EP1374234A1 - Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiere - Google Patents
Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiereInfo
- Publication number
- EP1374234A1 EP1374234A1 EP02735148A EP02735148A EP1374234A1 EP 1374234 A1 EP1374234 A1 EP 1374234A1 EP 02735148 A EP02735148 A EP 02735148A EP 02735148 A EP02735148 A EP 02735148A EP 1374234 A1 EP1374234 A1 EP 1374234A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- sulfonate
- formula
- represents hydrogen
- optical data
- chlorobenzenesulfonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 46
- 150000001875 compounds Chemical class 0.000 title claims abstract description 13
- 239000010410 layer Substances 0.000 claims abstract description 65
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 239000011241 protective layer Substances 0.000 claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 6
- -1 heterocyclic radical Chemical class 0.000 claims description 171
- JOYKCMAPFCSKNO-UHFFFAOYSA-N chloro benzenesulfonate Chemical compound ClOS(=O)(=O)C1=CC=CC=C1 JOYKCMAPFCSKNO-UHFFFAOYSA-N 0.000 claims description 65
- 229910052739 hydrogen Inorganic materials 0.000 claims description 53
- 239000001257 hydrogen Substances 0.000 claims description 53
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 33
- 150000002431 hydrogen Chemical class 0.000 claims description 29
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 24
- 150000003254 radicals Chemical class 0.000 claims description 24
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 22
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 22
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 22
- 125000002603 chloroethyl group Chemical group [H]C([*])([H])C([H])([H])Cl 0.000 claims description 22
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 22
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 claims description 22
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 22
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims description 22
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 22
- 238000010521 absorption reaction Methods 0.000 claims description 19
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 18
- 125000000217 alkyl group Chemical group 0.000 claims description 17
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 17
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 12
- 229910052801 chlorine Inorganic materials 0.000 claims description 11
- 239000000460 chlorine Substances 0.000 claims description 11
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 11
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 11
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims description 11
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 11
- 125000003944 tolyl group Chemical group 0.000 claims description 11
- LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 claims description 10
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 10
- 150000001450 anions Chemical class 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 10
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 claims description 10
- 229940077388 benzenesulfonate Drugs 0.000 claims description 10
- 150000004761 hexafluorosilicates Chemical class 0.000 claims description 10
- 125000002112 pyrrolidino group Chemical group [*]N1C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 claims description 10
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 9
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 claims description 9
- JVTAAEKCZFNVCJ-UHFFFAOYSA-M Lactate Chemical compound CC(O)C([O-])=O JVTAAEKCZFNVCJ-UHFFFAOYSA-M 0.000 claims description 9
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 claims description 9
- NIKBCKTWWPVAIC-UHFFFAOYSA-N butyl benzenesulfonate Chemical compound CCCCOS(=O)(=O)C1=CC=CC=C1 NIKBCKTWWPVAIC-UHFFFAOYSA-N 0.000 claims description 9
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims description 9
- 125000004093 cyano group Chemical group *C#N 0.000 claims description 9
- CCIVGXIOQKPBKL-UHFFFAOYSA-M ethanesulfonate Chemical compound CCS([O-])(=O)=O CCIVGXIOQKPBKL-UHFFFAOYSA-M 0.000 claims description 9
- RMIODHQZRUFFFF-UHFFFAOYSA-M methoxyacetate Chemical compound COCC([O-])=O RMIODHQZRUFFFF-UHFFFAOYSA-M 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 8
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 7
- 125000004174 2-benzimidazolyl group Chemical group [H]N1C(*)=NC2=C([H])C([H])=C([H])C([H])=C12 0.000 claims description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 6
- 125000003545 alkoxy group Chemical group 0.000 claims description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 239000000969 carrier Substances 0.000 claims description 5
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052794 bromium Inorganic materials 0.000 claims description 4
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 claims description 4
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 125000004344 phenylpropyl group Chemical group 0.000 claims description 4
- 125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 3
- 125000000339 4-pyridyl group Chemical group N1=C([H])C([H])=C([*])C([H])=C1[H] 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000001160 methoxycarbonyl group Chemical group [H]C([H])([H])OC(*)=O 0.000 claims description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- RJSYPKWVIJGNLO-UHFFFAOYSA-N CCOClOC Chemical group CCOClOC RJSYPKWVIJGNLO-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims description 2
- 125000004802 cyanophenyl group Chemical group 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- 125000003754 ethoxycarbonyl group Chemical group C(=O)(OCC)* 0.000 claims description 2
- 125000005842 heteroatom Chemical group 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- UCFFGYASXIPWPD-UHFFFAOYSA-N methyl hypochlorite Chemical compound COCl UCFFGYASXIPWPD-UHFFFAOYSA-N 0.000 claims description 2
- 125000004287 oxazol-2-yl group Chemical group [H]C1=C([H])N=C(*)O1 0.000 claims description 2
- 125000004292 pyrrolin-2-yl group Chemical group [H]C1([H])N=C(*)C([H])([H])C1([H])[H] 0.000 claims description 2
- 125000006413 ring segment Chemical group 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 125000000437 thiazol-2-yl group Chemical group [H]C1=C([H])N=C(*)S1 0.000 claims description 2
- 125000004301 thiazolin-2-yl group Chemical group [H]C1([H])SC(*)=NC1([H])[H] 0.000 claims description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1 -dodecene Natural products CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 claims 1
- NCKMMSIFQUPKCK-UHFFFAOYSA-N 2-benzyl-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1CC1=CC=CC=C1 NCKMMSIFQUPKCK-UHFFFAOYSA-N 0.000 claims 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims 1
- 229940069096 dodecene Drugs 0.000 claims 1
- 239000011358 absorbing material Substances 0.000 abstract 1
- 239000000975 dye Substances 0.000 description 26
- 239000012790 adhesive layer Substances 0.000 description 10
- 101100129500 Caenorhabditis elegans max-2 gene Proteins 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 7
- 238000002310 reflectometry Methods 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 230000008033 biological extinction Effects 0.000 description 6
- 238000013500 data storage Methods 0.000 description 6
- 238000004528 spin coating Methods 0.000 description 5
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000007740 vapor deposition Methods 0.000 description 4
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 238000002835 absorbance Methods 0.000 description 3
- 125000001309 chloro group Chemical group Cl* 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RKJUIXBNRJVNHR-UHFFFAOYSA-N 3H-indole Chemical compound C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000001208 nuclear magnetic resonance pulse sequence Methods 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 description 1
- NBUKAOOFKZFCGD-UHFFFAOYSA-N 2,2,3,3-tetrafluoropropan-1-ol Chemical compound OCC(F)(F)C(F)F NBUKAOOFKZFCGD-UHFFFAOYSA-N 0.000 description 1
- RIOSJKSGNLGONI-UHFFFAOYSA-N 2-phenylbenzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1C1=CC=CC=C1 RIOSJKSGNLGONI-UHFFFAOYSA-N 0.000 description 1
- WOWFGZLCKNNPIV-UHFFFAOYSA-N 3-phenylbenzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(C=2C=CC=CC=2)=C1S(O)(=O)=O WOWFGZLCKNNPIV-UHFFFAOYSA-N 0.000 description 1
- ZLQGITSKRNWIOT-UHFFFAOYSA-N 5-(dimethylamino)furan-2-carbaldehyde Chemical compound CN(C)C1=CC=C(C=O)O1 ZLQGITSKRNWIOT-UHFFFAOYSA-N 0.000 description 1
- 239000004923 Acrylic lacquer Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 125000001769 aryl amino group Chemical group 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 125000000043 benzamido group Chemical group [H]N([*])C(=O)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 125000000068 chlorophenyl group Chemical group 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000005281 excited state Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012362 glacial acetic acid Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000005283 ground state Effects 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 230000015654 memory Effects 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910001495 sodium tetrafluoroborate Inorganic materials 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- MYOWBHNETUSQPA-UHFFFAOYSA-N tetradecane-1-sulfonic acid Chemical compound CCCCCCCCCCCCCCS(O)(=O)=O MYOWBHNETUSQPA-UHFFFAOYSA-N 0.000 description 1
- 125000005425 toluyl group Chemical group 0.000 description 1
- 125000005389 trialkylsiloxy group Chemical group 0.000 description 1
- 125000004665 trialkylsilyl group Chemical group 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D221/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00
- C07D221/02—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00 condensed with carbocyclic rings or ring systems
- C07D221/04—Ortho- or peri-condensed ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D217/00—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems
- C07D217/12—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems with radicals, substituted by hetero atoms, attached to carbon atoms of the nitrogen-containing ring
- C07D217/14—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems with radicals, substituted by hetero atoms, attached to carbon atoms of the nitrogen-containing ring other than aralkyl radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
- C07D311/06—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2
- C07D311/08—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2 not hydrogenated in the hetero ring
- C07D311/12—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2 not hydrogenated in the hetero ring substituted in position 3 and unsubstituted in position 7
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
- C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D311/78—Ring systems having three or more relevant rings
- C07D311/80—Dibenzopyrans; Hydrogenated dibenzopyrans
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D455/00—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine
- C07D455/03—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing quinolizine ring systems directly condensed with at least one six-membered carbocyclic ring, e.g. protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine
- C07D455/04—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing quinolizine ring systems directly condensed with at least one six-membered carbocyclic ring, e.g. protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing a quinolizine ring system condensed with only one six-membered carbocyclic ring, e.g. julolidine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0091—Methine or polymethine dyes, e.g. cyanine dyes having only one heterocyclic ring at one end of the methine chain, e.g. hemicyamines, hemioxonol
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
- C09B23/04—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups one >CH- group, e.g. cyanines, isocyanines, pseudocyanines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/10—The polymethine chain containing an even number of >CH- groups
- C09B23/105—The polymethine chain containing an even number of >CH- groups two >CH- groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0025—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds
- C09B29/0029—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds the heterocyclic ring containing only nitrogen as heteroatom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/0025—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds
- C09B29/0074—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds the heterocyclic ring containing nitrogen and sulfur as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
- C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B44/00—Azo dyes containing onium groups
- C09B44/10—Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/045—Special non-pigmentary uses, e.g. catalyst, photosensitisers of phthalocyanine dyes or pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
- C09B47/085—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex substituting the central metal atom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B47/00—Porphines; Azaporphines
- C09B47/04—Phthalocyanines abbreviation: Pc
- C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
- C09B47/24—Obtaining compounds having —COOH or —SO3H radicals, or derivatives thereof, directly bound to the phthalocyanine radical
- C09B47/26—Amide radicals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/02—Dyestuff salts, e.g. salts of acid dyes with basic dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
- C09K9/02—Organic tenebrescent materials
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/004—Recording, reproducing or erasing methods; Read, write or erase circuits therefor
- G11B7/0045—Recording
- G11B7/00455—Recording involving reflectivity, absorption or colour changes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/248—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes porphines; azaporphines, e.g. phthalocyanines
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/249—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing organometallic compounds
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/254—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/26—Apparatus or processes specially adapted for the manufacture of record carriers
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/007—Arrangement of the information on the record carrier, e.g. form of tracks, actual track shape, e.g. wobbled, or cross-section, e.g. v-shaped; Sequential information structures, e.g. sectoring or header formats within a track
Definitions
- Optical data carrier containing a hemicyanine dye in the information layer as a light-absorbing compound
- the invention relates to a write-once optical data carrier which contains a hemicyanic dye in the information layer as a light-absorbing compound, and to a method for its production.
- the write-once optical data carriers using special light-absorbing substances or their mixtures are particularly suitable for use with high-density writable optical data storage media that are marked with blue ones
- Laser diodes in particular GaN or SHG laser diodes (360 - 460 ⁇ m) work and / or for use with DVD-R or CD-R discs that work with red (635 - 660 nm) or infrared (780 - 830 nm) laser diodes , and the application of the above-mentioned dyes to a polymer substrate, in particular polycarbonate, by spin coating or vapor deposition.
- the storage density can be increased by using shorter-wave laser radiation (635 to 660 nm) and a higher numerical aperture NA.
- the recordable format in this case is the DVD-R.
- NA is the numerical aperture of the objective lens used. To receive one The highest possible storage density should be aimed at using the smallest possible wavelength ⁇ . 390 nm are currently possible on the basis of semiconductor laser diodes.
- the patent literature describes dye-based writable optical data memories which are equally suitable for CD-R and DVD-R systems (JP-A 11 043 481 and JP-A 10 181 206).
- JP-A 11 043 481 and JP-A 10 181 206 For a high reflectivity and a high modulation level of the readout signal, as well as for a sufficient sensitivity when writing, use is made of the fact that the IR wavelength 780 nm of the CD-R lies at the foot of the long-wave flank of the absorption peak of the dye.
- the red wavelength 635 nm or 650 nm 'of the DVD-R lies at the foot of the short-wave flank of the absorption peak of the dye.
- the writable information layer made of light-absorbing organic substances must have a morphology which is as amorphous as possible in order to keep the noise signal as small as possible when writing or reading.
- the substances are applied by spin coating from a solution, by vapor deposition and / or sublimation, subsequent crystallization of the light-absorbing substances with metallic or dielectric layers in vacuum is prevented.
- the amorphous layer of light-absorbing substances should preferably have a high heat resistance, since otherwise further layers of organic or inorganic material, which are applied to the light-absorbing information layer by sputtering or vapor deposition, are blurred by diffusion
- An excessively high vapor pressure of a light-absorbing substance can sublimate the above-mentioned sputtering or vapor deposition of further layers in a high vacuum and thus reduce the desired layer thickness. This in turn leads to a negative influence on the reflectivity.
- the object of the invention is therefore to provide suitable compounds which meet the high requirements (such as light stability, favorable signal-to-noise ratio, damage-free application to the substrate material, etc.) for use in the information layer in a write-once optical data carrier, in particular for high-density recordable optical media Meet data storage formats in a laser wavelength range from 340 to 680 nm.
- the invention therefore relates to an optical data carrier, comprising a preferably transparent substrate, optionally already coated with one or more reflection layers, on the surface of which an information layer which can be written on with light, optionally one or more reflection layers and optionally a protective layer or a further substrate or a cover layer is applied, which can be written and read with blue or red light, preferably laser light, the information layer containing a light-absorbing compound and optionally a binder, characterized in that at least one hemicyanine dye is used as the light-absorbing compound. Blue laser light is particularly preferred.
- the light-absorbing compound should preferably be thermally changeable.
- the thermal change preferably takes place at a temperature ⁇ 600 ° C., particularly preferably at a temperature ⁇ 400 ° C., very particularly preferably at one
- Such a change can be, for example, a decomposition or chemical change in the chromophoric center of the light-absorbing compound.
- a hemicyanine of formula I is preferred
- X 1 represents nitrogen or
- X 2 represents O, S, NR 2 or CR 3 R 4 ,
- R 1 and R 2 independently of one another represent Ci to C 16 alkyl, C 3 to C 6 alkenyl, C 5 to C 7 cycloalkyl or C 7 to C 16 aralkyl,
- R 3 and R 4 independently of one another represent d- to C 4 -alkyl or
- a together with X 1 , X 2 and the C atom bonded between them represents a five- or six-membered aromatic or quasi-aromatic heterocyclic ring which contain 1 to 4 heteroatoms and / or benzylated or naphthanellated and / or substituted by nonionic radicals can be,
- R and R independently of one another for hydrogen, C ⁇ - to C 16 alkyl, C 4 - to C 7 -
- Cycloalkyl C 7 - to C ⁇ 6 aralkyl, C 6 - to C ⁇ 0 aryl or a heterocyclic radical or
- NR 5 R 6 stands for a five- or six-membered saturated ring attached via N, which may additionally contain an N or O and / or may be substituted by nonionic radicals,
- R 7 represents hydrogen, Ci- to C ⁇ - 6 alkyl, C - to C 16 -alkoxy or halogen or
- R 7 and R 5 form a two- or three-membered bridge which may contain an O or N and / or which may be substituted by nonionic radicals,
- R 8 for hydrogen, d to C 6 alkyl, to C 16 alkoxy, halogen, cyano, Q to C 4 alkoxycarbonyl, O-CO-R 10 , NR ⁇ -CO-R 10 , O-SO 2 -R 10 or
- R 9 for hydrogen, d to C 4 alkyl, cyano, CO-OR 12 , CO-NR 1! R 12 , CS-OR 12 or CS-NR ⁇ R 12
- R 10 is hydrogen, d to C 16 alkyl, C 4 to C 7 cycloalkyl, C 7 to C 16 aralkyl, d to C 16 alkoxy, mono- or bis-d to C 16 Alkylamino, C 6 to C 10 aryl, C 6 to do aryloxy, C 6 to C 10 arylamino or a heterocyclic radical,
- R, ⁇ represents hydrogen or d- to C-alkyl
- R. 1 1 2 represents d to C 4 alkyl, C 4 to C 7 cycloalkyl, C 7 to C 16 aralkyl or C 6 to do aryl and
- X may also stand for CR, where R has the meaning given above.
- Ring A together with X, X and the C atom bound between them may also be a partially hydrogenated heterocyclic ring.
- non-ionic radicals are for example C to C alkyl, d- to C 4 alkoxy, halogen, cyano, nitro, C ⁇ - to d-alkoxycarbonyl, d- to C alkylthio, d- to C - alkanoylamino, benzoylamino, Mono- or di-d to C 4 alkylamino in question.
- Alkyl, alkoxy, aryl and heterocyclic radicals can optionally carry further radicals such as alkyl, halogen, nitro, cyano, CO-NH 2 , alkoxy, trialkylsilyl, trialkylsiloxy or phenyl, the alkyl and alkoxy radicals can be straight-chain or branched , The alkyl radicals can be partially or perhalogenated, the alkyl and
- Alkoxy radicals can be ethoxylated or propoxylated or silylated, adjacent alkyl and / or alkoxy radicals on aryl or heterocyclic radicals can together form a three- or four-membered bridge and the heterocyclic radicals can be fused to benzene and / or quaternized.
- Ring A of the formula is particularly preferably
- Ring A of the formula is likewise particularly preferably
- Ci to C 6 alkyl d to C 6 -Alkoxy, fluorine, chlorine, bromine, iodine, cyano, nitro, Ci- to C 6 -alkoxycarbonyl C 6 - to Cio-aryl or C 6 - to Cio-aryloxy may be substituted.
- the hemicyanines used are those of the formula (I)
- benzthiazol-2-yl for benzthiazol-2-yl, benzimidazol-2-yl, 3,3-dimethyl-3H-indol-2-yl, pyrimid-2-one-4-yl, 2- or 4-pyridyl or 2- or 4-quinolyl stands, the radicals mentioned in each case by methyl, ethyl, methoxy, ethoxy, chlorine,
- R 1 for methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, phenethyl, phenylpropyl, allyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, cyanopropyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl or a radical of the formula
- R 2 in the case that the ring A is benzimidazol-2-yl has the same meaning as R 1 ,
- R 5 and R 6 independently of one another are methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, phenethyl, phenylpropyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, cyanopropyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl,
- R 5 can additionally represent hydrogen or NR 5
- R 6 represents pyrrolidino, piperidino, N-methylpiperidino, N-ethylpiperidino, N-hydroxyethylpiperidino or morpholino,
- R 7 represents hydrogen, methyl, methoxy or chlorine or
- R represents hydrogen, methyl, methoxy or chlorine
- R 9 represents hydrogen
- Biphenyl disulfonate optionally substituted by nitro, cyano, Ci to C 4 alkyl, Ci to C 4 alkoxy, Ci to C alkoxycarbonyl, benzoyl, chlorobenzoyl or toluoyl, the anion of naphthalenedicarboxylic acid, diphenyl ether disulfonate, tetraphenylborate, cyanotriphenyl, cyanotriphenyl, cyanotriphenyl Tetra-Cj- to C 2 o-alkoxyborate, tetraphenoxyborate, 7,8- or 7,9-dicarba-nido-undecaborate (l-) or (2-), which are optionally attached to the B- and / or C- Atoms through one or two d- to C 12 -alkyl- or P enyl- Groups are substituted, dodecahydro-dicarbadodecaborate (2-) or Bd- to C 12 -
- Bromide, iodide, tetrafluoroborate, perchlorate, methanesulfonate, benzenesulfonate, toluenesulfonate, dodecylbenzenesulfonate, tetradecanesulfonate are preferred.
- the hemicyanins used are those of the formulas (III) to (VI)
- R 1 is methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl or a radical of the formula
- R 5 and R 6 independently of one another represent methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl, methoxycarbonylethyl, ethoxycarbonylethyl, acetoxyethyl, phenyl, tolyl or methoxyphenyl or
- NR R represents pyrrolidino, N-methylpiperidino or morpholino
- R 7 represents hydrogen or
- R 7 ; R 5 represent a - (CH 2 ) 2 -, -C (CH 3 ) -CH 2 -C (CH 3 ) 2 - or -O- (CH 2 ) 2 bridge,
- R 8 represents hydrogen
- R represents hydrogen
- the hemicyanins used are those of the formulas (purple) and (INa)
- R 1 for methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl or a radical of the formula
- R 5 and R 6 independently of one another are methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, hydroxyethyl, 2-hydroxypropyl, methoxy- ethyl, ethoxyethyl, methoxycarbonylethyl, ethoxycarbonylethyl, acetoxyethyl, phenyl, tolyl or methoxyphenyl or
- NR 5 R 6 represents pyrrolidino, N-methylpiperidino, morpholino or N, N-bis- (2-cyanoethyl) amino,
- R 7 represents hydrogen or
- R 7 ; R 5 represent a - (CH 2 ) 2 -, -C (CH 3 ) -CH 2 -C (CH 3 ) 2 - or -O- (CH 2 ) 2 bridge,
- R represents hydrogen
- R represents hydrogen
- R 13 represents hydrogen, methyl, methoxy, chlorine, nitro, cyano or methoxycarbonyl
- R 14 represents hydrogen, methyl, methoxy or ethoxy
- R is preferably hydrogen, methyl, methoxy or methoxycarbonyl and R 14 is hydrogen.
- hemicyanins used are those of the formulas (NU) to (IX)
- R 1 for methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl or a radical of the formula
- R 5 and R 6 independently of one another are methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, Methoxyethyl, ethoxyethyl, methoxycarbonylethyl, ethoxycarbonylethyl, acetoxyethyl, phenyl, tolyl or methoxyphenyl or
- NR 5 R 6 represents pyrrolidino, N-methylpiperidino or morpholino
- R represents hydrogen or
- R 7 ; R 5 represent a - (CH 2 ) 2 -, -C (CH 3 ) -CH 2 -C (CH 3 ) 2 - or -O- (CH 2 ) 2 bridge,
- R 8 represents hydrogen
- R 9 represents hydrogen
- a write-once optical data medium which is written and read with the light of a blue laser
- Such a hemicyanine dye preferably does not have a shorter-wave maximum ⁇ max ⁇ up to a wavelength of 350 nm, particularly preferably up to 320 nm, very particularly preferably up to 290 nm.
- Hemicyanine dyes with an absorption maximum ⁇ max2 of 410 to 530 nm are preferred.
- Hemicyanine dyes with an absorption maximum ⁇ max2 of 420 to 510 nm are particularly preferred.
- Hemicyanine dyes with an absorption maximum ⁇ maX 2 of 430 to 500 nm are very particularly preferred.
- a write-once optical data medium which is written and read with the light of a red laser
- Such a hemicyanine dye preferably has no longer-wavelength maximum ⁇ max3 up to a wavelength of 750 nm, particularly preferably up to 800 nm, very particularly preferably up to 850 nm.
- Hemicyanine dyes with an absorption maximum ⁇ maX 2 of 530 to 630 nm are preferred.
- Hemicyanine dyes with an absorption maximum ⁇ max2 of 550 to 620 nm are particularly preferred.
- Hemicyanine dyes with an absorption maximum ⁇ maX 2 of 580 to 610 nm are very particularly preferred.
- hemicyanine dyes ⁇ / 2 and ⁇ o are preferably not more than 40 nm apart, more preferably not more than 30 nm apart, very particularly preferably not more than 20 nm apart.
- the hemicyanine dyes have a molar extinction coefficient ⁇ > 40,000 1 / mol cm, preferably> 60,000 1 / mol cm, particularly preferably> 80,000 1 / mol cm, very particularly preferably> 100,000 1 / mol cm.
- the absorption spectra are measured, for example, in solution.
- a method for determining such a dipole moment change ⁇ is described, for example, in F. Würthner et al., Angew. Chem. 1997, 109, 2933 and in the literature cited therein.
- a low solvatochromism (methanol / methylene chloride) is also a suitable selection criterion.
- Hemicyanins which are particularly preferred in the sense of the invention are those of the formulas (III) and (V).
- Hemicyanines of the formulas (I) and (III) to (VI) are known, for. B. from DE-OS 2 932
- the light-absorbing substances described guarantee a sufficiently high reflectivity (> 10%) of the optical data carrier in the blank state and a sufficiently high absorption for the thermal degradation of the information layer in the case of selective illumination with focused light if the light wavelength is in the range from 360 to 460 nm and 600 to 680 nm.
- the contrast between written and unwritten areas on the data carrier is realized by the change in reflectivity of the amplitude and the phase of the incident light by the optical properties of the information layer which have changed after thermal degradation.
- the hemicarm dyes are preferably applied to the optical data carrier by spin coating or vacuum evaporation.
- the hemicyanins can be mixed with one another or with other dyes with similar spectral properties.
- the information layer can be in addition to the hemicyanine dyes
- Additives contain such as binders, wetting agents, stabilizers, thinners and sensitizers as well as other components.
- the optical data storage device can carry further layers such as metal layers, dielectric layers and protective layers.
- Metals and dielectric layers serve u. a. to adjust the reflectivity and the heat balance. Depending on the laser wavelength, metals can be gold, silver, aluminum and the like. a. his.
- Dielectric layers are, for example, silicon dioxide and silicon nitride.
- Protective layers are, for example, photocurable, lacquers, adhesive layers and protective films.
- Adhesive layers can consist of pressure-sensitive material.
- the invention further relates to a write-once optical data carrier, comprising a preferably transparent substrate, on the surface of which at least one information layer which can be written on with light, optionally one Reflective layer and / or optionally a protective layer are applied, which can be written and read with blue light, preferably laser light, the information layer containing at least one of the abovementioned light-absorbing compounds and, if appropriate, a binder, wetting agent, stabilizers, thinners and sensitizers and further constituents ,
- the structure of the optical data carrier can be:
- Pressure-sensitive adhesive layers mainly consist of acrylic adhesives.
- the optical data carrier has, for example, the following layer structure (cf. FIG. 1): a transparent substrate (1), optionally a protective layer (2), an information layer (3), optionally a protective layer (4), optionally an adhesive layer (5), a cover layer (6).
- the structure of the optical data carrier can preferably:
- Protective layer (4) optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
- a transparent substrate (1) on the surface of which a protective layer (2), at least one information layer (3) which can be written on with light, preferably laser light, optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
- a transparent substrate (1) on the surface of which there is optionally a protective layer (2), at least one information layer (3) which can be written on with light, preferably laser light, optionally a protective layer (4), optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
- a preferably transparent substrate (1) on the surface of which at least one information layer (3) which can be written on with light, preferably laser light, optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
- the optical data carrier has, for example, the following layer structure
- a preferably transparent substrate 11
- an information layer (12)
- optionally a reflection layer 13
- optionally an adhesive layer 14
- another preferably transparent substrate 15
- the invention further relates to optical data carriers according to the invention described with blue or red light, in particular laser light.
- 3H-indole was stirred in a mixture of 5 ml of glacial acetic acid and 1 ml of acetic anhydride at 40 ° C. for 2 h. After cooling, it was poured onto 80 ml of water in which 2.6 g of sodium tetrafluoroborate were dissolved. It was suctioned off, washed with water and dried. 1.6 g of 42% of theory were obtained. Th.) Of a red powder of the formula
- the pregrooved polycarbonate substrate was manufactured as a disk using injection molding.
- the dimensions of the disk and the groove structure corresponded to those that are usually used for DND-R.
- the disk with the dye layer as an information carrier was with 100 nm
- a UV-curable acrylic lacquer was then applied by spin coating and cured using a UN lamp.
- the light reflected by the reflective layer of the disc was With the aid of the polarization-sensitive beam splitter mentioned above, it is coupled out of the beam path and focused on an Nierquadranendetector by an astigmatic lens.
- the write power was applied as an oscillating pulse sequence, the disk being alternately irradiated for 1 ⁇ s with the above-mentioned write power P w and for 4 ⁇ s with the read power P r ⁇ 0.44 mW.
- the disc was irradiated with this oscillating pulse sequence until it had turned around once. The marking generated in this way was then read out with the reading power P r ⁇ 0.44 mW and the above-mentioned signal-noise
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Manufacturing Optical Record Carriers (AREA)
- Indole Compounds (AREA)
Abstract
La présente invention concerne un support de données optique comprenant un substrat, qui est de préférence transparent et éventuellement déjà revêtu d'une ou de plusieurs couches de réflexion. Une couche d'information inscriptible au moyen de lumière, éventuellement une ou plusieurs couches de réflexion et éventuellement une couche de protection, un autre substrat ou une couche de revêtement sont appliqués à la surface dudit substrat et peuvent être pourvus d'une inscription et lus au moyen de lumière bleue ou rouge, de préférence au moyen d'une lumière laser. La couche d'information renferme un composé absorbant la lumière et éventuellement un liant et est caractérisée en ce qu'on utilise au moins un colorant à base d'hémicyanine en tant que composé absorbant la lumière.
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10115227 | 2001-03-28 | ||
DE10115227A DE10115227A1 (de) | 2001-03-28 | 2001-03-28 | Optischer Datenträger enthaltend in der Informationsschicht eine lichtabsorbierende Verbindung mit mehreren chromophoren Zentren |
DE10117462 | 2001-04-06 | ||
DE10117462A DE10117462A1 (de) | 2001-04-06 | 2001-04-06 | Optischer Datenträger enthaltend in der Informationsschicht einen Hemicyaninfarbstoff als lichtabsorbierende Verbindung |
DE10136064 | 2001-07-25 | ||
DE2001136064 DE10136064A1 (de) | 2001-07-25 | 2001-07-25 | Optischer Datenträger enthaltend in der Informationsschicht einen Xanthenfarbstoff als lichtabsorbierende Verbindung |
PCT/EP2002/003088 WO2002086879A1 (fr) | 2001-03-28 | 2002-03-20 | Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiere |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1374234A1 true EP1374234A1 (fr) | 2004-01-02 |
Family
ID=27214366
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02735148A Withdrawn EP1374234A1 (fr) | 2001-03-28 | 2002-03-20 | Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiere |
Country Status (6)
Country | Link |
---|---|
US (1) | US20030054291A1 (fr) |
EP (1) | EP1374234A1 (fr) |
JP (1) | JP2004524199A (fr) |
CN (1) | CN1527996A (fr) |
TW (1) | TWI251232B (fr) |
WO (1) | WO2002086879A1 (fr) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TW593658B (en) * | 2002-12-31 | 2004-06-21 | Ind Tech Res Inst | Fluorescent recording media dye, and fluorescent recording media |
TW593561B (en) * | 2003-05-14 | 2004-06-21 | Ind Tech Res Inst | Bis-styryl dye and method for manufacturing the same and its use for a high density optical recording medium |
TW200504741A (en) * | 2003-06-27 | 2005-02-01 | Ciba Sc Holding Ag | Optical recording materials having high storage density |
AU2005249031A1 (en) * | 2004-06-03 | 2005-12-15 | Clariant Finance (Bvi) Limited | Use of squaric acid dyes in optical layers for optical data recording |
DE102004028845A1 (de) * | 2004-06-16 | 2006-01-05 | Bayer Chemicals Ag | Optischer Datenträger enthaltend in der Informationsschicht einen Hemicyaninfarbstoff als lichtabsorbierende Verbindung |
EP1630205A1 (fr) * | 2004-08-24 | 2006-03-01 | Clariant International Ltd. | Colorants de type styrylpyridinium-imine et leur utilisation dans des couches optiques pour l'enregistrement optique de données |
WO2010055050A1 (fr) * | 2008-11-12 | 2010-05-20 | Basf Se | Matières de revêtement durcissables par rayonnement |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5856239A (ja) * | 1981-09-28 | 1983-04-02 | Tdk Corp | 光記録媒体 |
US4756987A (en) * | 1985-11-27 | 1988-07-12 | Mitsubishi Chemical Industries Limited | Optical recording medium |
DE69130344T2 (de) * | 1990-06-19 | 1999-04-08 | Canon Kk | Optisches Aufzeichnungsmedium, Verfahren zur optischen Aufzeichnung und Verfahren zur optischen Wiedergabe |
JPH0538878A (ja) * | 1991-08-07 | 1993-02-19 | Nippon Columbia Co Ltd | 光記録媒体 |
DE59207620D1 (de) * | 1991-10-30 | 1997-01-16 | Ciba Geigy Ag | NIR-Farbstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung |
JP3705877B2 (ja) * | 1996-11-21 | 2005-10-12 | 三井化学株式会社 | 光記録媒体 |
JPH1134497A (ja) * | 1997-07-24 | 1999-02-09 | Matsushita Electric Ind Co Ltd | 光記録媒体 |
CN1108304C (zh) * | 1997-09-26 | 2003-05-14 | 复旦大学 | 蓝光dvd-r用光信息存贮材料 |
US6103331A (en) * | 1997-09-26 | 2000-08-15 | Fuji Electric Co., Ltd. | Optical recording medium comprising organic dye thin film |
KR100370405B1 (ko) * | 2000-05-17 | 2003-01-29 | 삼성전자 주식회사 | 헤미시아닌 색소 및 이를 이용한 광기록매체 |
JP2002206061A (ja) * | 2000-07-05 | 2002-07-26 | Hayashibara Biochem Lab Inc | スチリル色素 |
JP2002074740A (ja) * | 2000-08-25 | 2002-03-15 | Hayashibara Biochem Lab Inc | 光記録媒体 |
-
2002
- 2002-03-20 WO PCT/EP2002/003088 patent/WO2002086879A1/fr not_active Application Discontinuation
- 2002-03-20 JP JP2002584312A patent/JP2004524199A/ja active Pending
- 2002-03-20 EP EP02735148A patent/EP1374234A1/fr not_active Withdrawn
- 2002-03-20 CN CNA02810904XA patent/CN1527996A/zh active Pending
- 2002-03-20 TW TW091105375A patent/TWI251232B/zh not_active IP Right Cessation
- 2002-03-20 US US10/102,282 patent/US20030054291A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO02086879A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2002086879A1 (fr) | 2002-10-31 |
US20030054291A1 (en) | 2003-03-20 |
CN1527996A (zh) | 2004-09-08 |
JP2004524199A (ja) | 2004-08-12 |
TWI251232B (en) | 2006-03-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1377976A2 (fr) | Support de donnees optique contenant dans la couche d'informations un colorant merocyanine en tant que compose photoabsorbant | |
WO2002077984A1 (fr) | Support de donnees optique renfermant dans la couche d'information un colorant au xanthene en tant que compose absorbant la lumiere | |
EP1386317A1 (fr) | Support de donnees optique dont la couche d'informations contient un colorant de cyanine en tant que compose d'absorption lumineuse | |
EP1377971A1 (fr) | Support de donnees optique contenant dans la couche d'informations un colorant amine heterocyclique cationique en tant que compose photoabsorbant | |
WO2002084656A1 (fr) | Support de donnees optique contenant dans la couche d'informations un colorant triazacyanine en tant que compose photoabsorbant | |
EP1709039A1 (fr) | Complexes metalliques utilises comme composes absorbant la lumiere dans la couche d'informations de supports de donnees optiques | |
EP1377968A2 (fr) | Support de donnees optique dont la couche d'informations contient un colorant azoique heterocyclique en tant que compose d'absorption lumineuse | |
WO2002086879A1 (fr) | Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiere | |
US6726972B2 (en) | Optical data storage medium containing a diaza hemicyanine dye as the light-absorbing compound in the information layer | |
WO2004072185A1 (fr) | Colorants azometalliques et support de donnees optique contenant un tel colorant azometallique dans la couche d'information en tant que compose photoabsorbant | |
DE102006022756A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen Indolcyaninfarbstoff als lichtabsorbierende Verbindung | |
DE10117462A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen Hemicyaninfarbstoff als lichtabsorbierende Verbindung | |
DE10117464A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen Merocyaninfarbstoff als lichtabsorbierende Verbindung | |
DE10202571A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen Cyaninfarbstoff als lichtabsorbierende Verbindung | |
DE102005054770A1 (de) | Mischungen von Azometallkomplexen als lichtabsorbierende Verbindungen in der Informationsschicht von optischen Datenträgern | |
WO2006007983A1 (fr) | Melanges de complexes metalliques azoiques utilises comme composes absorbant la lumiere dans la couche de donnees de supports de donnees otiques | |
WO2007006417A2 (fr) | Phthalocyaninsulfonamides axialement substitues utilises comme composes absorbant la lumiere dans la couche d'informations de supports de donnees optiques | |
DE10136063A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen kationischen aminoheterocyclischen Farbstoff als lichtabsorbierende Verbindung | |
DE10117463A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen Triazacyaninfarbstoff als lichtabsorbierende Verbindung | |
DE3738911A1 (de) | Naphtholactamtrimethinfarbstoffe sowie optisches aufzeichnungsmedium, enthaltend die neuen farbstoffe | |
EP1377970A1 (fr) | Support de donnees optique contenant un compose cyclisable dans la couche d'information | |
DE102004028845A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen Hemicyaninfarbstoff als lichtabsorbierende Verbindung | |
WO2006005444A1 (fr) | Complexes metalliques cationiques utilises en tant que composes d'absorption lumineuse dans la couche d'informations de supports de donnees optiques | |
DE10136064A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen Xanthenfarbstoff als lichtabsorbierende Verbindung | |
DE10117461A1 (de) | Optischer Datenträger enthaltend in der Informationsschicht einen heterocyclischen Azofarbstoff als lichtabsorbierende Verbindung |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20031028 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK RO SI |
|
RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: LANXESS DEUTSCHLAND GMBH |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20071002 |