EP1496310A1 - Schmelzofen, vergasungsschmelzofen und verfahren zur verarbeitung von abfall - Google Patents

Schmelzofen, vergasungsschmelzofen und verfahren zur verarbeitung von abfall Download PDF

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Publication number
EP1496310A1
EP1496310A1 EP03746447A EP03746447A EP1496310A1 EP 1496310 A1 EP1496310 A1 EP 1496310A1 EP 03746447 A EP03746447 A EP 03746447A EP 03746447 A EP03746447 A EP 03746447A EP 1496310 A1 EP1496310 A1 EP 1496310A1
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EP
European Patent Office
Prior art keywords
slag discharge
discharge port
slag
combustion chamber
slagging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP03746447A
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English (en)
French (fr)
Inventor
Nobuya Ebara Corporation AZUMA
Shigeru Ebara Corporation Kosugi
Takashi Ebara Corporation NAKAJIMA
Tetsuya Ebara Corporation ANDO
Toshio Ebara Corporation KOJIMA
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Ebara Corp
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Ebara Corp
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Publication of EP1496310A1 publication Critical patent/EP1496310A1/de
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
    • F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00—Pretreatment
    • F23G2201/40—Gasification
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00—Combustion
    • F23G2202/10—Combustion in two or more stages
    • F23G2202/104—Combustion in two or more stages with ash melting stage
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00—Specific waste
    • F23G2209/20—Medical materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00—Specific waste
    • F23G2209/28—Plastics or rubber like materials
    • F23G2209/281—Tyres
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00—Specific waste
    • F23G2209/30—Solid combustion residues, e.g. bottom or flyash

Definitions

  • the present invention relates to a slagging combustion furnace and a gasification and slagging combustion system for being supplied with a gas produced in a gasification furnace or the like and containing ash and unburned carbon, and combusting the supplied gas at a high temperature to melt the ash into molten slag.
  • a gasification and melting furnace gasification and slagging combustion system which can recover various metals, melt ash to produce molten slag and recover the produced molten slag, and recover energy in the form of heat, electric power or the like has come into the limelight as a waste treatment system.
  • the gasification and slagging combustion system is not a simple incineration treatment, but is a combination of pyrolysis gasification and high-temperature combustion, and is capable of performing material recycling.
  • FIG. 1 is a schematic view showing a conventional gasification andslagging combustion system whichisa combination of a fluidized-bed gasification furnace and a swirling-type slagging combustion furnace.
  • the gasification and slagging combustion system comprises a fluidized-bed gasification furnace 1 and a swirling-type slagging combustion furnace 10.
  • the gasification and slagging combustion system shown in FIG. 1 is a schematic view showing a conventional gasification andslagging combustion system whichisa combination of a fluidized-bed gasification furnace and a swirling-type slagging combustion furnace.
  • wastes are supplied to a fluidized bed 2 and gasified to produce a combustible gas containing unburned carbon and ash and having a temperature of about 500°C to about 600°C in the gasification furnace 1, and the produced combustible gas is introduced into the slagging combustion furnace 10 and combusted by a secondary air at a high temperature under a low air ratio of about 1.3 to about 1.5 to increase a temperature of the interior of the furnace to a melting point of ash or higher (for example, 1300°C or higher, preferably about 1350°C) in the swirling-type slagging combustion furnace 10.
  • a melting point of ash or higher for example, 1300°C or higher, preferably about 1350°C
  • a high-temperature combustion gas generated in the process in which ash content is melted to form molten slag is introduced into a waste heat boiler, a heat exchanger or the like in which thermal energy is recovered.
  • the structure of the slagging combustion furnace affects melting state of ash and stable operation of the slagging combustion furnace, and hence it has been considered that the structure of the slagging combustion furnace is technically important for the overall gasification and slagging combustion system.
  • FIG. 2 is a schematic view of the conventional slagging combustion furnace.
  • reference numeral 10 represents the slagging combustion furnace 10
  • the slagging combustion furnace 10 comprises a primary combustion chamber 11, a secondary combustion chamber 12, and a tertiary combustion chamber 13.
  • a passage which is formed within the slagging combustion furnace and allows a combustion gas 16 to pass therethrough comprises a substantially V-shaped passage as shown by the arrow, and a slag discharge port 17 is formed at the lowermost position of the V-shaped passage.
  • a produced gas 14 produced by gasification in the gasification furnace 1 (see FIG. 1) and containing unburned carbon and ash, or a mixed gas of the produced gas 14 and combustion gas is introduced into the upper part of the primary combustion chamber 11 in a direction tangential to an inner wall surface of the slagging combustion furnace 10.
  • Combustion air 15 is also introduced into the primary combustion chamber 11 in a direction tangential to the inner wall surface of the slagging combustion furnace 10.
  • the produced gas 14 or the mixed gas of the produced gas 14 and the combustion gas is mixed with the combustion air 15, and is combusted while forming a swirling flow of the gas, and moves to the secondary combustion chamber 12 and is combusted at a high temperature of 1200 to 1400°C, preferably about 1350°C in the secondary combustion chamber 12 and then the tertiary combustion chamber 13.
  • exhaust gas 16' is discharged from the tertiary combustion chamber 13, and is then introduced into a waste heat boiler or the like (not shown in the drawing) .
  • reference numerals 18 and 19 represent an auxiliary burner, respectively.
  • both of the produced gas 14 and the combustion air 15 are introduced in the direction tangential to the inner wall surface of the furnace.
  • one of the produced gas 14 and the combustion air 15 may be introduced in a direction tangential to the inner wall surface of the furnace to thus generate a swirling flow of the gas, and the other of the produced gas 14 and the combustion air 15 may be blown into the formed swirling flow, thereby combusting while having mixed with each other.
  • the produced gas 14 containing unburned carbon and ash and the combustion air 15 introduced into the upper part of the primary combustion chamber 11 are mixed with each other while forming a swirling flow of the gas in the primary combustion chamber 11, and the produced gas 14 is combusted in the primary combustion chamber 11, and then moves to the secondary combustion chamber 12 and the tertiary combustion chamber 13.
  • Ash is collected on the inner wall surface of the furnace due to the swirling flow in the furnace, and is melted at a high temperature to form molten slag 20.
  • the molten slag flows downwardly on the furnace bottom, and falls down from the slag discharge port 17 through a slag discharge chute 30 to the outside of the furnace. Then, the discharged molten slag 20 is brought into contact with slag cooling water (not shown in the drawing) to form water-quenched slag, and the granulated slag is recovered.
  • FIG. 3 is a view showing the furnace bottom having the slag discharge port of the slagging combustion furnace in an example.
  • the molten slag 20 flowing downwardly on the wall surface of the slagging combustion furnace 10 is collected at the furnace bottom, and falls down along an inner wall surface 17a of the slag discharge port 17.
  • the inner wall surface 17a of the slag discharge port 17 is concentratedly exposed to the molten slag 20 having a high temperature to cause damage of the inner wall surface 17a due to melting.
  • the slag discharge port 17 is a boundary between the high-temperature secondary and tertiary combustion chambers 12 and 13, and the low-temperature slag discharge chute 30 (the slag discharge chute 30 is cooled to a low temperature because slag cooling water is in the lower part of the slag discharge chute 30), and hence refractory material is subjected to severe conditions because of the formation of temperature gradient and is liable to be damaged or broken.
  • the inner wall of the slag discharge port 17 is integrally formed with the inner wall of the slagging combustion furnace 10, the replacement work of the inner wall of the slag discharge port 17 is not easy and is troublesome.
  • the inner wall of the slag discharge port 17 is formed by refractory material which is resistant to a thermal wear and a high temperature as preventive measures against a thermal wear and a thermal damage.
  • the inner wall of the slag discharge port 17 is integrally formedwith the inner wall of the slagging combustion furnace 10, it has been difficult to form only the inner wall of the slag discharge port 17 by refractory material which is resistant to a thermal wear and a high temperature.
  • the refractory material which is resistant to a thermal wear and a high temperature is expensive, it is uneconomical to form the entire inner wall of the slagging combustion furnace 10 by the refractory material which is resistant to a thermal wear and a high temperature.
  • water tubes may be provided on the inner wall of the slag discharge port 17.
  • the inner wall surface 17a of the slag discharge port 17 is cooled excessively, and hence the molten slag 20 is adhered to the inner wall surface 17a and solidified thereon to form aggregated slag 21 as shown in FIG. 3.
  • the slag discharge port 17 is clogged with the aggregated slag.
  • the refractory material if the refractory material is not dried and burned, the refractory material does not display its innate strength. Therefore, when the refractory material is cooled excessively by the water tubes, the refractory material is liable to be damaged or broken due to a shortage of strength.
  • FIG. 4 is a second view showing the slag discharge port of the slagging combustion furnace 10 in another example.
  • the combustion gas 16 which flows at the upstream side of the slag discharge port 17 along the upper surface 17b at the outer circumferential portion around the slag discharge port 17 collides with the inner wall surface 17a of the slag discharge port 17 to thus generate a turbulent flow of the gas in the slag discharge port 17.
  • This turbulent flow has a bad influence on discharge conditions of the molten slag discharged through the slag discharge port 17.
  • the molten slag 20 is adhered to the inner wall surface 17a of the slag discharge port 17 and solidified thereon to form aggregated slag 21 (see FIG. 3).
  • the slag discharge port 17 is clogged with the aggregated slag, or the combustion gas 16 containing harmful components is discharged through the slag discharge port 17 to the outside of the slagging combustion furnace, thus contaminating slag cooling water.
  • the present invention has been made in view of the above drawbacks. It is therefore an object of the present invention to provide a slagging combustion furnace and a gasification and slagging combustion system which allows an inner wall of a slag discharge port to be replaced easily with a new one if the inner wall of the slag discharge port is damaged by melting, allows the inner wall of the slag discharge port to be less susceptible to a thermal wear or a breakage, and can prevent molten slag from being adhered to the inner wall of the slag discharge port or being solidified thereon due to an excessive cooling of the slag discharge port.
  • Another object of the present invention is to provide a slagging combustion furnace and a gasification and slagging combustion system in which a turbulent flow of the gas is not generated in the slag discharge port of the slagging combustion furnace and discharge conditions of the molten slag are not affected.
  • Still another object of the present invention is to provide a slagging combustion furnace and a gasification and slagging combustion system which allows adhesion or solidification of the molten slag at the slag discharge port to be detected, can prevent the slag discharge port from being clogged, or can dissolve clogging of the slag discharge port.
  • a slagging combustion furnace comprising: a combustion chamber for combusting a combustible gas containing ash and melting the ash; and a slag discharge port for discharging molten slag produced by melting the ash; wherein the slag discharge port is formed by refractory material which is replaceable.
  • a slag discharge port is formed by a replaceable slag discharge port block which is a distinct member different from a furnace wall of a slagging combustion furnace
  • the slag discharge port block can be produced in advance using refractory material having a high resistance to a thermal wear and a high temperature through a predetermined manufacturing process (for example, a forming process and a drying process) in a plant.
  • a predetermined manufacturing process for example, a forming process and a drying process
  • the slag discharge port block is composed of refractory material (for example, high chromium refractory material) which is resistant to a thermal wear and a high temperature, the wall of the slag discharge port can be prevented from thermal wear or breakage. Further, since the portion around the slag discharge port is formed by the slag discharge port block, the slag discharge port is not cooled excessively because the refractory material is not required to be cooled or slight cooling of the refractory material is sufficient by water tubes, unlike a conventional discharge port, thus preventing molten slag from being adhered to the inner wall of the slag discharge port or being solidified thereon.
  • refractory material for example, high chromium refractory material
  • the slag discharge port comprises an opening formed at a central portion of a slag discharge port block, and at least one slag discharge groove extending from an outer peripheral portion of the slag discharge port block at the upstream side of a flow of combustion gas to the slag discharge port is formed in an upper surface of the slag discharge port block.
  • a slag discharge groove extending from an outer periphery of the slag discharge port block at an upstream side of a combustion gas passage to the slag discharge port is formed in an upper surface of the slag discharge port block, molten slag flowing downwardly on the inner wall surface of the slagging combustion furnace flows through the slag discharge groove into the slag discharge port, and falls down through the slag discharge port.
  • the discharge position of the molten slag is fixed.
  • the molten slag flows concentratedly, even if the scale of system or operational condition of the system is such that the amount of slag to be generated is small, the molten slag is less susceptible to being cooled.
  • the molten slag is prevented from being adhered to the surface of the slag discharge port block or being solidified thereon.
  • the upper surface of the slag discharge port block is a slant surface which is inclined downwardly toward the slag discharge port, and an upper end of an outer wall forming the slag discharge port at the upstream side of the flow of the combustion gas is higher than an upper end of the inner wall forming the slag discharge port at the downstream side of the flow of the combustion gas.
  • the upper surface of the slag discharge port block is formed into a slant surface which is inclined downwardly toward the slag discharge port, and the height of the inner wall of the slag discharge port at the upstream side of a flow of the combustion gas is higher than the height of the inner wall of the slag discharge port at the downstream side of the flow of the combustion gas, the combustion gas which has flowed into the upper surface of the slag discharge port block at the upstream side of the flow of the combustion gas passes through a location above the slag discharge port, and flows along the upper surface of the slag discharge port at the downstream side of the slag discharge port.
  • the combustion gas does not collide with the inner wall surface of the slag discharge port, the combustion gas can be prevented from flowing into the slag discharge port. Further, the gas flownear the slag discharge port is smoothed, and hence a fall position of the discharged molten slag is not deviated. If this deviation is large, the slag is attached to the inner surface of the slag discharge chute.
  • the upper surface of the slag discharge port block is a slant surface which is inclined downwardly toward an outer circumferential portion of the slag discharge port block.
  • the combustion gas which has flowed into the upper surface of the slag discharge port block at the upstream side of the flow of the combustion gas moves toward the slag discharge port in an upward flow.
  • the combustion gas is prevented from flowing into the slag discharge port.
  • the upper surface of the slag discharge port block is formed into the slant surface which is inclined downwardly toward the outer periphery of the slag discharge port block, molten slag attached to the upper surface is entirely collected at the outer circumferential portion, and molten slag flowing downwardly on the inner wall surface of the slagging combustion furnace is collected at the outer circumferential portion of the slag discharge port block. Then, the molten slag flows through the slag discharge groove into the slag discharge port, and falls down through the slag discharge port. Thus, the molten slag is prevented from being adhered to the surface of the slag discharge port block or being solidified thereon.
  • the slag discharge port block comprises a plurality of block pieces.
  • the slag discharge port block is composedof apluralityofblockpieces, the slag discharge port block can be easily produced and can be easily transported. Further, even if the slag discharge port block is damaged or broken, only the block piece which has been damaged or broken can be replaced. Thus, the replacement of the block piece is facilitated.
  • a gasification and slagging combustion system comprising: a gasification furnace for gasifyingwastes to produce a combustible gas containing the ash and the unburned carbon; and a slagging combustion furnace for combusting the combustible gas containing ash and unburned carbon and melting the ash; the slagging combustion furnace comprising any one of the above slagging combustion furnaces.
  • the slagging combustion furnace As described above, as a slagging combustion furnace of a gasification and slagging combustion system, by using any of the above slagging combustion furnaces, the slagging combustion furnace which exhibits the above features and good operational efficiency can be constructed.
  • a slagging combustion furnace comprising: a combustion chamber for combusting a combustible gas containing ash and melting the ash; and a slag discharge port for discharging molten slag produced by melting the ash; wherein the height of an inner wall forming the slag discharge port is higher at the upstream side of a flow of combustion gas than at the downstream side of the flow of the combustion gas.
  • the combustion gas which has flowed along the upper surface at the upstream side of the slag discharge port passes through a location above the slag discharge port, and reaches the upper surface at the downstream side of the slag discharge port.
  • the combustion gas flows smoothly without causing the combustion gas to collide with the inner wall of the slag discharge port and without generating a turbulent flow at the location near the slag discharge port, unlike the conventional, the flow of the combustion gas does not affect adversely the discharge state of the molten slag. Because the combustion gas passes through a location above the slag discharge port, and a flow direction of the combustion gas is changed by the upper surface at the downstream side of the slag discharge port, the amount of the combustion gas flowing into the slag discharge port can be greatly reduced.
  • an upper surface at an outer circumferential portion around the slag discharge port is a slant surface inclined upwardly toward the slag discharge port, and at least one slag discharge groove extending to the slag discharge port is formed in the slant surface at the upstream side of the flow of the combustion gas.
  • the upper surface at an outer circumferential portion around the slag discharge port is formed into a slant surface which is inclined upwardly toward the slag discharge port, and the height of the inner wall of the slag discharge port and the inclination angle of the slant surface at the upstream side of the flow of the combustion gas are set such that the combustion gas flowing along the slant surface at the upstream side reaches the slant surface at the downstream side, the combustion gas which has flowed into the upper surface at the upstream side of the slag discharge port passes though a location above the slag discharge port, and reaches the upper surface at the downstream side of the slag discharge port.
  • the combustion gas flows smoothly without causing the combustion gas to collide with the inner wall of the slag discharge port and without generating a turbulent flow at the location near the slag discharge port, the flow of the combustion gas does not affect adversely the discharge state of the molten slag.
  • the combustion gas which has flowed into the upper surface at the upstream side of the slag discharge port moves toward the slag discharge port in an upward flow.
  • the combustion gas is prevented from flowing into the slag discharge port.
  • a slag discharge groove extending from a slant surface at the upstream side of the combustion gas passage to the slag discharge port is formed in the upper surface at an outer circumferential portion around the slag discharge port, molten slag flowing downwardly on the inner wall of the slagging combustion furnace flows through the slag discharge groove into the slag discharge port.
  • the discharge position of the molten slag is fixed. Because molten slag flows concentratedly through a slag discharge groove, even if the scale of system or operational condition of the system is such that the amount of slag to be generated is small, the molten slag is less susceptible to being cooled. Thus, the molten slag is prevented from being adhered to the surface of the radially outer portion of the slag discharge port or being solidified thereon.
  • a waste treatment method comprising: gasifying wastes to produce a combustible gas containing ash in a fluidized-bed furnace; combusting the combustible gas and melting the ash to form molten slag in a slagging combustion furnace, the slagging combustion furnace comprising a primary combustion chamber, a secondary combustion chamber and a tertiary combustion chamber; trapping the molten slag on an inner wall surface of the primary combustion chamber and flowing the trapped molten slag downwardly into the secondary combustion chamber; flowing the molten slag on the inner wall surface of the secondary combustion chamber and discharging the molten slag through a slag discharge groove formed in a slag discharge port block to a slag discharge port formed in the slag discharge port block, the slag discharge port block being disposed at a lowermost part of the secondary combustion chamber, the slag discharge groove being formed at the primary combustion chamber side; trapping mol
  • the molten slag is concentratedly discharged through the slag discharge groove and part of combustion gas flows through the slag discharge groove to prevent the slag from being cooled.
  • a waste treatment method comprising: gasifying wastes to produce a combustible gas containing ash in a fluidized-bed furnace; combusting the combustible gas and melting the ash to form molten slag in a slagging combustion furnace, the slagging combustion furnace comprising a primary combustion chamber, a secondary combustion chamber and a tertiary combustion chamber; trapping the molten slag on a wall surface of the primary combustion chamber and flowing the trapped molten slag downwardly into the secondary combustion chamber; flowing the molten slag on the wall surface of the secondary combustion chamber to a slag discharge groove and discharging the molten slag through the slag discharge groove, a slag discharge port block disposed at a lowermost part of the secondary combustion chamber having a slag discharge groove at the primary combustion chamber side; trapping molten slag on a wall surface of the tertiary combustion chamber from combustion gas introduced
  • the slag discharge port and a portion around the slag discharge port can be prevented from being cooled by the steam, and can be kept at a high temperature.
  • a waste treatment method comprising: gasifying wastes to produce a combustible gas containing ash in a fluidized-bed furnace; combusting the combustible gas and melting the ash to form molten slag in a slagging combustion furnace, the slagging combustion furnace comprising a primary combustion chamber, a secondary combustion chamber and a tertiary combustion chamber; trapping the molten slag on a wall surface of the primary combustion chamber and flowing the trapped molten slag downwardly into the secondary combustion chamber; flowing the molten slag on the wall surface of the secondary combustion chamber to a slag discharge groove and discharging the molten slag through the slag discharge groove, a slag discharge port block disposed at a lowermost part of the secondary combustion chamber having the slag discharge groove at the primary combustion chamber side; trapping molten slag on a wall surface of the tertiary combustion chamber from combustion gas introduced into
  • a pressure differential between the interior of the slag discharge chute and the interior of the secondary combustion chamber is detected, and if the pressure differential exceeds a set value, then an inclination of clogging of the slag discharge port by attachment of slag and solidification of the slag is judged, and the slag discharge port and a portion around the slag discharge port are heated by a secondary combustion chamber burner to prevent the slag discharge port from being clogged.
  • a waste treatment apparatus comprising: a fluidized-bed furnace for gasifying wastes to produce a combustible gas containing ash; a slagging combustion furnace for combusting the combustible gas and melting the ash to form molten slag, the slagging combustion furnace comprising a primary combustion chamber, a secondary combustion chamber, a tertiary combustion chamber, and a slag discharge port block at a lowermost part of the secondary chamber and having a slag discharge groove at the primary combustion chamber side; wherein the molten slag is trapped on a wall surface of the primary combustion chamber and the trapped molten slag flows downwardly into the secondary combustion chamber, the molten slag flows on the wall surface of the secondary combustion chamber to the slag discharge groove and the molten slag is discharged from the slag discharge groove, molten slag is trapped on a wall surface of the tertiary combustion chamber from combustion gas introduced
  • a pressure differential between the interior of the slag discharge chute and the interior of the secondary combustion chamber is detected, and if the pressure differential exceeds a set value, then an inclination of clogging of the slag discharge port by attachment of slag and solidification of the slag is judged, and the slag discharge port and a portion around the slag discharge port are heated by a secondary combustion chamber burner to prevent the slag discharge port from being clogged.
  • FIG. 5 is a view showing a slag discharge port and its vicinity of a slagging combustion furnace according to the present invention.
  • a slag discharge port block 22 is provided at the furnace bottom between the secondary combustion chamber 12 and the tertiary combustion chamber 13 in the slagging combustion furnace 10.
  • Reference numeral 23 represents water tubes 23 provided under the slag discharge port block 22.
  • FIGS. 6A through 6C show the slag discharge port block 22, and FIG. 6A is a cross-sectional view (taken along line VI A -VI A of FIG. 6B), FIG. 6B is a plan view, and FIG. 6C is a cross-sectional view (taken along line VI C -VI C of FIG. 6B).
  • the slag discharge port block 22 is made of refractory material which is resistant to a thermal wear and a high temperature.
  • the refractory material comprises a high chromium refractory material containing chromium of 60% ormore.
  • the slag discharge port block 22 has a slag discharge port 17 at the central portion thereof.
  • the upper surface 22a of the slag discharge port block 22 is formed into a slant surface which is inclined downwardly toward the slag discharge port 17, and an inner circumferential surface 22c constituting an inner wall surface of the slag discharge port 17 is formed into a vertical surface.
  • the height h 1 at the upstream side (the arrow C side) of a flow of the combustion gas 16 is higher than the height h 2 at the downstream side (the arrow D side) of the flow of the combustion gas 16 (h 1 >h 2 ).
  • the slag discharge port block 22 has a slag discharge groove 22d formed in the upper surface 22a such that the slag discharge groove 22d extends from the outer periphery at the upstream side of the flow of the combustion gas 16 to the slag discharge port 17.
  • the width of the slag discharge groove 22d is wider at the outer circumferential side than at the slag discharge port 17 side, and the slag discharge groove 22d has a substantially semicircular cross section.
  • the combustion gas 16 flowing from the secondary combustion chamber 12 to the tertiary combustion chamber 13 flows into the upper surface 22a of the slag discharge port block 22 from the upstream side (the arrow C side) of the slag discharge port, and flows through a location above the slag discharge port 17 to the downstream side (the arrow D side) of the slag discharge port.
  • the height h 1 at the upstream side is higher than the height h 2 at the downstream side (h 1 >h 2 ). Therefore, as shown in FIG.
  • an inclination angle of the upper surface 22a at the upstream side is set such that the combustion gas 16 which has passed through the location above the slag discharge port 17 does not collide with the inner circumferential surface 22c, and hence the combustion gas 16 flows along the upper surface 22a at the downstream side into the tertiary combustion chamber 13. Therefore, the combustion gas 16 is prevented from being flowing into the slag discharge port 17.
  • the slag discharge port block 22 is composed of a distinct member different from the furnace wall of the slagging combustion furnace, the slag discharge port block 22 is not cooled excessively by the water tubes 23, and thus the molten slag 20 is not adhered to the slag discharge port block and is not solidified thereon due to an excessive cooling. Further, since the slag discharge groove 22d extending from the outer periphery at the upstream side to the slag discharge port 17 is formed in the upper surface 22a of the slag discharge port block 22, the molten slag 20 flowing downwardly on the inner wall surface of the slagging combustion furnace 10 collects in the slag discharge groove 22d, and then flows into the slag discharge port 17. Thus, the molten slag 20 is prevented from being adhered to the surface of the slag discharge port block 22 and being solidified thereon.
  • the number of the slag discharge grooves 22d may be one or plural.
  • the length of the inner circumferential surface 22c of the slag discharge port block 22 constituting the inner wall surface of the slag discharge port 17 is preferably short in view of preventing the molten slag 20 from being adhered thereto or solidified thereon.
  • the height h of the slag discharge port block 22 should be short.
  • FIG. 8 is a view showing a slag discharge port and its vicinity of a slagging combustion furnace according to the present invention.
  • FIG. 9A is a cross-sectional view of the slag discharge port block (cross-sectional view taken along line IX A -IX A of FIG. 9B), and
  • FIG. 9B is a plan view of the slag discharge port block 22 shown in FIG. 8.
  • the slag discharge port block 22 has an upper surface 22a which is a slant surface inclined downwardly toward the outer circumferential portion thereof.
  • a slag discharge groove 22d extending from an outer periphery at the upstream side of a flow of the combustion gas to the slag discharge port 17 is formed in the upper surface 22a.
  • the upper surface 22a of the slag discharge port block 22 is formed into the slant surface which is inclined downwardly toward the outer periphery of the slag discharge port block 22, molten slag attached to the upper surface 22a is entirely collected at the outer circumferential portion of the slag discharge port block 22. Then, the collected molten slag flows together with molten slag 20 flowing on the inner wall surface of the secondary combustion chamber 12 and the tertiary combustion chamber 13 of the slagging combustion furnace 10 into the connecting portion between the inner wall surface of the slagging combustion furnace 10 and the outer circumferential surface of the slag discharge port block 22.
  • the molten slag 20 flows through the slag discharge groove 22d into the slag discharge port 17, and falls down through the slag discharge port 17.
  • the number of the slag discharge grooves 22d may be one or plural.
  • the combustion gas 16 which has flowed into the upper surface 22a at the upstream side of the slag discharge port block 22 moves toward the slag discharge port 17 in an upward flow (see FIG. 9A).
  • the combustion gas 16 flows through a location above the slag discharge port 17, and hence the combustion gas 16 is prevented from flowing into the slag discharge port 17.
  • the upper surface of the slag discharge port block is formed into a slant surface which is inclined downwardly toward the outer periphery of the slag discharge port block, molten slag attached to the upper surface is entirely collected at the outer circumferential portion of the slag discharge port block, and molten slag flowing downwardly on the inner wall surface of the slagging combustion furnace is collected at the outer circumferential portion of the slag discharge port block. Then, the molten slag flows through the slag discharge groove 22d into the slag discharge port 17, and falls down through the slag discharge port 17. Thus, the molten slag is prevented from being adhered to the surface of the slag discharge port block and being solidified thereon.
  • the slag discharge port block 22 is produced in advance from refractory material through a forming process and a drying process as a precast block in a plant.
  • refractory material for example, high chromium refractory material containing chromium of 60% or more
  • the slag discharge port block 22 comprises a plurality of block pieces, which have been produced through the above forming process and drying process, then production of the block pieces, and transportation of the block pieces are facilitated, and only damaged or broken block pieces can be replaced.
  • the slag discharge port block 22 comprises a circular disk in the above embodiment, the slag discharge port block 22 may comprise an elliptical disk or a rectangular parallelepiped so as to fit the structure of the slagging combustion furnace 10.
  • FIG. 10 is a view showing a slag discharge port of a slagging combustion furnace according to another embodiment of the present invention. As shown in FIG. 10, a slag discharge port 17 is provided at the furnace bottom between the secondary combustion chamber 12 and the tertiary combustion chamber 13 of the slagging combustion furnace 10 .
  • the upper surface 17b of the furnace bottom at an outer circumferential portion around the slag discharge port 17 is formed into a slant surfacewhich is inclined downwardly toward the slag discharge port 17, and the height h 1 of the inner wall surface of the slag discharge port 17 at the upstream side of a flow of the combustion gas 16 is higher than the height h 2 of the inner wall surface of the slag discharge port 17 at the downstream side of the flow of the combustion gas 16 (h 1 >h 2 ).
  • FIG. 11 is an enlarged view showing an essential part of FIG. 10.
  • an inclination angle ⁇ of the upper surface 17b at the upstream side of the flow of the combustion gas 16, the height h 1 of the innerwall surface of the slag discharge port 17 at the upstream side of the flow of the combustion gas 16, and the height h 2 at the downstream side of the flow of the combustion gas 16 are set such that the combustion gas 16 flowing on the upper surface 17b at the upstream side of the slag discharge port 17 passes through a location above the slag discharge port 17, and reaches the upper surface 17b at the downstream side of the slag discharge port 17.
  • the combustion gas 16 which has flowed into the upper surface 17b at the upstream side of the slag discharge port 17 passes though a location above the slag discharge port 17 in a smooth stream without generating a turbulent flow at the location near the slag discharge port 17. Therefore, the flow of the combustion gas 16 does not affect adversely the discharge state of the molten slag 20 flowing into the slag discharge port 17. Further, the combustion gas 16 can be prevented from being discharged through the slag discharge port 17 to the outside of the furnace.
  • FIG. 12 is a view showing a slag discharge port and its vicinity of a slagging combustion furnace according to the present invention.
  • FIG. 13A is a cross-sectional view showing the slag discharge port shown in FIG. 12, and
  • FIG. 13B is a plan view showing the slag discharge port shown in FIG. 12.
  • the upper surface 17b of the furnace bottom at an outer circumferential portion around the slag discharge port 17 is formed into a slant surface which is inclined upwardly toward the slag discharge port 17.
  • a slag discharge groove 17d extending from an outer periphery at the upstream side of a flow of the combustion gas to the slag discharge port 17 is formed in the upper surface 17b.
  • the upper surface 17b at the outer circumferential portion around slag discharge port 17 is formed into the slant surface which is inclined upwardly toward the slag discharge port 17, molten slag 20 attached to the upper surface is entirely collected at the radially outer side of the slag discharge port 17, and molten slag flowing downwardly on the inner wall surface of the slagging combustion furnace is collected at the radially outer side of the slag discharge port 17.
  • the molten slag 20 is prevented from being adhered to the upper surface 17b and being solidified thereon.
  • a gasification and slagging combustion system comprises a gasification furnace for gasifying wastes to produce a gas containing ash and unburned carbon
  • the gasification furnace may comprise an internal circulating fluidized-bed gasification furnace, an external circulating fluidized-bed gasification furnace, a kiln furnace, or the like.
  • the swirling-type slagging combustion furnace has been described as a slagging combustion furnace, in the case where the present invention is characterized by the height of the slag discharge port and/or the inclination angle of the upper surface around the slag discharge port to prevent clogging of the slag discharge port of the slagging combustion furnace, the slagging combustion furnace is not limited to the swirling-type slagging combustion furnace, and may be any type of slagging combustion furnace.
  • FIG. 14 is a view showing a slagging combustion furnace according to another embodiment of the present invention.
  • a slag discharge port block 32 is disposed at the lowermost position of the secondary combustion chamber, and a slag discharge groove 32d is formed in the slag discharge port block 32 only at the primary combustion chamber 11 side.
  • FIGS. 15A through 15C show the slag discharge port block
  • FIG. 15A is a perspective view of the slag discharge port
  • FIG. 15B is a cross-sectional view taken along line XV B -XV B of FIG. 15A
  • FIG. 15C is a cross-sectional view taken along line XV C -XV C of FIG. 15A.
  • the slag discharge port block 32 has the slag discharge groove 32d which faces the primary combustion chamber 11.
  • the slag discharge port block 32 is disposed at the bottomportion of the secondary combustion chamber 12 which is an end portion of the primary combustion chamber 11.
  • molten slag 20 which has flowed on the inner wall surface of the slagging combustion furnace 10 is collected at the location around the slag discharge port block 32, and then is discharged from the slag discharge groove 32d. Because the discharge of molten slag is concentratedly carried out by the slag discharge groove 32d, the molten slag is prevented from being cooled. Further, since the slag discharge groove 32d is formed at the upstream side (the primary combustion chamber side) of a flow of the combustion gas 16, part of the combustion gas 16 flows through the slag discharge groove 32d, thus keeping the molten slag 20 at a high temperature.
  • FIG. 16 is a view showing a detailed structure of the embodiment.
  • FIGS. 17A and 17B are cross-sectional views showing the manner in which molten slag flows through the slag discharge port.
  • a line 40 is provided to connect a slag discharge chute 30 and the tertiary combustion chamber 13, and a dust collector 41 and a fan 42 are provided in the line 40.
  • the slag discharge chute 30 constitutes a'water quenching trough which cools molten slag 20 discharged through the slag discharge port by slag cooling water to form water-quenched slag.
  • the supply position of the mixed gas which is drawn from the slag discharge chute and is supplied to the slagging combustion furnace 10 is not limited to the tertiary combustion chamber 13.
  • the line 40 can be constructed such that the line 40 connects the slag discharge chute and at least one of a duct connecting the gasification furnace and the slagging combustion furnace, the primary combustion chamber, the secondary combustion chamber, the tertiary combustion chamber, and a flue provided upstream of a waste heat boiler.
  • the dust collector 41 and the fan 42 are provided in the line 40, and a warm-up device may be further provided.
  • the slag discharge port 17 can be prevented from clogging and the molten slag can be smoothly discharged through the slag discharge port 17 to the slag discharge chute 30 and then the water reservoir 43 as shown in FIGS. 16 and 17A.
  • the mixed gas contains unburned carbon and the like, such unburned carbon and the like can be combusted and treated, and hence the mixed gas can be properly treated.
  • the mixed gas is warmed up to a temperature of about 200°C or higher, preferably about 300°C or higher so as not to cause a remarkable temperature drop in the slagging combustion furnace, even if the mixed gas is supplied to the slagging combustion furnace.
  • the slag discharge port tends to be clogged with the slag adhesion and solidification.
  • it is important to avoid an inclination of clogging of the slag discharge port because if there is an indication of decreasing an opening area of the slag discharge port, the clogging of the slag discharge port rapidly progresses due to the following vicious circle.
  • the vicious circle is as follows: As the opening area of the slag discharge port is reduced, draft resistance (pressure loss) of the combustion gas 16 which passes through the slag discharge port is increased.
  • the pressure differential between the interior of the slag discharge chute 30 and the interior of the secondary combustion chamber 12 is detected by the pressure instrument 45, and if the pressure differential exceeds a set value, an inclination of clogging of the slag discharge port is judged, and the slag discharge port and a portion around the slag discharge port are heated by a secondary combustion chamber burner 46.
  • a signal indicative of a pressure differential measured by the pressure instrument 45 is sent to a controller (not shown) through a first signal transmitting means.
  • the controller judges whether the pressure differential is equal to or larger than a set value, and if the pressure differential is equal to or larger than the set value, then the controller sends a starting signal for starting the secondary combustion chamber burner 46 to the secondary combustion chamber burner 46 through a second signal transmitting means.
  • This arrangement can prevent the slag discharge port and a portion around the slag discharge port from being clogged.
  • the present invention is applicable to a slagging combustion furnace and a gasification and slagging combustion system for being supplied with a gas produced in a gasification furnace or the like and containing ash and unburned carbon, and combusting the supplied gas at a high temperature to melt ash into molten slag.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Gasification And Melting Of Waste (AREA)
EP03746447A 2002-04-12 2003-04-10 Schmelzofen, vergasungsschmelzofen und verfahren zur verarbeitung von abfall Withdrawn EP1496310A1 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2002110984 2002-04-12
JP2002110984 2002-04-12
JP2002113818 2002-04-16
JP2002113818 2002-04-16
PCT/JP2003/004568 WO2003087669A1 (fr) 2002-04-12 2003-04-10 Incinerateur, incinerateur de gazeification et procede de traitement des dechets

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EP1496310A1 true EP1496310A1 (de) 2005-01-12

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US (1) US20040237861A1 (de)
EP (1) EP1496310A1 (de)
JP (1) JPWO2003087669A1 (de)
KR (1) KR20040095194A (de)
AU (1) AU2003236057A1 (de)
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WO (1) WO2003087669A1 (de)

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AT412650B (de) * 2003-09-25 2005-05-25 Voest Alpine Ind Anlagen Verfahren und anlage zum granulieren von schlacke
JP4969186B2 (ja) * 2006-09-14 2012-07-04 Ｊｘ日鉱日石金属株式会社 産業廃棄物の処理方法及び産業廃棄物の処理設備
JP5016471B2 (ja) * 2007-12-19 2012-09-05 株式会社神鋼環境ソリューション 溶融炉
KR100990042B1 (ko) * 2010-05-31 2010-10-29 지에스건설 주식회사 슬래그 용융 산소버너 및 이를 이용한 용융로
CN102226528A (zh) * 2011-04-24 2011-10-26 陈金明 生活垃圾热解气化处理成套设备
US9989251B2 (en) 2013-01-21 2018-06-05 Conversion Energy Systems, Inc. System for gasifying waste, method for gasifying waste
JP6369161B2 (ja) * 2013-12-13 2018-08-08 株式会社Ihi タール改質炉
JP6413157B1 (ja) * 2017-04-28 2018-10-31 三菱重工環境・化学エンジニアリング株式会社 ガス化溶融システムの閉塞防止装置及びガス化溶融システムの閉塞防止方法
KR102302136B1 (ko) 2020-10-29 2021-09-14 주식회사케이.피.씨 가스화 용융로용 출탕장치

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US20040237861A1 (en) 2004-12-02
CA2456335A1 (en) 2003-10-23
KR20040095194A (ko) 2004-11-12
WO2003087669A1 (fr) 2003-10-23
JPWO2003087669A1 (ja) 2005-08-18
AU2003236057A1 (en) 2003-10-27

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