EP1334239B1 - Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken - Google Patents

Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken Download PDF

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Publication number
EP1334239B1
EP1334239B1 EP01955364A EP01955364A EP1334239B1 EP 1334239 B1 EP1334239 B1 EP 1334239B1 EP 01955364 A EP01955364 A EP 01955364A EP 01955364 A EP01955364 A EP 01955364A EP 1334239 B1 EP1334239 B1 EP 1334239B1
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EP
European Patent Office
Prior art keywords
active substance
dispensing device
supply containers
holder
phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01955364A
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German (de)
English (en)
French (fr)
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EP1334239A1 (de
Inventor
Ralph Butter-Jentsch
Roland Menke
Hans-Georg MÜHLHAUSEN
Frank Pessel
Thomas Jungmann
Stefan Huchler
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to EP05022491A priority Critical patent/EP1614817A1/de
Publication of EP1334239A1 publication Critical patent/EP1334239A1/de
Application granted granted Critical
Publication of EP1334239B1 publication Critical patent/EP1334239B1/de
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
    • E03D9/032—Devices connected to or dispensing into the bowl

Definitions

  • the invention relates to a dispensing device for delivering active substance fluids into the rinsing liquid in a toilet bowl having the features of the preamble of claim 1 and claim 2, respectively.
  • active ingredient fluid means flowable, that is liquid to viscous, possibly gelatinous or pasty or granular or otherwise pourable active substance preparations with cleansing, disinfecting, deodorizing, bleaching u. ⁇ . Effect (in particular described in the non-prepublished DE 199 30 362 A1, as well as in EP 0 775 741 A1 and EP 0 960 984 A2).
  • Dispensers of the type in question are known under the keyword “toilet bowl” in different versions.
  • dispensing devices for a single active substance fluid are known.
  • the active substance fluid is located there in a storage container which is fixedly arranged or replaceably inserted in a holder and has an outlet opening arranged on the bottom side of the storage container mounted on the holder.
  • the active substance fluid is added via an actuating element (eg made of an open-cell foam) which can be impregnated therewith and acted upon by the flushing fluid (eg, an open-cell foam) (EP 785 315 A1).
  • an actuating element eg made of an open-cell foam
  • the flushing fluid eg, an open-cell foam
  • the outlet opening of the reservoir after expulsion of a closure member of the reservoir of a holder fixedly arranged on the sealing member is largely closed, so that only a flow path with a small cross section for sending out the active substance fluid is available.
  • the device works by utilizing the capillary action of the open cell foam.
  • a similar construction is also known with a distribution ribbed plate.
  • Another dispensing device for a single active substance fluid (DE 299 02 066 U1) realized on the reservoir a valve-like working sealing element, which normally assumes a positive closed closed position in which the outlet opening is closed. This happens under the effect of the weight of a valve ball acting as a sealing element.
  • This sealing element can be adjusted against the biasing force in the outlet opening a little releasing release position.
  • the actuating element On one side of the axis, the actuating element has a loading region having a trough-like receptacle for rinsing liquid. The lying on the other side of the axis arm of the actuating element is applied to the bottom of the sealing element.
  • the sealing element If the rinsing liquid hits the area of influence, the sealing element is lifted off the valve seat at the outlet opening via the actuating element and releases the outlet opening a little.
  • the active substance fluid can infiltrate past the sealing element out of the outlet opening into the passing stream of the rinsing liquid or is entrained by the rinsing liquid.
  • a container On a suspendable on the edge of the toilet bowl holder is a container which has for storing the media at least two juxtaposed independent chambers.
  • Each chamber has a dispenser with a dispensing tube, which exits with its one free end on the bottom of the container in the environment and is surrounded at its other free end leading by a cover.
  • the two chambers of the container can be filled via slit-like passages of a cover part of overflowing rinse water, which then emerges in the manner of a siphon or overflow via the delivery tube with entrainment of the respective active ingredient in the Toilettenbekken.
  • the separation of the chambers in the container has the advantage that different media can be used, which would otherwise be detrimental to their desired effect in a common storage in only one chamber. The consistency of the media may vary in the different chambers.
  • the teaching is based on the problem to optimize the previously explained dispensing device for dispensing active fluids from at least two separate reservoir with respect to the control option for the delivery of the active fluids.
  • a dispensing device having the features of the preamble of claim 1 by the features of the characterizing part of claim 1.
  • the reservoir are protected against the ingress of rinsing liquid into their interior and exits from the outlet openings of the reservoir only active fluid.
  • This is realized in such a way that with each flushing operation, the delivery of a subset of the active substance fluid from each reservoir takes place in the rinse water.
  • the technical realization is carried out by providing a plate-like distribution element on the holder, wherein the interior of the two reservoir via the respective outlet opening is permanently in communication with this distribution element, but with the interposition of an arrangement which prevents free flow of the active substance fluid.
  • This plate-like distribution element is provided for the preferred case of two storage containers for both reservoirs together.
  • a sibling solution according to claim 2 solves the problem defined above by a positive closure of the outlet openings.
  • the constructive implementation is implemented by sealing elements for each of the two outlet openings, wherein a cooperating in the preferred embodiment with the two sealing elements actuator is provided which is temporarily such a force acted upon by the rinsing liquid in each case with a force that the sealing elements against the biasing force temporarily take the release position.
  • the dispenser shown in the drawing is used to deliver at least two active fluids in the rinsing fluid, with which is rinsed in a toilet bowl. What is understood in the meaning of the teaching as drug fluid has already been defined in the general part of the description, it should be pointed out.
  • Such a dispensing device initially has a holder 1 which can be suspended at the edge of the toilet bowl and at least two storage containers 2, 3, which are provided in the holder 1 and are separated from each other, for one active substance fluid in each case.
  • the drug fluids may be matched, different, compatible or incompatible drug fluids.
  • Active substance fluids which are suitable according to the invention are, for example, fragrance phases, in particular perfumed fragrance phases.
  • scent phases usually comprise at least one perfume, preferably perfume oil, at least one surfactant or an emulsifier and water and optionally further ingredients such as preservatives, thickeners, complexing agents, dyes, other surfactants or emulsifiers, stabilizers, lime solubilizer, etc.
  • Bleaching phases in particular chlorine-containing bleaching phases, preferably bleaching phases based on Hypochlorite, wherein the bleaching phases usually in addition to the actual bleach and water may optionally contain other ingredients such as thickeners, surfactants or emulsifiers, neutralizing agents, dyes, perfumes, etc.
  • lime-dissolving active substance phases preferably acidic lime-dissolving active substance phases.
  • Such lime-solubilizing active ingredient phases may contain, in addition to the actual lime solubilizer - preferably this is an organic or inorganic acid - and water optionally further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc.
  • Such highly concentrated surfactant phases may also contain other conventional ingredients in addition to the surfactants.
  • active-ingredient fluids having an antibacterial and / or fungicidal and / or antiviral active phase, wherein the active-substance phase, in addition to the antibacterial and / or fungicidal and / or antiviral active and water, optionally further ingredients, such as, for example, surfactants or emulsifiers, thickeners, fragrances , Preservatives, etc. may contain.
  • the active substance fluids are enzyme-containing active substance phases.
  • enzyme (s) and water such enzyme-containing active substance phases may optionally contain further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc.
  • the active substance fluids used according to the invention are absorbent, in particular odor-absorbing, active-substance phases. These may, in addition to the absorbent, in particular odor absorbent, and water optionally further ingredients such as surfactants or emulsifiers, thickeners, fragrances, preservatives, etc. included.
  • the dispensing device offers the possibility of using combinations of different active substance fluids in the storage containers 2, 3, wherein according to a preferred embodiment one of the storage containers 2, 3 contains a fragrance phase, in particular as defined above.
  • active substance fluid combinations to be used are perfumed fragrance phase combined with chlorine bleach (together not storage-stable), perfumed fragrance phase with highly concentrated surfactant phase (foam booster), fragrance phase with limesolvent, acidic active phase, fragrance phase with antibacterial active ingredient phase, different acid systems, fragrance phase combined with enzyme-containing active substance phase, perfumed acid phase combined with water-dyeing phase, fragrance phase with odor-absorbing phase, perfumed acid phase with active oxygen, perfumed acid phase with active substance phase, thickened with polyacrylate etc.
  • viscous to gel-like active substance fluids with viscosities in the range of a few thousand mPas, in particular from 2000 to 5000 mPas, preferably 2500 to 3500 mPas (measured with Rotovisko LVT, spindle 2, 6 rpm, 20 ° C).
  • each storage container 2, 3 has its own outlet opening 4, via which the respective active substance fluid can be dispensed into the rinsing liquid.
  • the outlet openings 4 of the reservoir 2, 3 are arranged so that only active fluid exits.
  • the delivery of a subset of the active substance fluid from each of the storage containers 2, 3 takes place in the rinsing liquid.
  • this is realized in that the outlet opening 4 of the respective storage container 2, 3 in the use position, as shown in Fig. 2, is arranged on the bottom side. Overflowing rinse water meets at most laterally on the reservoir 2, 3rd
  • the reservoir 2, 3 are mounted individually replaceable in the holder 1 or attachable.
  • An alternative is to couple the reservoir 2, 3 by means of an adapter o. The like. Together and so coupled in the holder 1 to install.
  • a further alternative is to couple the storage containers 2, 3 directly to one another and to mount them directly coupled in the holder 1.
  • the reservoir 2, 3 in a common, one-piece housing form, for example, as a separate chambers in a contiguous housing, and then to attach to the holder 1.
  • one or the other variant will be chosen.
  • the reservoir 2, 3 described in the prior art (DE 299 02 066 Ul, DE 199 15 322 A1) via each refill, possibly equipped with a valve, make individually refillable.
  • the illustrated embodiment shows the reservoir 2, 3 as exchangeable disposable containers, which will probably be more common in practice.
  • the illustrated and preferred embodiment shows the reservoir 2, 3 arranged on the holder 1 side by side. The same applies to an arrangement of the reservoir 2, 3 in a row. Alternatively, it could also be provided to arrange the storage containers 2, 3 one above the other for the purpose of a cascaded product delivery.
  • the illustrated and preferred embodiment also shows that the reservoir 2.3, which are here individually interchangeable, in the holder 1 by plugging in from above (in the use position) are attachable.
  • the reservoir 2, 3 attach laterally on the holder 1 and then swing in the position of use about a pivot axis.
  • the reservoir 2, 3 has a flexible wall portion or a total of a flexible wall and an application of the active substance contained therein by pressurizing the reservoir 2, 3 takes place. This pressurization can be exercised for example via a corresponding mechanism by the overflowing rinsing liquid.
  • the dispensing mechanisms in principle can be used, which are known for dispensing devices for a single active substance fluid from the prior art.
  • a plate-like distribution element is provided on the holder 1, which has an overflow during the rinsing of the rinsing liquid Beaufschlagungs Scheme, wherein the interior of the storage container. 2 , 3 via the outlet opening 4, possibly with the intermediate arrangement of a free flow of the active substance fluid preventing arrangement, is permanently connected to the distribution element in connection.
  • the plate-like distribution element is assigned to all storage containers 2, 3 together.
  • the illustrated and preferred embodiment shows a solution that operates with an actively closing sealing element.
  • an actively closing sealing element namely, the bottom side arranged outlet opening 4 of the reservoir 2, 3 closed by means of a sealing element 5.
  • the sealing element 5 is biased into the closing position closing the outlet opening 4 and adjustable against the biasing force in a release opening 4 a little releasing release position.
  • actuating element 6 which is temporarily such a force acted upon in such a way with each flushing by the rinsing liquid, that the sealing element 5 temporarily assumes the release position against the biasing force.
  • an actuation element 6 acts on an impingement process of flushing fluid applied to the actuation element 7, so that the flushing fluid impinges during the flushing process.
  • the actuator 6 is designed as a one-armed, at one end hinged to the holder 1 lever.
  • the sealing element 5 is on the actuating element 6 arranged at a certain distance from the loading area 7.
  • the sealing element 5 is arranged between the hinged to the holder 1 end of the actuating element 6 and the loading area 7.
  • the opening path of the sealing element 5 is thus comparatively low, the opening is as desired only with a very small gap.
  • this gap is opened asymmetrically with a corresponding design of the sealing element 5, namely, more strongly opening in the direction of the loading region 7, so that active substance fluid preferably exits in this direction.
  • This is the direction to the rinsing fluid with which the active fluid then mixes accordingly.
  • the active substance fluid can therefore run on the upper side of the actuating element 6 in the direction of the loading region 7 and already mixes with the overflowing rinsing fluid on this route.
  • the sealing element 5 is integrally formed on the actuating element 6. This is recommended in particular in the design of the actuating element 6 made of a plastic material, in particular of plastic spritzcalledem.
  • the holder 1 may be in a particularly preferred manner of plastic, in particular of injection-moldable plastic, preferably-thermoplastic material.
  • the actuating element 6 is integrally formed on the holder 1 and the biasing force is generated by the inherent elasticity of the confirmation element 6.
  • the illustrated and preferred embodiment is characterized in a special way by the fact that the actuating element 6, the sealing elements 5 for at least two reservoir 2, 3, preferably for all reservoir 2, 3, is assigned together. It can be seen in Fig. 1 in plan view, the wide and plate-like running actuator 6 with the also wide, trough-like Beaufschlagungs Scheme 7 and the recognizable small discharge openings 8, all in the frame-like bottom plate 9 of the holder 1. It is coordinated the arrangement of the outlet 4 These are in fact carried out asymmetrically with respect to the center of the entire dispensing device with the outlet openings 4 offset overall relative to the center of the dispensing device (FIG. 2). This results in a concentration of the active substance leakage to a relatively narrow range regardless of the fact that two reservoirs 2, 3 are provided.
  • Thickener at moderate to high speed sprinkle During the approximately 60 minutes of swelling time, continue to stir the mixer (test for freedom from specks with a glass plate test); if there are still specks, must be stirred. Surfactants, then add alcohols. Lastly, add the perfume and check approach for release parameters.
  • chlorine-containing bleaching phase (about 1% active chlorine)
  • fragrance phase combined with acidic, limescale active ingredient phase
  • fragrance phase combined with odor-absorbing active ingredient phase
  • FAEOS-Na C 12-14 + 2 EO 24.50% Base surfactant Alkyl (C8-10) -1,5-glucoside 2.88% Co.Tensid / Emulagtor 1,2-propanediol 10.00% Emulagtor hydroxyethyl 0.50% thickener Perfume oil, willow green 10.00% perfume Hemiacetals-isothiazolin combination 0.05% preservative dyes ⁇ 1.0% tap water ad.100 about 2500 mPas. 20 ° C, Rotovisko LVT, spindle 2, 6U / min 6.5 pH, undiluted clear solution

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Public Health (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Epidemiology (AREA)
  • Detergent Compositions (AREA)
  • Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
EP01955364A 2000-11-17 2001-07-21 Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken Expired - Lifetime EP1334239B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP05022491A EP1614817A1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE10057325 2000-11-17
DE10057325 2000-11-17
DE10113036A DE10113036B4 (de) 2000-11-17 2001-03-17 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken
DE10113036 2001-03-17
PCT/EP2001/008461 WO2002040791A1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP05022491A Division EP1614817A1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken

Publications (2)

Publication Number Publication Date
EP1334239A1 EP1334239A1 (de) 2003-08-13
EP1334239B1 true EP1334239B1 (de) 2006-01-04

Family

ID=26007712

Family Applications (4)

Application Number Title Priority Date Filing Date
EP05022491A Withdrawn EP1614817A1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken
EP01955364A Expired - Lifetime EP1334239B1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur abgabe von wirkstofffluiden in die spülflüssigkeit in einem toilettenbecken
EP09008185A Expired - Lifetime EP2116656B1 (de) 2000-11-17 2001-11-09 Abgabevorrichtung zur Abgabe von Wirkstofffluiden
EP09008188A Expired - Lifetime EP2123833B1 (de) 2000-11-17 2001-11-09 Abgabevorrichtung zur Abgabe von Wirkstofffluiden

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP05022491A Withdrawn EP1614817A1 (de) 2000-11-17 2001-07-21 Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken

Family Applications After (2)

Application Number Title Priority Date Filing Date
EP09008185A Expired - Lifetime EP2116656B1 (de) 2000-11-17 2001-11-09 Abgabevorrichtung zur Abgabe von Wirkstofffluiden
EP09008188A Expired - Lifetime EP2123833B1 (de) 2000-11-17 2001-11-09 Abgabevorrichtung zur Abgabe von Wirkstofffluiden

Country Status (21)

Country Link
US (2) US20040068782A1 (es)
EP (4) EP1614817A1 (es)
JP (1) JP2004526075A (es)
CN (1) CN1474901A (es)
AR (1) AR031465A1 (es)
AT (3) ATE315140T1 (es)
AU (1) AU2001277547A1 (es)
CR (1) CR6973A (es)
CZ (4) CZ299957B6 (es)
DE (4) DE10164866B4 (es)
ES (3) ES2206080T3 (es)
HU (1) HU228554B1 (es)
PL (1) PL196974B1 (es)
PT (2) PT2123833E (es)
RO (1) RO120857B1 (es)
RU (1) RU2266372C2 (es)
SI (1) SI21141B (es)
SK (1) SK5812003A3 (es)
TR (1) TR200301652T3 (es)
UA (1) UA74854C2 (es)
WO (1) WO2002040791A1 (es)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010018005A1 (de) 2008-08-14 2010-02-18 Henkel Ag & Co. Kgaa Kartusche für einen wc-spüler
DE102008037723A1 (de) 2008-08-14 2010-02-25 Henkel Ag & Co. Kgaa WC-Körbchen mit Spülwasserverteilelement
EP2305900A3 (de) * 2007-03-09 2011-07-06 Henkel AG & Co. KGaA Nachfülleinheit mit lösbarer Funktionskammer für ein WC-Wirkstoffabgabesystem und System mit solch einer Nachfülleinheit
US8316471B2 (en) 2006-12-28 2012-11-27 Henkel Ag & Co. Kgaa Modular system for dispensing active ingredient fluids to the flushing liquid of a toilet bowl
WO2014029510A1 (de) 2012-08-22 2014-02-27 Henkel Ag & Co. Kgaa Wc-körbchen mit variabler produktabgabe
DE102013210435A1 (de) 2013-06-05 2014-12-11 Henkel Ag & Co. Kgaa Vorrichtung zur Abgabe einer Wirkstoffzubereitung in ein Toilettenbecken
USD752198S1 (en) 2015-03-18 2016-03-22 S.C. Johnson & Son, Inc. Toilet rim block holder
USD752733S1 (en) 2015-03-18 2016-03-29 S.C. Johnson & Son, Inc. Toilet rim block holder
USD784491S1 (en) 2016-05-17 2017-04-18 S. C. Johnson & Son, Inc. Toilet rim block
USD789485S1 (en) 2016-05-17 2017-06-13 S. C. Johnson & Son, Inc. Toilet rim block holder
USD923139S1 (en) 2019-06-07 2021-06-22 S. C. Johnson & Son, Inc. Set of toilet rim-blocks

Families Citing this family (49)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10164866B4 (de) * 2000-11-17 2007-06-14 Henkel Kgaa Abgabevorrichtung zur Abgabe von Wirkstofffluiden in die Spülflüssigkeit in einem Toilettenbecken
US7511006B2 (en) * 2000-12-14 2009-03-31 The Clorox Company Low residue cleaning solution comprising a C8 to C10 alkylpolyglucoside and glycerol
GB2372046A (en) 2001-02-09 2002-08-14 Jeyes Group Ltd Liquid dispensing unit for a toilet bowl
DE10204928B4 (de) * 2002-02-07 2004-04-01 Henkel Kgaa Abgabevorrichtung zur Abgabe eines Wirkstofffluids in die Spülflüssigkeit in einem Toilettenbecken
EP1483456A1 (en) 2002-03-12 2004-12-08 Robert McBride Ltd Dispenser
DE10227965B3 (de) * 2002-06-22 2004-04-01 Henkel Kgaa Vorrichtung zur Abgabe wenigstens einer flüssigen Wirkstoffzubereitung in ein Toilettenbecken
US6662380B1 (en) 2002-08-29 2003-12-16 S.C. Johnson & Son, Inc. Dual action toilet rim mounted toilet bowl cleaner
DE10303155A1 (de) * 2003-01-27 2004-08-12 Henkel Kgaa Abgabevorrichtung zur Abgabe eines Wirkstofffluids in die Spülflüssigkeit in einem Toilettenbecken
ITRE20030016A1 (it) * 2003-02-17 2004-08-18 Re Le Vi Spa "dispenser multiplo per sostanze attive liquide, per vaso di wc"
EP1469132B2 (en) † 2003-04-15 2014-05-14 The Procter & Gamble Company A lavatory bowl rim-block providing a combination of ongoing perfume delivery with a perfume boost upon flushing
ITRE20030038A1 (it) * 2003-04-15 2004-10-16 Re Le Vi Spa "dispenser per sostanze attive liquide, per vaso di w. c. "
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US8316471B2 (en) 2006-12-28 2012-11-27 Henkel Ag & Co. Kgaa Modular system for dispensing active ingredient fluids to the flushing liquid of a toilet bowl
EP2305900A3 (de) * 2007-03-09 2011-07-06 Henkel AG & Co. KGaA Nachfülleinheit mit lösbarer Funktionskammer für ein WC-Wirkstoffabgabesystem und System mit solch einer Nachfülleinheit
EP3002373A1 (de) 2008-08-14 2016-04-06 Henkel AG & Co. KGaA Wc-körbchen mit spülwasserverteilelement
EP3002375A1 (de) 2008-08-14 2016-04-06 Henkel AG & Co. KGaA Wc-körbchen mit spülwasserverteilelement
DE102008037724A1 (de) 2008-08-14 2010-02-25 Henkel Ag & Co. Kgaa Kartusche für einen WC-Spüler
EP3002376A1 (de) 2008-08-14 2016-04-06 Henkel AG & Co. KGaA Wc-körbchen mit spülwasserverteilelement
DE102008037723A1 (de) 2008-08-14 2010-02-25 Henkel Ag & Co. Kgaa WC-Körbchen mit Spülwasserverteilelement
WO2010018005A1 (de) 2008-08-14 2010-02-18 Henkel Ag & Co. Kgaa Kartusche für einen wc-spüler
EP3002374A1 (de) 2008-08-14 2016-04-06 Henkel AG & Co. KGaA Wc-körbchen mit spülwasserverteilelement
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DE102013210435A1 (de) 2013-06-05 2014-12-11 Henkel Ag & Co. Kgaa Vorrichtung zur Abgabe einer Wirkstoffzubereitung in ein Toilettenbecken
USD752733S1 (en) 2015-03-18 2016-03-29 S.C. Johnson & Son, Inc. Toilet rim block holder
USD752198S1 (en) 2015-03-18 2016-03-22 S.C. Johnson & Son, Inc. Toilet rim block holder
USD784491S1 (en) 2016-05-17 2017-04-18 S. C. Johnson & Son, Inc. Toilet rim block
USD789485S1 (en) 2016-05-17 2017-06-13 S. C. Johnson & Son, Inc. Toilet rim block holder
USD923139S1 (en) 2019-06-07 2021-06-22 S. C. Johnson & Son, Inc. Set of toilet rim-blocks

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CN1474901A (zh) 2004-02-11
CZ305459B6 (cs) 2015-10-07
CR6973A (es) 2006-03-28
ES2206080T1 (es) 2004-05-16
PT2123833E (pt) 2011-06-15
TR200301652T3 (tr) 2003-11-21
DE10113036A1 (de) 2002-06-06
EP2123833A1 (de) 2009-11-25
HUP0301545A3 (en) 2006-03-28
ES2361806T3 (es) 2011-06-22
JP2004526075A (ja) 2004-08-26
AR031465A1 (es) 2003-09-24
PL361188A1 (en) 2004-09-20
SI21141A (sl) 2003-08-31
CZ299957B6 (cs) 2009-01-07
EP1334239A1 (de) 2003-08-13
WO2002040791A1 (de) 2002-05-23
UA74854C2 (en) 2006-02-15
CZ305484B6 (cs) 2015-10-21
ES2370687T3 (es) 2011-12-21
PT2116656E (pt) 2011-11-21
DE50115818D1 (de) 2011-04-21
DE10164866B4 (de) 2007-06-14
AU2001277547A1 (en) 2002-05-27
CZ305483B6 (cs) 2015-10-21
DE10113036B4 (de) 2005-02-17
EP2116656A1 (de) 2009-11-11
EP1614817A1 (de) 2006-01-11
RO120857B1 (ro) 2006-08-30
ATE501316T1 (de) 2011-03-15
EP2116656B1 (de) 2011-09-07
HU228554B1 (en) 2013-03-28
US20040107484A1 (en) 2004-06-10
EP2123833B1 (de) 2011-03-09
CZ20031361A3 (cs) 2004-03-17
DE50108626D1 (de) 2006-03-30
US20040068782A1 (en) 2004-04-15
ATE523640T1 (de) 2011-09-15
ATE315140T1 (de) 2006-02-15
PL196974B1 (pl) 2008-02-29
ES2206080T3 (es) 2006-06-16
RU2266372C2 (ru) 2005-12-20
SI21141B (sl) 2007-02-28
SK5812003A3 (en) 2004-06-08

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