EP1116446A2 - Procédé d'amélioration de la durée de conservation et / ou de la stabilité des aliments altérables sous l'action de microbes - Google Patents

Procédé d'amélioration de la durée de conservation et / ou de la stabilité des aliments altérables sous l'action de microbes Download PDF

Info

Publication number
EP1116446A2
EP1116446A2 EP01109105A EP01109105A EP1116446A2 EP 1116446 A2 EP1116446 A2 EP 1116446A2 EP 01109105 A EP01109105 A EP 01109105A EP 01109105 A EP01109105 A EP 01109105A EP 1116446 A2 EP1116446 A2 EP 1116446A2
Authority
EP
European Patent Office
Prior art keywords
gras
acid
alcohol
acetate
aldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01109105A
Other languages
German (de)
English (en)
Other versions
EP1116446A3 (fr
EP1116446B1 (fr
Inventor
Jörg-Peter Prof. Schür
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SCHUER, JOERG-PETER, PROF.
Original Assignee
SCHUER JOERG PETER PROF
Schuer Jorg-Peter Prof
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SCHUER JOERG PETER PROF, Schuer Jorg-Peter Prof filed Critical SCHUER JOERG PETER PROF
Publication of EP1116446A2 publication Critical patent/EP1116446A2/fr
Publication of EP1116446A3 publication Critical patent/EP1116446A3/fr
Application granted granted Critical
Publication of EP1116446B1 publication Critical patent/EP1116446B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00—General methods for preserving meat, sausages, fish or fish products
    • A23B4/14—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12
    • A23B4/18—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12 in the form of liquids or solids
    • A23B4/20—Organic compounds; Microorganisms; Enzymes
    • A23B4/22—Microorganisms; Enzymes; Antibiotics
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00—General methods for preserving meat, sausages, fish or fish products
    • A23B4/14—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12
    • A23B4/18—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12 in the form of liquids or solids
    • A23B4/20—Organic compounds; Microorganisms; Enzymes
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463—Organic compounds; Microorganisms; Enzymes
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463—Organic compounds; Microorganisms; Enzymes
    • A23L3/34635—Antibiotics
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463—Organic compounds; Microorganisms; Enzymes
    • A23L3/3472—Compounds of undetermined constitution obtained from animals or plants
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/3463—Organic compounds; Microorganisms; Enzymes
    • A23L3/3481—Organic compounds containing oxygen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S426/00—Food or edible material: processes, compositions, and products
    • Y10S426/805—Pet food for dog, cat, bird, or fish

Definitions

  • the present invention relates to a method for improving durability and / or stabilization of microbially perishable products, a process aid to carry out this method and the use of the process aid for applying to surfaces of microbially perishable products and / or their surroundings.
  • the preservatives in the list mentioned are bacteriostatic and / or fungistatically effective and significantly improve durability. However, many consumers reject them because of their impact are not known to the health of the consumer, or harmful Influences, especially with repeated recording over a long period of time, cannot be excluded.
  • Pasteurization is a thermal treatment from 30 to 120 minutes exposure time at 70 to 85 ° C.
  • Pasteurization significantly improves the shelf life of products treated in this way, is technically complex and consumes a lot of energy. The In addition, viability of spores is often not or only very incompletely impaired. Pasteurization is also for temperature sensitive Products not applicable or leads to a not insignificant Loss of quality, since at the latest due to the often necessary second thermization (up to 85 ° C) the "freshness" of the pasteurized product decreases. In addition, valuable components of food, cosmetics or pharmaceuticals, e.g. Vitamins, amino acids and many pharmaceuticals Active ingredients, thermolabile, so that there is a thermal treatment under the usual Pasteurization conditions prohibited.
  • a further possibility for improving the durability is to pack the endangered product in an airtight manner under nitrogen or CO 2 or to provide it in vacuum packaging, as is the case, for example, with ground coffee.
  • these methods are expensive and complex and therefore cannot be used for many foods.
  • the object of the invention is therefore to provide a method for improving durability and / or stabilization of microbially perishable products, in which during the process of manufacturing, processing or packaging the Products whose surfaces and / or their surroundings, especially those Ambient air and / or the surfaces of the directly or indirectly with the Devices or other materials that come into contact with a product or to provide several process aids.
  • This is intended in particular the shelf life improvement and stabilization of food and Feed, cosmetics, pharmaceuticals and others, from spoilage endangered products are made possible without synthetic Preservatives mixed into these treated substances or a Pasteurization at temperatures from 70 to 85 ° C must be applied. Likewise, a reduction in the funds used to Durability improvement and stabilization can be achieved.
  • this object is achieved by a process aid, which at least a microbicidal flavor, preferably at least two Flavorings.
  • the present invention further relates to a process aid, which is characterized in that is that it has at least one microbicidal flavor, preferably contains at least two flavorings
  • the present invention also relates to the use of the processing aid for applying to surfaces of microbially perishable products and / or their surroundings for the purpose of painting, smearing, Emulsifying, separating, cleaning, spraying, vaporizing, gasifying and Cutting.
  • the flavorings contained in the process aids according to the invention are only natural or nature-identical flavorings that are in accordance with FEMA recognized as safe (GRAS - Generally Recognized As Safe).
  • FEMA GRAS Flavor Substances Lists GRAS 3-16 No. 2001-3834 the natural and nature-identical Flavors listed by the FDA Food use approved (FDA regulation 21 CFR 172.515 for nature - identical flavorings (synthetic flavoring substances and Adjuvants) and FDA Regulation 21 CFR 182.20 for natural flavorings (Natural Flavoring Substances and Adjuvants).
  • FDA regulation 21 CFR 172.515 for nature - identical flavorings (synthetic flavoring substances and Adjuvants)
  • FDA Regulation 21 CFR 182.20 for natural flavorings (Natural Flavoring Substances and Adjuvants).
  • which these FDA standards fulfilling flavoring substances may be used "quantum satis”, i.e. she may be contained in the food up to the maximum concentration in which they have no
  • NAT4 substances that are under certain Requirements must be declared as identical to nature, e.g. if they Substances in combination and as a component with a natural or nature-identical Flavoring can be used.
  • processing aids have a taste and do not affect the smell of the treated products.
  • the process aids according to the invention are, for example, in the form of Lubricants, emulsifiers and cleaning agents, spraying agents, nebulizers, gas phase active agents, heat transfer agents and cutting or Release agents used.
  • the process aids can also be used as additives be used to the funds mentioned.
  • the processing aids are not the foods be added or mixed with these. Rather, only those Surfaces or cut surfaces of the food with the processing aids acted upon. This can be done in that the Food surfaces or cut surfaces directly with the process aids be charged. It is also possible to change the surface of Devices, production machines, packaging equipment, Transport equipment, packaging materials and the ambient air to move the process aid.
  • the microbicidal action of the processing aids occurs even when low concentrations are used. Only 0.01 to 5 g / kg, preferably 0.05 to 1 g / kg of food is used when it is applied. When used for the ambient air, only 0.001 to 10 g / m 3 of air are used, for example. Only 0.000001g to 0.1 g / cm 2 surface is used for the surfaces of devices.
  • microbicidal action time of the Flavorings used according to the invention under 24 hours, preferably is less than 12 hours. It is very particularly preferred to use process aids and Select concentrations so that the microbicidal action time is below 1 Hour, preferably less than 15 minutes.
  • the process aid according to the invention comprises flavorings which are selected are from the group of alcohols, aldehydes, phenols, acetates, acids, esters, Terpenes, acetals and their physiologically tolerable salts, essential oils and plant extracts.
  • Preferred embodiments of the process aids according to the invention include one or more flavorings consisting of one or more of the following Groups are selected:
  • Acetoin acetylmethylcarbinol
  • ethyl alcohol ethanol
  • propyl alcohol (1-propanol)
  • isopropyl alcohol (2-propanol, isopropanol)
  • propylene glycol glycerin
  • n-amyl alcohol (1-pentanol), iso-amyl alcohol (3-methyl-1-butanol), anise alcohol (4-methoxybenzyl alcohol, p-anise alcohol), citronellol, n-decyl alcohol (n-decanol), Geraniol, ⁇ - ⁇ -hexenol (3-hexenol), hydrocinnamic alcohol (3-phenyl-1-propanol), Lauryl alcohol (dodecanol), linalool, nerolidol, nonadienol (2,6-nonadien-1-01), Nonyl alcohol (nonanol-1), rhodinol, terpineol, bomeol, clineol (Eucalyptol), anisole, cuminyl alcohol (cuminol), 1-phenyl-1-propanol, 10-undecen-1-01, 1-hexadecanol.
  • Thymol Methyleugenol, Acetyleugenol, Safrol, Eugenol, Isoeugenol, Anethol, Phenol, methylchavicol (estragole; 3-4-methoxyphenyl-1-propene), carvacrol, ⁇ -bisabolol, Fomesol, anisole (methoxybenzene), propenylguaethol (5-propenyl-2-ethoxyphenol).
  • Camphor, limonene, ⁇ -caryophyllene Camphor, limonene, ⁇ -caryophyllene.
  • the processing aid contains only one of the flavorings mentioned, Isopropanol and ethanol are not used. Surprisingly It has been shown that a combination of at least two of the specified Flavoring has a far greater effect than one Single substance.
  • the processing aids are used undiluted and / or in water-soluble Dilution with water and / or food-approved solvents (e.g. alcohols) and / or in fat-soluble dilutions with vegetable (fat) oils.
  • food-approved solvents e.g. alcohols
  • fat-soluble dilutions with vegetable (fat) oils.
  • the process aids according to the invention e.g. readily water soluble Alcohols, preferably in concentrations of 0.1 to 99% by weight, based on the processing aid, used in conjunction with other flavorings become.
  • the process aids according to the invention preferably contain less than 50% by weight of ethanol, isopropanol or benzyl alcohol or one Mixture of these substances. It is particularly preferred if the proportion of mentioned alcohols at less than 30 wt .-%, in particular less than 20 % By weight. Sofem process aids are used, the benzyl alcohol and contain at least one further flavoring agent, the proportion of Benzyl alcohol are also more than 50% by weight.
  • the process aids are used for Shelf life improvement and stabilization from selected from the following group Food uses:
  • the process aid according to the invention acts in the environment of the susceptible to corruption Product, e.g. a food or feed, e.g. on Machine parts that are in contact with the product to be machined or processed, or in the air.
  • corruption Product e.g. a food or feed
  • Machine parts that are in contact with the product to be machined or processed, or in the air.
  • corruption-prone products i.e. they unfold theirs Effect on the surface or when penetrating into the product self.
  • the particular advantage of the process aid according to the invention is therefore that it reliably decontaminates on the one hand, while its effectiveness against Gram-positive and Gram-negative bacteria, fungi including yeast and has also proven viruses, while on the other hand it Food poses no danger as it is perfect for this is harmless and has no microbicidal, technological after-effects in the Owns food because the microbicidal effectiveness refers to that Production environment that by the measures of the invention contaminating microorganisms
  • the process aid according to the invention can be a lubricant that at the same time lubrication, decontamination of the lubricated parts and thus indirectly the shelf life stabilization of the products with these parts are in contact.
  • the process aid can also be an emulsifying, separating or Be a cleaning agent.
  • Such agents are used for emulsification and / or cleaning and thus also the decontamination of surfaces, objects, machines, Facilities, devices, cutting surfaces or devices, Transport devices and the like. It can also be used for Decontamination and cleaning of food, raw materials, cosmetics, Pharmaceuticals, paints, paper, pulp, livestock, poultry, fish and waste be used.
  • the process aid according to the invention can also be a spray his.
  • a spray enables a fine distribution of the decontaminating Active ingredients on all machine parts, transport devices, Cutters, work surfaces, etc. and at the same time can cause that immediately after the cutting or separating process and / or packaging portioning process packaged food by enclosed Spray in a climate with decontaminating and / or shelf life stabilizing Properties are kept. Mistable or sprayable Embodiments are moreover because of the comparatively smaller Very cost-effective if required.
  • the spray can also be used in and / or on packaging, e.g. Bags, Cardboard boxes or the like are blown in or sprayed / atomized, all the more so to make the packaged product more durable.
  • the spray agents are also used in the production environment (environment, cooling, Ventilation, fresh air) obscured at hygienic weak points (e.g. cooling sections) to be able to veningem the number of germs without that there working personnel are damaged.
  • hygienic weak points e.g. cooling sections
  • the process aids can also be sprayed on Food surfaces or cut surfaces are used to ensure that the To eliminate or eliminate food spoilage agents to reduce.
  • these spray agents can be used in transport facilities, warehouses and cold rooms and the like are used.
  • the process aid according to the invention is a gas phase active agent that is active in decontamination and / or Deodorization in the gas phase in more or less closed systems, such as packaging, waste systems, container systems, transport or Storage rooms and the like is used. Benefit from the effects of the gas phase agent both the packaged, contained, transported or stored in the container Good as well as the air and the respective environment.
  • the process aid according to the invention has also proven to be a good heat transfer medium proven.
  • heat transfer media are cooling, heating and Heat means meant that in circulating circulation systems of liquid Cooling, heating and heating systems used as decontaminating additives can be. They become aqueous or oily systems Prevention of growth of microorganisms in the liquids added to e.g. contamination from cooling leaks prevent.
  • this is the invention Process aids a cutting or separating agent for cutting knives and / or Cutting devices of all kinds and for all perishable products to be cut, to prevent contamination of the interfaces.
  • a flanking measure to improve the shelf life of food is cleaning or even disinfecting the environment with chemical Disinfectants that are subject to the biocide regulation. These substances are more or less toxic and should not be transferred to food.
  • chemical disinfection is a discontinuous measure that is pragmatic only at certain production times on machine parts and in Environment and after rinsing with water to remove the residual substances.
  • Mineral or cutting aids are usually used as cutting aids Compositions that are no longer permitted in many countries, or vegetable cutting oils are used, which are often already contaminated, i.e. are bacterially contaminated. See e.g. G. Schuster. Investigations on mold contamination of sliced bread, Bburger & Konditor 27 (11), pp. 345-347; G. Spicher The sources of direct contamination of the bread with mold; The cutting oil as a factor of mold contamination; Cereals, flour and bread 32 (4), pp. 91-94.
  • the cutting or separating agent according to the invention can be used wherever industrial is cut or separated and the clippings of a spoilage through bacteria or fungi or contamination by viruses. This applies e.g. for pulp and paper, but especially for food or Feed.
  • the process aid according to the invention is for cutting or separating bread, baked goods, fish and fish products, Potatoes and potato based products, fruits and vegetables and Products based on fruits and vegetables, confectionery, starch products, Pasta, meat and meat products, cheese products, poultry and poultry products suitable.
  • the process aid according to the invention is a cutting or. Separating agent (e.g. for cutting bread), this can be done in the usual way Vegetable oil-fat wax base with the addition of microbicidal processing aids be provided on the basis of flavorings.
  • the cutting or Release agents e.g. for use in the meat products industry
  • Natural emulsifiers for example lecithins in a concentration of 1 to 25% by weight, can also be added to the vegetable oils, waxes and fats, as it corresponds to the prior art.
  • Exemplary emulsifiers are lecithins, citric acid monoglycerides, diacetyltartaric acid, N-acetylphosphatidylethanolamine, phosphatidylinositol, phosphatidylserine, phosphatidic acids, phosptatidylcholine.
  • the cutting or separating agent according to the invention is provided as an emulsion on an aqueous basis, vegetable oils, vegetable fats and vegetable waxes with unsaturated and saturated C 16 - C 18 fatty acids, which also have a viscosity of approx. 10 mPas (20 ° C) to approx Have used 500 mPas (20 ° C).
  • Compound cutting and release agents can be mixed with Water in a ratio of 1: 1 to 1:40 as cutting or separating emulsion (milk) be applied.
  • the cutting or separating agent according to the invention is at least the machine parts in contact with the clippings are applied, to decontaminate them.
  • the agents are in doses of 1-20 g / kg of food used, the dosage of which is used Cutting or separating device and the clippings is dependent.
  • the cutting and separating means are mostly on the cutting or separating devices angry, e.g. when cutting bread on circular plate slicers sprayed on with which e.g. Sliced bread then cut becomes.
  • parts of the cutting devices e.g. Circular knives, band slicers (rotating band saws), electrical and mechanical Knives or knife devices, electric or mechanical saws or sawing devices, electric or mechanical chainsaws or Devices wetted so that the cutting or separating agent on the corresponding Machine part as well as by cutting or separating resulting surface can have a decontaminating or microbicidal effect.
  • the advantageous effect of the cutting and separating agents according to the invention manifests itself in an extended shelf life of the clippings, e.g. of sliced bread. It is not least due to the fact that the cutting and separating agent cover the surface of the clippings and also the deeper layers of the cut Food decontaminated by the in the cutting oil contained flavorings.
  • the flavorings described here also have a microbicidal effect in the Vapor phase as most of the aromas evaporate easily. Therefore, they work in the so-called environment of the food, e.g. in the packaging of the food, if after the cutting process e.g. in a foil packaging is packed.
  • This process of decontamination of the clippings after the actual one Cutting process can be caused by a weak thermal aftertreatment of the Supported food without loss of quality in the packaging become.
  • a weak thermal aftertreatment of the Supported food without loss of quality in the packaging become.
  • the advantageous effect of the cutting or separating agents can partly significantly increased if the application and cutting or separating techniques are so improved or redeveloped that intensive wetting of the food with cutting or separating agent.
  • the circular disc cutting blade with separate groove guides and grooves provided so that a thorough and intensive application of cutting or Release agent was possible.
  • Process aids for spraying cutting knives as cutting tools and for spraying transport devices using the example of sliced sausage Taking into account the reduction in spoilage (Enterobacter / Lactobacillen) on cutting knife, transport device and Sausage cut surfaces and improvement / extension of durability.
  • Sample no Sample description Total germ count / 7 cm 2 comment 1 tape 67 2nd tape ⁇ 100 3rd tape ⁇ 100 4th tape 51 20 mold 5 Sausage supporter 8th 6 Sausage supporter 0 7 Knife (outside) 39 8th Knife (inside) 28 9 Knife case (inside) en masse
  • Sample no Sample description Total germ count / 7 cm 2 18th Tape after rubbing with paper (13: 12h) 1 19th Tape after rubbing with paper (13: 12h) 0 20th Tape after rubbing with paper (13: 22h) 0 21 Tape after rubbing with paper (13: 20h) 1 22 Tape after rubbing with paper (13: 30h) 18th 23 Tape after rubbing with paper (13: 30h) 4th 24th Tape during continuous spraying 0 25th Tape during continuous spraying 0 26 Sliced sausage (top) 1 27 Sliced sausage (below) 0
  • the shelf life of sausage is determined according to the test results Use of the cutting agent, which is applied to the cutting devices is significantly improved. At the same time, there is a surprisingly good one Cleaning the cutting surfaces, the cutting devices. In addition, the Slicing ability of the sausage improved. Despite the high dilution of the used The durability of fabrics is significantly improved. Leave with vegetable oils excellent results are achieved in dilution from 1:10 to 1: 100.
  • Process aids for cutting by spraying on cutting knives (Band slicer), circular plate cutting machine and spray for spraying of the surfaces of the food taking into account the example of toast bread the reduction of spoilage on the machine parts and bread and / or cut surfaces (mold / Aspergillus niger) for simultaneous Improve / extend shelf life.
  • Process aids for atomizing in the air taking into account the reduction the spoilage agent in the air (mold / Aspergillus niger) and prevention resedimentation on baked goods using the example of baked goods the result of the improvement / extension of the durability.
  • Sample no Sample description bacteria Mould 1 Cold room before fog between the cooling towers 38 2nd Stair area before entering the cold room 1,500 3rd Cold room exit to packaging 2,500 625 4th 1. Cooling tower before the air flow from the cooling system - before ventilation 10: 00h 75 13 5 1. Cooling tower in front of the air flow from the cooling system directly before misting 11: 30h 80 140
  • Sample no . Sample description bacteria Mould 6 1. Cooling tower in front of the air flow of the cooling system - during the misting 11: 45h 15 13 7 1. Cooling tower in front of the air flow of the cooling system - at the end of the nebulization 13:00 0 0 8th 1. Cooling tower before the air flow of the cooling system - after the nebulization 14: 00h 0 0
  • the shelf life of baked goods is indirectly extended by continuous application of the process aid for atomizing in the Air (cooling tower, cooling / transport route), the number of Mold in the air is significantly reduced. A chemical preservation or pasteurization of the baked goods is no longer necessary.
  • Test organisms E. coli ATCC11229 Staph.aureus ATCC6538 Ps.aeruginosa ATCC15442 C.albicans ATCC10231 A.niger ATCC16404 Cladosporium herbarum (self-isolate) 2.
  • Culture media CSA (Tryptone Soya Agar Oxoid CM 131) COD (Tryptone Soya Broth Oxoid CM 129) YGC agar (Merck 16000) Tween 80 (Merck)
  • the fungi and bacteria are taken up with a swab (cotton swab) (with rotating movements over the movements over the overgrown plate) and evenly spread over the cut surface of a sliced bread sample, so that a concentration of 10 3 - 10 4 spores or Microorganisms per 100 cm 2 is reached.
  • a swab cotton swab
  • test agent 0.2-0.3 ml of the test agent are sprayed with an aerosol spray onto 100 cm 2 of sliced bread.
  • the test breads are packed in plastic bags (polyethylene or polypropylene), the plastic bags are closed and stored in the light at room temperature.
  • the growth of microorganisms on the contaminated bread is included compared to that on control bread.
  • the minimum shelf life is the number of Days after which the first growth of microorganisms with the naked eye can be recognized.
  • the killing factor is determined as a reduction factor (RF) in relation to a growth control of 10 5 -10 7 CFU / ml.
  • the gas phase test procedure is used to determine the kill factor Use of gas-phase process aids.
  • the determination is made in a so-called double petri dish performed on an absorbent surface, e.g. Bread or urea / formaldehyde foam blocks (0.5 x 1 x 3 cm) 0.5 ml of the gas phase active Given by means.
  • the bread or the foam block are in a compartment of a divided petri dish.
  • a filter paper disc (diameter 13 mm) inoculated with approx. 10 8 to 10 9 germs is placed.
  • the bowl is sealed airtight and incubated for 24 hours at a temperature of 30 ° C.
  • the filter paper disk is suspended in 9 ml COD and a dilution series made in COD.
  • the tubes are at Incubated at 30 ° C and evaluated. The kill factor is compared to one Control determined.
  • the respective test microorganism is inoculated with molten culture media containing 10 5 to 10 6 germs per ml.
  • the culture media are poured into petri dishes and cooled.
  • 80 ⁇ l of the agent to be tested (additive or process aid) are applied to a filter paper disc (diameter: 13 mm; Schleicher & Schüll, article 601/2), and four of the filters thus prepared are evenly distributed on the surface of a prepared petri dish.
  • the plates are then incubated at 37 ° C for 24 hours. After the incubation, the size of the inhibition area that may occur is determined.
  • the experiment shows the individual effects of ethanol, isopropanol in concentrations of 20 and 1% by weight and the combined action of 0.2% by weight of anisaldehyde and 0.04% by weight.
  • Oreganum oil compared with the synergistic effect of the combination of anisaldehyde, oregano oil and one of the water-soluble alcohols mentioned.
  • the experiment was carried out as a quantitative suspension experiment. Reduction factors Exposure time 1 hour A. niger Staph.
  • Example 7 Decontaminating or microbicidal activity of individual flavorings
  • Example 8 Influence of the cutting and separating agent according to the invention on the shelf life of bread
  • the shelf life of sliced bread was investigated a) in the case of bread cut with conventional cutting agents, which was not inoculated with microorganisms, and in the case of bread cut with the cutting agent according to the invention, which was artificially contaminated after cutting. Shelf life of the bread in days Cutting / release agent % By weight based on the ready-to-use agent Control Bread, Sliced Bread, Untreated 20 ° C Cladosporium herbarum 5 x 10 5 CFU / 100 cm 2 bread 20 ° C A. niger 2x10 4 CFU / 100 cm 2 bread 20 ° C Staph.
  • Example 9 Comparison of the influence of conventional cutting means with cutting means according to the invention on the durability of sliced bread
  • Example 10 Extension of the shelf life of sliced bread by weak thermal aftertreatment of the food cut with cutting release agent
  • the following table shows the shelf life of sliced bread which has been sliced once with conventional slicing oil, sliced with slicing / separating agents in accordance with Table 6 and has not been subjected to any thermal aftertreatment and then such bread which has been sliced with slicing / separating agents according to the invention has been cut and then subjected to a weak thermal post-treatment.
  • Sliced bread shelf life in days Table 8 Cutting / release agents Control bread cut with cutting oil without process aid according to the invention Control bread with cutting / separating agent acc.
  • Cut table 6 Bread with cutting / separating agent acc. Table 6 cut and thermally treated Exposure time in s / min Core temp. in ° C Shelf life in days a 3rd 11 10s 30s 1 min. 2 min.
  • the recipe examples consist of individual and / or several examples Aroma function groups are combined with one another and / or are synergistically combined.
  • the processing aids are either used undiluted or after one Dilution with water and / or food-grade solvents and / or Vegetable (fat) oils and / or emulsifiers from 0.01% by weight to 99.99% by weight applied, preferably in a mixing ratio of 1: 1 to 1: 100.
  • Some application examples for the use of one or more process aids for stability stabilization and / or improvement and / or environmental impact for example: Application of process aids Example No .: toast Nebulizer 16 Cutting means 11 Spray 17th Pastries Nebulizer 16 Sliced sausage Cutting means 11 Emulsifying, separating, cleaning supplies 13 bratwurst Spray 17th Boiler water for heating chocolate mass Heat, cold, Means of transmission 12th Conveyor belt lubricant 14 Waste bin Gas phase activity medium 15
  • Process for improving the durability and / or stabilization of microbially perishable products in the before, after or during the process for the manufacture, processing or packaging of the products their surfaces and / or their surroundings, in particular the ambient air and / or the surfaces of the directly or indirectly devices or other materials that come into contact with the products are charged with one or more process aids, characterized in that the processing aid contains at least one microbicidal flavoring agent, preferably at least two microbicidal flavoring agents
  • microbicidal action time of the processing aids is less than 1 hour, preferably less than 15 minutes.
  • flavourings contained in the processing aid are selected from the group of alcohols, aldehydes, phenols, acetates, esters, terpenes, acetals, polyphenols, acids and their physiologically compatible salts, essential oils and plant extracts.
  • Procedure as described above characterized in that a processing aid is used which contains more than 50% by weight of benzyl alcohol and at least one further flavoring agent.
  • the processing aid contains less than 50% by weight, preferably less than 30% by weight, particularly preferably less than 20% by weight of ethanol, isopropanol or benzyl alcohol or a mixture of these substances.
  • Process aids characterized in that it contains at least one microbicidal flavoring agent, preferably at least two microbicidal flavoring agents.
  • microbicidal action time is less than 1 hour, preferably less than 15 minutes.
  • Process aids as described above characterized in that it contains at least one flavoring agent selected from the group of alcohols, aldehydes, phenols, acetates, esters, terpenes, acetals, polyphenols, acids and their physiologically tolerable salts, essential oils and plant extracts.
  • at least one flavoring agent selected from the group of alcohols, aldehydes, phenols, acetates, esters, terpenes, acetals, polyphenols, acids and their physiologically tolerable salts, essential oils and plant extracts.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Botany (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Packages (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
  • Fertilizers (AREA)
EP01109105A 1995-03-31 1996-03-28 Procédé d'amélioration de la durée de conservation et / ou de la stabilité des aliments altérables sous l'action de microbes Expired - Lifetime EP1116446B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19512147 1995-03-31
DE19512147 1995-03-31
EP96909141A EP0762837B1 (fr) 1995-03-31 1996-03-28 Procede pour l'amelioration de la conservation et/ou la stabilisation de produits alterables sous l'action de microbes

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP96909141A Division EP0762837B1 (fr) 1995-03-31 1996-03-28 Procede pour l'amelioration de la conservation et/ou la stabilisation de produits alterables sous l'action de microbes
EP96909141.2 Division 1996-10-03

Publications (3)

Publication Number Publication Date
EP1116446A2 true EP1116446A2 (fr) 2001-07-18
EP1116446A3 EP1116446A3 (fr) 2003-04-02
EP1116446B1 EP1116446B1 (fr) 2012-02-08

Family

ID=7758471

Family Applications (2)

Application Number Title Priority Date Filing Date
EP96909141A Expired - Lifetime EP0762837B1 (fr) 1995-03-31 1996-03-28 Procede pour l'amelioration de la conservation et/ou la stabilisation de produits alterables sous l'action de microbes
EP01109105A Expired - Lifetime EP1116446B1 (fr) 1995-03-31 1996-03-28 Procédé d'amélioration de la durée de conservation et / ou de la stabilité des aliments altérables sous l'action de microbes

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP96909141A Expired - Lifetime EP0762837B1 (fr) 1995-03-31 1996-03-28 Procede pour l'amelioration de la conservation et/ou la stabilisation de produits alterables sous l'action de microbes

Country Status (10)

Country Link
US (3) US6514551B1 (fr)
EP (2) EP0762837B1 (fr)
JP (1) JPH10501445A (fr)
AT (2) ATE213593T1 (fr)
AU (1) AU5275096A (fr)
DE (2) DE19612340A1 (fr)
DK (1) DK0762837T3 (fr)
ES (1) ES2173274T3 (fr)
PT (1) PT762837E (fr)
WO (1) WO1996029895A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2867948A1 (fr) * 2004-03-29 2005-09-30 Hightech Bio Activities Holdin Composition decontaminante presentant a la fois des proprietes bactericides, fongicides et virucides, procedes d'obtention et utilisations d'une telle composition
FR2876586A1 (fr) * 2004-10-20 2006-04-21 Persee Medica Composition pour prevenir ou traiter le stress, notamment les bouffees de stress chronique et permanent
WO2013007722A1 (fr) 2011-07-11 2013-01-17 Sony Corporation Procédé d'utilisation de proxy dans un réseau

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0762837B1 (fr) 1995-03-31 2002-02-27 Jörg-Peter Prof. Schür Procede pour l'amelioration de la conservation et/ou la stabilisation de produits alterables sous l'action de microbes
DE19726429A1 (de) * 1997-06-23 1998-12-24 Schuer Joerg Peter Prof Verfahren und Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
US20020176882A1 (en) * 1997-06-23 2002-11-28 Schur Jorg Peter Additive the improvement and/or stabilization of the keeping quality of microbially perishable products
DE19831309A1 (de) * 1998-07-13 2000-01-27 Schuer Joerg Peter Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
DE19831306A1 (de) * 1998-07-13 2000-01-27 Schuer Joerg Peter Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
DE19831288A1 (de) * 1998-07-13 2000-01-27 Schuer Joerg Peter Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
CA2336565A1 (fr) * 1998-07-13 2000-01-27 Joerg Peter Schuer Composition antimicrobienne
US6139890A (en) * 1998-07-21 2000-10-31 Bio-Tek Industries, Inc. Method of extending the shelf life and/or reducing level of bacterial contamination on fruits and vegetables
DE19851778C2 (de) * 1998-11-10 2001-02-15 Weller Frank Uwe Kombination aus einem flüssigkeitsdichten Fleischtablett mit eingelegter Saug-Trennschicht
DE19931185A1 (de) 1999-07-07 2001-01-18 Joerg Peter Schuer Verfahren zur Entkeimung von Luft
DE19940283A1 (de) * 1999-08-25 2001-03-01 Joerg Peter Schuer Pflanzenschutz
DE19940605A1 (de) * 1999-08-27 2001-03-01 Joerg Peter Schuer Imprägnierungsverfahren
NL1013448C2 (nl) * 1999-11-01 2001-05-09 Nl I Voor Zuivelonderzoek Gebruik van nonaanzuur als schimmelwerend middel.
US20050014827A1 (en) * 2000-11-09 2005-01-20 Schur Jorg P. Synergistic medicament containing flavoring agents and having an antagonistic regenerative and/or protagonist decontamination effect
FR2817242B1 (fr) * 2000-11-30 2003-06-27 Cebal Tubes souples contenant des agents biocides
WO2002044055A1 (fr) * 2000-11-30 2002-06-06 Cebal S.A. Recipients ayant une paroi contenant des agents biocides
JP2002179509A (ja) * 2000-12-12 2002-06-26 Takasago Internatl Corp 抗カビ香料組成物
DE20100121U1 (de) * 2001-01-05 2002-05-16 Schuer Joerg Peter Vorrichtung zur Anreicherung von Luft mit Luftbehandlungsmittel
DE10100595A1 (de) * 2001-01-09 2002-07-18 Joerg Peter Schuer Verfahren zur untoxischen Geruchsneutralisierung von Luft
DK174676B1 (da) * 2001-01-18 2003-08-25 Slagteriernes Forskningsinst Fremgangsmåde og anlæg til fremstilling af skiveskårne fødevarer
US20030031588A1 (en) * 2001-06-13 2003-02-13 Schur Jorg Peter Device for enriching air with an air treatment agent, especially for the disinfection of air, and/or perfuming of air and/or for odor masking
EP1487504A4 (fr) * 2002-02-19 2010-09-01 Eden Research Plc Amelioration de la qualite de l'air interieur et composition antiseptique destinee a cet effet
AU2003225576A1 (en) * 2002-02-19 2003-09-09 Eden Research Plc Compositions and methods for preservation of food
MXPA04009937A (es) * 2002-04-08 2004-12-13 Kalsec Inc Composiciones de extracto a base de hierbas labiatae que se pueden dispersar facilmente en salmuera fria.
US7258883B2 (en) * 2003-02-14 2007-08-21 Preservation Sciences, Inc. Food and beverage perservative
FR2853495B1 (fr) * 2003-04-08 2006-08-11 Xeda International Procede de traitement de fruits et legumes a base de lecithine
EP1615502B1 (fr) * 2003-04-08 2016-03-23 Xeda International Procede de traitement de fruits et legumes a base de lecithines
US20050196492A1 (en) * 2004-03-04 2005-09-08 Muller Wayne S. Food preservative method and system using vanillin and constituent having isothiocynate compound
JP4354392B2 (ja) * 2004-12-13 2009-10-28 理研ビタミン株式会社 改質された天然腸の製造方法
AU2006228963B2 (en) * 2005-04-01 2012-06-07 Universite Laval Garlic extract and chitosan compositions, and uses thereof
DE102006018544A1 (de) * 2006-04-21 2007-10-25 Mayr-Melnhof Karton Ag Verpackung und Verwendung von Duftstoffen in einer Verpackung
US8716200B2 (en) 2006-09-13 2014-05-06 Ecolab Usa Inc. Conveyor lubricants including emulsion of a lipophilic compound and an emulsifier and/or an anionic surfactant and methods employing them
AR064778A1 (es) * 2007-01-12 2009-04-22 Albemarle Corp Biocidas a base de bromo adecuados para el procesamiento de alimentos
CA2698051C (fr) * 2007-08-29 2016-02-16 Mars, Incorporated Produit alimentaire pour chats en portions et procedes associes
JO3416B1 (ar) 2009-04-27 2019-10-20 Jeneil Biosurfactant Co Llc تركيبات مضادة للبكتيريا وطرق استخدامها
US8329618B1 (en) 2009-05-12 2012-12-11 Aceto Agricultural Chemical Corporation Tuber treatment composition
US20100291265A1 (en) * 2009-05-18 2010-11-18 Board Of Trustees Of Michigan State University Baking composition
PT3023009T (pt) 2009-08-06 2017-03-13 Anitox Corp Conservante de água e rações
EP2301368A1 (fr) 2009-09-08 2011-03-30 Mars, Incorporated Composition pour la prévention contre l'altération par des micro-organismes et utilisations et produits associés
US8293299B2 (en) 2009-09-11 2012-10-23 Kraft Foods Global Brands Llc Containers and methods for dispensing multiple doses of a concentrated liquid, and shelf stable Concentrated liquids
JP5907655B2 (ja) * 2009-12-21 2016-04-26 テーブルマーク株式会社 食品保存料、カビ及び／又は酵母の増殖を阻害する方法、酵母及び／又は細菌の生育を阻害する方法
ES2357389B1 (es) * 2011-03-11 2011-09-26 Biofungitek, Sociedad Limitada Composición fungicida y bactericida que comprende compuestos orgánicos volátiles de origen natural.
MX2014004618A (es) 2011-10-20 2014-05-27 Anitox Corp Formulaciones antimicrobianas con acido pelargonico.
EP2785205B1 (fr) * 2011-11-30 2020-12-30 Anitox Corporation Mélange antimicrobien d'aldéhydes, d'acides organiques et d'esters d'acide gras
US11013248B2 (en) 2012-05-25 2021-05-25 Kraft Foods Group Brands Llc Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings
BR112015012864A2 (pt) 2012-12-05 2017-07-11 Kemin Ind Inc intensificador da palatabilidade para ração seca, e, método para conservar uma ração seca para animal de estimação
EP2995201A1 (fr) * 2014-09-04 2016-03-16 Purac Biochem B.V. Conservation de produits à base de viande avec un melage d'un derive de la vanillin et cannelle
US20160242428A1 (en) * 2015-02-13 2016-08-25 Hydromer, Inc. Antimicrobial formulations and methods for sanitizing meat products
MA43029A (fr) * 2015-09-30 2018-08-08 Itene Instituto Tecnologico Del Embalaje Transp Y Logistica Composition antimicrobienne contenant du citral, de l'hexanal et du linalol comme principes actifs et application dans l'emballage de fruits ou de légumes traités de façon minimale
US11793215B1 (en) * 2018-09-07 2023-10-24 Incuvator Fund I, Llc Production of finish feed product and feed ingredient from viscera
EP3747280A1 (fr) * 2019-06-07 2020-12-09 Lucta, S.A. Combinaison antimicrobienne destinée à être utilisée dans l'alimentation des animaux
WO2024095804A1 (fr) * 2022-11-02 2024-05-10 味の素株式会社 Agent de suppression de détérioration au stockage et procédé de suppression de détérioration au stockage d'aliment ou de boisson

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB172993A (en) * 1920-06-12 1921-12-12 Robert Lauder Mackenzie Wallis Improvements in and relating to the employment of antiseptic, disinfectant, or preservative agents
GB1060447A (en) * 1963-05-14 1967-03-01 Maple Leaf Trust Compositions for the preservation of foodstuffs, for the sterilization and hygiene ofair in confined spaces and for cosmetic and pharmaceutical purposes
DE2423076A1 (de) * 1973-05-15 1974-12-05 Ivar Harry Sanick Verfahren zum schutz von nahrungsmitteln gegen befall durch mikroorganismen und mittel zur durchfuehrung des verfahrens
DE3138277A1 (de) * 1980-09-26 1982-04-15 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo, Osaka Fluessiges bakterizid fuer nahrungsmittel und nahrungsmittel-verarbeitungsmaschinen oder -geraete
US4446161A (en) * 1982-03-29 1984-05-01 General Foods Corporation Aromatic, monohydric alcohols as preservatives for foods
EP0557946A1 (fr) * 1992-02-26 1993-09-01 The Green Cross Corporation Composition contenant l'isothiocyanate allylique et son utilisation

Family Cites Families (105)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE515423A (fr)
US1331331A (en) * 1919-01-03 1920-02-17 Erslev Knud Process for improving tobacco
US1790596A (en) * 1927-05-16 1931-01-27 Claude B Schneible Column
US2409088A (en) * 1943-07-09 1946-10-08 Weits John Device for washing and conditioning air and gases
US2496281A (en) * 1944-07-12 1950-02-07 Whiting Corp Fly ash and dust collector
US2596106A (en) * 1947-11-22 1952-05-13 Claude B Schneible Column apparatus
US2683074A (en) * 1949-11-28 1954-07-06 York Corp Process for deodorizing and sterilizing air
GB790075A (en) 1954-10-28 1958-02-05 Irwin Irville Lubowe Solubilizing of mineral, vegetable and animal oils for cosmetic and industrial purposes
US2886297A (en) * 1956-12-26 1959-05-12 Phillips Petroleum Co Brine creaming of latices
US3191363A (en) * 1961-04-07 1965-06-29 Carrier Corp Apparatus for treating air
FR1386506A (fr) * 1963-12-02 1965-01-22 Perfectionnements aux dépoussiéreurs électrostatiques à condensation de vapeur
FR1400428A (fr) 1964-03-18 1965-05-28 Ajem Lab Inc Laveur d'air
US3442602A (en) * 1964-07-09 1969-05-06 Charles C Diehl Method and mechanism for deodorizing polluted atmospheric air
US3518096A (en) * 1965-10-06 1970-06-30 Stella Layton Food preserving process
US3557535A (en) * 1968-11-25 1971-01-26 Poma Inc Air washer
US3788045A (en) * 1971-09-13 1974-01-29 Peabody Engineering Corp Gas cleaning apparatus
US3908031A (en) * 1973-03-12 1975-09-23 Heller And Co B Ethanol vapor sterilization of natural spices and other foods
FR2228434A1 (en) 1973-05-08 1974-12-06 Delpech Lucien Fungicides for treatment of plants or wood - contg. a natural or synthetic phenol
US3989485A (en) * 1973-09-13 1976-11-02 Intensa, S.A. Process and apparatus for scrubbing exhaust gas from cyclone collectors
DE2405004C3 (de) * 1974-02-02 1979-11-29 Haarmann & Reimer Gmbh, 3450 Holzminden Desodorierende Mittel
US4602011A (en) * 1975-10-24 1986-07-22 Chapman Chemical Company Antimicrobial compositions and methods of using same
JPS5332134A (en) 1976-09-04 1978-03-27 Katsuraya Fine Goods Aromatic compound and its preparation method
IE46095B1 (en) * 1976-12-03 1983-02-23 Rivieren Rech Fondamentale Apparatus for sterilization and other purification of air
US4361554A (en) * 1981-05-06 1982-11-30 Texas Botanical Research, Company Organic insecticide
JPS57194775A (en) * 1981-05-21 1982-11-30 Asama Kasei Kk Storing and quality improving agent of food
WO1984000694A1 (fr) 1981-09-22 1984-03-01 Wilhelm O H Grunert Procede de neutralisation de substances irritantes et de gaz toxiques
DE3138288A1 (de) 1981-09-25 1983-04-07 Siemens AG, 1000 Berlin und 8000 München Anordnung und verfahren zur erzeugung eines elektrischen ladungsbildes
US4647458A (en) * 1981-09-25 1987-03-03 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo Liquid bactericide for foods and food processing machines or utensils, employing a synergistic mixture of ethyl alcohol, an organic acid and phosphoric acid
EP0103878B1 (fr) 1982-09-17 1990-12-27 Humán Oltoanyagtermelö és Kutato Intézet Préparations pour le traitement des plaies de la surface de la peau et procédé pour leur obtention
US4579569A (en) * 1982-10-14 1986-04-01 Fume-Klean Apparatus for neutralizing and removing fumes
SE8300356L (sv) * 1983-01-25 1984-07-26 Tetra Pak Int Sett och anordning for forangning av en vetska
JPS59172416A (ja) 1983-03-18 1984-09-29 Terumo Corp 脂肪輸液
US4544666A (en) * 1983-04-22 1985-10-01 Phyton/Ag, Inc. Chemotherapeutic agents for the control of plant diseases
SU1189454A1 (ru) 1983-05-19 1985-11-07 Ural Vni Pi Khim Promy Средство для освежения воздуха
FI834370A (fi) * 1983-11-29 1985-05-30 Enbom A W Ab Oy Centrifugavskiljare.
US4977142A (en) * 1984-07-11 1990-12-11 University Of Sydney Antiallergenic agent
ATE50144T1 (de) * 1984-07-11 1990-02-15 Univ Sydney Antiallergikum.
US4810268A (en) * 1985-11-07 1989-03-07 Ppg Industries, Inc. Apparatus and method of washing air
JPS62111675A (ja) * 1985-11-08 1987-05-22 Sanraku Inc 食品防腐剤
JPH0724544B2 (ja) 1985-11-26 1995-03-22 三栄源エフ・エフ・アイ株式会社 生野菜の大腸菌殺菌と鮮度保持
JPS6359338A (ja) * 1986-08-28 1988-03-15 Nippon Ekishiyou Kk オゾン除去剤
US5091405A (en) * 1987-01-05 1992-02-25 E. I. Du Pont De Nemours And Company Insecticidal pyrazolines
DE3721137A1 (de) 1987-06-26 1989-01-05 Dietl Hans Fettemulsion zur intravenoesen anwendung
DE3734147C2 (de) 1987-10-09 1998-10-29 Braun Melsungen Ag Isotone omega-3-fettsäurenhaltige Fettemulsion und ihre Verwendung
JPH0672706B2 (ja) 1988-05-31 1994-09-14 清水建設株式会社 香り供給方法および香り供給装置
JPH02100660A (ja) 1988-10-07 1990-04-12 Nasa:Kk 食品保存方法
JPH02142703A (ja) * 1988-11-24 1990-05-31 Kurita Water Ind Ltd 有害生物防除剤
CA2012288A1 (fr) 1989-03-16 1990-09-16 Wolfgang Beilfuss Desinfectant pour l'hygiene vegetale
DE3913707C2 (de) * 1989-04-26 1998-01-29 Amc Int Alfa Metalcraft Corp Doppelwandiger Kochtopf
US5089268A (en) * 1990-05-02 1992-02-18 Katz David P Egg phosphatide lipid emulsions altered for a specific therapeutic fatty acid composition
JPH0469308A (ja) 1990-07-06 1992-03-04 Doi Kyohei ムカデ用忌避剤
US5143720A (en) * 1990-11-28 1992-09-01 Microcide, Inc. Disinfecting and sanitizing compositions
US5201919A (en) * 1991-12-17 1993-04-13 Inline Scrubber Corporation Integral in-line gas scrubber
US5322689A (en) * 1992-03-10 1994-06-21 The Procter & Gamble Company Topical aromatic releasing compositions
JP2660196B2 (ja) * 1992-04-17 1997-10-08 株式会社アラミック 米の品質保存剤
US5766314A (en) * 1992-11-13 1998-06-16 France Grignotage Process and device for treating working atmosphere using a cyclone exchanger
FR2699818B1 (fr) 1992-12-24 1995-02-03 Oreal Composition cosmétique ou pharmaceutique contenant en association un polyphénol et un extrait de gingko.
US5653991A (en) * 1993-03-24 1997-08-05 The Rod Family Trust Process for repelling and killing insects and compositions to effect the same comprising a monoterpene
WO1994022321A1 (fr) 1993-04-01 1994-10-13 Kalamazoo Holdings, Inc. Solutions antioxydantes a base de catechines de the vert solubles dans les lipides
US5439690A (en) * 1993-05-21 1995-08-08 Ecosmart, Inc. Non-hazardous pest control
US6004569A (en) * 1993-05-21 1999-12-21 Ecosmart Technologies, Inc. Non-hazardous pest control
TW298560B (fr) * 1993-05-26 1997-02-21 Cpc International Inc
US5472684A (en) * 1993-06-02 1995-12-05 Colgate Palmolive Company Oral compositions for plaque and gingivitis
US5747416A (en) * 1993-07-08 1998-05-05 Mcardle; Blaise Herbicidal and insecticidal protein-polysaccharide delivery compositions and methods for controlling plant and insect populations
DE4325968C2 (de) * 1993-08-03 1997-04-10 Balcke Duerr Ag Vorrichtung zum Kühlen von Gasen und gegebenenfalls Trocknen von dem Gas zugegebenen Feststoffteilchen
US5362520A (en) * 1993-08-23 1994-11-08 Rodriguez Ricardo M Bleaching and finishing composition and method
JP3661707B2 (ja) * 1993-10-28 2005-06-22 三省製薬株式会社 皮膚外用剤
US5416075A (en) * 1993-11-30 1995-05-16 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Biospecific emulsions
GB9404303D0 (en) * 1994-03-04 1994-04-20 Royal Free Hosp School Med Antibacterial agent
FR2717392B1 (fr) * 1994-03-16 1996-06-07 Prodifa Sarl Diffuseur dynamique d'une substance telle qu'un parfum.
US5474774A (en) 1994-03-25 1995-12-12 Jlb, Inc. Adhesion inhibiting composition
US5397385A (en) * 1994-03-28 1995-03-14 Watts; James L. Anti-fouling coating composition containing capsaicin
JPH07314409A (ja) * 1994-03-29 1995-12-05 Takeda Chem Ind Ltd 材木の処理法
US5574065A (en) 1994-04-21 1996-11-12 Clintec Nutrition Co. Method and composition for normalizing injury response
JPH0820510A (ja) * 1994-07-06 1996-01-23 Kaneka San Supaisu:Kk 抗菌活性のある香辛料、およびこれを原料とする抗菌剤
US5480519A (en) * 1995-02-06 1996-01-02 Texas Instruments Incorporated Electrochemical etch system and method
US5569461A (en) * 1995-02-07 1996-10-29 Minnesota Mining And Manufacturing Company Topical antimicrobial composition and method
EP0762837B1 (fr) * 1995-03-31 2002-02-27 Jörg-Peter Prof. Schür Procede pour l'amelioration de la conservation et/ou la stabilisation de produits alterables sous l'action de microbes
DE69612011T3 (de) * 1995-11-24 2010-02-18 Unilever N.V. Zusammensetzung auf basis von fischöl
US6348187B1 (en) * 1996-01-24 2002-02-19 Warner-Lambert Company Peroxide/essential oils containing mouthwash compositions and two-part mouthwash systems
DE19617278A1 (de) 1996-04-30 1997-11-13 Hubert Dr Christ Universalreiniger, Verfahren zur Herstellung und seiner Verwendung
US5661104A (en) * 1996-06-11 1997-08-26 Givaudan-Roure (International) Sa Preservative compositions for use in aqueous systems
US6284259B1 (en) * 1997-11-12 2001-09-04 The Procter & Gamble Company Antimicrobial wipes which provide improved residual benefit versus Gram positive bacteria
US20020176882A1 (en) * 1997-06-23 2002-11-28 Schur Jorg Peter Additive the improvement and/or stabilization of the keeping quality of microbially perishable products
DE19726429A1 (de) 1997-06-23 1998-12-24 Schuer Joerg Peter Prof Verfahren und Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
US20020014707A1 (en) * 1997-07-11 2002-02-07 Fls Miljo A/S Method of flue gas conditioning and a flue gas conditioning device
EP1014969B1 (fr) * 1997-09-09 2008-11-12 Rutgers, The State University of New Jersey Extrait de proanthocyanidine d'origine vegetale empechant efficacement une adherence de bacteries a fimbriae de type p a des surfaces
US6007055A (en) * 1997-12-29 1999-12-28 Schifftner; Kenneth C. Gas and liquid contact apparatus
US6207290B1 (en) * 1998-04-07 2001-03-27 Burlington Bio-Medical & Scientific Corp. Antifoulant compositions and methods of treating wood
US6033705A (en) * 1998-07-08 2000-03-07 Isaacs; Charles E. Method for treating foodstuffs to reduce or prevent microbial activity
CA2336565A1 (fr) 1998-07-13 2000-01-27 Joerg Peter Schuer Composition antimicrobienne
DE19831309A1 (de) 1998-07-13 2000-01-27 Schuer Joerg Peter Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
DE19831306A1 (de) 1998-07-13 2000-01-27 Schuer Joerg Peter Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
DE19831288A1 (de) 1998-07-13 2000-01-27 Schuer Joerg Peter Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
DE19850994A1 (de) 1998-11-05 2000-05-11 Menno Chemie Vertriebsges M B Mittel zur Abwehr und Inaktivierung pathogener Erreger von Pflanzenwurzeln, -stengeln, -blüten, -blättern und -samen
DE19931185A1 (de) 1999-07-07 2001-01-18 Joerg Peter Schuer Verfahren zur Entkeimung von Luft
DE19940283A1 (de) 1999-08-25 2001-03-01 Joerg Peter Schuer Pflanzenschutz
DE19940605A1 (de) 1999-08-27 2001-03-01 Joerg Peter Schuer Imprägnierungsverfahren
DE20100121U1 (de) * 2001-01-05 2002-05-16 Schuer Joerg Peter Vorrichtung zur Anreicherung von Luft mit Luftbehandlungsmittel
DE10100595A1 (de) * 2001-01-09 2002-07-18 Joerg Peter Schuer Verfahren zur untoxischen Geruchsneutralisierung von Luft
EP1228769A1 (fr) * 2001-02-02 2002-08-07 Jörg-Peter Prof. Schür Preparation symbiotique regénératrice
WO2002101299A1 (fr) 2001-06-13 2002-12-19 Schuer Joerg Peter Dispositif pour traiter l'air avec un agent de traitement de l'air, notamment pour aseptiser, parfumer l'air et/ou masquer des odeurs
DE10128563A1 (de) 2001-06-13 2003-01-02 Joerg Peter Schuer Vorrichtung zur Anreicherung von Luft mit einem Luftbehandlungsmittel insbesondere zur Luftentkeimung und/oder Luftbeduftung
US20030031588A1 (en) * 2001-06-13 2003-02-13 Schur Jorg Peter Device for enriching air with an air treatment agent, especially for the disinfection of air, and/or perfuming of air and/or for odor masking
DE10141734A1 (de) 2001-08-25 2003-03-06 Joerg Peter Schuer Vorrichtung zur Anreicherung von Luft mit einem Luftbehandlungsmittel insbesondere zur Luftentkeimung, Luftbeduftung und/oder Geruchsmaskierung

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB172993A (en) * 1920-06-12 1921-12-12 Robert Lauder Mackenzie Wallis Improvements in and relating to the employment of antiseptic, disinfectant, or preservative agents
GB1060447A (en) * 1963-05-14 1967-03-01 Maple Leaf Trust Compositions for the preservation of foodstuffs, for the sterilization and hygiene ofair in confined spaces and for cosmetic and pharmaceutical purposes
DE2423076A1 (de) * 1973-05-15 1974-12-05 Ivar Harry Sanick Verfahren zum schutz von nahrungsmitteln gegen befall durch mikroorganismen und mittel zur durchfuehrung des verfahrens
DE3138277A1 (de) * 1980-09-26 1982-04-15 Kabushiki Kaisha Ueno Seiyaku Oyo Kenkyujo, Osaka Fluessiges bakterizid fuer nahrungsmittel und nahrungsmittel-verarbeitungsmaschinen oder -geraete
US4446161A (en) * 1982-03-29 1984-05-01 General Foods Corporation Aromatic, monohydric alcohols as preservatives for foods
EP0557946A1 (fr) * 1992-02-26 1993-09-01 The Green Cross Corporation Composition contenant l'isothiocyanate allylique et son utilisation

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Section Ch, Week 8302 Derwent Publications Ltd., London, GB; Class D13, AN 83-03563K XP002007735 & JP 57 194775 A (ASAMA KASEI KK), 30. November 1982 (1982-11-30) *
DATABASE WPI Section Ch, Week 8726 Derwent Publications Ltd., London, GB; Class D13, AN 87-181806 XP002007736 & JP 62 111675 A (SANRAKU OCEAN), 22. Mai 1987 (1987-05-22) *
DATABASE WPI Section Ch, Week 9028 Derwent Publications Ltd., London, GB; Class C03, AN 90-213153 XP002007734 & JP 02 142703 A (KURITA WATER IND KK), 31. Mai 1990 (1990-05-31) *
DATABASE WPI Section Ch, Week 9411 Derwent Publications Ltd., London, GB; Class D13, AN 94-088588 XP002007733 & JP 06 038678 A (OKUBO T), 15. Februar 1994 (1994-02-15) *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2867948A1 (fr) * 2004-03-29 2005-09-30 Hightech Bio Activities Holdin Composition decontaminante presentant a la fois des proprietes bactericides, fongicides et virucides, procedes d'obtention et utilisations d'une telle composition
WO2005092094A1 (fr) * 2004-03-29 2005-10-06 Hightech Bio-Activities Holding Gmbh Composition decontaminante presentant a la fois des proprietes bactericides, fongicides et viruscides, procedes d’obtention et utilisations d’une telle composition
US8529968B2 (en) 2004-03-29 2013-09-10 Hightech Bio-Activities Holding Gmbh Decontaminating composition having simultaneously bactericidal, fungicidal and virocidal properties, methods for obtaining and using said composition
FR2876586A1 (fr) * 2004-10-20 2006-04-21 Persee Medica Composition pour prevenir ou traiter le stress, notamment les bouffees de stress chronique et permanent
WO2006042928A1 (fr) * 2004-10-20 2006-04-27 Persee Medica Composition pour prevenir ou traiter le stress, notamment les bouffees de stress chronique et permanent
WO2013007722A1 (fr) 2011-07-11 2013-01-17 Sony Corporation Procédé d'utilisation de proxy dans un réseau

Also Published As

Publication number Publication date
PT762837E (pt) 2002-07-31
EP0762837A1 (fr) 1997-03-19
AU5275096A (en) 1996-10-16
JPH10501445A (ja) 1998-02-10
ATE213593T1 (de) 2002-03-15
EP1116446A3 (fr) 2003-04-02
US7108879B2 (en) 2006-09-19
ES2173274T3 (es) 2002-10-16
ATE544359T1 (de) 2012-02-15
EP1116446B1 (fr) 2012-02-08
DE19612340A1 (de) 1996-11-07
US20030198718A1 (en) 2003-10-23
US20070087094A1 (en) 2007-04-19
EP0762837B1 (fr) 2002-02-27
WO1996029895A1 (fr) 1996-10-03
DK0762837T3 (da) 2002-06-10
DE59608782D1 (de) 2002-04-04
US6514551B1 (en) 2003-02-04

Similar Documents

Publication Publication Date Title
EP0762837B1 (fr) Procede pour l'amelioration de la conservation et/ou la stabilisation de produits alterables sous l'action de microbes
EP0991318B1 (fr) Additif pour ameliorer la conservabilite et/ou pour stabiliser des produits perissables sur le plan microbien
DE60216944T3 (de) Mikrobizide formulierung, die essentielle öle oder deren derivate enthält
DE69937339T2 (de) Bakterizide
DE60128490T2 (de) Labiate-extrakt und hopfenextrakt zum verlängern der farblebensdauer und zur hemmung von mikroorganismenwachstum in frischem fleisch, fisch und geflügel
EP1206184B1 (fr) Protection phytosanitaire
EP1096865B1 (fr) Composition antimicrobienne
Akram et al. The use of essential oils in active food packaging: a review of recent studies
US20020176882A1 (en) Additive the improvement and/or stabilization of the keeping quality of microbially perishable products
Vigil et al. 14 Naturally Occurring Compounds—Plant Sources
DE19831288A1 (de) Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
EP1206183B1 (fr) Procede d'impregnation
DE19831306A1 (de) Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
DE19831309A1 (de) Additiv zur Haltbarkeitsverbesserung und/oder Stabilisierung von mikrobiell verderblichen Produkten
JP2002029908A (ja) 植物成長調整剤
Abdel-Khalek Effect of gamma irradiation on the microbial, chemical quality and the biological activity of some spices and herbs
Jamil Preservative effects of Thymus citriodorus and Rosmarinus officinalis volatile oils on prolonging shelf life of raw chicken
EP1053686A1 (fr) Compositions pour la conservation d'aliments pour animaux
Sali et al. Antioxidant or Antimicrobial Nature of Essential Oils to Minimize Food Waste
MXPA99011980A (en) Additive for improving the storage life of and/or stabilising microbially perishable products

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AC Divisional application: reference to earlier application

Ref document number: 762837

Country of ref document: EP

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE

17P Request for examination filed

Effective date: 20030924

AKX Designation fees paid

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE

17Q First examination report despatched

Effective date: 20040216

APBK Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNE

APBN Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2E

APBR Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3E

APAF Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNE

APBT Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9E

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAC Information related to communication of intention to grant a patent modified

Free format text: ORIGINAL CODE: EPIDOSCIGR1

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: SCHUER, JOERG-PETER, PROF.

RIN1 Information on inventor provided before grant (corrected)

Inventor name: SCHUER, JOERG-PETER, PROF.

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AC Divisional application: reference to earlier application

Ref document number: 0762837

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LI LU MC NL PT SE

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 544359

Country of ref document: AT

Kind code of ref document: T

Effective date: 20120215

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 59611525

Country of ref document: DE

Effective date: 20120405

REG Reference to a national code

Ref country code: NL

Ref legal event code: T3

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: BOHEST AG

REG Reference to a national code

Ref country code: IE

Ref legal event code: FD4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120608

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120509

BERE Be: lapsed

Owner name: SCHUR, JORG-PETER

Effective date: 20120331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120208

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120208

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120331

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120208

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 59611525

Country of ref document: DE

Representative=s name: ,

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120208

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20121109

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120331

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 59611525

Country of ref document: DE

Effective date: 20121109

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120519

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20130131

Year of fee payment: 18

Ref country code: CH

Payment date: 20130327

Year of fee payment: 18

Ref country code: FR

Payment date: 20130220

Year of fee payment: 18

Ref country code: GB

Payment date: 20130327

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20130319

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20130306

Year of fee payment: 18

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120328

REG Reference to a national code

Ref country code: CH

Ref legal event code: PCAR

Free format text: NEW ADDRESS: HOLBEINSTRASSE 36-38, 4051 BASEL (CH)

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 59611525

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: V1

Effective date: 20141001

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 544359

Country of ref document: AT

Kind code of ref document: T

Effective date: 20140328

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20140328

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20141128

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 59611525

Country of ref document: DE

Effective date: 20141001

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140331

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141001

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140331

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140328

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141001

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140328