the Piezo crystal 20 then moves the vibrating plate 24 abruptly, whereby the color wax application is interrupted abruptly. Due to the extremely fast voltage change, the delivered amount of wax can be very finely dosed, so that can be achieved with the pertinent application method resolutions of 100 to 9600 dpi, preferably up to several 10,000 dpi. As a result, a very good printing and wax color quality is achieved.
  • the adhesive closure member 10 can be continuously passed under the color wax applicator, whereby by meaningful control of the piezoelectric crystals 20 and by suitable choice of wax colors, the color and printing design during the walkthrough process.
  • color wax in particular those have proved to be advantageous, which are solvent-free.
  • colored waxes are used, which are preferably kneadable at 20 ° C and otherwise hard to brittle hard.
  • the wax used in each case should have a coarse to fine crystalline structure, be colored translucent to opaque in its color design; but not glassy.
  • the color wax used should melt without decomposition and be slightly liquid above the melting point, ie less viscous.
  • a strong temperature-dependent consistency and solubility has proven to be favorable, and if the color wax used can be polished under light pressure, this enables a post-treatment possibility in which modify the surface design of the wax, for example, that the applied to the fastener part wax appears shiny.
  • it is also possible to fix the wax for example by the applied wax subsequently with water vapor and / or with an alkaline cold bath and / or by mechanical treatment, for example by means of a pressure calender, which presses on the bewachste surface of the adhesive closure part 10 , is additionally fixed.
  • after-treatment can also be carried out by means of IR or UV light or by the introduction of intrinsic energy.
  • it is possible to post-actinize the closure product by means of actinic energy.
  • the pertinent exchange media interact particularly well with the plastic material for the respective adhesive closure part 10, if the plastic material belongs to one of the following groups: polyethylenes, polypropylenes, polybutenes and polyisobutenes and poly (4-methyl-1-pentene) s, polymers of higher ⁇ Olefins, eg Poly (1-hexene), poly (1-octene) or poly (1-octadecene).
  • polyethylenes polypropylenes
  • polymers of higher ⁇ Olefins eg Poly (1-hexene
  • poly (1-octene) or poly (1-octadecene polymers of higher ⁇ Olefins
  • copolymers of different olefins e.g. which are recognized by ethylene with propylene as belonging.
  • Another good feedstock for the molded fastener parts is polyester.
  • the plastic material used in each case is surface-functionalized with the proton and / or electron exchange medium mentioned, a particularly good bonding of the respective application wax to the surface 16 of the adhesive closure part 10 is to be expected, the change in the surface energy for the adhesive closure part 10 thus obtained within the surface 16 takes place and does not present itself as a coating.
  • Another way of surface activation for the plastic material of the adhesive closure member 10 is to actually apply a coating to said surface 16, for example in the form of fluorine.
  • the fluorine application has proven to be favorable for the subsequent adhesion of the color wax on the adhesive closure part 10.
  • some of the plastics mentioned for the adhesive closure member 10 are attacked on its surface and taking advantage of this effect can be specifically the surface 16 of the adhesive closure part 10 for the addition of the color wax modify.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
EP08802854A 2007-11-20 2008-10-10 Verfahren zum einfärben und/oder bedrucken von haftverschlussteilen Active EP2212466B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL08802854T PL2212466T3 (pl) 2007-11-20 2008-10-10 Sposób barwienia i/lub nadrukowywania części zamknięcia przyczepnego

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007055428A DE102007055428B3 (de) 2007-11-20 2007-11-20 Verfahren zum Einfärben und/oder Bedrucken von Haftverschlußteilen
PCT/EP2008/008564 WO2009065466A1 (de) 2007-11-20 2008-10-10 Verfahren zum einfärben und/oder bedrucken von haftverschlussteilen

Publications (2)

Publication Number Publication Date
EP2212466A1 EP2212466A1 (de) 2010-08-04
EP2212466B1 true EP2212466B1 (de) 2011-11-16

Family

ID=40278906

Family Applications (1)

Application Number Title Priority Date Filing Date
EP08802854A Active EP2212466B1 (de) 2007-11-20 2008-10-10 Verfahren zum einfärben und/oder bedrucken von haftverschlussteilen

Country Status (8)

Country Link
US (1) US8945685B2 (ja)
EP (1) EP2212466B1 (ja)
JP (1) JP5399405B2 (ja)
CN (1) CN101855399B (ja)
AT (1) ATE533888T1 (ja)
DE (1) DE102007055428B3 (ja)
PL (1) PL2212466T3 (ja)
WO (1) WO2009065466A1 (ja)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104163035A (zh) * 2014-06-25 2014-11-26 太仓市虹鹰印花有限公司 石蜡热印装置
JP6071158B2 (ja) * 2015-06-16 2017-02-01 株式会社ボックス 顔面へ取付けられるアンカー部材、その着色方法及び顔面装着部材

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JPH07186518A (ja) * 1993-12-26 1995-07-25 Ricoh Co Ltd インクジェット記録方法およびインクジェット記録用インク組成物
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Also Published As

Publication number Publication date
WO2009065466A1 (de) 2009-05-28
EP2212466A1 (de) 2010-08-04
JP5399405B2 (ja) 2014-01-29
PL2212466T3 (pl) 2012-04-30
DE102007055428B3 (de) 2009-03-05
JP2011502769A (ja) 2011-01-27
US8945685B2 (en) 2015-02-03
ATE533888T1 (de) 2011-12-15
CN101855399B (zh) 2013-07-31
CN101855399A (zh) 2010-10-06
US20100239780A1 (en) 2010-09-23

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