EP1395470A1 - Balai d'essuie-glace - Google Patents

Balai d'essuie-glace

Info

Publication number
EP1395470A1
EP1395470A1 EP02732391A EP02732391A EP1395470A1 EP 1395470 A1 EP1395470 A1 EP 1395470A1 EP 02732391 A EP02732391 A EP 02732391A EP 02732391 A EP02732391 A EP 02732391A EP 1395470 A1 EP1395470 A1 EP 1395470A1
Authority
EP
European Patent Office
Prior art keywords
polyethylene
wiper
lip
wiper blade
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP02732391A
Other languages
German (de)
English (en)
Inventor
Andreas Vogt
Lutz Mueller
Ulrich Hasenkox
Guido Klamt
Wilma Dierkes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Robert Bosch GmbH
Original Assignee
Robert Bosch GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Robert Bosch GmbH filed Critical Robert Bosch GmbH
Priority to EP20080105696 priority Critical patent/EP2048048A3/fr
Priority to EP20050100133 priority patent/EP1522472B1/fr
Publication of EP1395470A1 publication Critical patent/EP1395470A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00—Cleaning of vehicles
    • B60S1/02—Cleaning windscreens, windows or optical devices
    • B60S1/04—Wipers or the like, e.g. scrapers
    • B60S1/32—Wipers or the like, e.g. scrapers characterised by constructional features of wiper blade arms or blades
    • B60S1/38—Wiper blades
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B05D1/06—Applying particulate materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
    • B05D1/22—Processes for applying liquids or other fluent materials performed by dipping using fluidised-bed technique
    • B05D1/24—Applying particulate materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/26—Processes for applying liquids or other fluent materials performed by applying the liquid or other fluent material from an outlet device in contact with, or almost in contact with, the surface
    • B05D1/265—Extrusion coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60S—SERVICING, CLEANING, REPAIRING, SUPPORTING, LIFTING, OR MANOEUVRING OF VEHICLES, NOT OTHERWISE PROVIDED FOR
    • B60S1/00—Cleaning of vehicles
    • B60S1/02—Cleaning windscreens, windows or optical devices
    • B60S1/04—Wipers or the like, e.g. scrapers
    • B60S1/32—Wipers or the like, e.g. scrapers characterised by constructional features of wiper blade arms or blades
    • B60S1/38—Wiper blades
    • B60S2001/3827—Wiper blades characterised by the squeegee or blade rubber or wiping element
    • B60S2001/3829—Wiper blades characterised by the squeegee or blade rubber or wiping element characterised by the material of the squeegee or coating thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2321/00—Characterised by the use of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31909—Next to second addition polymer from unsaturated monomers

Definitions

  • the invention is based on a wiper blade for a windshield wiper, in particular for a windshield wiper of a motor vehicle, according to the type defined in the preamble of claim 1 and a method for producing a wiper blade according to the type defined in the preamble of claim 7.
  • a wiper blade of the type mentioned in the introduction is known from practice and comprises a squeegee which is formed with a squeegee lip.
  • the squeegee or the squeegee lip consists of a rubber material that is made, for example, on the basis of natural rubber.
  • Squeegees or squeegee lips of known wiper blades have the disadvantage that when they are pressed onto a glass in a conventional windshield they have a relatively high dry friction coefficient ⁇ t r 'a and the like.
  • the wiper blade according to the invention for a windshield wiper in particular for a windshield wiper of a motor vehicle, with the features according to the preamble of claim 1, in which the wiper rubber lip is partially made of polyethylene, has the advantage that the use of polyethylene as a material for the wiper rubber lip low dry friction values ⁇ tx can be achieved ..
  • the squeegee lip can either be coated with polyethylene and / or contain polyethylene in volume.
  • the polyethylene is PE-UHMW.
  • PE-UHMW ie polyethylene with an ultra-high molecular weight, is particularly suitable for coating squeegee lips, since it already has a low dry friction coefficient as a solid material.
  • a solid material sample made of PE-UHMW with a contact length of 8 mm and a load of 0.128 N on a rotating glass shaft that moves at 0.1 m / s has a dry friction coefficient ⁇ t r of 0.21.
  • PE-UHMW bonds firmly to the rubber material by diffusion. If the PE-UHMW is applied to the rubber material as a powder, it sinters during vulcanization. PE-UHMW, in particular, adheres to a rubber material in such a way that the polyethylene-rubber composite tears in the composite from a certain load.
  • the polyethylene of the wiper blade according to the invention can be PE-HD, ie high-density polyethylene, or also PE-X, ie cross-linked polyethylene.
  • PE-X is melted onto a rubber material in the manufacture of the wiper blade according to the invention and thermally crosslinked during vulcanization.
  • the invention also relates to a method for producing a wiper blade for a windshield wiper, which comprises a squeegee with a squeegee lip. In this method, the squeegee lip is made by vulcanizing a rubber material together with polyethylene.
  • the rubber material can be made on the basis of natural rubber. However, it is also conceivable to use synthetic rubber materials as the base material for the squeegee lip.
  • the vulcanization takes place under the conditions customary for vulcanizing a rubber.
  • the polyethylene is preferably in powder form as the starting material, specifically with a grain size of approximately 0.1 to 30 ⁇ m.
  • the rubber material is coated with polyethylene before vulcanization.
  • the vulcanization of the molded part coated with polyethylene can then be carried out in a molding tool.
  • the vulcanized workpiece made of the rubber material and the polyethylene is easy to demold.
  • the coating of the rubber material with polyethylene before the vulcanization can take place in such a way that the molded rubber material is coated with a dispersion containing polyethylene particles or that the rubber material is dusted with polyethylene powder.
  • a conventional electrostatic powder coating process is particularly suitable for applying a polyethylene powder.
  • the unvulcanized rubber material is advantageously dusted over its entire surface with PE powder. However, partial coverage is possible.
  • the polyethylene can also be applied to the rubber material using a fluidized bed.
  • the rubber material is extruded hot and sticky from an extruder head.
  • the rubber material then passes through an opening into a low-concentration fluidized bed made of very fine PE-UHMW powder with a grain size between 0.1 ⁇ m and 15 ⁇ m, then leaves the fluidized bed through an opening and is then blown with clean purge air. This removes the polyethylene particles that do not adhere to the rubber material.
  • the purge air can also be used to operate the fluidized bed.
  • 'unvulcanized rubber material is pressed in a hot press with stainless steel tool, for example, at a temperature of 180 ° C and a pressure of 70 bar for a period of 10 seconds in shape, then removed and cooled with water. After drying, the partially vulcanized molded rubber part is thinly dusted on both sides with PE-UHMW powder. Then the dusted molding is at a pressure of 70 bar, a temperature of 180 ° C for a period of 5 minutes in one vulcanized to the rubber mold corresponding mold.
  • the rubber material and the polyethylene can also be connected to one another by a coextrusion process.
  • a polyethylene melt, polyethylene film, polyethylene monofilament or polyethylene cord is fed in at least in the area of the squeegee lip of the squeegee. Then the rubber material and the polyethylene attached to it are vulcanized together.
  • the wiper rubber with the wiper rubber lip by an injection molding process.
  • a film, a monofilament or a cord made of polyethylene is introduced into an injection molding prior to injection molding, or else the injection mold is coated with a dispersion or a powder made of polyethylene.
  • the squeegee lip is expediently produced from a mixture which comprises the rubber material and the polyethylene.
  • the mixture contains between 1% and 50% polyethylene powder, in particular PE-UHMW powder.
  • Figure 1 is a schematic representation of a wiper blade in cross section
  • FIG. 2 is a cross-sectional view of a second embodiment of a wiper blade
  • Figure 3 shows a third embodiment of a wiper blade in cross section
  • Figure 4 shows a fourth embodiment of a wiper blade.
  • FIG. 1 shows a wiper blade which consists of a wiper lip 2 made of rubber material, which has a wiper edge 5, a head part 3 made of rubber material, which is only partially shown here, and a so-called folding web 4 made of rubber material, which is arranged between the head part 3 and the wiper lip 2 is.
  • the wiper lip 2, the head part 3 and the folding web 4 are provided with a surface which is formed from a polyethylene layer 1 which, for the sake of clarity, is compared to the wiper lip 2, the head part 3 and the transfer bridge 4 is shown enlarged.
  • the polyethylene layer 1 consists of PE-UHMW, ie of ultra-high molecular weight polyethylene.
  • the wiper blade according to FIG. 1 is produced in such a way that first partially vulcanized rubber material is pressed in an extruder by means of a tool in the form of a wiper blade, then dusted with PE-UHMW powder and then vulcanized.
  • the vulcanization conditions correspond to the usual vulcanization conditions.
  • the material properties of the wiper rubber lip are such that, in a measurement in which the wiper blade 1 is in contact with a rotating glass plate and wiping speeds and pressure conditions are present as in a motor vehicle, dry friction values ⁇ tr between 0.32 and 0.48 can be achieved.
  • the exemplary embodiment of a wiper blade shown in FIG. 2 essentially comprises the same components as the wiper blade according to FIG. 1. However, the wiper blade according to FIG. 2 differs from that according to FIG. 1 by a so-called wiper edge 5, which is free of polyethylene.
  • the embodiment of a wiper blade shown in Figure 3 also includes essentially the same components as the embodiment of Figure 1, but differs from the latter in that the. the wiper lip 2 formed wiping edge 5, the folding bridge 4 and the head part 3 are free of polyethylene and the Wiper lip 2 is coated only in its lateral areas adjacent to the wiping edge 5, ie is only partially coated with polyethylene.
  • FIG. 4 shows a wiper blade which essentially comprises a head part 3 made of rubber material, only partially shown, a folding web 4 made of rubber material adjoining the head part 3 and a wiper lip 6 with a wiper edge 5.
  • the wiper lip 6 consists of rubber material, in which polyethylene in the form of PE-UHMW is embedded.
  • the wiper lip 6 is made from a starting material that contains about 40% polyethylene.
  • the squeegee is an extrusion.
  • the squeegee can also be produced in a known manner by an extrusion process or by compression molding.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

L'invention concerne un balai d'essuie-glace pour un essuie-glace, en particulier pour un essuie-glace d'un véhicule automobile, lequel balai d'essuie-glace comprend une raclette en caoutchouc présentant une lèvre d'essuyage (2). L'objectif de cette invention est d'obtenir un coefficient de frottement à sec réduit. A cet effet, cette lèvre d'essuyage (2) est partiellement constituée de polyéthylène.
EP02732391A 2001-05-23 2002-04-12 Balai d'essuie-glace Ceased EP1395470A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP20080105696 EP2048048A3 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace
EP20050100133 EP1522472B1 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10125045 2001-05-23
DE2001125045 DE10125045A1 (de) 2001-05-23 2001-05-23 Wischerblatt
PCT/DE2002/001365 WO2002094624A1 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace

Related Child Applications (2)

Application Number Title Priority Date Filing Date
EP20080105696 Division EP2048048A3 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace
EP20050100133 Division EP1522472B1 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace

Publications (1)

Publication Number Publication Date
EP1395470A1 true EP1395470A1 (fr) 2004-03-10

Family

ID=7685795

Family Applications (3)

Application Number Title Priority Date Filing Date
EP20080105696 Withdrawn EP2048048A3 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace
EP02732391A Ceased EP1395470A1 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace
EP20050100133 Expired - Lifetime EP1522472B1 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP20080105696 Withdrawn EP2048048A3 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP20050100133 Expired - Lifetime EP1522472B1 (fr) 2001-05-23 2002-04-12 Balai d'essuie-glace

Country Status (11)

Country Link
US (1) US20040148728A1 (fr)
EP (3) EP2048048A3 (fr)
JP (1) JP2004525032A (fr)
KR (1) KR20040002978A (fr)
CN (2) CN100418813C (fr)
BR (1) BR0209978B1 (fr)
CZ (1) CZ300569B6 (fr)
DE (1) DE10125045A1 (fr)
ES (1) ES2493625T3 (fr)
PL (1) PL209748B1 (fr)
WO (1) WO2002094624A1 (fr)

Families Citing this family (21)

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Publication number Priority date Publication date Assignee Title
DE10227994A1 (de) * 2002-06-22 2004-01-08 Robert Bosch Gmbh Wischblatt zum Reinigen von Scheiben insbesondere von Kraftfahrzeugen
EP1561656B1 (fr) * 2004-02-09 2011-11-30 Robert Bosch Gmbh Balai d'essuie-glace et méthode pour sa fabrication
DE102007034328A1 (de) * 2007-07-24 2009-01-29 Robert Bosch Gmbh Strangextrudat sowie Verfahren zu seiner Herstellung und Verwendung
DE102008004636A1 (de) * 2008-01-16 2009-07-23 Robert Bosch Gmbh Verfahren zur Herstellung von Strangprofilen
DE102008041077A1 (de) * 2008-08-07 2010-02-11 Robert Bosch Gmbh Wischleiste
DE102009000072B4 (de) 2009-01-08 2024-03-14 Robert Bosch Gmbh Wischblatt
DE102009003234B4 (de) * 2009-05-19 2024-05-16 Robert Bosch Gmbh Verfahren zur Herstellung eines Wischgummis, Wischgummi und Verwendung von mit einem Adhäsionsmittel beschichteten Polymerpartikeln
DE102009026914A1 (de) * 2009-06-12 2010-12-16 Robert Bosch Gmbh Verfahren zur Beschichtung eines Strangprofils
CA2710851A1 (fr) * 2009-08-07 2011-02-07 James B. Defrank Essuie-glace
KR101684724B1 (ko) * 2010-04-28 2016-12-08 페더랄-모굴 에스.아. 차창 와이퍼 장치
US8443483B2 (en) * 2010-08-30 2013-05-21 GM Global Technology Operations LLC Wiper blade for vehicle window wiper
DE102012204749B4 (de) * 2012-03-26 2023-05-25 Robert Bosch Gmbh Wischgummi-Herstellung mittels überkritischem Fluid
DE102012209233A1 (de) * 2012-05-31 2013-12-05 Robert Bosch Gmbh Wischgummiprofil und Verfahren zur Herstellung desselben
JP6301646B2 (ja) 2012-12-25 2018-03-28 アスモ株式会社 車両用ワイパ装置
JP6447355B2 (ja) * 2014-06-20 2019-01-09 株式会社デンソー ブレードラバーの製造方法及びブレードラバー
US10414379B2 (en) 2014-12-18 2019-09-17 Kimblade Co., Ltd. Wiper blade
WO2016098970A1 (fr) * 2014-12-18 2016-06-23 주식회사 킴블레이드 Balai d'essuie-glace
KR101693832B1 (ko) * 2016-06-17 2017-01-06 주식회사 킴블레이드 단공형 각도 유지형 와이퍼 블레이드
DE102017007186A1 (de) * 2017-07-27 2019-01-31 Robert Bosch Gmbh Reinigungsvorrichtung
JP2021102689A (ja) * 2019-12-25 2021-07-15 三井化学株式会社 粉体塗料および該粉体塗料の塗装品
JP2021102690A (ja) * 2019-12-25 2021-07-15 三井化学株式会社 粉体塗料および粉体塗料の塗装品

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US4638525A (en) * 1984-07-30 1987-01-27 Toyoda Goseki Co., Ltd. Wiper blade rubber
US5977229A (en) * 1995-10-02 1999-11-02 Hoechst Aktiengesellschaft Hydrophilically modified polyethylene resins
US6004496A (en) * 1996-02-22 1999-12-21 Specialty Silicone Products, Inc. Method of making a silicone rubber windshield wiper
WO2002081582A2 (fr) * 2001-04-05 2002-10-17 Robert Bosch Gmbh Composant de laque lubrifiante, laque lubrifiante et procede pour enduire des elastomeres tels que des raclettes d'essuie-glace

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* Cited by examiner, † Cited by third party
Title
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BR0209978B1 (pt) 2011-05-31
WO2002094624A8 (fr) 2004-01-29
EP2048048A3 (fr) 2009-05-13
KR20040002978A (ko) 2004-01-07
CN1511094A (zh) 2004-07-07
BR0209978A (pt) 2004-04-06
US20040148728A1 (en) 2004-08-05
CN100523063C (zh) 2009-08-05
EP1522472B1 (fr) 2014-06-11
CZ300569B6 (cs) 2009-06-17
EP1522472A2 (fr) 2005-04-13
CN100418813C (zh) 2008-09-17
ES2493625T3 (es) 2014-09-12
JP2004525032A (ja) 2004-08-19
CZ20033192A3 (en) 2004-04-14
DE10125045A1 (de) 2002-12-05
EP2048048A2 (fr) 2009-04-15
CN1676310A (zh) 2005-10-05
PL209748B1 (pl) 2011-10-31
EP1522472A3 (fr) 2006-08-09
PL366743A1 (en) 2005-02-07
WO2002094624A1 (fr) 2002-11-28

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