EP1390329A2 - Paraffine microcristalline - Google Patents

Paraffine microcristalline

Info

Publication number
EP1390329A2
EP1390329A2 EP02732741A EP02732741A EP1390329A2 EP 1390329 A2 EP1390329 A2 EP 1390329A2 EP 02732741 A EP02732741 A EP 02732741A EP 02732741 A EP02732741 A EP 02732741A EP 1390329 A2 EP1390329 A2 EP 1390329A2
Authority
EP
European Patent Office
Prior art keywords
paraffin
microcrystalline
paraffins
catalyst
particular according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02732741A
Other languages
German (de)
English (en)
Other versions
EP1390329B1 (fr
Inventor
Michael Matthäi
Günter Hildebrand
Helmuth Schulze-Trautmann
Thorsten Butz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hywax GmbH
Original Assignee
Sasol Wax GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sasol Wax GmbH filed Critical Sasol Wax GmbH
Publication of EP1390329A2 publication Critical patent/EP1390329A2/fr
Application granted granted Critical
Publication of EP1390329B1 publication Critical patent/EP1390329B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S208/00—Mineral oils: processes and products
    • Y10S208/95—Processing of "fischer-tropsch" crude

Definitions

  • the invention relates to a microcrystalline paraffin, its production and its use.
  • Microwaxes known consists of a mixture of saturated hydrocarbons which are solid at room temperature and have a chain length distribution of C 25 to C 80 .
  • microcrystalline paraffins contain many branched iso-alkanes and alkyl-substituted cycloalkanes (naphthenes) as well as - albeit generally small - fractions of aromatics.
  • the content of iso-alkanes and naphthenes is between 40 and 70% determined according to the EWF standard
  • the solidification range is between 50 and 100 ° C according to DIN ISO 2207.
  • the needle penetration has values between 2 x 10 _1 and 160 x 10 _1 mm according to DIN 51579. The solidification point and the needle penetration are used to distinguish between plastic and hard paraffin among the microcrystalline paraffins.
  • 35 stalline paraffins are easy to form and knead and have solidification points between 65 and 80 ° C and penetration values from 10 to 30 x 10 _1 mm.
  • the oil content can be up to 5%.
  • the hard microcrystalline paraffins are tough and weakly adhesive with solidification points of 80 to 95 ° C and penis
  • Microcrystalline paraffins have a high molecular weight and thus high boiling points. So far, they have been obtained from the residues of vacuum distillation of petroleum, in particular in the production of lubricating oil (residue waxes), as well as from excretions of the petroleum during its production, transport and storage, in technologically very complex and cost-intensive processes with several Stages, for example deasphalting, solvent extraction, dewaxing, deoiling and refining.
  • the de-oil for example deasphalting, solvent extraction, dewaxing, deoiling and refining.
  • microcrystalline paraffins contain sulfur, nitrogen and oxygen compounds as impurities. As a result, they are not completely odorless and have a dark yellow to dark brown color.
  • the necessary refining is carried out by bleaching (technical applications) or by hydrorefining (applications in the food and pharmaceutical industries).
  • Microcrystalline paraffins are mainly used as a mixture component in Pa ⁇
  • .0 raffin or wax mixtures used. However, they are mostly used in areas up to 5%. The main aim is to increase the hardness and melting point of these mixtures and to improve flexibility and oil retention. Typical applications are, for example, the production of waxes for impregnation, Be ⁇
  • zeolites Omega zeolite, ZSN-5, X zeolite, Y zeolite and other zeolites.
  • DE 695 15 959 T2 describes the hydroisomerization of wax-containing feedstocks to products which are suitable for the production of lubricating oils.
  • a temperature of 270 ° to 360 ° C and a pressure of 500 to 1,500 psi or from 3.44 MPa to 10.36 MPa are used.
  • the catalyst is based on a catalyzing metal component on a porous, heat-resistant metal oxide support (see page 2, paragraph 1), in particular on 0.1 to 5% by weight of platinum on aluminum oxide or zeolites, such as e.g. Offretit, Zeolite X, Zeolite Y, ZSM -5, ZSM-2 etc. (see page 3, middle).
  • the feed material to be isomerized can be any wax or wax-containing material, in particular also a Fischer-Tropsch wax (see page 5, center).
  • the hydrogen is fed to the reactor at a rate of 1,000 to 10,000 SCF / bbl and the wax with 0.1 to 10 LHSV (see page 6, center).
  • the isomerization product is liquid (see page 7, line 7). It can be fractionated by distillation or by treatment with solvents, e.g. with a MEK / toluene mixture (see page 7, last paragraph).
  • All of the liquid product from the isomerization plant is more advantageously treated in a second stage under mild conditions using the Group VIII noble metal isomerization catalyst and a refractory metal oxide to reduce PNA and other contaminants in the isomer and thus an oil with improved daylight resistance (see page 8, paragraph 2).
  • Mild conditions are understood to mean: a temperature in the range of approximately 170 ° to 270 ° C, a pressure of about 300 to 1,500 psL, a hydrogen gas rate of about 500 to 1,000 SCF / bbl and a flow rate of about 0.25 to 10 vol./vol./h.
  • DE 38 72851 T2 describes the production of a middle distillate fuel from a paraffin wax, in particular an FT wax (see claim 2), in which the wax under hydroisomerization conditions in the presence of a certain catalyst based on a metal of VIII. Group, in particular platinum (claim 12), and aluminum oxide as a carrier material is treated with hydrogen, so that a middle formate product and a bottom product with an initial boiling point above 371 ° C. are obtained (see claim 1), in particular one Lubricating oil fraction with a low pour point (see claim 5).
  • the wax is fed to the reactor at a rate of 0.2 to 2 V / V.
  • the hydrogen is fed to the reactor at a rate of about 0.089 to 2.67 m 3 H2 per 11 wax.
  • the catalyst has a decisive influence on the conversion. If it is based on platinum and a ⁇ -zeolite with a pore diameter of about 0.7 nm, the desired conversion to a middle distillate product is not observed, especially when the temperature decreases to 293.9 ° C. (see example 3).
  • the invention is concerned with the task of specifying a novel microcrystalline paraffin, a process for its production and the use of this microcrystalline paraffin.
  • microcrystalline paraffin which can be produced by catalytic hydroisomerization at temperatures above 200 ° C., from paraffins (FT paraffins) containing Fischer-Tropsch synthesis with a C chain length distribution in the range from C 20 to C 105 . ben is. It has surprisingly been found that such a microcrystalline paraffin is free of naphthenes and aromatics. It is also surprising that crystallinity has been retained despite isomerization. Continuous production with defined properties is possible. A product to be called micro wax in the low and high freezing point range is provided.
  • FT paraffins Fischer-Tropsch paraffins
  • the FT paraffins are paraffins which, according to the Fischer-Tropsch process, are made in a known way from synthesis gas (CO and H2) in the presence of a catalyst were produced at an elevated temperature.
  • Such FT paraffins with a high proportion of n-paraffins and a C chain length in the range from C 20 to C 105 become high-melting, microcrystalline paraffins with a high by the J E process described here
  • microcrystalline paraffin is according to the process aspect of the invention.
  • FT paraffin as starting material a) with a C chain length in the range from C 20 to C 105 , ,, b) preferably with a solidification point in the range from 70 to 105 ° C, in particular about 70, 80, 95 or 105 ° C according to DIN ISO 2207, c) penetration at 25 ° C from 1 to 15; d) a ratio of iso to n-alkanes of 1: 5 to 1:11
  • a catalyst preferably in the form of extrudates, spheres, tablets, granules or powders, advantageously on the basis of a) 0.1 to 2.0, in particular 0.4 to 1.0,% by weight, based on the catalyst annealed at 800 ° C., on hydrogenating metal of the eighth subgroup, in particular platinum, and b) a support material made of a zeolite with a pore diameter in the range from 0.5 to 0.8 nm (5.0 to 8.0 ⁇ ) .
  • the loading of the reactor with the FT paraffin is expediently in the range from 0.1 to 2.0, in particular from 0.2 to 0.8 v / v. h (volume of FT paraffin per volume of the reactor within one hour).
  • the yield of hydroisomerizates is between 90 and 96% by mass, based on the FT paraffin used in each case.
  • the catalyst used is preferably formed on the basis of a? Zeolite.
  • the catalytic hydroisomerization of the FT paraffins is preferably carried out continuously in a flow reactor with a fixed catalyst, in particular in the form of extrudates, spheres or tablets, where
  • the reactor if, as is preferred, oriented vertically, can be flowed through from top to bottom and from bottom to top.
  • the process can also be carried out discontinuously in e.g. be carried out in a stirred autoclave in a batch process, the catalyst in a permeable
  • microcrystalline paraffins obtained according to the invention have the following properties:
  • n-alkanes Compared to the FT paraffins used, they have lower solidification points and, in addition to n-alkanes, contain a high, in particular higher proportion by weight of iso- than n-alkanes.
  • the proportion of n- or iso-alkanes is determined by gas chromatography.
  • the increased degree of isomerization achieved by the hydroisomerization is expressed in increased penetration values, a reduced degree of crystallization and a reduced one
  • the degree of crystallization is determined by an X-ray diffraction analysis. It denotes the crystalline fraction in the product obtained in relation to that amorphous portion. The amorphous components lead to a different diffraction of the X-rays than the crystalline components.
  • the needle penetration at 25 ° C. in the products according to the invention is in the range from 20 to 160, measured according to. DIN 51579. The products obtained are solid at 20 ° C in the sense that they do not run.
  • the crystalline fraction is particularly reduced as follows: While a crystalline fraction occurs in a range of 60 to 75% in the feed, a 30 to 45% fraction is observed in the hydroisomerizate. Especially in the range of 35 to 40 (36, 37, 38, 39)%.
  • the crystalline fractions and the amorphous fractions are each indicated in MA% by the X-ray diffraction analysis mentioned.
  • microcrystalline paraffins produced according to the invention from FT paraffins have physical and material properties which are similar or comparable to those of petroleum-based microcrystalline paraffins (microwaxes).
  • microcrystalline paraffins produced by catalytic hydroisomerization can also be deoiled with a solvent.
  • this does not mean that the hydroisomerization products described have a content of conventional oil.
  • very short-chain n- or iso-alkanes are removed.
  • a deoiled microcrystalline paraffin is obtained in a yield of 80 to 90% by weight, based on the amount used Hydroisomerate obtained. It has the following properties It has the following properties:
  • microcrystalline hydroisomerizate prepared in accordance with the invention and the corresponding deoiled microcrystalline hydroisomerizate can be used like a micro wax (see introduction).
  • the hydroisomerate obtained can also be oxidized.
  • oxidized products which differ according to melting range and degree of oxidation and are used primarily as corrosion protection agents and as cavity and underbody protection agents for motor vehicles. They are also used in emulsions as care and release agents and as an additive for printing and
  • the acid and ester groups which are statistically distributed over hydrocarbon chains, can be converted with inorganic or organic bases to formulations which are dispersible in water (emulsifying waxes) and lead to products with very good metal adhesion.
  • Heat seal and hot melt adhesives as a blend component in candles and other wax products in wax mixtures for crayons, floor and car care products as well as for dental technology and pyrochemicals. They are also part of light protection waxes for the tire industry, electrical insulation materials, scaffold and model waxes for the investment casting industry, and wax formulation for explosives, ammunition and propellant technology.
  • Products of this type are also suitable as release agents in the pressing of wood, particle board and fiberboard in the production of ceramic parts and, because of their retention capacity, for the production of solvent-based care products, grinding and polishing pastes and as matting agents for paints.
  • these products can be used for the formulation of adhesive waxes, cheese waxes, cosmetic preparations, chewing gum bases, cast and cable masses, sprayable pesticides, petroleum jelly, artificial chimney logs, lubricants and hot melt adhesives.
  • a food safety test is carried out, for example, according to FDA, ⁇ 175. 250.
  • the hydroisomerisate is white, odorless and slightly sticky and is therefore very different from the brittle, hard product.
  • the iso-alkane content is increased about 6 times, which is due to the increased penetration value, the reducedn crystalline portion and the lowered enthalpy of fusion is documented.
  • the synthetic, microcrystalline paraffin thus produced can be classified according to its characteristic values between a plastic and a hard, petroleum-based microwax. With the hydroisomer, a paraffin with a pronounced microcrystalline structure was obtained, the C chain length distribution of which, based on the carbon atoms, was 23 to 91 in roughly corresponds to that of the input product with 27 to 95, but just shifted towards smaller chain lengths. The chain length was determined by gas chromatography.
  • An FT paraffin with a solidification point at 70 ° C. was catalytically isomerized with hydrogen at a pressure of 5 MPa (50 bar), a temperature of 250 ° C. and a v / vh ratio of 0.3.
  • the structural change that occurred was documented by the key figures in the table.
  • the hydroisomerisate is white and odorless as well as pasty and slightly sticky.
  • the iso-alkane content is increased about 5 times.
  • the high degree of isomerization is expressed in the significantly increased penetration value, the reduced crystalline fraction and the reduced melting enthalpy. The so obtained
  • the synthetic microcrystalline paraffin produced in this way is, according to its characteristic values, a soft plastic microcrystalline paraffin obtained on the basis of petroleum
  • Paraffins which mainly consist of n-alkanes and have a fine crystalline structure and a brittle-hard consistency, in non-flowing, pasty or solid paraffins were converted, which have lower melting temperatures than the feed products. These paraffins are characterized by a high content of branched alkanes and consequently have a microcrystalline structure with a significantly reduced degree of crystallization as well as a plastic to slightly sticky consistency.
  • the branched alkanes are predominantly methyl alkanes, the methyl groups preferably occurring in the 2-, 3-, 4- or 5-position. Poly-branched alkanes were also formed to a small extent.
  • a catalyst (cylindrical extrudate, diameter 1.5 mm, length approx. 5 mm) was used uncrushed. 92 ml of catalyst were poured undiluted into the reactor tube (total volume 172 ml, inner diameter 22 mm). The catalyst zone was also covered with the earth material. A thermocouple was positioned in the reactor so that the temperature was measured at a depth of 2 cm and 17 cm of the catalyst bed. The catalysts were dried and activated (water is expelled by high temperature and platinum is reduced).
  • An FT paraffin C80 (solidification point 81 ° C., mass ratio n- / iso-paraffins: 93.9 / 6.1) was used as the paraffin feed product.
  • the oil content of the starting product was 0.5%.
  • the catalyst was a platinum catalyst on beta zeolite.
  • ß -Zeolithen is referred to the reference "Atlas of Zeolithe Strucüire-type", Elsevier Fourth Revised Edition, 1996.
  • the fully synthetic microcrystalline paraffins produced by the hydroisomerization according to the invention contain no highly branched iso-alkanes, no cyclic hydrocarbons (naphthenes) and in particular no aromatics and sulfur compounds. They meet the highest purity requirements for microcrystalline paraffins and are therefore ideally suited for use in the cosmetic and pharmaceutical industries as well as for packaging and preservation in the food industry.

Abstract

L'invention concerne une nouvelle paraffine microcristalline entièrement synthétique, pouvant être obtenue, de manière simple et avec un rendement élevé, par hydro-isomérisation catalytique de paraffine FT (formée par synthèse de Fischer-Tropsch) comportant 20 à 105 atomes de carbone. Ces nouvelles paraffines peuvent être pâteuses à solides à température ambiante et présentent une teneur plus élevée en isoparaffine qu'en n-paraffines. Elles ne contiennent pas de composés aromatiques et par conséquent sont particulièrement adaptées aux applications dans l'industrie pharmaceutique, cosmétique et alimentaire.
EP02732741.0A 2001-05-30 2002-05-31 Procédé pour la production de paraffine microcristalline Expired - Lifetime EP1390329B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10126516A DE10126516A1 (de) 2001-05-30 2001-05-30 Verfahren zur Herstellung von mikrokristallinen Paraffinen
DE10126516 2001-05-30
PCT/EP2002/005970 WO2002096842A2 (fr) 2001-05-30 2002-05-31 Paraffine microcristalline

Publications (2)

Publication Number Publication Date
EP1390329A2 true EP1390329A2 (fr) 2004-02-25
EP1390329B1 EP1390329B1 (fr) 2013-04-10

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ID=7686764

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02732741.0A Expired - Lifetime EP1390329B1 (fr) 2001-05-30 2002-05-31 Procédé pour la production de paraffine microcristalline

Country Status (11)

Country Link
US (1) US7875166B2 (fr)
EP (1) EP1390329B1 (fr)
JP (1) JP2004529192A (fr)
CN (2) CN101892080B (fr)
AU (1) AU2002304654A1 (fr)
DE (1) DE10126516A1 (fr)
ES (1) ES2408810T3 (fr)
PL (1) PL203361B1 (fr)
RU (1) RU2276184C2 (fr)
WO (1) WO2002096842A2 (fr)
ZA (1) ZA200300781B (fr)

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Also Published As

Publication number Publication date
AU2002304654A1 (en) 2002-12-09
DE10126516A1 (de) 2002-12-05
US20040192979A1 (en) 2004-09-30
CN101892080B (zh) 2012-12-19
RU2276184C2 (ru) 2006-05-10
EP1390329B1 (fr) 2013-04-10
WO2002096842A2 (fr) 2002-12-05
CN1668722B (zh) 2010-05-26
US7875166B2 (en) 2011-01-25
CN1668722A (zh) 2005-09-14
CN101892080A (zh) 2010-11-24
ZA200300781B (en) 2004-02-10
RU2003137572A (ru) 2005-05-27
PL203361B1 (pl) 2009-09-30
PL368411A1 (en) 2005-03-21
JP2004529192A (ja) 2004-09-24
WO2002096842A3 (fr) 2003-11-13
ES2408810T3 (es) 2013-06-21

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