EP2097505B1 - PROCÉDÉ POUR PRODUIRE DE LA FONTE BRUTE À BASE D'ACIER INOXYDABLE SANS UTILISER DE l'ÉNÉRGIE ÉLECTRIQUE - Google Patents
PROCÉDÉ POUR PRODUIRE DE LA FONTE BRUTE À BASE D'ACIER INOXYDABLE SANS UTILISER DE l'ÉNÉRGIE ÉLECTRIQUE Download PDFInfo
- Publication number
- EP2097505B1 EP2097505B1 EP07856191.7A EP07856191A EP2097505B1 EP 2097505 B1 EP2097505 B1 EP 2097505B1 EP 07856191 A EP07856191 A EP 07856191A EP 2097505 B1 EP2097505 B1 EP 2097505B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- pig iron
- aod
- converter
- carried out
- twin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910000805 Pig iron Inorganic materials 0.000 title claims description 33
- 229910001220 stainless steel Inorganic materials 0.000 title claims description 17
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000010935 stainless steel Substances 0.000 title claims description 15
- 238000000034 method Methods 0.000 claims description 40
- 238000011282 treatment Methods 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 15
- 238000005275 alloying Methods 0.000 claims description 11
- 238000007600 charging Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 9
- 238000009847 ladle furnace Methods 0.000 claims description 5
- 229910005347 FeSi Inorganic materials 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 229910000604 Ferrochrome Inorganic materials 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000002203 pretreatment Methods 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 230000006978 adaptation Effects 0.000 claims description 2
- 238000001311 chemical methods and process Methods 0.000 claims description 2
- 238000010079 rubber tapping Methods 0.000 claims 1
- 239000000161 steel melt Substances 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000010959 steel Substances 0.000 description 10
- 238000005261 decarburization Methods 0.000 description 6
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000007670 refining Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000005266 casting Methods 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/005—Manufacture of stainless steel
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/06—Deoxidising, e.g. killing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/068—Decarburising
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/068—Decarburising
- C21C7/0685—Decarburising of stainless steel
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C2300/00—Process aspects
- C21C2300/08—Particular sequence of the process steps
Definitions
- the invention relates to a method for stainless steel production without electrical energy supply based on liquid pig iron and FeCr solids, wherein the liquid pig iron after a pre-treatment in the blast furnace and a DDD treatment (dephosphorization, desilication, desulfurization) heated in an AOD converter, ennobled or alloyed, reduced and finally an adjustment / adjustment of the treated molten steel in a ladle furnace is performed.
- a DDD treatment dephosphorization, desilication, desulfurization
- the method is based on a running according to a process model and the metallurgical plant controlling computational technology, in the process model, the behavior for at least one variable process parameter between an actual process variable, a manipulated variable and describes a process end size.
- An example of the manufacturing process for AISI 304 grades is described.
- Stainless steels of the ferritic steel group AISI 4xx are conventionally produced in principle from typical scrap in the EAF and later additionally alloyed and decarburized in the AOD converter.
- pig iron pretreated in a steel mill is melted down Scrap and alloy outside the oven mixed in a pan and then charged into the converter.
- the object of the invention is that of the WO 2006/050963 A2 Known method with AOD technology for direct charging of pig iron and alloying in the converter for stainless steel production of all stainless steel, such as AISI 3xx, 4xx, 2xx, both austenitic and ferritic range using autogenous chemical energy to use.
- the stated object for the production of stainless steel number of said steel grade is achieved by the characterizing features of claim 1, characterized in that the stainless steel production of all stainless steel in both the austenitic and ferritic in the blast furnace pretreated slag-free liquid quantity of pig iron and separated into two classic "Twin" AOD In the first twin AOD-L converter, the required chemical process steps (the DDD treatment, charging and heating, decarburization and alloying) are carried out using parallel countercurrent flow using autogenous chemical energy First, the DDD treatment and in the second Twin AOD-L converter, first the decarburization is performed.
- the heating of the pig iron to a desired or required for the subsequent process steps temperature is carried out by Si oxidation.
- FeSi is charged into the Twin AOD-L converter and oxygen / inert gas mixture is blown through the side nozzles and a top lance into and onto the pig iron.
- the first Twin AOD-L converter uses a 3- or 4-hole top lance and the second Twin AOD-L converter uses a single-hole top lance.
- the heating of the pre-metal is carried out according to the invention after the DDD treatment, it is possible, above all, to charge Ni or Ni alloys into the Twin AOD-L converters.
- the balance energy can be designed in this way.
- the decarburization and alloying of the melt takes place in the first Twin AOD-L converter after completion of the DDD treatment and charging and heating, while in the second Twin AOD-L Converter after completion of the decarburization and all associated treatment steps (such as desulfurization and alloying with parting off) the pig iron is heated.
- the separation according to the invention of the pretreated slag-free molten pig iron quantity on two twin AOD-L converters arranged in parallel in the process line downstream of the blast furnace and the process steps carried out in a contrary manner makes it advantageously possible to produce all RST steel grades.
- there is a decoupling of the demand for electrical energy for all qualities since only the energy already present in the pig iron or via the charged with the charged FeSi autogenous chemical energy is used.
- a more reliable temperature control, reduced process costs and reduced investment costs are achieved by this separation of the amount of pig iron and the process control, since only smaller quantities of pig iron have to be treated.
- FIG. 1 In a drawing figure, an exemplary process line for the production of stainless steel is shown.
- the liquid quantity of pig iron is separated after its exit from the blast furnace 1 and introduced into two twin AOD-L converters 2, 3 arranged downstream of the blast furnace 1.
- the process steps are carried out in a contrary process, the DDD treatment and the refining and alloying of the molten pig iron.
- the molten steel from both Twin AOD-L converters is brought together in a ladle 4 and from there to the final adaptation / adjustment in the ladle furnace 5 and from there to the casting machine 6.
- FIG. 2 the contrary sequence of the process steps carried out in the Twin AOD-L converters 2 and 3 is shown. While in the Twin AOD-L converter 2 (on the left in the drawing) a DDD treatment V7 is started, followed by charging and heating V8 by FeSi followed by AOD treatment V9 with decarburization and alloying to produce, for example, AISI 3xx , 4xx, 2xx stainless steel grades, the DDD treatment V7 in the Twin AOD-L converter 3 (in the drawing on the right) with subsequent charging and heating V8 is only carried out after completion of the AOD treatment V9.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Claims (8)
- Procédé pour la fabrication d'acier inoxydable en l'absence d'un apport d'énergie électrique, sur base de fonte brute liquide et de substances solides de type FeCr, la fonte brute liquide, après un prétraitement dans un haut-fourneau (1) et après un traitement DDD (déphosphoration, désilication, désulfuration). dans un convertisseur à l'argon oxygène de décarburation (AOD) (2, 3), étant chauffée, affinée, respectivement alliée, réduite, et dans lequel on soumet ensuite la masse fondue d'acier traitée à une adaptation/à un réglage dans un four-poche (5), caractérisé en ce que, pour la fabrication d'acier inoxydable de toute qualité d'acier inoxydable, aussi bien dans la phase austénitique que dans la phase ferritique, on sépare la quantité de fonte brute liquide exempte de scories, qui a été soumise à un prétraitement dans le haut-fourneau et on l'introduit dans deux convertisseurs « twin » classiques (2, 3) du type à l'argon oxygène de décarburation à lance (AOD-L), dans lesquels, avec un écoulement contraire parallèle, on met en oeuvre les étapes opératoires chimiques requises (du traitement DDD (V7), du chauffage (V8) et de la décarburation et de l'alliage (V9)) en utilisant de l'énergie chimique autogène, dans lequel, dans le premier convertisseur twin AOD-L (2), on procède d'abord au traitement DDD (V7) et au chauffage (V8), et dans le deuxième convertisseur twin AOD-L (3), on procède d'abord à la décarburation (V9).
- Procédé selon la revendication 1, caractérisé en ce que, au terme du traitement DDD (V7), avant le chargement et le chauffage ultérieur (V8), on procède à un décrassage de la fonte brute.
- Procédé selon la revendication 2, caractérisé en ce que, pour le chauffage (V8) de la fonte brute, on met en oeuvre une oxydation du silicium, pour laquelle on charge la fonte brute avec du FeSi.
- Procédé selon la revendication 3, caractérisé en ce que, dans le premier convertisseur twin AOD-L (2), au terme du traitement (V7) et du chauffage (V8), on met en oeuvre la décarburation et l'alliage (V9) de la masse fondue.
- Procédé selon la revendication 4, caractérisé en ce que, dans le premier convertisseur twin AOD-L (2), pour la mise en oeuvre de l'oxydation du silicium on insuffle, via des buses latérales et une lance supérieure (lance supérieure à 3 trous, respectivement à 4 trous), un mélange oxygène/gaz inerte dans et sur la fonte brute.
- Procédé selon la revendication 3, caractérisé en ce que, dans le deuxième convertisseur twin AOD-L (3), au terme de la décarburation (V9) et de toutes les étapes de traitement qui y sont liées (comme par exemple la désulfuration et l'alliage conjointement avec le tronçonnage), on charge et on chauffe la fonte brute.
- Procédé selon la revendication 6, caractérisé en ce que, dans le deuxième convertisseur twin AOD-L (3), pour l'oxydation du silicium on insuffle, via des buses latérales et une lance supérieure (lance supérieure à 1 trou, respectivement à 3 trous), un mélange oxygène/gaz inerte dans et sur la fonte brute.
- Procédé selon une ou plusieurs des revendications 1 à 7, caractérisé en ce qu'on introduit dans les deux convertisseurs twin AOD-L (2, 3) respectivement la même quantité de fonte brute.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006056672A DE102006056672A1 (de) | 2006-11-30 | 2006-11-30 | Verfahren und Vorrichtung zur Rostfreistahlerzeugung ohne elektrische Energiezufuhr auf der Basis von Roheisen |
PCT/EP2007/010012 WO2008064797A1 (fr) | 2006-11-30 | 2007-11-20 | Procédé et dispositif pour produire de la fonte brute à base d'acier inoxydable sans utiliser d'alimentation électrique |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2097505A1 EP2097505A1 (fr) | 2009-09-09 |
EP2097505B1 true EP2097505B1 (fr) | 2016-08-10 |
Family
ID=39032113
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07856191.7A Active EP2097505B1 (fr) | 2006-11-30 | 2007-11-20 | PROCÉDÉ POUR PRODUIRE DE LA FONTE BRUTE À BASE D'ACIER INOXYDABLE SANS UTILISER DE l'ÉNÉRGIE ÉLECTRIQUE |
Country Status (9)
Country | Link |
---|---|
US (2) | US8430945B2 (fr) |
EP (1) | EP2097505B1 (fr) |
JP (1) | JP5415275B2 (fr) |
KR (1) | KR101123038B1 (fr) |
CN (1) | CN101541941B (fr) |
CA (1) | CA2671074C (fr) |
DE (1) | DE102006056672A1 (fr) |
ES (1) | ES2602303T3 (fr) |
WO (1) | WO2008064797A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006056671A1 (de) * | 2006-11-30 | 2008-06-05 | Sms Demag Ag | Verfahren und Vorrichtung zur Rostfreistahlerzeugung ohne elektrische Energiezufuhr auf der Basis von in einer DDD-Anlage vorbehandeltem Roheisen |
DE102014222727A1 (de) | 2014-11-06 | 2016-05-12 | Sms Group Gmbh | Verfahren und Vorrichtung zur Erzeugung eines Rostfreistahls |
CN110894565B (zh) * | 2019-12-04 | 2021-07-16 | 山西太钢不锈钢股份有限公司 | 超高硅碳铬熔液冶炼不锈钢的方法 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT263830B (de) * | 1965-02-11 | 1968-08-12 | Bot Brassert Oxygen Technik Ag | Anlage zur Erzeugung von Stahl |
SE329861B (fr) | 1969-03-26 | 1970-10-26 | Skf Svenska Kullagerfab Ab | |
DE1940761C3 (de) * | 1969-08-11 | 1973-02-01 | Demag Ag | Anlage fuer kontinuierliche Stahlerzeugung |
JPS59107016A (ja) * | 1982-12-11 | 1984-06-21 | Nisshin Steel Co Ltd | ステンレス鋼製造用含Ni溶湯を得る方法 |
JPS59182909A (ja) * | 1983-03-31 | 1984-10-17 | Nippon Steel Corp | 製鋼精錬用ランス |
JPS59211519A (ja) | 1983-05-18 | 1984-11-30 | Nisshin Steel Co Ltd | 低p含クロム鋼の製造法 |
JPS6112812A (ja) * | 1984-06-27 | 1986-01-21 | Sumitomo Metal Ind Ltd | ステンレス鋼の脱炭方法 |
JPH04224617A (ja) * | 1990-12-26 | 1992-08-13 | Kawasaki Steel Corp | Cr鉱石溶融還元によるステンレス鋼の製造方法 |
JP2848010B2 (ja) * | 1991-04-23 | 1999-01-20 | 住友金属工業株式会社 | 溶融金属精錬用上吹ランス |
JPH0892614A (ja) * | 1994-09-27 | 1996-04-09 | Kawasaki Steel Corp | 低塩基度スラグを排滓する溶銑予備処理方法 |
DE19621143A1 (de) | 1996-01-31 | 1997-08-07 | Mannesmann Ag | Verfahren zur Erzeugung nichtrostender Stähle |
JPH09302405A (ja) | 1996-05-15 | 1997-11-25 | Kawasaki Steel Corp | ステンレス鋼の溶製方法 |
JPH11131122A (ja) * | 1997-10-28 | 1999-05-18 | Nippon Steel Corp | 高炉溶銑とフェロクロム合金を用いたステンレス粗溶鋼の脱炭精錬方法 |
ITRM20010146A1 (it) | 2001-03-21 | 2002-09-21 | Acciai Speciali Terni Spa | Metodo e sistema di controllo per convertitori aod. |
AT411068B (de) | 2001-11-13 | 2003-09-25 | Voest Alpine Ind Anlagen | Verfahren zur herstellung einer metallschmelze in einer hüttentechnischen anlage |
GB0213027D0 (en) * | 2002-06-07 | 2002-07-17 | Jsr Farming Group | Compound |
DE10227031A1 (de) * | 2002-06-17 | 2004-01-08 | Sms Demag Ag | Verfahren und Produktionsanlage zum Erzeugen von Produkten aus C-Stahl oder aus Rostfrei-Stahl |
DE102005032929A1 (de) | 2004-11-12 | 2006-05-18 | Sms Demag Ag | Herstellung von Rostfreistahl der ferritischen Stahlgruppe AISI 4xx in einem AOD-Konverter |
DE102006056671A1 (de) * | 2006-11-30 | 2008-06-05 | Sms Demag Ag | Verfahren und Vorrichtung zur Rostfreistahlerzeugung ohne elektrische Energiezufuhr auf der Basis von in einer DDD-Anlage vorbehandeltem Roheisen |
-
2006
- 2006-11-30 DE DE102006056672A patent/DE102006056672A1/de not_active Withdrawn
-
2007
- 2007-11-20 KR KR1020097008208A patent/KR101123038B1/ko active IP Right Grant
- 2007-11-20 WO PCT/EP2007/010012 patent/WO2008064797A1/fr active Application Filing
- 2007-11-20 JP JP2009538619A patent/JP5415275B2/ja not_active Expired - Fee Related
- 2007-11-20 ES ES07856191.7T patent/ES2602303T3/es active Active
- 2007-11-20 CA CA2671074A patent/CA2671074C/fr not_active Expired - Fee Related
- 2007-11-20 CN CN200780043801.4A patent/CN101541941B/zh not_active Expired - Fee Related
- 2007-11-20 EP EP07856191.7A patent/EP2097505B1/fr active Active
- 2007-11-20 US US12/312,882 patent/US8430945B2/en active Active
-
2012
- 2012-03-23 US US13/428,854 patent/US8765051B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
KR20090060353A (ko) | 2009-06-11 |
CN101541941B (zh) | 2014-08-13 |
CA2671074A1 (fr) | 2008-06-05 |
ES2602303T3 (es) | 2017-02-20 |
JP2010511100A (ja) | 2010-04-08 |
CN101541941A (zh) | 2009-09-23 |
KR101123038B1 (ko) | 2012-03-21 |
US20120175828A1 (en) | 2012-07-12 |
US8765051B2 (en) | 2014-07-01 |
US20100011909A1 (en) | 2010-01-21 |
DE102006056672A1 (de) | 2008-06-05 |
EP2097505A1 (fr) | 2009-09-09 |
US8430945B2 (en) | 2013-04-30 |
WO2008064797A1 (fr) | 2008-06-05 |
CA2671074C (fr) | 2011-09-20 |
JP5415275B2 (ja) | 2014-02-12 |
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