EP1341958A1 - Materiau textile muni de cyclodextrines polymeres et procede permettant de le produire - Google Patents

Materiau textile muni de cyclodextrines polymeres et procede permettant de le produire

Info

Publication number
EP1341958A1
EP1341958A1 EP01989583A EP01989583A EP1341958A1 EP 1341958 A1 EP1341958 A1 EP 1341958A1 EP 01989583 A EP01989583 A EP 01989583A EP 01989583 A EP01989583 A EP 01989583A EP 1341958 A1 EP1341958 A1 EP 1341958A1
Authority
EP
European Patent Office
Prior art keywords
cyclodextrin
textile material
textile
polymer matrix
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01989583A
Other languages
German (de)
English (en)
Inventor
Hans-Jürgen BUSCHMANN
Eckhard Schollmeyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huntsman Advanced Materials Switzerland GmbH
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Ciba SC Holding AG filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of EP1341958A1 publication Critical patent/EP1341958A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
    • D06M15/423—Amino-aldehyde resins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer

Definitions

  • the aqueous or organic solution of cyclodextrin and / or cyclodextrin derivatives used in the first step contains the cyclodextrin or cyclodextrin derivative as the first polymer-forming component. It is understood that the cyclodextrins or their derivatives are polyfunctional, i.e. H. have at least two functions suitable for polymer formation. In addition, the solution may have other additives which are necessary for polymer formation or which promote polymer formation.
  • textile material means that the textile materials represent, for example, fibers, filaments, yarns, piles or fabrics.
  • polyalcohols, polyamines or other polyfunctional molecules with at least two functions suitable for crosslinking are suitable as the second polymer-forming component.
  • chain lengths of C 2 to C 2 in particular C to C 10
  • these crosslinkers is preferred, aliphatic polyfunctional crosslinkers being preferred over aromatic ones.
  • the second polymer-forming component are the - and / or polyfunctional compounds, such as dicarboxylic acids, dicarboxylic acid anhydrides, diisocyanates, aminocarboxylic acids, diols, diamines or thiols.
  • cyclodextrin and a second polymer-forming component reactive therewith for example a diisocyanate, a dicarboxylic acid dichloride, a dicarboxylic acid anhydride or the like, are expediently mixed with any necessary customary auxiliaries, for example catalysts, and, if appropriate, dissolved in an unreactive solvent, so that the crosslinking reaction begins.
  • the mixture in the crosslinking is then applied to the textile material in a conventional manner and introduced into it, for example by spraying or soaking, so that the crosslinking can take place.
  • Cyanuric chloride is particularly suitable for this reaction.
  • Particularly preferred materials for the second component are di- and polyisocyanates in their monomeric or oligomeric forms, for example hexamethylene diisocyanate, isophorone diisocyanate, or also MDI or TDI.
  • Mixing of the two components and application are coordinated with one another in such a way that partial contact (prepolymer formation) has already taken place on contact with the textile material and the final crosslinking itself takes place on and in the textile material. If small amounts of water are added (less than 1% by weight, preferably 0.2 to 0.5% by weight), foaming can additionally be achieved.
  • the polymerization of the components provided for this takes place before, during and after application to the textile material at the usual temperatures and time frame provided for the materials. Removal of solvents or solvent residues, if required, takes place at the normal temperatures which are acceptable for the textile material.
  • the solvent is then removed in a drying step in a temperature range from 60 to 150 ° C.
  • the treatment time in the multi-stage process depends on the textile material used and the treatment temperature and can vary in a range from 5 minutes to 120 minutes.
  • the textile material which contains the polymer matrix according to the invention is constructed in such a way that the polymer matrix forms a "mixed fabric" with the existing textile material, which contains the cyclodextrin in the polymer matrix as a building block.
  • the textile materials used in the field of filter application can preferably have a rigid design of the textile material as well as a higher loading with cyclodextrin, cyclodextrin derivatives or mixtures thereof.
  • Preferred materials are those which have a fine foam on the surface of the textile material in order to additionally enlarge the surface.
  • a cotton and a polyester standard fabric with a basis weight of 100 g / m 2 were padded with the following liquor, the textile material first being immersed in the liquor for 2 minutes and then padding for 3 m / min at a line pressure of 50 kp / cm 2 has been.
  • the fabric treated in this way was condensed after drying for 90 minutes at 150 ° C. over a period of 2 minutes.
  • the basic composition of the fleet consisted of dimethylol urea in an amount of 50 g / l magnesium chloride hexahydrate in an amount of 10 g / l, ammonium sulfate in an amount of 1 g / l and? -Cyclodextrin.
  • Six basic compositions were prepared in which the? -Cyclodextrin was mixed in amounts of 0 g / l, 10 g / l, 20 g / l, 30 g / l, 40 g / l and 50 g /
  • the finished tissue samples were washed fifty times each according to the conditions described above. Afterwards, these materials were immersed again in the standardized butyric acid solution, squeezed and rinsed. There was again the reduction of Concentration of the butyric acid solution observed. The measured values in the fleet corresponded to those of the first measurement.
  • the standard polyester fabric resulted in a product that contained the cyclodextrin fully incorporated into the polymer matrix.
  • the cotton standard fabric still contained numerous bonds of the polymer matrix to the fiber, although the cyclodextrin was predominantly in the polymer matrix.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

L'invention concerne un matériau textile muni de cyclodextrine, qui présente une matrice polymère contenant de la cyclodextrine et/ou un dérivé de cyclodextrine. L'invention concerne en outre un procédé permettant de produire un tel matériau textile.
EP01989583A 2000-12-07 2001-12-07 Materiau textile muni de cyclodextrines polymeres et procede permettant de le produire Withdrawn EP1341958A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10060710 2000-12-07
DE10060710A DE10060710A1 (de) 2000-12-07 2000-12-07 Textiles Material ausgerüstet mit einer Polymermatrix und Cyclodextrinen, Cyclodextrinderivaten oder Mischungen davon, ein Verfahren zu deren Herstellung und deren Verwendung
PCT/EP2001/014367 WO2002046520A1 (fr) 2000-12-07 2001-12-07 Materiau textile muni de cyclodextrines polymeres et procede permettant de le produire

Publications (1)

Publication Number Publication Date
EP1341958A1 true EP1341958A1 (fr) 2003-09-10

Family

ID=7666057

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01989583A Withdrawn EP1341958A1 (fr) 2000-12-07 2001-12-07 Materiau textile muni de cyclodextrines polymeres et procede permettant de le produire

Country Status (8)

Country Link
US (1) US20050260905A1 (fr)
EP (1) EP1341958A1 (fr)
KR (1) KR20030074646A (fr)
CN (1) CN1479822A (fr)
AU (1) AU2002227995A1 (fr)
BR (1) BR0115992A (fr)
DE (1) DE10060710A1 (fr)
WO (1) WO2002046520A1 (fr)

Families Citing this family (18)

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MXPA05013495A (es) * 2003-06-26 2006-03-09 Ciba Sc Holding Ag Composiciones liquidas acuosas de ciclodextrina o derivados de ciclodextrina y proceso que usa dichas composiciones.
DE102004035898B4 (de) * 2004-07-23 2008-04-24 Cht R. Beitlich Gmbh Textilausrüstungsmittel enthaltend einen Komplex aus gamma-Cyclodextrin und alpha-Tocopherol
KR100786974B1 (ko) * 2007-03-16 2007-12-17 이승인 공해 없는 요소수지와 그를 이용한 강력 비스코오스 레이온필라멘트사의 제조방법
US7879747B2 (en) * 2007-03-30 2011-02-01 Kimberly-Clark Worldwide, Inc. Elastic laminates having fragrance releasing properties and methods of making the same
DE102007034724A1 (de) 2007-07-23 2009-01-29 Stiftung Nano Innovations, Olten Verfahren und Zusammensetzung zur Beschichtung von Oberflächen
DE102007043323A1 (de) 2007-09-12 2009-03-19 Septana Gmbh Sol-Gel Beschichtungen von Oberflächen mit geruchsbindenden Eigenschaften
DE102007062525A1 (de) 2007-12-20 2009-06-25 Tag Composites & Carpets Gmbh Polyurethane mit Cyclodextrinen als Synthesebausteinen
EP2563305A1 (fr) * 2010-04-26 2013-03-06 Aalborg Universitet Procédé de fonctionnalisation d'une surface de matériau solide avec des cyclodextrines à auto-assemblage ou à auto-ségrégation et produits associés
WO2012101618A1 (fr) 2011-01-28 2012-08-02 Barcelcom Têxteis S.A. Tuyaux et bas de contention pourvus d'agents bioactifs pour le traitement de l'insuffisance veineuse et des varices
ITRM20120120A1 (it) * 2011-03-31 2012-10-01 Gianis S R L Legante e procedimento di produzione di tessili contenenti ciclodestrine fissate con detto legante.
DE102015107174B4 (de) 2015-05-07 2022-07-07 Lisa Dräxlmaier GmbH Cyclodextrinhaltige Heißschmelzklebemassen und Verfahren zur Herstellung
CN105088775A (zh) * 2015-09-11 2015-11-25 无锡市长安曙光手套厂 一种接枝β环糊精的释香织物及其制备方法
DE102016110472A1 (de) 2016-06-07 2017-12-07 Lisa Dräxlmaier GmbH Verwendung von Cyclodextrinen zur Verminderung von Emissionen
CN109137504B (zh) * 2018-08-01 2021-12-07 湖南七纬科技有限公司 一种织物硬挺剂及其制备方法
CN109096905B (zh) * 2018-08-21 2020-11-03 青岛科技大学 一种持久抗菌型改性聚氨酯及其制备方法
CN109610157B (zh) * 2018-09-18 2021-04-20 杭州创屹机电科技有限公司 一种人造皮革用抗菌防臭麻纤维基底布的制备方法
CN109468835A (zh) * 2018-10-11 2019-03-15 杭州创屹机电科技有限公司 一种皮肤损伤治疗用可穿戴麻纤维面料的制备方法
CN116284504A (zh) * 2023-01-04 2023-06-23 昆明理工大学 一系列交联型环糊精聚合物及其制备方法与应用

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60152535A (ja) * 1984-01-20 1985-08-10 Ichiro Shibauchi 架橋剤及びその製造方法
US4931524A (en) * 1986-02-17 1990-06-05 Dai-Ichi Kogyo Seiyaku Co., Ltd. Surface-treatment of synthetic or semi-synthetic fiber textile materials
US4917956A (en) * 1988-07-11 1990-04-17 Uop Method of preparing cyclodextrin-coated surfaces
DE4035378C2 (de) * 1990-11-07 2000-11-02 Oeffentliche Pruefstelle Und T Textiles Material sowie Verfahren zur Herstellung eines derartigen textilen Materials
FR2789704B1 (fr) * 1999-02-15 2003-09-26 Univ Lille Sciences Tech Procede de traitement d'une fibre ou d'un materiau a base de fibres en vue d'ameliorer ses proprietes adsorbantes et fibre ou materiau a base de fibres presentant des proprietes adsorbantes ameliorees

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0246520A1 *

Also Published As

Publication number Publication date
BR0115992A (pt) 2004-01-13
AU2002227995A1 (en) 2002-06-18
KR20030074646A (ko) 2003-09-19
CN1479822A (zh) 2004-03-03
WO2002046520A1 (fr) 2002-06-13
US20050260905A1 (en) 2005-11-24
DE10060710A1 (de) 2002-06-13

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