EP1146155A1 - Markisenstoff und Verfahren zu seiner Herstellung - Google Patents

Markisenstoff und Verfahren zu seiner Herstellung Download PDF

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Publication number
EP1146155A1
EP1146155A1 EP01108540A EP01108540A EP1146155A1 EP 1146155 A1 EP1146155 A1 EP 1146155A1 EP 01108540 A EP01108540 A EP 01108540A EP 01108540 A EP01108540 A EP 01108540A EP 1146155 A1 EP1146155 A1 EP 1146155A1
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EP
European Patent Office
Prior art keywords
awning fabric
awning
fabric according
yarn
pes
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Granted
Application number
EP01108540A
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English (en)
French (fr)
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EP1146155B1 (de
Inventor
Wolfgang Dr. Schulz
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Schmitz Werke GmbH and Co KG
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Schmitz Werke GmbH and Co KG
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Classifications

    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D1/00—Woven fabrics designed to make specified articles
    • D03D1/0035—Protective fabrics
    • D03D1/007—UV radiation protecting
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C3/00—Stretching, tentering or spreading textile fabrics; Producing elasticity in textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/54—Polyesters using dispersed dyestuffs
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/14—Dyeability
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/22—Physical properties protective against sunlight or UV radiation
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2505/00—Industrial
    • D10B2505/18—Outdoor fabrics, e.g. tents, tarpaulins
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F10/00—Sunshades, e.g. Florentine blinds or jalousies; Outside screens; Awnings or baldachins
    • E04F10/02—Sunshades, e.g. Florentine blinds or jalousies; Outside screens; Awnings or baldachins of flexible canopy materials, e.g. canvas ; Baldachins
    • E04F10/06—Sunshades, e.g. Florentine blinds or jalousies; Outside screens; Awnings or baldachins of flexible canopy materials, e.g. canvas ; Baldachins comprising a roller-blind with means for holding the end away from a building
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/259—Coating or impregnation provides protection from radiation [e.g., U.V., visible light, I.R., micscheme-change-itemave, high energy particle, etc.] or heat retention thru radiation absorption
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/259—Coating or impregnation provides protection from radiation [e.g., U.V., visible light, I.R., micscheme-change-itemave, high energy particle, etc.] or heat retention thru radiation absorption
    • Y10T442/2598—Radiation reflective
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861—Coated or impregnated synthetic organic fiber fabric

Definitions

  • the invention is directed to an awning fabric and a method its manufacture and on an awning with such awning fabric.
  • Awning fabrics are subject to high demands on UV light stability, Tear resistance, weather resistance and water and dirt repellency. Conventionally, they are therefore spinneret-dyed Polyacrylonitrile fibers (PAC) using ply threads Nm 34x2 (dtex 588) produced. To achieve good water repellency and a clear appearance of the longitudinal stripes of the pattern about 30 warp threads / cm and about 15 weft threads / cm are used. The corresponding Tissue is then made with handle-enhancing and water-repellent Synthetic resins equipped.
  • PAC Polyacrylonitrile fibers
  • the invention is based on the object, an awning fabric to create which with good UV stability and weather resistance has the lowest possible basis weight.
  • This object is achieved in that it is made of polyester (PES) filament yarn (endless yarn) is made.
  • PET polyester
  • the essence of the invention is therefore that not only conventionally hardly used polyester yarn used, but this especially in the form of an endless yarn instead of the conventionally used Staple fiber yarn.
  • polyester yarn By such a continuous yarn, the surface is much smoother what the pollution counteracts. It is made by the polyester yarn one achieved very high tensile strength. It also gets a very high resistance ensured against UV radiation, characterized in that polyester filament yarn has a round cross section, matting and lubricating agents, conventionally a germ cell for fiber degradation by UV rays form, are used in the fibers in the smallest amounts, preferably below 0.05%. Traditionally, this value is 1.5% for mats Fiber types and 0.3-0.5% for semi-matt fiber types.
  • the warp thread density at 35 to 50 threads / cm and the weft density is 20 to 25 threads / cm.
  • An in the context of the invention preferred and achievable basis weight is between 200 and 250 gsm. Due to this low basis weight The awning fabric wound on the cloth cover of the awning less thick and allows greater seam spacing than the usual 120 cm. Thereby a cheaper packaging of the awning fabric is achieved and the entire awning can be made leaner.
  • the well-known so-called "Christmas tree effect", which is due to the thickness overlay of is wound on each other wound seam areas is counteracted.
  • the awning fabric is a basis weight from 200 to 250 gsm.
  • the basis weight is clearly lower than that of conventional awning fabrics whose weight exceeds 300 gsm.
  • the awning fabric is wet dyed, preferably with a Disperse dye, such as nitro, azo and Anthrachinonfarbstoffe. So it is not the usual spinneret dyeing in primary spinning but the dyeing takes place in aqueous solution at the processor, which is a strong expansion of the otherwise limited color palette allows.
  • a Disperse dye such as nitro, azo and Anthrachinonfarbstoffe. So it is not the usual spinneret dyeing in primary spinning but the dyeing takes place in aqueous solution at the processor, which is a strong expansion of the otherwise limited color palette allows.
  • a UV blocker is advantageously provided, which makes it possible the inventively provided polyester yarns in the required Wetness to dye wetness.
  • Suitable UV blockers are based on this built a triazine derivative. This UV blocker can be used in the dyebath be applied.
  • the invention is also directed to a process for the preparation of a Awning fabric, which is intended to be made of polyester filament yarn Woven, wet dyed and in a tenter at a temperature of about 185 ° is fixed. Matting and lubricating agents are titanium dioxide in introduced into the fiber in an amount of less than 0.05%.
  • the invention further relates to an awning with an above described awning fabric.
  • the awning fabric thus obtained wet-dyed with disperse dyes, such as nitro, azo and Anthrachinonfarbstoffen.
  • the dyebath is a UV blocker based on a triazine derivative added.
  • the tissue is then at higher Temperatures tense and cooled again. This is tension fixed in the tissue.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Woven Fabrics (AREA)
  • Walking Sticks, Umbrellas, And Fans (AREA)
  • Coloring (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Building Awnings And Sunshades (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Tents Or Canopies (AREA)

Abstract

Markisenstoff, hergestellt aus Polyester (PES)-Filamentgarn (Endlosgarn) und/oder ­Monofilgarn.

Description

Die Erfindung richtet sich auf einen Markisenstoff und ein Verfahren zu seiner Herstellung sowie auf eine Markise mit einem derartigen Markisenstoff.
An Markisenstoffe werden hohe Anforderungen an UV-Lichtstabilität, Reißfestigkeit, Wetterstabilität und Wasser- und Schmutzabstoßung gestellt. Herkömmlicherweise werden sie deshalb aus spinndüsengefärbten Polyacrylnitrilfasern (PAC) unter Verwendung von Zwirnen der Feinheit Nm 34x2 (dtex 588) hergestellt. Zur Erzielung einer guten Wasserabstoßung und eines klaren Erscheinungsbildes der Längsstreifen der Musterung werden ca. 30 Kettfäden/cm und ca. 15 Schußfäden/cm eingesetzt. Das entsprechende Gewebe wird dann mit griffverbessernden und wasserabstoßenden Kunstharzen ausgerüstet.
Vereinzelt wurde auch versucht, andere Fasermaterialien einzusetzen, wobei sich diese aber vor allem wegen der mangelnden UV-Stabilität der Fasern und der Farbstoffe nicht durchsetzen konnten. Das Flächengewicht dieser Stoffe lag bei 300 g/qm und darüber.
Hiervon ausgehend liegt der Erfindung die Aufgabe zugrunde, einen Markisenstoff zu schaffen, welcher bei guter UV-Stabilität und Wetterfestigkeit ein möglichst niedriges Flächengewicht aufweist.
Diese Aufgabe wird erfindungsgemäß dadurch gelöst, daß er aus Polyester (PES)-Filamentgarn (Endlosgarn) hergestellt ist.
Der Kern der Erfindung besteht also darin, daß man nicht nur herkömmlicherweise kaum eingesetztes Polyestergarn verwendet, sondern dieses speziell in Form eines Endlosgarns statt des herkömmlicherweise verwendeten Stapelfasergarns.
Durch ein derartiges Endlosgarn wird die Oberfläche sehr viel glatter, was der Verschmutzung entgegenwirkt. Es wird durch das Polyester-Garn eine sehr hohe Reißfestigkeit erreicht. Außerdem wird eine sehr hohe Resistenz gegen UV-Strahlung dadurch gewährleistet, daß Polyester-Filamentgarn einen runden Querschnitt aufweist, Mattierungs- und Gleitmittel, die herkömmlicherweise eine Keimzelle für den Faserabbau durch UV-Strahlen bilden, werden in den Fasern in geringsten Mengen eingesetzt, vorzugsweise unter 0,05 %. Herkömmlicherweise beträgt dieser Wert 1,5 % bei matten Fasertypen und 0,3 - 0,5 % bei halbmatten Fasertypen.
Vorzugsweise ist vorgesehen, daß die Kettfadendichte bei 35 bis 50 Fäden/cm und die Schußfadendichte bei 20 bis 25 Fäden/cm liegt.
Ein im Rahmen der Erfindung bevorzugtes und erzielbares Flächengewicht liegt bei 200 bis 250 g/qm. Aufgrund dieses geringen Flächengewichtes wickelt der Markisenstoff auf der Tuchhülle der Markise weniger dick auf und erlaubt größere Nahtabstände als die bisher üblichen 120 cm. Dadurch wird eine preisgünstigere Konfektionierung des Markisentuches erreicht und die gesamte Markise kann schlanker gebaut werden. Dem bekannten sogenannten "Tannenbaumeffekt", der durch die Dickenüberlagerung der aufeinandergewickelten Nahtbereiche bedingt ist, wird entgegengewirkt. Vorzugsweise ist vorgesehen, daß der Markisenstoff ein Flächengewicht von 200 bis 250 g/qm aufweist. Damit liegt das Flächengewicht deutlich niedriger als dasjenige herkömmlicher Markisenstoffe, deren Gewicht über 300 g/qm lag.
Vorteilhafterweise ist der Markisenstoff naßgefärbt, vorzugsweise mit einem Dispersionsfarbstoff, wie Nitro-, Azo- sowie Anthrachinonfarbstoffe. Es wird also nicht die übliche Spinndüsen-Färbung beim Primärspinnen verwendet, sondern das Färben erfolgt in wässriger Lösung beim Verarbeiter, was eine starke Ausweitung der ansonsten begrenzten Farbpalette ermöglicht.
Weiterhin ist mit Vorteil ein UV-Blocker vorgesehen, der es ermöglicht, die erfindungsgemäß vorgesehene Polyester-Garne in der erforderlichen Echtheit naß zu färben. Hierfür geeignete UV-Blocker sind auf der Basis eines Triazinderivates aufgebaut. Dieser UV-Blocker kann im Färbebad aufgebracht werden.
Die Erfindung richtet sich auch auf ein Verfahren zur Herstellung eines Markisenstoffes, wonach vorgesehen ist, daß er aus Polyester-Filamentgarn gewebt, naßgefärbt und in einem Spannrahmen bei einer Temperatur von ca. 185 ° fixiert wird. Als Mattierungs- und Gleitmittel wird Titandioxid in einer Menge von weniger als 0,05 % in die Faser eingebracht.
Gegenstand der Erfindung ist weiterhin auch eine Markise mit einem vorstehend beschriebenen Markisenstoff.
Nachfolgend wird die Erfindung anhand bevorzugter Ausführungsbeispiele näher erläutert:
  • Ausführungsbeispiel 1 :
  • Kettfadendichte 38,5 Fäden/cm, PES-Filament dtex 167/2
  • Schußfadendichte 22,0 Fäden/cm, PES-Filamentgarn dtex 167/2
  • Flächengewicht ca. 235 g/qm
  • Ausführungsbeispiel 2:
  • Kettfadendichte 46,5 Fäden/cm, PES-Filament dtex 110/2
  • Schußfadendichte 21,0 Fäden/cm, PES-Filamentgarn dtex 167/2
  • Flächengewicht ca. 200 g/qm.
    • In beiden Ausführungsbeispielen wird der so gewonnene Markisenstoff naßgefärbt mit Dispersionsfarbstoffen, wie Nitro-, Azo- sowie Anthrachinonfarbstoffen. Dem Färbebad ist ein UV-Blocker auf Basis eines Triazinderivates zugesetzt. In einem Spannrahmen wird das Gewebe dann bei höheren Temperaturen gespannt und wieder abgekühlt. Damit sind Spannungen im Gewebe fixiert.

    Claims (11)

    1. Markisenstoff, dadurch gekennzeichnet, daß er aus Polyester (PES)-Filamentgarn (Endlosgarn) und/oder - Monofilgarn hergestellt ist.
    2. Markisenstoff nach Anspruch 1, dadurch gekennzeichnet, daß er ein Flächengewicht von 200 bis 250 g/qm aufweist.
    3. Markisenstoff nach Anspruch 1, dadurch gekennzeichnet, daß er naßgefärbt ist, insbesondere mittels eines Dispersionsfarbstoffes, wie Nitro-, Azo- sowie Anthrachinonfarbstoffe.
    4. Markisenstoff nach Anspruch 1, dadurch gekennzeichnet, daß ein UV-Blocker vorgesehen ist.
    5. Markisenstoff nach Anspruch 4, dadurch gekennzeichnet, daß der UV-Blocker auf der Basis eines Triazinderivates aufgebaut ist.
    6. Markisenstoff nach Anspruch 5, dadurch gekennzeichnet, daß das Polyester-Garn rund ist.
    7. Verfahren zur Herstellung eines Markisenstoffes nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß er aus Polyester-Filamentgarn und/oder - Monofilgarn gewebt wird.
    8. Verfahren zur Herstellung eines Markisenstoffes nach Anspruch 7, dadurch gekennzeichnet, daß er naßgefärbt wird.
    9. Verfahren zur Herstellung eines Markisenstoffes nach Anspruch 7, dadurch gekennzeichnet, daß er in einem Spannrahmen bei einer Temperatur von ca. 185 ° fixiert wird.
    10. Verfahren zur Herstellung eines Markisenstoffes nach Anspruch 7, dadurch gekennzeichnet, daß als Mattierungs- und Gleitmittel Titandioxid in einer Menge von weniger als 0,05 % in die Faser eingebracht werden.
    11. Markise, insbesondere Gelenkarm- oder Wintergartenmarkise, umfassend einen Markisenstoff nach einem der Ansprüche 1 bis 10.
    EP01108540A 2000-04-14 2001-04-05 Markisenstoff und Verfahren zu seiner Herstellung Expired - Lifetime EP1146155B1 (de)

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    DE10018484 2000-04-14
    DE10018484A DE10018484A1 (de) 2000-04-14 2000-04-14 Markisenstoff und Verfahren zu seiner Herstellung

    Publications (2)

    Publication Number Publication Date
    EP1146155A1 true EP1146155A1 (de) 2001-10-17
    EP1146155B1 EP1146155B1 (de) 2003-09-03

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    US (1) US20010031590A1 (de)
    EP (1) EP1146155B1 (de)
    JP (1) JP4653899B2 (de)
    KR (1) KR20010098449A (de)
    CN (1) CN1273665C (de)
    AR (1) AR028334A1 (de)
    AT (1) ATE248941T1 (de)
    AU (1) AU783575B2 (de)
    BR (1) BR0101460B1 (de)
    DE (2) DE10018484A1 (de)
    DK (1) DK1146155T3 (de)
    ES (1) ES2204776T3 (de)
    HK (1) HK1037010A1 (de)
    ID (1) ID29839A (de)
    MX (1) MXPA01003844A (de)
    MY (1) MY128286A (de)
    PT (1) PT1146155E (de)
    RU (1) RU2213817C2 (de)
    ZA (1) ZA200102778B (de)

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    Publication number Priority date Publication date Assignee Title
    KR100389049B1 (en) * 2002-04-15 2003-06-25 Gu Ui Mun Awning fabric and method for producing thereof
    ES2234407B1 (es) 2003-07-10 2006-11-01 Telya Products, S.L. Procedimiento de fabricacion de telas de toldos y similares.
    FR2857383B1 (fr) * 2003-12-29 2007-12-14 Telya Products Sl Procede de fabrication de toiles pour baches et similaires.
    US20080154011A1 (en) * 2006-12-22 2008-06-26 Mingsong Wang Opaque colored and white monofilaments having stability to prolonged exposure to UV light
    CN102899905B (zh) * 2012-09-17 2014-06-04 南通市田园装饰布有限公司 一种涤纶防晒室外装饰布
    CN106192191B (zh) * 2016-08-19 2017-10-31 常州市宏发纵横新材料科技股份有限公司 一种膜结构建筑篷盖用经编衬纬布及其制备方法

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    HK1037010A1 (en) 2002-01-25
    MY128286A (en) 2007-01-31
    BR0101460A (pt) 2001-11-13
    AR028334A1 (es) 2003-05-07
    DE10018484A1 (de) 2001-10-18
    ATE248941T1 (de) 2003-09-15
    CN1318659A (zh) 2001-10-24
    DK1146155T3 (da) 2004-01-05
    AU3341901A (en) 2001-10-18
    CN1273665C (zh) 2006-09-06
    JP2002088611A (ja) 2002-03-27
    EP1146155B1 (de) 2003-09-03
    JP4653899B2 (ja) 2011-03-16
    BR0101460B1 (pt) 2012-01-10
    RU2213817C2 (ru) 2003-10-10
    ZA200102778B (en) 2001-10-05
    PT1146155E (pt) 2004-01-30
    MXPA01003844A (es) 2004-11-10
    ES2204776T3 (es) 2004-05-01
    US20010031590A1 (en) 2001-10-18
    DE50100569D1 (de) 2003-10-09
    KR20010098449A (ko) 2001-11-08
    AU783575B2 (en) 2005-11-10

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