EP1902834A1 - Matériau décoratif - Google Patents

Matériau décoratif Download PDF

Info

Publication number
EP1902834A1
EP1902834A1 EP07005983A EP07005983A EP1902834A1 EP 1902834 A1 EP1902834 A1 EP 1902834A1 EP 07005983 A EP07005983 A EP 07005983A EP 07005983 A EP07005983 A EP 07005983A EP 1902834 A1 EP1902834 A1 EP 1902834A1
Authority
EP
European Patent Office
Prior art keywords
ionizing radiation
curable resin
gloss
resin layer
decorative material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP07005983A
Other languages
German (de)
English (en)
Other versions
EP1902834B1 (fr
Inventor
Hideaki Mori
Kaori Imamichi
Takeshi Nakamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Cosmo Inc
Original Assignee
Toppan Cosmo Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Cosmo Inc filed Critical Toppan Cosmo Inc
Publication of EP1902834A1 publication Critical patent/EP1902834A1/fr
Application granted granted Critical
Publication of EP1902834B1 publication Critical patent/EP1902834B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F7/00—Designs imitating three-dimensional effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/02—Superimposing layers

Definitions

  • the present invention relates to a decorative material to be used for interior and exterior finishing of buildings and architecture, fittings, or surface decorations or the like of furniture. More specifically, the present invention relates to a decorative material which, in the case of a woodgrain pattern for example, expresses uneven irregularities such as vessel parts stereoscopically by differences in surface gloss.
  • a synthetic-resin coated layer which is transparent or semitransparent and which has low gloss is formed on the entire printing surface of the substrate where appropriate patterns including recess patterns are printed. Thereafter, on the surface of the synthetic resin layer except the part which corresponds to the recess patterns, a synthetic-resin coated layer which is transparent or semitransparent and which has high gloss is formed. Needless to say, when the relationship between high and low gloss is reversed, it is possible to obtain a decorative material where the relationship between recesses and salients is reversed.
  • the decorative material which is provided with a surface-protective layer formed of an ionizing radiation-curable resin
  • a surface-protective layer formed of an ionizing radiation-curable resin is known (for example, refer to Patent document 2). Since this surface-protective layer is cured by irradiating an electron beam, blocking does not occur even when coating is carried out with relatively high speed. However, in order to avoid the effects of mutual adhesion with the ink layer or shrinkage due to the curing of resin, a certain coating thickness or an intermediate layer is required.
  • Patent document 1 Japanese Patent Publication No. 3629964
  • Patent document 2 Japanese Patent Publication No. 3756406
  • the present invention is made in view of the above circumstances and its object is to provide a decorative material which can express uneven irregular shapes due to the differences in the surface gloss conditions even when the thickness thereof is thin and which is high in productivity.
  • the present invention adopts the following method in order to solve the above problems.
  • a first aspect of the decorative material according to the present invention is a decorative material provided with a picture pattern corresponding to an expression region, which is a salient or a recess, on a substrate and characterized in that an ionizing radiation-curable resin layer is provided with a stepwise gradation in gloss conditions in the vicinity of the outline of the picture pattern except immediately above thereof and the viscosity of the ionizing radiation-curable resin layer is 0.1 to 1 Pa ⁇ s.
  • this invention is provided with the ionizing radiation-cured resin layer on the surface thereof so as to have a gradation in gloss conditions, it is possible to produce decorative materials expressing uneven irregular shapes where the depth (height) thereof changes continuously, with higher speed. Moreover, since the viscosity of the ionizing radiation-curable resin is 0.1 to 1 Pa ⁇ s, it is possible to favorably express uneven irregular shapes where the depth (height) thereof changes continuously without the ionizing radiation-curable resin being too soft to run off and it is also possible to produce continuously with high speed without difficulties in providing the layer due to the resin being too hard.
  • a second aspect of a decorative material according to the present invention is the aforementioned decorative materials characterized in that a gloss adjusting layer having a gloss after its formation different to that of the ionizing radiation-curable resin layer after the formation thereof and also forms the surface of the aforementioned expression region, which is a recess or a salient, is provided and the ionizing radiation-curable resin layer is provided on the gloss adjusting layer.
  • the ionizing radiation-curable resin layer is made as a high gloss layer and the gloss adjusting layer is made as a low gloss layer for example, uneven irregular shapes expressed due to gloss will be more explicit.
  • the invention also satisfies the effect of stress relaxation at the time of curing the ionizing radiation-curable resin due to this gloss adjusting layer and thus, can maintain excellent design.
  • a third aspect of the decorative material according to the present invention is characterized in that it is the abovementioned decorative material where a base pattern is provided on the entire surface of the substrate and the picture pattern is partially provided in the base pattern.
  • This invention can achieve an excellent design stereoscopically by the base pattern present on the entire surface and the partially provided picture pattern, which expresses a recess or a salient.
  • a fourth aspect of the decorative material according to the present invention is characterized in that it is the abovementioned decorative material where the picture pattern is formed from a water-based ink.
  • this invention uses the water-based ink, it is possible to reduce the amount of volatile organic compounds.
  • a fifth aspect of the decorative material according to the present invention is characterized in that it is the abovementioned decorative material where a sealer layer formed from an aqueous resin is provided between the picture pattern and the substrate.
  • this invention is excellent in adhesive properties among respective layers and is capable of improving various surface resistances.
  • a sixth aspect of the decorative material according to the present invention is characterized in that it is the abovementioned decorative material where the ionizing radiation-curable resin layer is formed from a monomer of (meth)acrylate-based resins.
  • this invention is excellent in adhesive properties among layers with respect to the lower layer after coating while having a favorable viscosity and is capable of improving various surface resistances even when the thickness thereof is thin.
  • a seventh aspect of the decorative material according to the present invention is characterized in that it is the abovementioned decorative material where silicone oil is added to the ionizing radiation-curable resin layer.
  • a decorative material 1 according to the present embodiment is a decorative material where a picture pattern 4 corresponding to an expression region 3, which is a recess or a salient, is provided on a substrate 2.
  • the decorative material 1 has the picture pattern 4 partially provided in a base pattern 5, which is provided on the entire surface of the substrate 2, a gloss adjusting layer 6 provided by covering the picture pattern 4 and which forms the surface of the expression region 3, which is a recess or a salient, and an ionizing radiation-curable resin layer 7 provided in the vicinity of the outline of the picture pattern 4 except the expression region 3, which is a recess or a salient and which is immediately above the picture pattern 4, and which has a stepwise gradation in terms of gloss conditions.
  • a sealer layer 8 formed from an aqueous resin is provided between the picture pattern 4 and substrate 2.
  • the expression region 3, which is a recess or a salient means a region to visually express as a recess or a salient when compared to the part in which the ionizing radiation-curable resin layer 7 is provided.
  • paper such as tissue paper, titanium paper, resin-impregnated paper, flameproof paper, and mineral paper; woven or non-woven fabrics formed from natural fibers or synthetic fibers; substrates based on synthetic resins such as homo- or random polypropylene resins, polyolefin-based resins such as polyethylene resins, copolyester resins, crystalline polyester resins in an amorphous state, polyethylene naphthalate resins, polybutylene resins, acrylic resins such as methylmethacrylate resins and polymethylmethacrylate resins, styrene-based resins, polyamide-based resins, cellulose-based resins, polycarbonate resins, polychlorinated vinyl resins, polychlorinated vinylidene resins, and fluorine resins; wood-based substrates such as a wood veneer, sliced veneer, plywood, glued laminated wood, particle board, and medium density fiber board; mineral substrate
  • materials constituting the base pattern 5 and picture pattern 4 are not particularly limited, together with an appropriate binder resin, printing ink or coating materials, which are formed by dissolving or dispersing coloring agents such as dyes or pigments in an appropriate solvent, are generally used.
  • coloring agents for example, inorganic pigments such as carbon black, titanium white, zinc white, red iron oxide, chrome yellow, iron blue, and cadmium red; organic pigments such as azo pigments, lake pigments, anthraquinone pigments, phthalocyanine pigments, isoindolinone pigments, and dioxazine pigments; or mixtures of two or more of these pigments can be used.
  • inorganic pigments such as carbon black, titanium white, zinc white, red iron oxide, chrome yellow, iron blue, and cadmium red
  • organic pigments such as azo pigments, lake pigments, anthraquinone pigments, phthalocyanine pigments, isoindolinone pigments, and dioxazine pigments
  • dioxazine pigments for example, inorganic pigments such as carbon black, titanium white, zinc white, red iron oxide, chrome yellow, iron blue, and cadmium red
  • organic pigments such as azo pigments, lake pigments, anthr
  • binder resins for example, various synthetic resins such as acrylic resins, styrene resins, polyester resins, urethane resins, polyvinyl resins, alkyd resins, petroleum resins, ketone resins, epoxy resins, melamine resins, fluororesins, silicone resins, cellulose resins, and gum resins, mixtures thereof, or copolymers thereof can be used.
  • synthetic resins such as acrylic resins, styrene resins, polyester resins, urethane resins, polyvinyl resins, alkyd resins, petroleum resins, ketone resins, epoxy resins, melamine resins, fluororesins, silicone resins, cellulose resins, and gum resins, mixtures thereof, or copolymers thereof can be used.
  • a solvent for example, toluene, xylene, cyclohexane, ethyl acetate, butyl acetate, methyl alcohol, ethyl alcohol, isopropyl alcohol, acetone, methyl ethyl ketone, methylisobutylketone, cyclohexanone, water, or the like, or a mixture thereof can be used.
  • agents including various additives such as extender pigments, plasticizers, dispersing agents, surfactants, tackifiers, adhesion auxiliaries, desiccants, curing agents, curing accelerators, or concrete retarders are used where appropriate.
  • the base pattern 5 needs to contain, at least, the picture pattern 4 which corresponds to the expression region 3, which is a recess or a salient.
  • a decorative material 10 as one which is provided with, although not essential, a surface pattern 9 as shown in Fig. 2 in order to confer designs visually recognized as a color pattern, which is independent of uneven surface irregularities, in the vicinity of the outline of, but excluding immediately above, the picture pattern 4 which corresponds to the expression region 3, which is a recess or a salient.
  • the base solid and woodgrain form are provided as the base pattern 5 in the decorative material 1 of the present invention and the vessel pattern is provided as the picture pattern 4 which corresponds to the expression region 3, which is a recess or a salient.
  • the base pattern 5 in the present invention is not limited to woodgrain patterns and it can be appropriately applied to rift patterns, abstract patterns, or the like.
  • Fig. 1 is described so that the picture pattern 4 which corresponds to the expression region 3, which is a recess or a salient, is provided on the surface of the base pattern 5.
  • this does not necessarily define the upper and lower relationship between the two patterns and both patterns may be provided as a continuous picture form on an identical surface or in a manner where the upper and lower relationship between the two is reversed, or a transparent layer (transparent substrate is also possible) or the like may be interposed between the two patterns.
  • the entire base pattern 5 or a part thereof may also be formed by being integrated with the substrate 2 by mixing or infiltrating coloring agents in the substrate 2.
  • the picture pattern 4 corresponding to the expression region 3, which is a recess or a salient, and the base pattern 5 are configured so that the two patterns can be identified in terms of colors.
  • the base pattern 5 and picture pattern 4 are generally formed by appropriate printing methods such as the gravure printing method, offset printing method, screen printing method, electrostatic printing method, and ink-jet printing method.
  • methods are not limited to those above and, for example, the aforementioned base solid may also be formed by coating methods such as the roll coating method, knife coating method, and die coating method.
  • other patterns can also be formed by arbitrary image-forming methods which are conventionally known.
  • the gloss adjusting layer 6 is constituted from printing ink, coating agents, or the like, which are similar to those cited as the aforementioned constituting materials of the base pattern 5 and picture pattern 4. This is with the proviso that, since the gloss adjusting layer 6 needs to be provided with transparency, which makes at least the base pattern 5 and picture pattern 4 possible to be seen through the layer, as a printing ink, coating agents, or the like which form the layer, it is necessary to use those which contain no coloring agents such as dyes or pigments at all or only in a small amount to an extent where the required transparency is not impaired.
  • the gloss adjusting layer 6 is one which constitutes the most outer surface layer of the decorative material 1 in the expression region 3, which is a recess or a salient
  • the layer is preferably constituted from materials having a hardening resin as a major component to achieve surface physical properties required by the decorative material 1 such as abrasion resistance, scratch resistance, solvent resistance, and stain resistance.
  • thermosetting resins such as melamine resins, epoxy resins, aminoalkyd resins, urethane resins, polyester resins, and silicone resins
  • ionizing radiation-curable resins such as acrylic resins can favorably be used.
  • ionizing radiation generally refers to a radiation which imposes ionization effects on substances and includes X-rays, ⁇ -rays, ⁇ -rays (electron rays), and short wavelength ultraviolet rays
  • UV-curable resins due to photoinitiators can also be used, the term also includes long wavelength ultraviolet rays, which do not impose ionization effects.
  • the ionizing radiation-curable resin layer 7 is configured so as to change the gloss conditions thereof continuously or stepwise in the vicinity of the outline of the expression region 3, which is a recess or a salient.
  • the gloss conditions change from one close to that of the surface of the region 3 to that in the part other than the vicinity of the picture pattern 4, which corresponds to the region 3.
  • the ionizing radiation-curable resin layer 7 when expressing the expression region 3 as a recess, is designed so as to have a higher gloss than that of the surface of the region 3.
  • the ionizing radiation-curable resin layer 7 is formed by being provided with a gradation so that in the vicinity of the outline of the region 3, when departing from the outline of the region 3 and proceeding to the inside of the part where the ionizing radiation-curable resin layer 7 is formed, the gloss of the ionizing radiation-curable resin layer 7 gradually becomes higher.
  • the ionizing radiation-curable resin layer 7 when expressing the expression region 3 as a salient, is designed so as to have a lower gloss than that of the surface of the region 3. Moreover, the ionizing radiation-curable resin layer 7 is formed by being provided with a gradation so that in the vicinity of the outline of the region 3, when departing from the outline of the region 3 and proceeding to the inside of the part where the ionizing radiation-curable resin layer 7 is formed, the gloss of the ionizing radiation-curable resin layer 7 gradually becomes lower.
  • the outline of the picture pattern 4 corresponding to the expression region 3, which is a recess or a salient, does not necessarily precisely coincide with the outline of the stair-like region 3 and it may be deviated to the inside or outside of the outline of the stair-like region 3 to some extent. It is also possible to appropriately adjust the virtual appearance of uneven irregularities by positively deviating the outlines of both patterns slightly from each other. In addition, it is also possible to confer changes in virtual appearance of uneven irregularities depending on places by changing directions or distances of deviations between the outlines of both patterns inside the stair-like region 3.
  • resins used for the ionizing radiation-curable resin layer 7 are those having a viscosity of 0.1 to 1 Pa ⁇ s. This is because when the viscosity is within this range, favorable adhesive properties among layers are achieved. In addition, when the viscosity is lower than 0.1 Pa ⁇ s, layers will become too flexible and will easily collapse and when the viscosity exceeds 1 Pa ⁇ s, layers will become stiff and adhesive properties with the adjacent layers will be deteriorated.
  • resins specifically, ionizing radiation-curable monomers, which do not increase the viscosity thereof with time during printing, are used. These resins do not increase the viscosity thereof since a curing reaction does not proceed when they are in a coating-liquid state at normal temperature during printing. On the other hand, since a curing reaction proceeds rapidly after resins are irradiated with ionizing radiation and resins are cured completely, there are advantages such as the lack of generation of blocking due to poor drying even when printed matter is retrieved or laminated.
  • the compounds having ethylenic unsaturated double bonds can be used and these include monofunctional monomers, difunctional monomers, and polyfunctional monomers such as trifunctional monomers.
  • the monomers are those which are not hydrophilic and for example, they do not have any of -CHO group, -OH group, and -COOH group.
  • monofunctional monomers which have ethylenic unsaturated double bonds include 2-(2-ethoxyethoxy)ethyl (meth)acrylate, stearyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, lauryl (meth)acrylate, 2-phenoxyethyl (meth)acrylate, isodecyl (meth)acrylate, isooctyl (meth)acrylate, tridecyl (meth)acrylate, caprolactone (meth)acrylate, ethoxylated nonylphenol (meth)acrylate, propoxylated nonylphenol (meth)acrylate, phenoxyethyl (meth)acrylate, phenoxydiethylene (meth)acrylate, ethylene oxide-modified nonylphenyl (meth)acrylate, methoxytriethylene glycol (meth)acrylate, ethylene oxide 2-ethylhexyl (meth)acrylate,
  • difunctional monomers examples include 1,3-butanediol di(meth)acrylate, 1,4- butanediol di(meth)acrylate, polyethylene glycol di(meth)acrylate, polypropylene glycol di(meth)acrylate, neopentyl glycol di(meth)acrylate, propoxylated neopentyl glycol di(meth)acrylate, ethoxylated neopentyl glycol di(meth)acrylate, neopentyl glycol hydroxypivalate di(meth)acrylate, (hydrogenated) bisphenol A di(meth)acrylate, (hydrogenated) ethylene oxide-modified bisphenol A di(meth)acrylate, (hydrogenated) propylene glycol-modified bisphenol A di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, 2-ethyl-2-butylpropanediol di(meth)
  • polyfunctional monomers include tris(2-hydroxyethyl)isocyanurate tri(meth)acrylate, ethoxylated trimethylolpropane tri(meth)acrylate, propoxylated trimethylolpropane tri(meth)acrylate, propoxylated glyceryl tri(meth)acrylate, pentaerythritol tri(meth)acrylate, trimethylolpropane (meth)acrylate, ethylene oxide-modified trimethylolpropane (meth)acrylate, propylene oxide-modified trimethylolpropane (meth)acrylate, tris(acryloxyethyl) isocyanurate, pentaerythritol tetra(meth)acrylate, ditrimethylolpropane tetra(meth)acrylate, ethoxylated pentaerythritol tetra(meth)acrylate, penta(meth)acrylate ester, and dipent
  • monomers such as urethane (meth)acrylate, polyester (meth)acrylate, polyether (meth)acrylate, and polyacryl (meth)acrylate are desirable since their surface easily becomes smooth after coating due to their low viscosity and anchor effects to the sealer layer 8, base pattern 5, or the like also improve.
  • Silicone oil is added to the ionizing radiation-curable resin layer 7. This is added as an antipollution agent for preventing surface contaminants of the ionizing radiation-curable resin layer 7 from becoming attached or for allowing the attached contaminants to be easily wiped away with various detergents or solvents. Silicone oil is incorporated in the matrix resin constituted from ionizing radiation-curable monomers.
  • silicone oil unmodified silicone oil, amino-modified silicone oil, epoxy-modified silicone oil, carboxy-modified silicone oil, mercapto-modified silicone oil, carbinol-modified silicone oil, methacryl-modified silicone oil, and phenol-modified silicone oil can be used.
  • the amount of silicone oil is preferably 0.01 to 5 weight% when the total weight of ionizing radiation-curable monomers is taken as a standard. This is because when the amount of silicone oil is less than 0.01 weight%, effects of the addition thereof are not achieved and when the amount exceeds 5 weight%, the aqueous resins of the picture pattern 4 or the like are repelled to cause adhesive failures.
  • the gloss of the ionizing radiation-curable resin layer 7 needs to be designed higher than that of the gloss adjusting layer 6.
  • the gloss of the ionizing radiation-curable resin layer 7 needs to be designed lower than that of the gloss adjusting layer 6.
  • gloss-adjusting agents such as silica, alumina, calcium carbonate, and barium sulfate may be added where appropriate.
  • the gradation provided in the ionizing radiation-curable resin layer 7 be a stepwise gradation in terms of changes in gloss conditions as shown in Fig. 1 even when the aim is to express continuous changes in depth (height).
  • gradation since there are many cases where continuous gradation results in a poor sense of tone although the size of uneven irregularities is highly minute (for example, like the case of vessel grooves of wood or the like where stereoscopic vision present in the cross-sectional shape of a natural vessel groove is not sufficiently expressed), it is preferable that gradation be stepwise.
  • a gravure printing method is used and it is carried out by changing the depth or area ratio of the gravure printing plate so that desired gradation is achieved.
  • Other printing methods such as a general offset printing method, screen printing method, electrostatic printing method, and ink jet method are also used where appropriate.
  • gradation is not limited to the gradation due to changes in the coating amount of ionizing radiation-curable resins and it is possible to express gradation due to changes in area ratio of halftone dots or the like (not illustrated) and it is also possible to use changes in the coating amount and changes in the area ratio concomitantly (not illustrated).
  • the surface of the expression region 3 When the expression region 3 is expressed as a recess, the surface of the expression region 3 must be in a low-gloss condition. In order to achieve the condition, as shown in the example in Fig. 1, when the base pattern 5 corresponding to the expression region 3 is exposed in the surface in the region 3, there is a need to adjust the pattern in a low-gloss condition by appropriately adding gloss adjusting agents or the like to printing ink or the like, which forms the base pattern 5. On the other hand, when the expression region 3 is expressed as a salient, there is a need to use printing ink, which makes the surface gloss after printing high, as the printing ink to form the picture pattern 4 corresponding to the region 3.
  • the base pattern 5 when expressing a recess or a salient where slope sections of the outline of the recess or the salient also have identical colors to that of the bottom face or the top face, it is preferable to form the base pattern 5 in the region where the ionizing radiation-curable resin layer 7 reaches the outline of a region, which is outside the expression region 3 and has gradation.
  • the ionizing radiation-curable resin layer 7 reaches the outline of a region, which is outside the expression region 3 and has gradation.
  • a decorative material 1 it is possible to express uneven irregular shapes where the depth (height) changes continuously like vessels of natural wood or the like since the ionizing radiation-curable resin layer 7 is provided on the surface of the decorative material 1 so as to have gradation in gloss conditions.
  • the viscosity of the ionizing radiation-curable resin 0.1 to 1 Pa ⁇ s at this juncture, it is possible to favorably express uneven irregular shapes where the depth (height) thereof changes continuously without the ionizing radiation-curable resin being too soft to run off and it is also possible to produce the decorative material 1 continuously at a high speed without difficulties in providing the layer due to the resin being too hard.
  • the stress generated at the time when the ionizing radiation-curable resin is cured can be favorably relaxed and peeling among layers can favorably be suppressed.
  • the ionizing radiation-curable resin layer 7 as the high gloss layer and by providing the gloss adjusting layer 6 with low gloss between the layer 7 and the picture pattern 4, it is possible to make the expression of uneven irregular shapes due to gloss more distinctly. Furthermore, due to this gloss adjusting layer 6, the stress generated when the ionizing radiation-curable resin is cured can be relaxed and peeling of the picture pattern 4 or the base pattern 5 or the like can be suppressed. For this reason, it is possible to favorably maintain more stereoscopically excellent design achieved by the base pattern 5 on the entire surface and the picture pattern 4, which is partially provided and which expresses a recess or a salient.
  • the sealer layer 8 formed of an aqueous resin is provided on the substrate 2, adhesive properties among respective layers will be excellent and various surface resistances can be improved.
  • silicone oil is added to the ionizing radiation-curable resin layer 7, it is possible to improve the surface stain resistance.
  • gloss conditions of the ionizing radiation-curable resin layer 7 in the part other than the vicinity of the expression region 3, which is a recess or a salient are constant.
  • Tissue paper with a basis weight of 29 g/m 2 (“HPN-29” produced by Tentok Paper Co., Ltd.) was used as the substrate 2.
  • An aqueous urethane-based coating (a mixture of 100 parts of "LW059 SEALER” and 5 parts of "LT109 HARDERNER” both produced by Toyo Ink MFG. Co., Ltd.) was coated on the surface thereof as a sealer layer 8 formed of an aqueous resin so that the coating amount after drying will be 2 g/m 2 .
  • a colored solid layer of one color was printed thereon on the entire surface by gravure printing using an aqueous acrylic resin-based gravure printing ink ("PCW" produced by Toyo Ink MFG. Co., Ltd.) as a water-based ink of the base pattern 5. Furthermore, a woodgrain pattern was printed and a vessel pattern, which conformed with the woodgrain pattern, was sequentially printed as the picture pattern 4 corresponding to the expression region 3, which is a recess or a salient.
  • PCW aqueous acrylic resin-based gravure printing ink
  • a resin (“LT097EB Primer” produced by Toyo Ink MFG. Co., Ltd.) formed from an acrylic resin, in which silica powder was added to adjust the gloss thereof to low, urethane resin, casein, trifunctional monomer, and an additive was coated on the entire surface of the above patterns as the gloss adjusting layer 6 so that the coating amount after drying will be 5 g/m 2 .
  • an ionizing radiation-curable resin (a mixture of 50 weight parts of pentaerythritol tri(meth)acrylate, 50 weight parts of ethoxylated trimethylolpropane (meth)acrylate, and 0.5 weight parts of amino-modified silicone oil) formed from silicone acrylate monomer to achieve high gloss was coated as the ionizing radiation-curable resin layer 7 on the surface except the vessel-pattern part with a coating amount of 4 g/m 2 by providing gradation in the vicinity of the outline of the vessel-pattern layer.
  • an electron beam was irradiated in a nitrogen atmosphere under the irradiation conditions of 45 KGy (5 Mrad) dose, 1.5 kV, 100 mA, and line speed of 200 m/min to cure the ionizing radiation-curable resin.
  • Tissue paper with a basis weight of 29 g/m 2 (“HPN-29” produced by Tentok Paper Co., Ltd.) was used as the substrate 2.
  • a colored solid layer of one color was printed thereon on the entire surface using a gravure printing ink formed of an oil-based acrylic resin ("PCNT” produced by Toyo Ink MFG. Co., Ltd.) as the base pattern 5.
  • PCNT oil-based acrylic resin
  • a woodgrain pattern was printed and a vessel pattern (150 lines in line number of a pattern printing-plate), which conformed with the woodgrain pattern, was sequentially printed as the picture pattern 4 corresponding to the expression region 3, which is a recess or a salient.
  • a coating (a mixture of 100 parts of "EXP-UV60425 mat” and 10 parts of "W325N”) formed from a two-component curable urethane resin, in which silica powder was added to adjust the gloss thereof to low, and a UV-curable resin was coated on the entire surface of the above patterns as the gloss adjusting layer 6 so that the coating amount after drying will be 5 g/m 2 .
  • a UV-curable resin (a mixture of 50 parts of "EXP-UV60425 HighMat” and 50 parts of "EXP-UV60425 gloss” both produced by Dainippon Ink and Chemicals Inc.) formed from a urethane acrylate monomer to achieve high gloss was coated as the ionizing radiation-curable resin layer 7 on the surface except the vessel-pattern part with a coating amount after drying of 2 g/m 2 by providing gradation (line number of 100 lines) in the vicinity of the outline of the vessel-pattern layer.
  • an electron beam-curable colored enamel coating (produced by Toyo Ink MFG. Co., Ltd.) is provided as the surface pattern 9 only on the surface of the picture pattern 4 corresponding to the expression region 3, which is a recess or a salient, the provision was easily carried out without any problems such as gradation collapse or positional deviations.
  • block isocyanate-curable urethane resin produced by Toyo Ink MFG. Co., Ltd.
  • UV-curable resin a mixture of 50 parts of "EXP-UV60425 HighMat” and 50 parts of "EXP-UV60425 gloss” both produced by Dainippon Ink and Chemicals Inc.
  • uneven irregular shapes which had sloping sections where the depth (height) thereof changed continuously, are provided with a line speed of 80 m/min in the vicinity of the region of the picture pattern 4 corresponding to the expression region 3, which is a recess or a salient, blocking occurred at the time of retrieving.
  • the surface pattern 9 was further provided thereafter, gradation collapsed and design properties thereof were impaired.
  • the decorative materials obtained in each of the abovementioned Examples were decorative materials having an appearance of uneven irregularities of vessel grooves, which is analogous to natural vessels, due to the gradation in gloss conditions in the outline section of the vessel pattern and excellent in design properties. Moreover, they could be produced with good workability without generating problems such as the so-called plate fill in during printing, blocking due to poor drying, or trapping.
  • the present invention can be used as a decorative material for interior and exterior finishing of buildings and architecture, fittings, or surface decorations or the like of furniture. More specifically, the present invention can be used as a decorative material which, in the case of a woodgrain pattern for example, expresses uneven irregularities such as vessel parts stereoscopically by differences in surface gloss.
EP07005983A 2006-09-22 2007-03-23 Matériau décoratif Active EP1902834B1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006257232A JP2008074002A (ja) 2006-09-22 2006-09-22 化粧材

Publications (2)

Publication Number Publication Date
EP1902834A1 true EP1902834A1 (fr) 2008-03-26
EP1902834B1 EP1902834B1 (fr) 2011-05-11

Family

ID=38830418

Family Applications (1)

Application Number Title Priority Date Filing Date
EP07005983A Active EP1902834B1 (fr) 2006-09-22 2007-03-23 Matériau décoratif

Country Status (4)

Country Link
US (1) US20080075966A1 (fr)
EP (1) EP1902834B1 (fr)
JP (1) JP2008074002A (fr)
AT (1) ATE508864T1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1977908A3 (fr) * 2007-04-02 2012-05-23 Toppan Cosmo, Inc. Matériau décoratif amélioré
EP2883712A1 (fr) * 2013-12-10 2015-06-17 Unilin, BVBA Revêtement de sol et procédé de fabrication d'un revêtement de sol
EP3640035A1 (fr) * 2018-10-15 2020-04-22 Canon Production Printing Holding B.V. Procédé d'ajustement local de la brillance pendant l'impression d'une image

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4835491B2 (ja) * 2007-03-29 2011-12-14 株式会社トッパン・コスモ 化粧材
JP2011046032A (ja) * 2009-08-26 2011-03-10 Toppan Cosmo Inc 化粧シート
JP5699321B2 (ja) * 2010-03-31 2015-04-08 大日本印刷株式会社 化粧シート
EP3632978A4 (fr) * 2017-06-02 2020-06-03 Toppan Printing Co., Ltd. Corps moulé en résine, stratifié et feuille décorative
JP7383222B2 (ja) * 2019-08-07 2023-11-20 Ｔｏｐｐａｎホールディングス株式会社 化粧紙、化粧材、及び化粧紙の製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5336530A (en) * 1990-08-03 1994-08-09 Dai Nippon Printing Co., Ltd. Process for producing decorative material
US5763048A (en) * 1994-03-31 1998-06-09 Dai Nippon Printing Co., Ltd. Matte decorative sheet having scratch resistance
EP0872338A1 (fr) * 1996-08-28 1998-10-21 Dai Nippon Printing Co., Ltd. Feuille decoree
US6326074B1 (en) * 1998-05-20 2001-12-04 Dai Nippon Printing Co., Ltd. Synchronously embossed decorative sheet and method for producing the same

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2980765B2 (ja) * 1991-07-31 1999-11-22 大日本印刷株式会社 化粧シートの製造方法
JP3269538B2 (ja) * 1993-06-30 2002-03-25 凸版印刷株式会社 立体模様化粧紙の製造方法
JP3585620B2 (ja) * 1995-12-20 2004-11-04 大日本印刷株式会社 化粧材
EP2402157A1 (fr) * 1998-07-14 2012-01-04 Dai Nippon Printing Co., Ltd. Matériau décoratif
JP3629964B2 (ja) * 1998-07-29 2005-03-16 凸版印刷株式会社 化粧材
JP2000326446A (ja) * 1999-05-18 2000-11-28 Toppan Printing Co Ltd 化粧シート及び化粧材
JP2001105541A (ja) * 1999-10-06 2001-04-17 Dainippon Printing Co Ltd 耐摩耗性化粧材
JP4061014B2 (ja) * 2000-09-28 2008-03-12 大日本印刷株式会社 化粧材
JP2003321507A (ja) * 2002-04-30 2003-11-14 Dainippon Ink & Chem Inc 活性エネルギー線硬化性組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5336530A (en) * 1990-08-03 1994-08-09 Dai Nippon Printing Co., Ltd. Process for producing decorative material
US5763048A (en) * 1994-03-31 1998-06-09 Dai Nippon Printing Co., Ltd. Matte decorative sheet having scratch resistance
EP0872338A1 (fr) * 1996-08-28 1998-10-21 Dai Nippon Printing Co., Ltd. Feuille decoree
US6326074B1 (en) * 1998-05-20 2001-12-04 Dai Nippon Printing Co., Ltd. Synchronously embossed decorative sheet and method for producing the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1977908A3 (fr) * 2007-04-02 2012-05-23 Toppan Cosmo, Inc. Matériau décoratif amélioré
EP2883712A1 (fr) * 2013-12-10 2015-06-17 Unilin, BVBA Revêtement de sol et procédé de fabrication d'un revêtement de sol
BE1021743B1 (nl) * 2013-12-10 2016-01-14 Unilin Bvba Vloerkleding en werkwijze voor het vervaardigen
EP3640035A1 (fr) * 2018-10-15 2020-04-22 Canon Production Printing Holding B.V. Procédé d'ajustement local de la brillance pendant l'impression d'une image
US11186098B2 (en) 2018-10-15 2021-11-30 Canon Production Printing Holding B.V. Method for locally adjusting gloss while printing an image

Also Published As

Publication number Publication date
EP1902834B1 (fr) 2011-05-11
US20080075966A1 (en) 2008-03-27
JP2008074002A (ja) 2008-04-03
ATE508864T1 (de) 2011-05-15

Similar Documents

Publication Publication Date Title
EP1902834B1 (fr) Matériau décoratif
JP5003086B2 (ja) 化粧シート
JP3629964B2 (ja) 化粧材
JP6369084B2 (ja) 化粧シート及びこれを用いた化粧板
US8003196B2 (en) Decorative material
JP4894418B2 (ja) 化粧シート
JP4725067B2 (ja) 化粧材
JP7294321B2 (ja) 化粧材
JP4835491B2 (ja) 化粧材
JP4189207B2 (ja) 化粧材及びその製造方法
JP4467696B2 (ja) 化粧材
JP2005212237A (ja) 化粧材
JP2001328228A (ja) 化粧材
JP4725013B2 (ja) 化粧材
JP2002086658A (ja) 化粧材
JPH1128799A (ja) 化粧板およびその製造方法
JP3135319B2 (ja) 高級塗装感を有する化粧材及びその製造方法
JP4162203B2 (ja) 化粧材及びその製造方法
JP7139650B2 (ja) 化粧材
JP7383222B2 (ja) 化粧紙、化粧材、及び化粧紙の製造方法
JP2004195903A (ja) 化粧材
US20230331033A1 (en) Decorative sheet, decorative material, plate, and method of manufacturing decorative sheet
JP2022136462A (ja) 化粧材
JP2024040257A (ja) 化粧材及びその製造方法
JP2022170199A (ja) 化粧紙の製造方法、化粧紙及び化粧材

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR MK YU

17P Request for examination filed

Effective date: 20080627

AKX Designation fees paid

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAC Information related to communication of intention to grant a patent modified

Free format text: ORIGINAL CODE: EPIDOSCIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC MT NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602007014446

Country of ref document: DE

Effective date: 20110622

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20110511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110912

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110911

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110822

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110812

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20120214

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602007014446

Country of ref document: DE

Effective date: 20120214

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120331

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120323

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120331

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110811

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110511

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120323

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20070323

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20150319

Year of fee payment: 9

Ref country code: GB

Payment date: 20150324

Year of fee payment: 9

Ref country code: SE

Payment date: 20150324

Year of fee payment: 9

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 602007014446

Country of ref document: DE

Representative=s name: PATENTANWAELTE MUNK, DE

Ref country code: DE

Ref legal event code: R081

Ref document number: 602007014446

Country of ref document: DE

Owner name: TOPPAN PRINTING CO., LTD., JP

Free format text: FORMER OWNER: TOPPAN COSMO, INC., TOKYO, JP

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20160323

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160324

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20161130

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160323

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160331

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20230213

Year of fee payment: 17

Ref country code: BE

Payment date: 20230216

Year of fee payment: 17

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230530

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240130

Year of fee payment: 18