EP1271241A2 - Verfahren zur Verarbeitung lichtempfindlichen Silberhalogenidfarbmaterials - Google Patents

Verfahren zur Verarbeitung lichtempfindlichen Silberhalogenidfarbmaterials Download PDF

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Publication number
EP1271241A2
EP1271241A2 EP02018220A EP02018220A EP1271241A2 EP 1271241 A2 EP1271241 A2 EP 1271241A2 EP 02018220 A EP02018220 A EP 02018220A EP 02018220 A EP02018220 A EP 02018220A EP 1271241 A2 EP1271241 A2 EP 1271241A2
Authority
EP
European Patent Office
Prior art keywords
group
processing
solution
formula
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02018220A
Other languages
English (en)
French (fr)
Other versions
EP1271241B1 (de
EP1271241A3 (de
Inventor
Hiroyuki Seki
Hisashi Okada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujifilm Holdings Corp
Original Assignee
Fuji Photo Film Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Photo Film Co Ltd filed Critical Fuji Photo Film Co Ltd
Publication of EP1271241A2 publication Critical patent/EP1271241A2/de
Publication of EP1271241A3 publication Critical patent/EP1271241A3/de
Application granted granted Critical
Publication of EP1271241B1 publication Critical patent/EP1271241B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/42—Bleach-fixing or agents therefor ; Desilvering processes
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/42—Bleach-fixing or agents therefor ; Desilvering processes
    • G03C7/421—Additives other than bleaching or fixing agents
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/22—Subtractive cinematographic processes; Materials therefor; Preparing or processing such materials
    • G03C7/24—Subtractive cinematographic processes; Materials therefor; Preparing or processing such materials combined with sound-recording

Definitions

  • the heterocyclic residue is preferably 2-pyrrolyl, 2-imidazolyl, 4-imidazolyl, 3-pyrazolyl, 2-pyridyl, 2-pyrazinyl, 3-pyridazinyl, 3-(1,2,4-triazolyl), 4-(1,2,3-triazolyl), 2-(1,3,5-triazinyl), 3-(1,2,4-triazinyl), 5-(1,2,4-triazinyl), 6-(1,2,4-triazinyl), 2-indolyl, 3-indazolyl, 7-indazolyl, 2-purinyl, 6-purinyl, 8-purinyl, 2-(1,3,4-thiadiazolyl), 2-(1,3,4-oxadiazolyl), 2-quinolyl, 8-quinolyl, 1-phthalazinyl, 2-quinoxalinyl, 5-quinoxalinyl, 2-quinazolinyl, 4-quinazolinyl, 8-quinazolinyl
  • the ring formed by Q b may have a substituent and examples of the substituent include an alkyl group (having preferably from 1 to 8, more preferably from 1 to 6, still more preferably from 1 to 4 carbon atoms, e.g., methyl, ethyl), an alkenyl group (having preferably from 2 to 8, more preferably from 2 to 6, still more preferably from 2 to 4 carbon atoms, e.g., vinyl, allyl), an alkynyl group (having preferably from 2 to 8, more preferably from 2 to 6, still more preferably from 2 to 4 carbon atoms, e.g., propargyl), an aryl group (having preferably from 6 to 12, more preferably from 6 to 10, still more preferably from 6 to 8 carbon atoms, e.g., phenyl, p-methylphenyl), an alkoxy group (having preferably from 1 to 8, more preferably from 1 to 6, still more preferably from 1 to 4 carbon atoms, e.
  • Aspartic acids and glutamic acids used as a raw material are not particularly limited and an industrially available one can be used. These acids may be used in the form of a metal salt (for example, an alkali metal salt (e.g., Li salt, Na salt, K salt, Rb salt, Cs salt), an alkaline earth metal salt (e.g., Ca salt, Mg salt, Ba salt), a transition metal salt (e.g., Zn salt)), a tertiary ammonium salt (e.g., triethylammonium salt), a quaternary ammonium salt (e.g. tetrabutylammonium salt) or a pyridinium salt, or of course in the form of a free acid.
  • the shape thereof may be any of a solid, a slurry and an aqueous solution.
  • the amount of the solvent in the addition reaction varies depending upon the raw materials for reaction, the reaction temperature or the reaction scale, however, it is from 1 to 15 times, preferably from 0.9 to 10 times, more preferably from 1 to 5 times, still more preferably from 1 to 3 times, the weight of the amino acids.
  • the iron(III) complex salt of the compound represented by formula (I) or (II) of the present invention may be previously taken out as an iron(III) complex salt before the addition or the compound represented by formula (I) or (II) and an iron(III) salt (e.g., ferric nitrate and ferric chloride) may be placed together in a solution to cause complex formation in the processing solution.
  • an iron(III) salt e.g., ferric nitrate and ferric chloride
  • the compound represented by formula (I) or (II) is preferably used at a proportion of from 70 to 100 mol%, more preferably from 80 to 100 mol%, still more preferably 100 mol% based on the total amount of the bleaching agent.
  • various bleaching accelerators may be added to the pre-bath of the processing solution having bleaching ability.
  • the bleaching accelerator include compounds having a mercapto group or a disulfide group described in U.S. Patent 3,893,858, German Patent No. 1,290,821, British Patent 1,138,842, JP-A-53-95630 and Research Disclosure No. 17129 (July, 1978), thiazolidine derivatives described in JP-A-50-140129, thiourea derivatives described in U.S. Patent 3,706,561, iodides described in JP-A-58-16235, polyethylene oxides described in German Patent No. 2,748,430, and polyamine compounds described in JP-B-45-8836. Further, the compounds described in U.S. Patent 4,552,834 are preferred.
  • the bleaching accelerator may be incorporated into the light-sensitive material.
  • jet stirring described in JP-A-1-309059 is particularly preferably performed.
  • the solution having bleaching ability of the present invention can be re-used by recovering the overflow solution after use in the processing and adding thereto components to correct the composition.
  • This use method is usually called regeneration and the regeneration is preferred also in the present invention.
  • matters described in Fuji Film Processinq Manual, Fuji Color Negative Film, CN-16 Processing issued by Fuji Photo Film Co., Ltd., pp. 39-40 (revised in August, 1990) may be applied.
  • the color developer contains the color developing agent in an amount of preferably from 0.01 to 0.08 mol/l, more preferably from 0.015 to 0.06 mol/l, still more preferably from 0.02 to 0.05 mol/l.
  • the replenisher of the color developer preferably contains the color developing agent in an amount of from 1.1 to 3 times the above-described amount.
  • the temperature in the processing with the color developer is generally from 20 to 55°C, preferably from 30 to 55°C.
  • the processing time is, in the case of a light-sensitive material for photographing, generally from 20 seconds to 10 minutes, preferably from 30 seconds to 8 minutes, more preferably from 1 to 6 minutes, most preferably from 1 minute and 10 seconds to 3 minutes and 30 seconds, and in the case of a material for printing, it is generally from 10 seconds to 1 minute and 20 seconds, preferably from 10 to 60 seconds, more preferably from 10 to 40 seconds.
  • the above-described color developer is preferably packed in a container made of a material having a carbon dioxide permeation rate of 25 ml/m 2 •24 hrs ⁇ atm or less to give a void ratio of from 0.15 to 0.05.
  • a support and a back layer for a light-sensitive material were prepared as follows and thereon light-sensitive layers described in Example 1 were provided to prepare Light-Sensitive Material Sample 102.
  • Silica particles (0.3 ⁇ m) as a matting agent and an alumina oxide (0.15 ⁇ m) as an abrasive subjected to covering treatment with 3-poly(polymerization degree: 15)oxyethylene-propyloxytrimethoxysilane (15 wt%) each was added to give a coverage of 10 mg/m 2 .
  • the drying was conducted at 115°C for 6 minutes (rollers and the conveyance device in the drying zone all were heated to 115°C).
  • Sample 102 in the portion 150 m traced back from the processing end was measured on the output signal level of isolated frequency using a Sendust-made magnetic reproducing head having a head gap of 2.5 ⁇ m and a turn number of 2,000.
  • the results obtained are shown in Table 4.
  • the magnetic output results are shown in terms of the ratio of an average output in the final 1 m portion to the average output in the 1 m portion at the starting of measurement by the unit % taking the latter as 100.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
EP02018220A 1995-08-23 1996-08-23 Verfahren zur Verarbeitung lichtempfindlichen Silberhalogenidfarbmaterials Expired - Lifetime EP1271241B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP23593795 1995-08-23
JP23593795 1995-08-23
EP19960113549 EP0789275B1 (de) 1995-08-23 1996-08-23 Verfahren zur Verarbeitung lichtempfindliches Silberhalogenidfarbmaterials

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP19960113549 Division EP0789275B1 (de) 1995-08-23 1996-08-23 Verfahren zur Verarbeitung lichtempfindliches Silberhalogenidfarbmaterials

Publications (3)

Publication Number Publication Date
EP1271241A2 true EP1271241A2 (de) 2003-01-02
EP1271241A3 EP1271241A3 (de) 2003-01-29
EP1271241B1 EP1271241B1 (de) 2006-04-05

Family

ID=16993442

Family Applications (2)

Application Number Title Priority Date Filing Date
EP19960113549 Expired - Lifetime EP0789275B1 (de) 1995-08-23 1996-08-23 Verfahren zur Verarbeitung lichtempfindliches Silberhalogenidfarbmaterials
EP02018220A Expired - Lifetime EP1271241B1 (de) 1995-08-23 1996-08-23 Verfahren zur Verarbeitung lichtempfindlichen Silberhalogenidfarbmaterials

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP19960113549 Expired - Lifetime EP0789275B1 (de) 1995-08-23 1996-08-23 Verfahren zur Verarbeitung lichtempfindliches Silberhalogenidfarbmaterials

Country Status (2)

Country Link
EP (2) EP0789275B1 (de)
DE (2) DE69630510T2 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0859276A1 (de) * 1997-02-13 1998-08-19 Eastman Kodak Company Wiederherstellung des Cyanfarbstoffbildes durch eine Bleichzusammensetzung, die eine Eisen(II)-Polycarbonsäure enthält
JP2001109116A (ja) * 1999-08-03 2001-04-20 Fuji Photo Film Co Ltd ハロゲン化銀カラー写真感光材料の処理方法及びハロゲン化銀写真感光材料用の処理液

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE665814A (de) * 1964-06-24 1965-12-23
EP0426193A1 (de) * 1989-11-02 1991-05-08 Fuji Photo Film Co., Ltd. Photographisches Silberhalogenidmaterial, Verarbeitungslösung und dessen Verarbeitungsverfahren
EP0595102A1 (de) * 1992-10-29 1994-05-04 Fuji Photo Film Co., Ltd. Verarbeitungsverfahren für farbphotographisches Silberhalogenidmaterial
EP0657777A2 (de) * 1993-12-07 1995-06-14 Fuji Photo Film Co., Ltd. Verfahren zur Verarbeitung eines farbphotographischen Silberhalogenidmaterials

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS517930A (ja) * 1974-06-27 1976-01-22 Konishiroku Photo Ind Shiankapuraaoganjusuru harogenkaginkaraashashinkankozairyono hyohaku oyobi teichakushorihoho
JPH0836252A (ja) * 1994-07-22 1996-02-06 Fuji Photo Film Co Ltd ハロゲン化銀カラー写真感光材料の処理方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE665814A (de) * 1964-06-24 1965-12-23
EP0426193A1 (de) * 1989-11-02 1991-05-08 Fuji Photo Film Co., Ltd. Photographisches Silberhalogenidmaterial, Verarbeitungslösung und dessen Verarbeitungsverfahren
EP0595102A1 (de) * 1992-10-29 1994-05-04 Fuji Photo Film Co., Ltd. Verarbeitungsverfahren für farbphotographisches Silberhalogenidmaterial
EP0657777A2 (de) * 1993-12-07 1995-06-14 Fuji Photo Film Co., Ltd. Verfahren zur Verarbeitung eines farbphotographischen Silberhalogenidmaterials

Also Published As

Publication number Publication date
DE69636024D1 (de) 2006-05-18
DE69630510D1 (de) 2003-12-04
EP0789275A1 (de) 1997-08-13
EP0789275B1 (de) 2003-10-29
DE69636024T2 (de) 2006-08-31
EP1271241B1 (de) 2006-04-05
EP1271241A3 (de) 2003-01-29
DE69630510T2 (de) 2004-05-06

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