EP1664353B2 - Verfahren und anlage zum granulieren von schlacke - Google Patents
Verfahren und anlage zum granulieren von schlacke Download PDFInfo
- Publication number
- EP1664353B2 EP1664353B2 EP04765337A EP04765337A EP1664353B2 EP 1664353 B2 EP1664353 B2 EP 1664353B2 EP 04765337 A EP04765337 A EP 04765337A EP 04765337 A EP04765337 A EP 04765337A EP 1664353 B2 EP1664353 B2 EP 1664353B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- slag
- granulation
- gases
- condensation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002893 slag Substances 0.000 title claims abstract description 49
- 238000000034 method Methods 0.000 title claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 85
- 239000007789 gas Substances 0.000 claims abstract description 56
- 238000005469 granulation Methods 0.000 claims abstract description 34
- 230000003179 granulation Effects 0.000 claims abstract description 34
- 238000002347 injection Methods 0.000 claims abstract description 26
- 239000007924 injection Substances 0.000 claims abstract description 26
- 239000008187 granular material Substances 0.000 claims abstract description 18
- 238000009833 condensation Methods 0.000 claims abstract description 17
- 230000005494 condensation Effects 0.000 claims abstract description 17
- 238000009434 installation Methods 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 238000003723 Smelting Methods 0.000 claims abstract description 6
- 238000002485 combustion reaction Methods 0.000 claims description 15
- 230000004888 barrier function Effects 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims 3
- 239000003546 flue gas Substances 0.000 claims 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010079 rubber tapping Methods 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B3/00—General features in the manufacture of pig-iron
- C21B3/04—Recovery of by-products, e.g. slag
- C21B3/06—Treatment of liquid slag
- C21B3/08—Cooling slag
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2100/00—Handling of exhaust gases produced during the manufacture of iron or steel
- C21B2100/40—Gas purification of exhaust gases to be recirculated or used in other metallurgical processes
- C21B2100/42—Sulphur removal
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/02—Physical or chemical treatment of slags
- C21B2400/022—Methods of cooling or quenching molten slag
- C21B2400/024—Methods of cooling or quenching molten slag with the direct use of steam or liquid coolants, e.g. water
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/02—Physical or chemical treatment of slags
- C21B2400/03—Removing sulfur
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/02—Physical or chemical treatment of slags
- C21B2400/032—Separating slag from liquid, e.g. from water, after quenching
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/05—Apparatus features
- C21B2400/062—Jet nozzles or pressurised fluids for cooling, fragmenting or atomising slag
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/05—Apparatus features
- C21B2400/066—Receptacle features where the slag is treated
- C21B2400/072—Tanks to collect the slag, e.g. water tank
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B2400/00—Treatment of slags originating from iron or steel processes
- C21B2400/05—Apparatus features
- C21B2400/066—Receptacle features where the slag is treated
- C21B2400/074—Tower structures for cooling, being confined but not sealed
Definitions
- the invention relates to a method for granulating slag, in particular from a blast furnace and / or a smelting reduction plant, wherein a granulate-water mixture formed during granulation is fed to a granulation vessel and then to a dewatering plant in which the slag granules are dehydrated, and wherein the Granulating resulting H 2 S-containing vapors and gases are at least partially condensed in a congruent with the Grenulier disposer condensing space by injecting water.
- the air introduced into the system leads in other plant areas according to DE 35 11 958 C to a slight overpressure and passes through Granulatabsch- and other openings as well as over covers in the atmosphere. With the air, however, the harmful gases in concentrations that are above the permitted limits escape uncontrolled into the atmosphere.
- an overpressure is set in the granulating container and in the condenser space below the water injection. This is done by setting the water injection.
- the overpressure has the positive effect that the H 2 S-containing residual gases without forced delivery devices, such as fans and the like., Are passed to the downstream combustion point, ie slag trough.
- the amount of air introduced into the granulator reduces the amount of air and H 2 S cargo discharged from the system.
- the sulfur-containing vapors and gases produced during granulation are precipitated in a condensing tower 10 arranged above the granulation container 4.
- a device 11 for water injection is arranged, which is supplied via a fed from the collecting tank 23 water supply 12 with calcium oxide-containing water.
- a means 13 for collecting water and condensate e.g. formed by water gutters, arranged, which upper a discharge line 14 is connected to the water basin 7c.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Furnace Details (AREA)
- Manufacture Of Iron (AREA)
- Processing Of Solid Wastes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL04765337T PL1664353T5 (pl) | 2003-09-25 | 2004-09-17 | Sposób i instalacja do granulacji żużla |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0152503A AT412650B (de) | 2003-09-25 | 2003-09-25 | Verfahren und anlage zum granulieren von schlacke |
PCT/EP2004/010442 WO2005031008A1 (de) | 2003-09-25 | 2004-09-17 | Verfahren und anlage zum granulieren von schlacke |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1664353A1 EP1664353A1 (de) | 2006-06-07 |
EP1664353B1 EP1664353B1 (de) | 2007-01-17 |
EP1664353B2 true EP1664353B2 (de) | 2011-10-12 |
Family
ID=33136548
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04765337A Expired - Lifetime EP1664353B2 (de) | 2003-09-25 | 2004-09-17 | Verfahren und anlage zum granulieren von schlacke |
Country Status (14)
Country | Link |
---|---|
US (2) | US7600397B2 (ko) |
EP (1) | EP1664353B2 (ko) |
KR (1) | KR101186277B1 (ko) |
CN (1) | CN1856583B (ko) |
AT (2) | AT412650B (ko) |
AU (1) | AU2004276445B2 (ko) |
BR (1) | BRPI0414805A (ko) |
CA (1) | CA2539601A1 (ko) |
DE (1) | DE502004002708D1 (ko) |
ES (1) | ES2280998T5 (ko) |
PL (1) | PL1664353T5 (ko) |
PT (1) | PT1664353E (ko) |
RU (1) | RU2355771C2 (ko) |
WO (1) | WO2005031008A1 (ko) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5055285B2 (ja) | 2005-09-30 | 2012-10-24 | タータ スチール リミテッド | 鋼プラント廃棄物及び廃熱から水素及び(又は)他の気体を製造する方法 |
EP2013139A4 (en) * | 2006-04-28 | 2009-12-16 | Tata Steel Ltd | CONSTRUCTION FOR THE PRODUCTION OF HYDROGEN GAS BY THERMOCHEMICAL DECOMPOSITION OF WATER USING STEEL PLASTER SLABS AND WASTE MATERIALS |
KR100709061B1 (ko) * | 2006-09-29 | 2007-04-18 | 주식회사 티아이엔지니어링건축사사무소 | 건축용 안전창호 구조 |
JP5303977B2 (ja) * | 2008-03-20 | 2013-10-02 | Jfeスチール株式会社 | スラグの処理方法 |
LU91626B1 (en) * | 2009-12-03 | 2011-06-06 | Wurth Paul Sa | Installation and method for processing molten material produced by a metallurgical plant, in particular for processing blast furnace slag |
LU91765B1 (en) * | 2010-12-14 | 2012-06-15 | Wurth Paul Sa | Steam condensation tower for a granulation installation |
CN103060494B (zh) * | 2013-01-09 | 2016-01-27 | 北京世纪源博科技股份有限公司 | 一种蒸汽回收型高炉冲渣水系统 |
CN103060498B (zh) * | 2013-01-09 | 2015-03-11 | 北京世纪源博科技股份有限公司 | 一种高炉冲渣水余热发电系统 |
CN103555870B (zh) * | 2013-10-30 | 2015-07-01 | 江苏沙钢集团有限公司 | 一种无冷却塔型高温炉渣水淬冷凝工艺及系统 |
RU2017110486A (ru) * | 2014-09-21 | 2018-10-01 | Хэтч Лтд. | Газовое распыление расплавленных материалов с использованием побочных отходящих газов |
CN108707709B (zh) * | 2018-08-21 | 2023-07-25 | 北京京诚科林环保科技有限公司 | 一种高炉水渣粒化塔正压粒化装置及正压粒化方法 |
CN109529560A (zh) * | 2018-12-27 | 2019-03-29 | 中冶京诚工程技术有限公司 | 一种高炉水渣系统过滤池蒸汽消白的方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4402492A (en) † | 1982-06-16 | 1983-09-06 | United States Steel Corporation | Burner apparatus for molten metal fume suppression |
US4475720A (en) † | 1983-03-14 | 1984-10-09 | Broom Gilbert R | Casthouse emission control system |
LU88441A1 (fr) † | 1993-12-16 | 1995-07-10 | Wurth Paul Sa | Procédé pour le traitement d'un mélange de vapeurs d'eau et d'air pollué par des gaz sulfurés |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3738820A (en) * | 1970-06-01 | 1973-06-12 | Kinney S Eng Inc | Method of and apparatus for the processing of molten slag |
DE2253806C3 (de) * | 1972-11-03 | 1978-06-15 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Umsetzung des in Gasgemischen enthaltenen Schwefelwasserstoffs mit Schwefeldioxid nach dem Claus-Prozess |
US3912487A (en) * | 1974-06-24 | 1975-10-14 | Mikhail Alexeevich Sharanov | Apparatus for producing granulated slag |
DE3511958A1 (de) * | 1985-04-02 | 1986-10-16 | AJO-Stahlbau GmbH & Co KG, 5905 Freudenberg | Verfahren und einrichtung zum herstellen von schlackensand (granulat) aus hochofenschlacke |
CN1009207B (zh) * | 1986-04-21 | 1990-08-15 | Ajo钢铁制造有限公司 | 由高炉炉渣制造炉渣砂(粒渣)的方法和装置 |
US5082483A (en) * | 1990-06-08 | 1992-01-21 | National Slag Limited | Enclosures for slag pelletization apparatus and method of operation thereof |
ATE134698T1 (de) * | 1991-11-29 | 1996-03-15 | Noell En Und Entsorgungstechni | Verfahren zur thermischen verwertung von abfallstoffen |
AU672698B2 (en) * | 1993-06-30 | 1996-10-10 | Mitsubishi Materials Corporation | Apparatus for water-granulating slag |
US5540895A (en) * | 1994-06-03 | 1996-07-30 | Paul Wurth S.A. | Device for the treatment of mixture of steam and air contaminated with sulphurous gases, formed during the granulation and dehydration of blast furnace slag |
LU88543A1 (fr) * | 1994-10-06 | 1996-04-29 | Wurth Paul Sa | Procédé pour la granulation humide de laitier |
JP2868432B2 (ja) * | 1995-03-08 | 1999-03-10 | ラサ商事株式会社 | 溶鉱炉溶滓の水砕システムにおける有害ガス処理方法および処理設備 |
GB9719512D0 (en) * | 1997-09-12 | 1997-11-19 | Boc Group Plc | Treatment of a combustible gas stream |
JP3947892B2 (ja) * | 1999-06-29 | 2007-07-25 | バブコック日立株式会社 | 硫黄分回収方法及びその硫黄分回収方法を適用したガス化プラント |
CN1140636C (zh) * | 2000-04-07 | 2004-03-03 | 张维田 | 炉渣粒化蒸汽冷凝回收装置 |
DE10152672C2 (de) * | 2001-10-05 | 2003-11-13 | Voest Alpine Ind Anlagen | Schlackengranulierungsanlage |
WO2003087669A1 (fr) * | 2002-04-12 | 2003-10-23 | Ebara Corporation | Incinerateur, incinerateur de gazeification et procede de traitement des dechets |
-
2003
- 2003-09-25 AT AT0152503A patent/AT412650B/de not_active IP Right Cessation
-
2004
- 2004-09-17 US US10/572,775 patent/US7600397B2/en not_active Expired - Fee Related
- 2004-09-17 CN CN2004800278280A patent/CN1856583B/zh not_active Expired - Fee Related
- 2004-09-17 BR BRPI0414805-3A patent/BRPI0414805A/pt active Search and Examination
- 2004-09-17 WO PCT/EP2004/010442 patent/WO2005031008A1/de active IP Right Grant
- 2004-09-17 PL PL04765337T patent/PL1664353T5/pl unknown
- 2004-09-17 AT AT04765337T patent/ATE351927T1/de not_active IP Right Cessation
- 2004-09-17 CA CA002539601A patent/CA2539601A1/en not_active Abandoned
- 2004-09-17 KR KR1020067007716A patent/KR101186277B1/ko not_active IP Right Cessation
- 2004-09-17 ES ES04765337T patent/ES2280998T5/es not_active Expired - Lifetime
- 2004-09-17 PT PT04765337T patent/PT1664353E/pt unknown
- 2004-09-17 RU RU2006113925/02A patent/RU2355771C2/ru not_active IP Right Cessation
- 2004-09-17 DE DE502004002708T patent/DE502004002708D1/de not_active Expired - Lifetime
- 2004-09-17 AU AU2004276445A patent/AU2004276445B2/en not_active Ceased
- 2004-09-17 EP EP04765337A patent/EP1664353B2/de not_active Expired - Lifetime
-
2009
- 2009-08-28 US US12/549,832 patent/US8302430B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4402492A (en) † | 1982-06-16 | 1983-09-06 | United States Steel Corporation | Burner apparatus for molten metal fume suppression |
US4475720A (en) † | 1983-03-14 | 1984-10-09 | Broom Gilbert R | Casthouse emission control system |
LU88441A1 (fr) † | 1993-12-16 | 1995-07-10 | Wurth Paul Sa | Procédé pour le traitement d'un mélange de vapeurs d'eau et d'air pollué par des gaz sulfurés |
Non-Patent Citations (7)
Title |
---|
"Air pollution engineering manual", METALLUUGICAL INDUSTRY, 2000 - 2000, pages 565 - 573 † |
K-H. GROSSPIETSCH ET AL.: "Neue Schlackengranulationsanlage verbessert", STAHL UND EISEN, no. 8, 15 August 2003 (2003-08-15) - 15 August 2003 (2003-08-15), pages 61 - 67 † |
KLAUS GÖRNER, KURT HÜBNER: "Gasreinung und Luftreinhaltung", 2002, SPRINGER-VERLAG, ISBN: 3-540-42006-1, pages: F61 - F65 † |
PAUL N. CHEREMISINOFF: "Air Pollution Control and Design for Industry", 1993, MARCEL DEKKER, INC, USA, ISBN: 0-8247-9057-X, pages: 235 - 252 † |
R. MAHR: "From laphole zone to casthouse arrangement", MODERN BLAST FURNACE DESIGN, August 1978 (1978-08-01) - August 1978 (1978-08-01) † |
ROBERT NOYES: "Pollution prevention technology handbook", 1993, NOYES PUBLICATION, USA, ISBN: 0-8155-1311-9, pages: 177 - 181 † |
W. FRITZ ET AL.: "Reinigung von Abgasen", 1990, VOGEL BUCHVERLAG, ISBN: 3-8023-0244-3, pages: 23-24 - 180-193 † |
Also Published As
Publication number | Publication date |
---|---|
PL1664353T5 (pl) | 2013-02-28 |
WO2005031008A1 (de) | 2005-04-07 |
CN1856583B (zh) | 2010-12-01 |
RU2355771C2 (ru) | 2009-05-20 |
KR20060093337A (ko) | 2006-08-24 |
PT1664353E (pt) | 2007-04-30 |
ES2280998T5 (es) | 2012-02-17 |
US8302430B2 (en) | 2012-11-06 |
AT412650B (de) | 2005-05-25 |
PL1664353T3 (pl) | 2007-06-29 |
CA2539601A1 (en) | 2005-04-07 |
US20090315233A1 (en) | 2009-12-24 |
KR101186277B1 (ko) | 2012-09-27 |
ATA15252003A (de) | 2004-10-15 |
CN1856583A (zh) | 2006-11-01 |
BRPI0414805A (pt) | 2006-11-14 |
EP1664353A1 (de) | 2006-06-07 |
US20070107466A1 (en) | 2007-05-17 |
US7600397B2 (en) | 2009-10-13 |
EP1664353B1 (de) | 2007-01-17 |
RU2006113925A (ru) | 2007-10-27 |
AU2004276445B2 (en) | 2009-11-12 |
AU2004276445A1 (en) | 2005-04-07 |
ES2280998T3 (es) | 2007-09-16 |
ATE351927T1 (de) | 2007-02-15 |
DE502004002708D1 (de) | 2007-03-08 |
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