EP1374234A1 - Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiere - Google Patents

Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiere

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Publication number
EP1374234A1
EP1374234A1 EP02735148A EP02735148A EP1374234A1 EP 1374234 A1 EP1374234 A1 EP 1374234A1 EP 02735148 A EP02735148 A EP 02735148A EP 02735148 A EP02735148 A EP 02735148A EP 1374234 A1 EP1374234 A1 EP 1374234A1
Authority
EP
European Patent Office
Prior art keywords
sulfonate
formula
represents hydrogen
optical data
chlorobenzenesulfonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02735148A
Other languages
German (de)
English (en)
Inventor
Horst Berneth
Friedrich-Karl Bruder
Wilfried Haese
Rainer Hagen
Karin HASSENRÜCK
Serguei Kostromine
Peter Landenberger
Rafael Oser
Thomas Sommermann
Josef-Walter Stawitz
Thomas Bieringer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Deutschland GmbH
Original Assignee
Bayer Chemicals AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE10115227A external-priority patent/DE10115227A1/de
Priority claimed from DE10117462A external-priority patent/DE10117462A1/de
Priority claimed from DE2001136064 external-priority patent/DE10136064A1/de
Application filed by Bayer Chemicals AG filed Critical Bayer Chemicals AG
Publication of EP1374234A1 publication Critical patent/EP1374234A1/fr
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D221/00—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00
    • C07D221/02—Heterocyclic compounds containing six-membered rings having one nitrogen atom as the only ring hetero atom, not provided for by groups C07D211/00 - C07D219/00 condensed with carbocyclic rings or ring systems
    • C07D221/04—Ortho- or peri-condensed ring systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D217/00—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems
    • C07D217/12—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems with radicals, substituted by hetero atoms, attached to carbon atoms of the nitrogen-containing ring
    • C07D217/14—Heterocyclic compounds containing isoquinoline or hydrogenated isoquinoline ring systems with radicals, substituted by hetero atoms, attached to carbon atoms of the nitrogen-containing ring other than aralkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/04—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring
    • C07D311/06—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2
    • C07D311/08—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2 not hydrogenated in the hetero ring
    • C07D311/12—Benzo[b]pyrans, not hydrogenated in the carbocyclic ring with oxygen or sulfur atoms directly attached in position 2 not hydrogenated in the hetero ring substituted in position 3 and unsubstituted in position 7
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D311/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings
    • C07D311/02—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only hetero atom, condensed with other rings ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D311/78—Ring systems having three or more relevant rings
    • C07D311/80—Dibenzopyrans; Hydrogenated dibenzopyrans
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D455/00—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine
    • C07D455/03—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing quinolizine ring systems directly condensed with at least one six-membered carbocyclic ring, e.g. protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine
    • C07D455/04—Heterocyclic compounds containing quinolizine ring systems, e.g. emetine alkaloids, protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing quinolizine ring systems directly condensed with at least one six-membered carbocyclic ring, e.g. protoberberine; Alkylenedioxy derivatives of dibenzo [a, g] quinolizines, e.g. berberine containing a quinolizine ring system condensed with only one six-membered carbocyclic ring, e.g. julolidine
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
    • C07D491/04—Ortho-condensed systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/0091—Methine or polymethine dyes, e.g. cyanine dyes having only one heterocyclic ring at one end of the methine chain, e.g. hemicyamines, hemioxonol
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/02—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups
    • C09B23/04—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain containing an odd number of >CH- or >C[alkyl]- groups one >CH- group, e.g. cyanines, isocyanines, pseudocyanines
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
    • C09B23/10—The polymethine chain containing an even number of >CH- groups
    • C09B23/105—The polymethine chain containing an even number of >CH- groups two >CH- groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C09B29/0025—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds
    • C09B29/0029—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds the heterocyclic ring containing only nitrogen as heteroatom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C09B29/0025—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds
    • C09B29/0074—Monoazo dyes prepared by diazotising and coupling from diazotized amino heterocyclic compounds the heterocyclic ring containing nitrogen and sulfur as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B29/00—Monoazo dyes prepared by diazotising and coupling
    • C09B29/34—Monoazo dyes prepared by diazotising and coupling from other coupling components
    • C09B29/36—Monoazo dyes prepared by diazotising and coupling from other coupling components from heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B44/00—Azo dyes containing onium groups
    • C09B44/10—Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B47/00—Porphines; Azaporphines
    • C09B47/04—Phthalocyanines abbreviation: Pc
    • C09B47/045—Special non-pigmentary uses, e.g. catalyst, photosensitisers of phthalocyanine dyes or pigments
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B47/00—Porphines; Azaporphines
    • C09B47/04—Phthalocyanines abbreviation: Pc
    • C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
    • C09B47/085—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex substituting the central metal atom
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B47/00—Porphines; Azaporphines
    • C09B47/04—Phthalocyanines abbreviation: Pc
    • C09B47/08—Preparation from other phthalocyanine compounds, e.g. cobaltphthalocyanineamine complex
    • C09B47/24—Obtaining compounds having —COOH or —SO3H radicals, or derivatives thereof, directly bound to the phthalocyanine radical
    • C09B47/26—Amide radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00—Dyes not provided for by a single group of this subclass
    • C09B69/02—Dyestuff salts, e.g. salts of acid dyes with basic dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K9/00—Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
    • C09K9/02—Organic tenebrescent materials
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/004—Recording, reproducing or erasing methods; Read, write or erase circuits therefor
    • G11B7/0045—Recording
    • G11B7/00455—Recording involving reflectivity, absorption or colour changes
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
    • G11B7/248—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes porphines; azaporphines, e.g. phthalocyanines
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
    • G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
    • G11B7/249—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing organometallic compounds
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
    • G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
    • G11B7/254—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
    • G11B7/26—Apparatus or processes specially adapted for the manufacture of record carriers
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
    • G11B7/007—Arrangement of the information on the record carrier, e.g. form of tracks, actual track shape, e.g. wobbled, or cross-section, e.g. v-shaped; Sequential information structures, e.g. sectoring or header formats within a track

Definitions

  • Optical data carrier containing a hemicyanine dye in the information layer as a light-absorbing compound
  • the invention relates to a write-once optical data carrier which contains a hemicyanic dye in the information layer as a light-absorbing compound, and to a method for its production.
  • the write-once optical data carriers using special light-absorbing substances or their mixtures are particularly suitable for use with high-density writable optical data storage media that are marked with blue ones
  • Laser diodes in particular GaN or SHG laser diodes (360 - 460 ⁇ m) work and / or for use with DVD-R or CD-R discs that work with red (635 - 660 nm) or infrared (780 - 830 nm) laser diodes , and the application of the above-mentioned dyes to a polymer substrate, in particular polycarbonate, by spin coating or vapor deposition.
  • the storage density can be increased by using shorter-wave laser radiation (635 to 660 nm) and a higher numerical aperture NA.
  • the recordable format in this case is the DVD-R.
  • NA is the numerical aperture of the objective lens used. To receive one The highest possible storage density should be aimed at using the smallest possible wavelength ⁇ . 390 nm are currently possible on the basis of semiconductor laser diodes.
  • the patent literature describes dye-based writable optical data memories which are equally suitable for CD-R and DVD-R systems (JP-A 11 043 481 and JP-A 10 181 206).
  • JP-A 11 043 481 and JP-A 10 181 206 For a high reflectivity and a high modulation level of the readout signal, as well as for a sufficient sensitivity when writing, use is made of the fact that the IR wavelength 780 nm of the CD-R lies at the foot of the long-wave flank of the absorption peak of the dye.
  • the red wavelength 635 nm or 650 nm 'of the DVD-R lies at the foot of the short-wave flank of the absorption peak of the dye.
  • the writable information layer made of light-absorbing organic substances must have a morphology which is as amorphous as possible in order to keep the noise signal as small as possible when writing or reading.
  • the substances are applied by spin coating from a solution, by vapor deposition and / or sublimation, subsequent crystallization of the light-absorbing substances with metallic or dielectric layers in vacuum is prevented.
  • the amorphous layer of light-absorbing substances should preferably have a high heat resistance, since otherwise further layers of organic or inorganic material, which are applied to the light-absorbing information layer by sputtering or vapor deposition, are blurred by diffusion
  • An excessively high vapor pressure of a light-absorbing substance can sublimate the above-mentioned sputtering or vapor deposition of further layers in a high vacuum and thus reduce the desired layer thickness. This in turn leads to a negative influence on the reflectivity.
  • the object of the invention is therefore to provide suitable compounds which meet the high requirements (such as light stability, favorable signal-to-noise ratio, damage-free application to the substrate material, etc.) for use in the information layer in a write-once optical data carrier, in particular for high-density recordable optical media Meet data storage formats in a laser wavelength range from 340 to 680 nm.
  • the invention therefore relates to an optical data carrier, comprising a preferably transparent substrate, optionally already coated with one or more reflection layers, on the surface of which an information layer which can be written on with light, optionally one or more reflection layers and optionally a protective layer or a further substrate or a cover layer is applied, which can be written and read with blue or red light, preferably laser light, the information layer containing a light-absorbing compound and optionally a binder, characterized in that at least one hemicyanine dye is used as the light-absorbing compound. Blue laser light is particularly preferred.
  • the light-absorbing compound should preferably be thermally changeable.
  • the thermal change preferably takes place at a temperature ⁇ 600 ° C., particularly preferably at a temperature ⁇ 400 ° C., very particularly preferably at one
  • Such a change can be, for example, a decomposition or chemical change in the chromophoric center of the light-absorbing compound.
  • a hemicyanine of formula I is preferred
  • X 1 represents nitrogen or
  • X 2 represents O, S, NR 2 or CR 3 R 4 ,
  • R 1 and R 2 independently of one another represent Ci to C 16 alkyl, C 3 to C 6 alkenyl, C 5 to C 7 cycloalkyl or C 7 to C 16 aralkyl,
  • R 3 and R 4 independently of one another represent d- to C 4 -alkyl or
  • a together with X 1 , X 2 and the C atom bonded between them represents a five- or six-membered aromatic or quasi-aromatic heterocyclic ring which contain 1 to 4 heteroatoms and / or benzylated or naphthanellated and / or substituted by nonionic radicals can be,
  • R and R independently of one another for hydrogen, C ⁇ - to C 16 alkyl, C 4 - to C 7 -
  • Cycloalkyl C 7 - to C ⁇ 6 aralkyl, C 6 - to C ⁇ 0 aryl or a heterocyclic radical or
  • NR 5 R 6 stands for a five- or six-membered saturated ring attached via N, which may additionally contain an N or O and / or may be substituted by nonionic radicals,
  • R 7 represents hydrogen, Ci- to C ⁇ - 6 alkyl, C - to C 16 -alkoxy or halogen or
  • R 7 and R 5 form a two- or three-membered bridge which may contain an O or N and / or which may be substituted by nonionic radicals,
  • R 8 for hydrogen, d to C 6 alkyl, to C 16 alkoxy, halogen, cyano, Q to C 4 alkoxycarbonyl, O-CO-R 10 , NR ⁇ -CO-R 10 , O-SO 2 -R 10 or
  • R 9 for hydrogen, d to C 4 alkyl, cyano, CO-OR 12 , CO-NR 1! R 12 , CS-OR 12 or CS-NR ⁇ R 12
  • R 10 is hydrogen, d to C 16 alkyl, C 4 to C 7 cycloalkyl, C 7 to C 16 aralkyl, d to C 16 alkoxy, mono- or bis-d to C 16 Alkylamino, C 6 to C 10 aryl, C 6 to do aryloxy, C 6 to C 10 arylamino or a heterocyclic radical,
  • R, ⁇ represents hydrogen or d- to C-alkyl
  • R. 1 1 2 represents d to C 4 alkyl, C 4 to C 7 cycloalkyl, C 7 to C 16 aralkyl or C 6 to do aryl and
  • X may also stand for CR, where R has the meaning given above.
  • Ring A together with X, X and the C atom bound between them may also be a partially hydrogenated heterocyclic ring.
  • non-ionic radicals are for example C to C alkyl, d- to C 4 alkoxy, halogen, cyano, nitro, C ⁇ - to d-alkoxycarbonyl, d- to C alkylthio, d- to C - alkanoylamino, benzoylamino, Mono- or di-d to C 4 alkylamino in question.
  • Alkyl, alkoxy, aryl and heterocyclic radicals can optionally carry further radicals such as alkyl, halogen, nitro, cyano, CO-NH 2 , alkoxy, trialkylsilyl, trialkylsiloxy or phenyl, the alkyl and alkoxy radicals can be straight-chain or branched , The alkyl radicals can be partially or perhalogenated, the alkyl and
  • Alkoxy radicals can be ethoxylated or propoxylated or silylated, adjacent alkyl and / or alkoxy radicals on aryl or heterocyclic radicals can together form a three- or four-membered bridge and the heterocyclic radicals can be fused to benzene and / or quaternized.
  • Ring A of the formula is particularly preferably
  • Ring A of the formula is likewise particularly preferably
  • Ci to C 6 alkyl d to C 6 -Alkoxy, fluorine, chlorine, bromine, iodine, cyano, nitro, Ci- to C 6 -alkoxycarbonyl C 6 - to Cio-aryl or C 6 - to Cio-aryloxy may be substituted.
  • the hemicyanines used are those of the formula (I)
  • benzthiazol-2-yl for benzthiazol-2-yl, benzimidazol-2-yl, 3,3-dimethyl-3H-indol-2-yl, pyrimid-2-one-4-yl, 2- or 4-pyridyl or 2- or 4-quinolyl stands, the radicals mentioned in each case by methyl, ethyl, methoxy, ethoxy, chlorine,
  • R 1 for methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, phenethyl, phenylpropyl, allyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, cyanopropyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl or a radical of the formula
  • R 2 in the case that the ring A is benzimidazol-2-yl has the same meaning as R 1 ,
  • R 5 and R 6 independently of one another are methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, phenethyl, phenylpropyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, cyanopropyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl,
  • R 5 can additionally represent hydrogen or NR 5
  • R 6 represents pyrrolidino, piperidino, N-methylpiperidino, N-ethylpiperidino, N-hydroxyethylpiperidino or morpholino,
  • R 7 represents hydrogen, methyl, methoxy or chlorine or
  • R represents hydrogen, methyl, methoxy or chlorine
  • R 9 represents hydrogen
  • Biphenyl disulfonate optionally substituted by nitro, cyano, Ci to C 4 alkyl, Ci to C 4 alkoxy, Ci to C alkoxycarbonyl, benzoyl, chlorobenzoyl or toluoyl, the anion of naphthalenedicarboxylic acid, diphenyl ether disulfonate, tetraphenylborate, cyanotriphenyl, cyanotriphenyl, cyanotriphenyl Tetra-Cj- to C 2 o-alkoxyborate, tetraphenoxyborate, 7,8- or 7,9-dicarba-nido-undecaborate (l-) or (2-), which are optionally attached to the B- and / or C- Atoms through one or two d- to C 12 -alkyl- or P enyl- Groups are substituted, dodecahydro-dicarbadodecaborate (2-) or Bd- to C 12 -
  • Bromide, iodide, tetrafluoroborate, perchlorate, methanesulfonate, benzenesulfonate, toluenesulfonate, dodecylbenzenesulfonate, tetradecanesulfonate are preferred.
  • the hemicyanins used are those of the formulas (III) to (VI)
  • R 1 is methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl or a radical of the formula
  • R 5 and R 6 independently of one another represent methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl, methoxycarbonylethyl, ethoxycarbonylethyl, acetoxyethyl, phenyl, tolyl or methoxyphenyl or
  • NR R represents pyrrolidino, N-methylpiperidino or morpholino
  • R 7 represents hydrogen or
  • R 7 ; R 5 represent a - (CH 2 ) 2 -, -C (CH 3 ) -CH 2 -C (CH 3 ) 2 - or -O- (CH 2 ) 2 bridge,
  • R 8 represents hydrogen
  • R represents hydrogen
  • the hemicyanins used are those of the formulas (purple) and (INa)
  • R 1 for methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl or a radical of the formula
  • R 5 and R 6 independently of one another are methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, hydroxyethyl, 2-hydroxypropyl, methoxy- ethyl, ethoxyethyl, methoxycarbonylethyl, ethoxycarbonylethyl, acetoxyethyl, phenyl, tolyl or methoxyphenyl or
  • NR 5 R 6 represents pyrrolidino, N-methylpiperidino, morpholino or N, N-bis- (2-cyanoethyl) amino,
  • R 7 represents hydrogen or
  • R 7 ; R 5 represent a - (CH 2 ) 2 -, -C (CH 3 ) -CH 2 -C (CH 3 ) 2 - or -O- (CH 2 ) 2 bridge,
  • R represents hydrogen
  • R represents hydrogen
  • R 13 represents hydrogen, methyl, methoxy, chlorine, nitro, cyano or methoxycarbonyl
  • R 14 represents hydrogen, methyl, methoxy or ethoxy
  • R is preferably hydrogen, methyl, methoxy or methoxycarbonyl and R 14 is hydrogen.
  • hemicyanins used are those of the formulas (NU) to (IX)
  • R 1 for methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanomethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, methoxyethyl, ethoxyethyl or a radical of the formula
  • R 5 and R 6 independently of one another are methyl, ethyl, propyl, butyl, pentyl, hexyl, benzyl, cyclohexyl, chloroethyl, cyanoethyl, hydroxyethyl, 2-hydroxypropyl, Methoxyethyl, ethoxyethyl, methoxycarbonylethyl, ethoxycarbonylethyl, acetoxyethyl, phenyl, tolyl or methoxyphenyl or
  • NR 5 R 6 represents pyrrolidino, N-methylpiperidino or morpholino
  • R represents hydrogen or
  • R 7 ; R 5 represent a - (CH 2 ) 2 -, -C (CH 3 ) -CH 2 -C (CH 3 ) 2 - or -O- (CH 2 ) 2 bridge,
  • R 8 represents hydrogen
  • R 9 represents hydrogen
  • a write-once optical data medium which is written and read with the light of a blue laser
  • Such a hemicyanine dye preferably does not have a shorter-wave maximum ⁇ max ⁇ up to a wavelength of 350 nm, particularly preferably up to 320 nm, very particularly preferably up to 290 nm.
  • Hemicyanine dyes with an absorption maximum ⁇ max2 of 410 to 530 nm are preferred.
  • Hemicyanine dyes with an absorption maximum ⁇ max2 of 420 to 510 nm are particularly preferred.
  • Hemicyanine dyes with an absorption maximum ⁇ maX 2 of 430 to 500 nm are very particularly preferred.
  • a write-once optical data medium which is written and read with the light of a red laser
  • Such a hemicyanine dye preferably has no longer-wavelength maximum ⁇ max3 up to a wavelength of 750 nm, particularly preferably up to 800 nm, very particularly preferably up to 850 nm.
  • Hemicyanine dyes with an absorption maximum ⁇ maX 2 of 530 to 630 nm are preferred.
  • Hemicyanine dyes with an absorption maximum ⁇ max2 of 550 to 620 nm are particularly preferred.
  • Hemicyanine dyes with an absorption maximum ⁇ maX 2 of 580 to 610 nm are very particularly preferred.
  • hemicyanine dyes ⁇ / 2 and ⁇ o are preferably not more than 40 nm apart, more preferably not more than 30 nm apart, very particularly preferably not more than 20 nm apart.
  • the hemicyanine dyes have a molar extinction coefficient ⁇ > 40,000 1 / mol cm, preferably> 60,000 1 / mol cm, particularly preferably> 80,000 1 / mol cm, very particularly preferably> 100,000 1 / mol cm.
  • the absorption spectra are measured, for example, in solution.
  • a method for determining such a dipole moment change ⁇ is described, for example, in F. Würthner et al., Angew. Chem. 1997, 109, 2933 and in the literature cited therein.
  • a low solvatochromism (methanol / methylene chloride) is also a suitable selection criterion.
  • Hemicyanins which are particularly preferred in the sense of the invention are those of the formulas (III) and (V).
  • Hemicyanines of the formulas (I) and (III) to (VI) are known, for. B. from DE-OS 2 932
  • the light-absorbing substances described guarantee a sufficiently high reflectivity (> 10%) of the optical data carrier in the blank state and a sufficiently high absorption for the thermal degradation of the information layer in the case of selective illumination with focused light if the light wavelength is in the range from 360 to 460 nm and 600 to 680 nm.
  • the contrast between written and unwritten areas on the data carrier is realized by the change in reflectivity of the amplitude and the phase of the incident light by the optical properties of the information layer which have changed after thermal degradation.
  • the hemicarm dyes are preferably applied to the optical data carrier by spin coating or vacuum evaporation.
  • the hemicyanins can be mixed with one another or with other dyes with similar spectral properties.
  • the information layer can be in addition to the hemicyanine dyes
  • Additives contain such as binders, wetting agents, stabilizers, thinners and sensitizers as well as other components.
  • the optical data storage device can carry further layers such as metal layers, dielectric layers and protective layers.
  • Metals and dielectric layers serve u. a. to adjust the reflectivity and the heat balance. Depending on the laser wavelength, metals can be gold, silver, aluminum and the like. a. his.
  • Dielectric layers are, for example, silicon dioxide and silicon nitride.
  • Protective layers are, for example, photocurable, lacquers, adhesive layers and protective films.
  • Adhesive layers can consist of pressure-sensitive material.
  • the invention further relates to a write-once optical data carrier, comprising a preferably transparent substrate, on the surface of which at least one information layer which can be written on with light, optionally one Reflective layer and / or optionally a protective layer are applied, which can be written and read with blue light, preferably laser light, the information layer containing at least one of the abovementioned light-absorbing compounds and, if appropriate, a binder, wetting agent, stabilizers, thinners and sensitizers and further constituents ,
  • the structure of the optical data carrier can be:
  • Pressure-sensitive adhesive layers mainly consist of acrylic adhesives.
  • the optical data carrier has, for example, the following layer structure (cf. FIG. 1): a transparent substrate (1), optionally a protective layer (2), an information layer (3), optionally a protective layer (4), optionally an adhesive layer (5), a cover layer (6).
  • the structure of the optical data carrier can preferably:
  • Protective layer (4) optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
  • a transparent substrate (1) on the surface of which a protective layer (2), at least one information layer (3) which can be written on with light, preferably laser light, optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
  • a transparent substrate (1) on the surface of which there is optionally a protective layer (2), at least one information layer (3) which can be written on with light, preferably laser light, optionally a protective layer (4), optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
  • a preferably transparent substrate (1) on the surface of which at least one information layer (3) which can be written on with light, preferably laser light, optionally an adhesive layer (5), and a transparent cover layer (6) are applied.
  • the optical data carrier has, for example, the following layer structure
  • a preferably transparent substrate 11
  • an information layer (12)
  • optionally a reflection layer 13
  • optionally an adhesive layer 14
  • another preferably transparent substrate 15
  • the invention further relates to optical data carriers according to the invention described with blue or red light, in particular laser light.
  • 3H-indole was stirred in a mixture of 5 ml of glacial acetic acid and 1 ml of acetic anhydride at 40 ° C. for 2 h. After cooling, it was poured onto 80 ml of water in which 2.6 g of sodium tetrafluoroborate were dissolved. It was suctioned off, washed with water and dried. 1.6 g of 42% of theory were obtained. Th.) Of a red powder of the formula
  • the pregrooved polycarbonate substrate was manufactured as a disk using injection molding.
  • the dimensions of the disk and the groove structure corresponded to those that are usually used for DND-R.
  • the disk with the dye layer as an information carrier was with 100 nm
  • a UV-curable acrylic lacquer was then applied by spin coating and cured using a UN lamp.
  • the light reflected by the reflective layer of the disc was With the aid of the polarization-sensitive beam splitter mentioned above, it is coupled out of the beam path and focused on an Nierquadranendetector by an astigmatic lens.
  • the write power was applied as an oscillating pulse sequence, the disk being alternately irradiated for 1 ⁇ s with the above-mentioned write power P w and for 4 ⁇ s with the read power P r ⁇ 0.44 mW.
  • the disc was irradiated with this oscillating pulse sequence until it had turned around once. The marking generated in this way was then read out with the reading power P r ⁇ 0.44 mW and the above-mentioned signal-noise

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Optical Record Carriers And Manufacture Thereof (AREA)
  • Thermal Transfer Or Thermal Recording In General (AREA)
  • Indole Compounds (AREA)
  • Manufacturing Optical Record Carriers (AREA)

Abstract

La présente invention concerne un support de données optique comprenant un substrat, qui est de préférence transparent et éventuellement déjà revêtu d'une ou de plusieurs couches de réflexion. Une couche d'information inscriptible au moyen de lumière, éventuellement une ou plusieurs couches de réflexion et éventuellement une couche de protection, un autre substrat ou une couche de revêtement sont appliqués à la surface dudit substrat et peuvent être pourvus d'une inscription et lus au moyen de lumière bleue ou rouge, de préférence au moyen d'une lumière laser. La couche d'information renferme un composé absorbant la lumière et éventuellement un liant et est caractérisée en ce qu'on utilise au moins un colorant à base d'hémicyanine en tant que composé absorbant la lumière.
EP02735148A 2001-03-28 2002-03-20 Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiere Withdrawn EP1374234A1 (fr)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
DE10115227A DE10115227A1 (de) 2001-03-28 2001-03-28 Optischer Datenträger enthaltend in der Informationsschicht eine lichtabsorbierende Verbindung mit mehreren chromophoren Zentren
DE10115227 2001-03-28
DE10117462A DE10117462A1 (de) 2001-04-06 2001-04-06 Optischer Datenträger enthaltend in der Informationsschicht einen Hemicyaninfarbstoff als lichtabsorbierende Verbindung
DE10117462 2001-04-06
DE2001136064 DE10136064A1 (de) 2001-07-25 2001-07-25 Optischer Datenträger enthaltend in der Informationsschicht einen Xanthenfarbstoff als lichtabsorbierende Verbindung
DE10136064 2001-07-25
PCT/EP2002/003088 WO2002086879A1 (fr) 2001-03-28 2002-03-20 Support de donnees optique dont la couche d'information renferme un colorant a base d'hemicyanine qui sert de compose absorbant la lumiere

Publications (1)

Publication Number Publication Date
EP1374234A1 true EP1374234A1 (fr) 2004-01-02

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US (1) US20030054291A1 (fr)
EP (1) EP1374234A1 (fr)
JP (1) JP2004524199A (fr)
CN (1) CN1527996A (fr)
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WO (1) WO2002086879A1 (fr)

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TW593658B (en) * 2002-12-31 2004-06-21 Ind Tech Res Inst Fluorescent recording media dye, and fluorescent recording media
TW593561B (en) * 2003-05-14 2004-06-21 Ind Tech Res Inst Bis-styryl dye and method for manufacturing the same and its use for a high density optical recording medium
JP2007526835A (ja) * 2003-06-27 2007-09-20 チバ　スペシャルティ　ケミカルズ　ホールディング　インコーポレーテッド 高記憶密度を有する光学記録材料
JP2008501548A (ja) * 2004-06-03 2008-01-24 クラリアント・インターナシヨナル・リミテツド 光学データ記録用光学層におけるスクアリン酸色素の使用
DE102004028845A1 (de) * 2004-06-16 2006-01-05 Bayer Chemicals Ag Optischer Datenträger enthaltend in der Informationsschicht einen Hemicyaninfarbstoff als lichtabsorbierende Verbindung
EP1630205A1 (fr) * 2004-08-24 2006-03-01 Clariant International Ltd. Colorants de type styrylpyridinium-imine et leur utilisation dans des couches optiques pour l'enregistrement optique de données
EP2356182B1 (fr) * 2008-11-12 2015-05-06 Basf Se Matières de revêtement durcissables par rayonnement

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5856239A (ja) * 1981-09-28 1983-04-02 Tdk Corp 光記録媒体
US4756987A (en) * 1985-11-27 1988-07-12 Mitsubishi Chemical Industries Limited Optical recording medium
EP0463784B1 (fr) * 1990-06-19 1998-10-14 Canon Kabushiki Kaisha Support d'enregistrement optique, méthode d'enregistrement optique et méthode de reproduction optique
JPH0538878A (ja) * 1991-08-07 1993-02-19 Nippon Columbia Co Ltd 光記録媒体
EP0540468B1 (fr) * 1991-10-30 1996-12-04 Ciba-Geigy Ag Colorants absorbants dans l'infra-rouge proche, procédé pour leur préparation et leur utilisation
JP3705877B2 (ja) * 1996-11-21 2005-10-12 三井化学株式会社 光記録媒体
JPH1134497A (ja) * 1997-07-24 1999-02-09 Matsushita Electric Ind Co Ltd 光記録媒体
US6103331A (en) * 1997-09-26 2000-08-15 Fuji Electric Co., Ltd. Optical recording medium comprising organic dye thin film
CN1108304C (zh) * 1997-09-26 2003-05-14 复旦大学 蓝光dvd－r用光信息存贮材料
KR100370405B1 (ko) * 2000-05-17 2003-01-29 삼성전자 주식회사 헤미시아닌 색소 및 이를 이용한 광기록매체
JP2002206061A (ja) * 2000-07-05 2002-07-26 Hayashibara Biochem Lab Inc スチリル色素
JP2002074740A (ja) * 2000-08-25 2002-03-15 Hayashibara Biochem Lab Inc 光記録媒体

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO02086879A1 *

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US20030054291A1 (en) 2003-03-20
JP2004524199A (ja) 2004-08-12
WO2002086879A1 (fr) 2002-10-31
CN1527996A (zh) 2004-09-08

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