EP1101623B1 - Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren - Google Patents

Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren Download PDF

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Publication number
EP1101623B1
EP1101623B1 EP00123910A EP00123910A EP1101623B1 EP 1101623 B1 EP1101623 B1 EP 1101623B1 EP 00123910 A EP00123910 A EP 00123910A EP 00123910 A EP00123910 A EP 00123910A EP 1101623 B1 EP1101623 B1 EP 1101623B1
Authority
EP
European Patent Office
Prior art keywords
base paper
paper according
receiving layer
ink
recording material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00123910A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1101623A2 (de
EP1101623A3 (de
Inventor
Hartmut Dr.-Ing. Schulz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Original Assignee
Felix Schoeller Jr Foto und Spezialpapiere GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Felix Schoeller Jr Foto und Spezialpapiere GmbH filed Critical Felix Schoeller Jr Foto und Spezialpapiere GmbH
Publication of EP1101623A2 publication Critical patent/EP1101623A2/de
Publication of EP1101623A3 publication Critical patent/EP1101623A3/de
Application granted granted Critical
Publication of EP1101623B1 publication Critical patent/EP1101623B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays

Definitions

  • the invention relates to an ink jet (ink jet) - Recording material with one for this purpose novel base paper.
  • the recording material becomes different Requirements such as high color density of the printed Points, a quick ink absorption and related adequate smudge resistance, one does not have that necessary extent beyond dye diffusion in Transverse direction of the printed dots as well as a smaller one Mottle and a high water resistance.
  • Inkjet recording materials consist of a Carrier material, one arranged thereon Ink receiving layer and optionally further Auxiliary layers.
  • Ink-jet printer for producing photo-like prints use inks with a high proportion of water as Solvent.
  • Using conventional ink-jet papers occurs due to the high water content caused by the Papers occurs due to the high water content caused by the Ink receptive layer penetrates into the paper underlay, a ripple in the transverse direction (cockle).
  • These Ripple leads to a contact of the Recording material with the printhead and has a Deterioration of the printed image result.
  • the head contact can damage the Lead receiving material. It is therefore necessary for the Production of photo-like ink-jet prints Use recording material in which the Base paper has a high dimensional stability and thus able to handle a large amount of water without showing the above-mentioned ripple.
  • JP 06-262845 A discloses a receiving material, whose paper carrier contains a hardwood pulp and a sizing of starch and alkylketene dimer.
  • the claimed paper should have a good absorption capacity and have uniformity of the printed dots.
  • a disadvantage of this receiver is the insufficient dimensional stability (waviness) at high Water intake.
  • the cockle problem should be in JP 11-099737 by a Ink jet paper to be solved, which in addition to a Ink receiving layer at least one other, so-called Carrier layer contains, consisting of a water-insoluble Resin such as polyethylene or polypropylene.
  • Carrier layer contains, consisting of a water-insoluble Resin such as polyethylene or polypropylene.
  • the disadvantage is the long drying time of the printed Recording paper.
  • JP 52053012 A discloses a recording sheet for the ink-jet printing process, which does not nucleate has experienced, and with an ink-receiving layer is provided.
  • the object of the invention is a recording material to provide for the ink-jet printing process, the one good dimensional stability and high Has water absorbency and beyond next high color density, excellent smudge resistance and has good water resistance.
  • This object is achieved by a non-engineered, containing 5 to 55 wt.% Of a filler and impregnated with a impregnating resin base paper, wherein the resin receptacle is adjusted so that the base paper on the back of a fluid intake of at most 20 g / m 2 , preferably but 3 to 6 g / m 2 .
  • the back side of the base paper is the side opposite the image bearing side.
  • the invention also provides an ink jet recording material with the previously described Base paper as a base and at least one on the Front side disposed ink receiving layer. Between the underlay and the ink receiving layer and on the Ink receiving layer can be arranged more layers be.
  • the filler contained in the base paper can a Titanium dioxide, zinc sulfide, calcium carbonate, kaolin, talc, Clay or mixtures of these fillers.
  • the Filler content is 5 to 55 wt.%, Preferably 20 or 25 to 50% by weight.
  • softwood pulps long fiber pulps
  • hardwood pulps short fiber pulps
  • the fiber length after the grinding process should preferably be 0.6 to 1.2 mm.
  • a eucalyptus pulp or a mixture of eucalyptus and softwood pulp is used.
  • the pulp suspension may also include wet strength agents such as Polyamide / polyamine-epichlorohydrin resin, Retention aids such as quaternary polyammonium salts, Defoamers, penetration accelerators such as saccharides and other aids are added.
  • wet strength agents such as Polyamide / polyamine-epichlorohydrin resin, Retention aids such as quaternary polyammonium salts, Defoamers, penetration accelerators such as saccharides and other aids are added.
  • wet strength agents such as Polyamide / polyamine-epichlorohydrin resin
  • Retention aids such as quaternary polyammonium salts, Defoamers
  • penetration accelerators such as saccharides and other aids are added.
  • the invention contains Recording material a so-called one-sided smooth Base paper.
  • the unilaterally smooth base paper is preferably produced on a Yankee paper machine, the long wire side of the paper web with the help of a heated cylinder is smoothed.
  • the long Contact time of the paper with the cylinder can be one closed surface generated, which is a smoothness of 1000 ml / sec, measured according to Bendtson, not should fall below.
  • inventions of the invention can also be open on both sides, i. unsmoothed base paper can be used, only after impregnation smoothed on one or both sides in a calender can be.
  • the resin is a common one Impregnating resin used in the paper industry. It may be selected from the group of diallyl phthalates, Epoxy resins, urea-formaldehyde resins, uric acid-acrylic ester copolyesters, Melamine-formaldehyde resins, Melamine-phenol-formaldehyde resins, phenol-formaldehyde resins, Poly (meth) acrylates or unsaturated polyester resins.
  • the coating composition contains a mixture of one Acrylic acid ester and urea-formaldehyde resin. Especially good results are at a mixing ratio (Mass) acrylic acid ester / urea-formaldehyde resin of 1:10 to 10: 1 to achieve.
  • Impregnation with the resin may be performed "in-line” in the paper machine in a glue box or "off-line” outside the paper machine in a size press or impregnation line.
  • the base paper may be impregnated from the front side or from the back side or from both sides, whereby the resin penetrates into the interior of the base paper.
  • the resin absorption of the paper is adjusted so that the impregnated base paper on the back has a liquid absorption of at most 20 g / m 2 , preferably 3 to 6 g / m 2 .
  • the amount of the resin (impregnating agent) may be 2 to 25 g / m 2 , preferably 5 to 8 g / m 2 .
  • any ink receiving layer can be applied.
  • These are mostly hydrophilic Coatings that are water soluble or water-dispersible polymers, for example Polyvinyl alcohol, cationic polyvinyl alcohol, Polyvinyl pyrrolidone, polyvinyl acetate, starch, gelatin, Casein or carboxymethylcellulose.
  • the Ink-receiving layer can additionally pigments and cationic substances for fixing the ink dyes contain.
  • the ink receiving layer contains a polyvinyl alcohol or a mixture of polyvinyl alcohol and an acrylic ester homopolymer and / or copolymer.
  • the ink receiving layer may contain a cationic dye fixing agent and a pigment.
  • the coating weight of the ink receiving layer is 2 to 20 g / m 2 , especially 6 to 15 g / m 2 .
  • the ink receiving layer can be applied by the usual methods and by airbrush or roller blade dosing.
  • the recording paper may contain an additional polymer layer arranged on the receiving layer.
  • the polymer contained in this layer has a Shore hardness (D)> 50 (ASTM D 2240).
  • Particularly suitable is an acrylic ester homopolymer and / or copolymer.
  • the coating weight of the layer is 1 to 10 g / m 2, in particular 2 to 6 g / m 2.
  • a mixture of 90% by weight hardwood sulfate pulp and 10% by weight of softwood sulfate pulp was used in a Consistency from 4% to a freeness of 42 ° SR ground. Subsequently, the addition of 5 wt.% was carried out Polyamide / polyamine-epichlorohydrin resin and 25 wt.% Of a Pigment mixture of titanium dioxide (rutile form) and kaolin in a mixing ratio of 1: 1. The weights of the Additives refer to the pulp.
  • a base paper with a basis weight of 100 g / m 2 and a thickness of 120 microns was made.
  • the air permeability of 8 Gurley seconds per 100 ml paper was impregnated with the following impregnating agent: Acrylate / styrene copolymer (47% aqueous dispersion) (Primal® E-2556) 33% by weight Urea-formaldehyde (50% aqueous solution) (Urecoll® TS) 33% by weight Defoamer (OEKOFOAM® -E 190) 1% by weight water 33% by weight
  • the impregnation took place in the paper machine with the help of a glue box.
  • the application weights are listed in Table 1 and refer to the dried mass. Also mentioned in Table 1 is the measured from the back of the impregnated base paper according to DIN 53132 liquid absorption. example Application weight, g / m 2 Fluid intake, g / m 2 B1 8th 4 B2 12 3 B3 18 4
  • the base papers prepared according to the examples were coated with an ink receiving layer having the following composition: Polyvinyl alcohol, 20% aqueous solution (Mowiol® 20-98) 760 g Styrene copolymer, 20% dispersion (Basoplast® 265 D) 170 g butanol 70 g
  • the coating of the papers took place by means of doctor metering.
  • the coating weight of the ink receiving layer was 10 g / m 2 for all papers.
  • the papers provided with the ink-receiving layer were coated with a lacquer layer having the following composition, based on the weight of the dried layer, in an amount of 3 g / m 2 : n-butyl acrylate / styrene copolymer (50% aqueous Dispersion-Acronal® S 305 D) 95% by weight crosslinking agent 5% by weight
  • the base paper prepared according to Example 1 was without Impregnation with the coating composition according to the invention coated with the ink receiving layer of Example 1.
  • a base paper was produced with a basis weight of 100 g / m 2 (quantities based on the mass of pulp). Subsequently, the base paper was surface-sized with starch and provided with an ink-receiving layer containing 80% by weight of silica and 20% by weight of polyvinyl alcohol.
  • the recording papers of the invention were with an ink jet printer HP Deskjet ® 550C of the company Hewlett Packard printed. On the printed papers were the cockle behavior, the color density, the Smudge resistance, water resistance and the Water absorption tested.
  • the color density was measured with a Gretag densitometer Colors cyan, magenta, yellow and black in incident light measured.
  • the paper to be tested was placed on a level pad and the flatness of the paper visually with grades 1 to 5 (very good to very bad).
  • the printed papers were in 25 ° C for one minute put warm water and dried. The color density was measured before and after watering. Indicated is the remaining color density in percent.
  • test results are summarized in Table 2.
  • example color density water resistance cockle desiccation cyan magenta yellow black cyan magenta yellow black 1 2.4 2.0 1.9 2.1 98.6 81.5 98.1 98.0 1 ⁇ 10 sec 2 2.3 2.0 1.9 2.2 98.5 83.3 98.5 98.1 1 ⁇ 10 sec 3 2.4 2.0 1.9 2.1 99.5 82.0 98.5 98.5 1 ⁇ 10 sec V1 0.8 0.7 0.6 0.8 - - - - 1 ⁇ 10 sec V2 2.4 1.9 1.8 2.2 96.0 80.1 97.6 97.7 5 ⁇ 10 sec

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paper (AREA)
  • Ink Jet (AREA)
  • Duplication Or Marking (AREA)
  • Materials For Medical Uses (AREA)
EP00123910A 1999-11-15 2000-11-03 Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren Expired - Lifetime EP1101623B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19955081 1999-11-15
DE19955081A DE19955081C1 (de) 1999-11-15 1999-11-15 Basispapier für ein Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren

Publications (3)

Publication Number Publication Date
EP1101623A2 EP1101623A2 (de) 2001-05-23
EP1101623A3 EP1101623A3 (de) 2002-04-03
EP1101623B1 true EP1101623B1 (de) 2005-08-10

Family

ID=7929209

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00123910A Expired - Lifetime EP1101623B1 (de) 1999-11-15 2000-11-03 Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren

Country Status (12)

Country Link
US (1) US6599592B1 (pt)
EP (1) EP1101623B1 (pt)
JP (1) JP2001199157A (pt)
CN (1) CN1182977C (pt)
AT (1) ATE301549T1 (pt)
BR (1) BR0005397B1 (pt)
CA (1) CA2325237C (pt)
DE (2) DE19955081C1 (pt)
DK (1) DK1101623T3 (pt)
ES (1) ES2246209T3 (pt)
PL (1) PL196450B1 (pt)
PT (1) PT1101623E (pt)

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PL2695745T3 (pl) 2012-08-06 2016-03-31 Unilin Bvba Sposób wytwarzania paneli o powierzchni dekoracyjnej
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CN104919007B (zh) 2012-11-13 2017-09-26 纳幕尔杜邦公司 包含二氧化硅的自分散性颜料
WO2014078041A1 (en) 2012-11-13 2014-05-22 E. I. Du Pont De Nemours And Company Décor paper comprising self-dispersing pigments
AU2013345225A1 (en) 2012-11-13 2015-05-28 E. I. Du Pont De Nemours And Company Decor paper comprising self-dispersing pigments
AU2013345217B2 (en) 2012-11-13 2017-01-12 E. I. Du Pont De Nemours And Company Process for preparing self-dispersing pigments
US9546450B2 (en) 2012-11-13 2017-01-17 The Chemours Company Tt, Llc Laminates prepared from decor paper comprising self-dispersing pigments
ES2790978T3 (es) 2012-11-13 2020-10-30 Chemours Co Fc Llc Pigmentos autodispersantes
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Also Published As

Publication number Publication date
PT1101623E (pt) 2005-11-30
JP2001199157A (ja) 2001-07-24
CA2325237A1 (en) 2001-05-15
PL343882A1 (en) 2001-05-21
ATE301549T1 (de) 2005-08-15
CA2325237C (en) 2005-06-14
BR0005397A (pt) 2001-09-18
ES2246209T3 (es) 2006-02-16
EP1101623A2 (de) 2001-05-23
EP1101623A3 (de) 2002-04-03
DE50010911D1 (de) 2005-09-15
PL196450B1 (pl) 2008-01-31
CN1182977C (zh) 2005-01-05
CN1295932A (zh) 2001-05-23
US6599592B1 (en) 2003-07-29
DE19955081C1 (de) 2001-08-09
BR0005397B1 (pt) 2010-06-15
DK1101623T3 (da) 2005-12-12

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