EP2035136A1 - Masse absorbante et procédé d'extraction de mercure - Google Patents
Masse absorbante et procédé d'extraction de mercureInfo
- Publication number
- EP2035136A1 EP2035136A1 EP07730179A EP07730179A EP2035136A1 EP 2035136 A1 EP2035136 A1 EP 2035136A1 EP 07730179 A EP07730179 A EP 07730179A EP 07730179 A EP07730179 A EP 07730179A EP 2035136 A1 EP2035136 A1 EP 2035136A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- mercury
- silver
- alumina
- absorption
- mass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
- B01J20/08—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/104—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
Definitions
- Mercury is a contaminant in many streams. Often these are streams that occur in the course of processing or burning fossil fuels or waste, as fossil fuels such as crude oil, natural gas or coal or waste contain traces of mercury in elemental or usually organically bound form. There are also mercury contaminant streams from processes in which mercury is used, for example the electrolysis hydrogen produced in the chlorine production by the amalgam process. Due to the high toxicity of mercury, it is usually necessary to remove mercury from such streams. Mercury may also corrode aluminum workpieces by amalgamating aluminum to destroy its surface oxide layer so that flows of material passing through aluminum apparatus or containers must be virtually free of mercury.
- a silver and alumina-containing absorption mass was found, which is characterized in that the alumina is at least 50 wt .-% theta-alumina. Furthermore, a process has been found for the removal of impurities from streams by contacting them with an absorption mass which is characterized in that the absorption mass according to the invention is used.
- an absorption mass consisting essentially of silver and / or silver oxide and alumina, that is, an absorption mass which, except for unavoidable impurities or insignificant amounts, does not contain portions other than alumina, silver or silver oxide.
- an absorption mass which substantially (that is, except for unavoidable impurities, by-products from the production or constituents which show no effect in the inventive use of the absorption mass) of silver oxide Ag2 ⁇ on theta-alumina.
- the BET surface area of the absorption mass of the invention is at least 1 m 2 / g, preferably at least 5 m 2 / g and more preferably at least 10 m 2 / g and at most 500 m 2 / g, preferably at most 400 m 2 / g and most preferably at most 300 m 2 / g.
- the BET surface area is in the range of 30 to 120 m 2 / g, in the range of 40 to 100 m 2 / g or in the range of 60-90 m 2 / g.
- the usual method for measuring BET surfaces is known, usually the one-point method with nitrogen is used based on DIN 66132.
- the shaped bodies are converted by calcination into a finished carrier.
- the calcination temperature is in the range of 900 ° C to 1100 ° C, preferably in the range of 950 ° C to 1050 ° C, and most preferably in the range of 980 ° C to 1030 ° C.
- the calcination time is generally between 0.5 and 5 hours, preferably between 1 and 4 hours, and most preferably between 1, 5 and 3 hours.
- the calcination takes place in a conventional furnace, for example in a rotary kiln, in a belt calciner or in a chamber furnace.
- the calcination can be followed directly by the drying without intermediate cooling of the moldings.
- the BET surface area and the pore volume are adjusted by known methods (in particular using finely divided or coarser starting materials, calcination time and temperature).
- the silver to be deposited on the support and further constituents can be applied to the support by any known method, for example by coating from the gas phase (chemical or physical vapor deposition).
- the preferred method is the impregnation with a solution of the substances to be deposited and / or compounds, which convert in the course of further processing in the substances to be deposited.
- the individual substances to be deposited can be deposited individually and / or in partial quantities in several process steps or jointly and completely in one process step.
- the co-deposition is in a impregnation step.
- the absorption mass is prepared in a conventional manner by calcination.
- This calcination essentially serves to convert the impregnated salts into the components or precursors of such components to be deposited, and differs from the above-described calcination, which serves for the preparation of the support material and the support structure.
- this calcination essentially decomposes the nitrates into metals and / or metal oxides remaining in the catalyst and nitrous gases which escape.
- Silver nitrate decomposes to silver oxide
- the absorption mass After calcination, the absorption mass is basically ready for use. If desired, it is activated by pre-reduction prior to its use in a known manner and, if appropriate, also passivated on the surface again.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
L'invention concerne un procédé d'extraction de mercure et/ou d'arsenic ou leurs composés de courants de matériaux par mise en contact avec une masse absorbante contenant un oxyde d'aluminium et de l'argent, caractérisé en ce que l'oxyde d'aluminium est constitué d'au moins 50 % en poids d'oxyde d'aluminium thêta.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07730179A EP2035136A1 (fr) | 2006-06-21 | 2007-06-15 | Masse absorbante et procédé d'extraction de mercure |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06115816 | 2006-06-21 | ||
EP07730179A EP2035136A1 (fr) | 2006-06-21 | 2007-06-15 | Masse absorbante et procédé d'extraction de mercure |
PCT/EP2007/055935 WO2007147781A1 (fr) | 2006-06-21 | 2007-06-15 | Masse absorbante et procédé d'extraction de mercure |
Publications (1)
Publication Number | Publication Date |
---|---|
EP2035136A1 true EP2035136A1 (fr) | 2009-03-18 |
Family
ID=38476836
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP07730179A Withdrawn EP2035136A1 (fr) | 2006-06-21 | 2007-06-15 | Masse absorbante et procédé d'extraction de mercure |
Country Status (8)
Country | Link |
---|---|
US (1) | US20090200207A1 (fr) |
EP (1) | EP2035136A1 (fr) |
JP (1) | JP2009541025A (fr) |
KR (1) | KR20090031900A (fr) |
CN (1) | CN101472678A (fr) |
AR (1) | AR061542A1 (fr) |
TW (1) | TW200808440A (fr) |
WO (1) | WO2007147781A1 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0717195A2 (pt) * | 2006-11-21 | 2014-01-21 | Dow Global Technologies Inc | "método para remover mercúrio de uma corrente líquida ou gasosa de hidrocarbonetos compreendendo mercúrio" |
JP5455939B2 (ja) * | 2008-03-10 | 2014-03-26 | ビーエーエスエフ ソシエタス・ヨーロピア | 炭化水素流から水銀を除去する方法 |
CN103521165A (zh) * | 2013-10-22 | 2014-01-22 | 北京三聚环保新材料股份有限公司 | 一种铜系脱汞剂的制备方法 |
CN103521166A (zh) * | 2013-10-22 | 2014-01-22 | 北京三聚环保新材料股份有限公司 | 铜系脱汞剂的制备方法 |
CN104645927B (zh) * | 2013-11-25 | 2018-01-16 | 北京三聚环保新材料股份有限公司 | 一种银系脱汞剂的制备方法 |
CN103706243B (zh) * | 2013-12-12 | 2016-05-04 | 许国森 | 吸收剂防逃逸装置 |
JP6858055B2 (ja) * | 2017-03-30 | 2021-04-14 | 水澤化学工業株式会社 | 鉛吸着剤 |
CN113522005B (zh) | 2021-07-21 | 2022-07-01 | 西安向阳航天材料股份有限公司 | 一种铜基硫化物脱汞剂载体的制备方法 |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3232028A (en) * | 1962-07-02 | 1966-02-01 | Isomet Corp | Composition and method for absorption and regeneration of carbon dioxide |
IT1043119B (it) * | 1975-10-03 | 1980-02-20 | Tecneco Spa | Metodo per la rimozione di mer curio metallico |
US4230486A (en) * | 1978-04-28 | 1980-10-28 | Olin Corporation | Process for removal and recovery of mercury from liquids |
US5053209A (en) * | 1988-01-09 | 1991-10-01 | Mobil Oil Corporation | Removal of mercury from natural gas and liquid hydrocarbons utilizing silver on alumina adsorbent |
FR2628338B1 (fr) * | 1988-03-10 | 1991-01-04 | Inst Francais Du Petrole | Procede pour l'elimination du mercure dans les hydrocarbures |
US4892567A (en) * | 1988-08-15 | 1990-01-09 | Mobil Oil Corporation | Simultaneous removal of mercury and water from fluids |
US4874525A (en) * | 1988-10-26 | 1989-10-17 | Uop | Purification of fluid streams containing mercury |
US4909926A (en) * | 1989-02-01 | 1990-03-20 | Mobil Oil Corporation | Method for removing mercury from hydrocarbon oil by high temperature reactive adsorption |
US5080799A (en) * | 1990-05-23 | 1992-01-14 | Mobil Oil Corporation | Hg removal from wastewater by regenerative adsorption |
US5082569A (en) * | 1990-12-03 | 1992-01-21 | Uop | Removal of metals from liquefied hydrocarbons |
DE4221207A1 (de) * | 1992-06-27 | 1994-01-05 | Huels Chemische Werke Ag | Verfahren zur Entfernung von Quecksilber aus Flüssigkeiten |
US5322628A (en) * | 1992-09-08 | 1994-06-21 | Mobil Oil Corporation | Method for simultaneously drying and removing metallic and organic mercury from fluids |
US5523067A (en) * | 1993-07-26 | 1996-06-04 | Uop | Removal of mercury from naturally occurring streams containing entrained mineral particles |
KR100279881B1 (ko) * | 1998-06-29 | 2001-03-02 | 손재익 | 탄화수소혼합물로부터에틸렌및프로필렌,그리고불포화탄화수소분리용흡착제제조방법,그리고이흡착제를이용한분리방법 |
US6383981B1 (en) * | 1999-07-20 | 2002-05-07 | Süd-Chemie Inc. | Adsorbent for the removal of trace quantities from a hydrocarbon stream and process for its use |
CN1118540C (zh) * | 1999-09-24 | 2003-08-20 | 中国石油化工集团公司 | 一种从烃油中脱除砷的方法 |
DE10048219A1 (de) * | 2000-02-10 | 2002-04-11 | Sued Chemie Ag | Katalysator für die Hydrierung von ungesättigten Kohlenwasserstoffen |
CN1273567C (zh) * | 2002-10-28 | 2006-09-06 | 上海化工研究院 | 脱除含炔碳氢化合物中砷的方法及脱砷剂 |
DE10255240A1 (de) * | 2002-11-26 | 2004-06-09 | Basf Ag | Verfahren zur Entfernung von Quecksilber aus mit Quecksilber verunreinigten Lösungen |
US7153807B2 (en) * | 2003-03-04 | 2006-12-26 | Exxon Mobil Chemical Patents Inc. | Catalysts for selective hydrogenation of alkynes and alkadienes |
CN100355488C (zh) * | 2003-05-07 | 2007-12-19 | 韩国高化环保技术有限公司 | 通过多次喷射还原氮氧化物的催化方法及其用法 |
US7341977B2 (en) * | 2003-06-20 | 2008-03-11 | Nanoscale Corporation | Method of sorbing sulfur compounds using nanocrystalline mesoporous metal oxides |
DE102004059282A1 (de) * | 2004-10-13 | 2006-04-27 | Basf Ag | Selektivhydrierkatalysator |
JP5455939B2 (ja) * | 2008-03-10 | 2014-03-26 | ビーエーエスエフ ソシエタス・ヨーロピア | 炭化水素流から水銀を除去する方法 |
-
2007
- 2007-06-15 CN CNA2007800231945A patent/CN101472678A/zh active Pending
- 2007-06-15 EP EP07730179A patent/EP2035136A1/fr not_active Withdrawn
- 2007-06-15 US US12/305,836 patent/US20090200207A1/en not_active Abandoned
- 2007-06-15 JP JP2009515840A patent/JP2009541025A/ja not_active Withdrawn
- 2007-06-15 KR KR1020097000697A patent/KR20090031900A/ko not_active Application Discontinuation
- 2007-06-15 WO PCT/EP2007/055935 patent/WO2007147781A1/fr active Application Filing
- 2007-06-20 AR ARP070102710A patent/AR061542A1/es not_active Application Discontinuation
- 2007-06-20 TW TW096122120A patent/TW200808440A/zh unknown
Non-Patent Citations (1)
Title |
---|
See references of WO2007147781A1 * |
Also Published As
Publication number | Publication date |
---|---|
AR061542A1 (es) | 2008-09-03 |
KR20090031900A (ko) | 2009-03-30 |
CN101472678A (zh) | 2009-07-01 |
TW200808440A (en) | 2008-02-16 |
JP2009541025A (ja) | 2009-11-26 |
US20090200207A1 (en) | 2009-08-13 |
WO2007147781A1 (fr) | 2007-12-27 |
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Legal Events
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STAA | Information on the status of an ep patent application or granted ep patent |
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