EP1825052B1 - Fibres de polyolefine teintes, leur utilisation et procede de fabrication desdites fibres - Google Patents

Fibres de polyolefine teintes, leur utilisation et procede de fabrication desdites fibres Download PDF

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Publication number
EP1825052B1
EP1825052B1 EP05817916A EP05817916A EP1825052B1 EP 1825052 B1 EP1825052 B1 EP 1825052B1 EP 05817916 A EP05817916 A EP 05817916A EP 05817916 A EP05817916 A EP 05817916A EP 1825052 B1 EP1825052 B1 EP 1825052B1
Authority
EP
European Patent Office
Prior art keywords
fibres
vat
polyolefin
coloured
plasma
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP05817916A
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German (de)
English (en)
Other versions
EP1825052A1 (fr
Inventor
Frank GÄHR
Thomas Lehr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Deutsche Institute fuer Textil und Faserforschung Stuttgart
Original Assignee
Deutsche Institute fuer Textil und Faserforschung Stuttgart
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Publication date
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Publication of EP1825052A1 publication Critical patent/EP1825052A1/fr
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Publication of EP1825052B1 publication Critical patent/EP1825052B1/fr
Not-in-force legal-status Critical Current
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025—Corona discharge or low temperature plasma
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
    • D06P1/24—Anthraquinone dyes or anthracene nucleus containing vat dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/79—Polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/79—Polyolefins
    • D06P3/793—Polyolefins using vat or sulfur dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2005—Treatments with alpha, beta, gamma or other rays, e.g. stimulated rays

Definitions

  • the invention relates to vat dyes dyed polyolefin fibers, their use for forming a textile and a process for producing such colored polyolefin dyed or dyed fabrics based on polyolefin fibers or of textiles based on colored polyolefin fibers.
  • the object of the invention is therefore to produce advantageous dyed with vat dyes polyolefin fibers, which are characterized by excellent wash, rub and especially light-fastness values.
  • the dyeings are said to be comparable to vat dyeings on cellulose fibers in terms of hue and brilliance with the corresponding values of cellulosic fibers provided with vat dyeings.
  • a particularly suitable method for producing such dyed with vat dyes polyolefin fibers are proposed, the disadvantages of the previously established methods should be excluded, such as the lack of flexibility of spin dyeing, the negative effect on the fabric handle of a pigment dyeing and their poor rubbing fastness and also the poor washing and lightfastnesses of other colors on optionally modified polypropylene.
  • polyolefin fibers dyed with vat dyes which are characterized by a light fastness according to DIN EN ISO 105-B02 (at 50 ° C and 144 h exposure) of at least 5, a wash fastness to DIN EN ISO 105-C08C of at least 4 and a rubbing fastness according to DIN EN ISO 105-X12 dry of at least 4.
  • the light fastness of the polyalefin fibers according to the invention is at least about 6, whose wash fastness is at least 4 to 5 and / or whose rubbing fastness is at least about 4.
  • vat dyes which are particularly advantageous in the context of the invention.
  • a dyeing is preferred with indanthrene dyes. These are dyes that consist of two or more bridged anthraquinone molecules. These dyes prove to be extremely light, washing and weathering in the practice of the present invention.
  • a particularly suitable anthraquinone dye is indanthrene blue.
  • Indanthren brilliant green FFB Indanthren brilliant orange GK
  • Indanthren brilliant orange Indanthren brilliant pink R 5
  • Indanthren brilliant violet R Indanthren-dark blue BOA
  • Indanthren blue BC Indanthren blue RS ,
  • the inventively desired effects are achieved in that the polyolefin fibers have been subjected to a plasma treatment before coloring them with a vat dye.
  • the color yield during dyeing or printing compared with the non-plasma-treated polyolefin fiber increased by at least 55%, in the case of particularly suitable dyes by at least 120%.
  • the type of plasma treatment is not critical. It can take place in the atmospheric plasma (corona) or in the preferred case in the low-pressure plasma. In both cases, preferably oxygen or air plasmas are used.
  • the plasma treatment of the polyolefin materials is carried out until the polyolefin has an oxygen incorporation of at least 10%, in particular at least 20%, in the surface layer to be detected by means of ESCA (electron spectroscopy for chemical analysis), the layer thickness being given as 6 nm.
  • ESCA electron spectroscopy for chemical analysis
  • the invention thus relates to colored with vat dyes polyolefin fibers.
  • the idea according to the invention which is reflected above in the advantageous parameters, is not critically dependent on the type of polyolefin used in each case.
  • the vat dyeing can also be carried out in many ways, but the procedure is in particular the foulard HT process, which is described, for example, in H.-K. Rouette, "Lexikon fur Textilveredelung", Laumann-Verlag, Dülmen, 1995, is described.
  • This means that a suitably concentrated dye liquor is applied to the material, for example by means of a padder, and the dye is subsequently taken up by the respective fiber under the action of, for example, high-temperature or saturated steam.
  • the polyolefin is present in the form of a homo- or copolymer of ethylene, propylene and / or butylene, in particular in the form of a homopolymer of ethylene, propylene and / or butylene.
  • the vat dyed polyolefin fibers of the present invention can be used to particular advantage in forming a textile.
  • the nature of the textile is not relevant to achieving the desirable effects.
  • the polyolefin fibers according to the invention may be present in particular in a textile in the form of a woven, knitted fabric, fleece or fabric. It has proven to be expedient if such textiles contain not only the inventively colored polyolefin fibers integrated. Rather, in individual cases, it is of particular value to additionally include other fibers, i. into the fabrics, knitted fabrics, nonwovens or fabrics. These may be in particular cellulose, polyester and / or polyamide fibers.
  • the cellulose fibers are of particular value, especially if they are in the form of cotton or viscose fibers. Nevertheless, the method is also suitable for fibers based on cellulose esters, in particular cellulose acetates of very different degrees of acetylation.
  • the object of the present invention was also to propose a suitable preparation process for the polyolefin fibers according to the invention which are dyed with vat dyes.
  • the invention also relates to an advantageous process for the production of colored polyolefin fibers or colored textiles based on the colored polyolefin fibers, as described extensively above, after which the polyolefin Polyolefin fiber-based fibers or textiles are subjected to a plasma treatment prior to dyeing with vat dyes.
  • the coloring of the polyolefin fibers with vat dyes is carried out according to the pigment-pad method.
  • the plasma treatment takes place in the form already treated above, ie an oxygen or air plasma treatment is carried out. In this case, the plasma treatment is carried out until the desired state has been established or the particular values of the light fastness, wash fastness and rub fastness which characterize the dyed polyolefin fibers according to the invention have been established.
  • the color yield in the dyeing can be increased by at least 55%, in particular by at least 120%, compared with the non-plasma-treated polyolefin fiber.
  • a polypropylene fabric having a basis weight of 130 g / m 2 each in the dimension of 30 cm (warp) x 15 cm (weft) is used.
  • the fabric is prefixed at 130 ° C for 30 seconds in a suitable tenter.
  • the fixed tissue is subjected to a plasma treatment using the following parameters: Plasma reactor "Domino" of the company Buck Plasma-Electronic (low pressure plasma), Power: 200 W / s Gas pressure: 80 Pa Base pressure: 40 Pa Process gas stream: 160 sccm of oxygen Electrode gap: 8 cm duration: 5 min
  • a nonwoven fabric of the composition 70% viscose / 30% polypropylene with a basis weight of 60 g / m 2 in the dimension of 40 cm x 30 cm is used.
  • the plasma treatment was carried out analogously to example 1.
  • the thermofusion was carried out in a laboratory dryer type LTE from Mathis, Switzerland at 175 ° C. for 2 min and a calibration gap of 2 mm.
  • Dye fleets of CI Vat Yellow 1, CI Vat Red 32 and CI Vat Blue 14 are padded onto the nonwoven at room temperature using a padder (contact pressure 1.0 bar).
  • the composition and concentration of the dye liquors is analogous to Example 1. It is pre-dried for 1 min at 80 ° C and then fixed in hot steam under the conditions described in Example 1.
  • a nonwoven fabric of composition 70% polypropylene / 30% polyethylene having a basis weight of 50 g / m 2 in the dimension of 40 cm x 30 cm is used.
  • the plasma treatment was carried out analogously to Example 1.
  • the thermofusion was carried out analogously to Example 2, but with a 3 mm calibration gap.
  • a dye liquor of CI Vat Yellow 1 (composition and concentration see Example 2) was padded onto the nonwoven at room temperature (contact pressure 1.0 bar).
  • the further work steps were carried out analogously to Example 2.
  • ⁇ u> Table 6: ⁇ / u> (color depths of the polypropylene / polyethylene polyethylene pulp dyed non-woven and with plasma pre-treatment) dye CI Color Index-No. K / S (color depth) without plasma pretreatment K / S (color depth) with plasma pretreatment CI Vat Yellow 1 0.85 1.13
  • Example 2 It is used a prefixed polypropylene fabric analogous to the specification mentioned in Example 1.
  • the material was plasma treated according to the parameters shown in Example 1.
  • Plasma-treated tissue pieces were each treated with the vat C.I. Vat Red 32, C.I. Vat Blue 4 and C.I. Vat Yellow 1 printed in a planographic printing process and the obtained color depths and fastness compared with printing the same dyes on non-plasma-treated polypropylene fabric.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Coloring (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Claims (14)

  1. Procédé de production de fibres de polyoléfine teintes ou de textiles teints à base de fibres de polyoléfine teintes, dans lequel les fibres ou respectivement les textiles sont soumis à un traitement par plasma avant la teinture, caractérisé en ce que les fibres de polyoléfine ou les textiles à base de fibres de polyoléfine sont soumis à un traitement par plasma d'oxygène ou d'air suffisamment longtemps pour que la polyoléfine des fibres ou du textile présente, dans la couche superficielle des fibres d'une épaisseur de couche de 6 nm, une inclusion d'oxygène d'au moins 10 % détectable par analyse ES-CA (électron spectroscopy for chemical analysis), puis les fibres de polyoléfine ou respectivement le textile à base de fibres de polyoléfine sont teints avec des colorants pour cuve d'après la technique de foulardage au pigment, les fibres de polyoléfine teintes obtenues ou respectivement les textiles teints à base de fibres de polyoléfine teintes obtenus étant caractérisés par les particularités suivantes :
    - une solidité à la lumière selon la norme DIN EN ISO 105-B02 (à 50°C et avec exposition à la lumière pendant 144 heures) au moins égale à 5,
    - une solidité au lavage selon la norme DIN EN ISO 105-C08C au moins égale à 4 ainsi qu'
    - une solidité au frottement selon la norme DIN EN ISO 105-X12 à sec au moins égale à 3.
  2. Procédé suivant la revendication 1, caractérisé en ce que la teinture des fibres ou du textile est effectuée au moyen de la technique de foulardage HT.
  3. Procédé suivant l'une des revendications 1 et 2, caractérisé en ce que la teinture est effectuée avec un colorant pour cuve sous forme d'un colorant anthraquinonique.
  4. Procédé suivant la revendication 3, caractérisé en ce que la teinture est effectuée avec du bleu d'indanthrène.
  5. Procédé suivant au moins l'une des revendications 1 à 4, caractérisé en ce que la polyoléfine des fibres se présente sous forme de polyéthylène, de polypropylène et/ou de polybutylène.
  6. Procédé suivant au moins l'une des revendications 1 à 5, caractérisé en ce que le textile se présente sous forme d'un tissu, d'un tricot, d'un voile ou d'une étoffe.
  7. Fibres de polyoléfine teintes avec un colorant pour cuve ou respectivement textiles teints à base de fibres de polyoléfine teintes avec un colorant pour cuve, obtenus d'après le procédé suivant au moins l'une des revendications 1 à 6 et possédant les caractéristiques suivantes :
    - une solidité à la lumière selon la norme DIN EN ISO 105-B02 (à 50°C et avec exposition à la lumière pendant 144 heures) au moins égale à 5,
    - une solidité au lavage selon la norme DIN EN ISO 105-C08C au moins égale à 4 ainsi que
    - une solidité au frottement selon la norme DIN EN ISO 105-X12 à sec au moins égale à 3.
  8. Fibres ou textiles suivant la revendication 7, caractérisés en ce que la solidité à la lumière a une valeur au moins égale à 6 environ et/ou la solidité au lavage a une valeur d'au moins 4 à 5.
  9. Fibres ou textiles suivant la revendication 7 ou 8, caractérisés en ce que les fibres sont teintes avec un colorant pour cuve sous forme d'un colorant anthraquinonique, en particulier de bleu d'indanthrène.
  10. Fibres ou textiles suivant au moins l'une des revendications 7 à 9, caractérisés en ce que la polyoléfine se présente sous forme de polyéthylène, de polypropylène et/ou de polybutylène.
  11. Fibres ou textiles suivant au moins l'une des revendications 7 à 10, caractérisés en ce que le rendement du colorant lors de la teinture, comparativement à la fibre de polyoléfine non traitée par plasma, est élevé d'au moins 55 %, en particulier d'au moins 120 %
  12. Utilisation des fibres suivant au moins l'une des revendications 7 à 11 pour la réalisation d'un textile, en particulier sous forme d'un tissu, d'un tricot, d'un voile ou d'une étoffe.
  13. Utilisation suivant la revendication 12, caractérisée en ce que des fibres de cellulose, de polyester et/ou de polyamide sont présentes en plus des fibres de polyoléfine.
  14. Utilisation suivant la revendication 13, caractérisée en ce que la cellulose est présente sous forme de coton, de fibres de viscose ou sous forme d'un ester de cellulose, en particulier comme acétate de cellulose.
EP05817916A 2004-12-14 2005-12-09 Fibres de polyolefine teintes, leur utilisation et procede de fabrication desdites fibres Not-in-force EP1825052B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200410060143 DE102004060143A1 (de) 2004-12-14 2004-12-14 Gefärbte Polyolefin-Fasern, deren Verwendung sowie Verfahren zu deren Herstellung
PCT/EP2005/013253 WO2006063741A1 (fr) 2004-12-14 2005-12-09 Fibres de polyolefine teintes, leur utilisation et procede de fabrication desdites fibres

Publications (2)

Publication Number Publication Date
EP1825052A1 EP1825052A1 (fr) 2007-08-29
EP1825052B1 true EP1825052B1 (fr) 2009-07-15

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP05817916A Not-in-force EP1825052B1 (fr) 2004-12-14 2005-12-09 Fibres de polyolefine teintes, leur utilisation et procede de fabrication desdites fibres

Country Status (3)

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EP (1) EP1825052B1 (fr)
DE (2) DE102004060143A1 (fr)
WO (1) WO2006063741A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102011110154A1 (de) 2011-08-12 2013-02-14 Deutsche Institute Für Textil- Und Faserforschung Denkendorf Verfahren zur herstellung von oberflächenmodifizierten polyolefin-garnen, die danach erhältlichen polyolefingarne sowie deren verwendung

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3052510A (en) * 1962-09-04 Art of dyeing synthetic polymeric
US3056643A (en) * 1960-09-28 1962-10-02 Hercules Powder Co Ltd Vat dyeing of polypropylene
DE1268580B (de) * 1961-03-09 1968-05-22 Basf Ag Verfahren zum Faerben von Gebilden aus Polyolefinen
US3104150A (en) * 1961-09-27 1963-09-17 Hercules Powder Co Ltd Dyeing with leuco-vat dye esters polypropylene fibers and cellulosic fiber unions therewith
DE2210877A1 (de) * 1972-03-07 1973-09-20 Hoechst Ag Verfahren zum faerben unmodifizierter polyolefinfasern mit kuepen-, leukokuepenester- oder schwefelfarbstoffen
GB2188947A (en) * 1986-04-14 1987-10-14 Shell Int Research Plasma treatment for making non-polar polymeric material dyeable with an acid dye
JPH0397977A (ja) * 1989-09-06 1991-04-23 Kanebo Ltd 繊維布の着色方法
JPH03227464A (ja) * 1990-01-29 1991-10-08 Hodogaya Chem Co Ltd 超高分子量ポリエチレン成形体の染色方法
US5607483A (en) * 1994-07-29 1997-03-04 The Secretary Of State For Defence In Her Britannic Majesty's Government Of The U.K. Of Great Britain & Northern Ireland Dyed materials
WO2000010703A1 (fr) * 1998-08-20 2000-03-02 The University Of Tennessee Research Corporation Traitement au plasma de materiaux polymeres afin d'ameliorer leur receptivite a la teinture

Also Published As

Publication number Publication date
DE502005007722D1 (de) 2009-08-27
WO2006063741A1 (fr) 2006-06-22
EP1825052A1 (fr) 2007-08-29
DE102004060143A1 (de) 2006-07-06

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