EP0806299B1 - Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren - Google Patents
Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren Download PDFInfo
- Publication number
- EP0806299B1 EP0806299B1 EP97106976A EP97106976A EP0806299B1 EP 0806299 B1 EP0806299 B1 EP 0806299B1 EP 97106976 A EP97106976 A EP 97106976A EP 97106976 A EP97106976 A EP 97106976A EP 0806299 B1 EP0806299 B1 EP 0806299B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ink
- printing material
- material according
- recording material
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
- B41M5/506—Intermediate layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
- B41M5/508—Supports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
- B41M5/52—Macromolecular coatings
- B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/256—Heavy metal or aluminum or compound thereof
Definitions
- the invention relates to a recording material for the Ink jet printing process (ink jet printing process).
- droplets of a recording liquid are applied to the surface of the recording material using various techniques.
- a recording liquid ink
- an ink jet is ejected from the nozzle, which dissolves into microscopic drops due to the surface tension.
- the drops are charged electrically and placed on the base or deflected into a reservoir by means of downstream deflection plates which are controlled by the digital signals.
- the image signal triggers a mechanical impulse that ejects the drop.
- the first "drop-on-demand” printers used the piezoelectric effect to cause the drops to be ejected.
- the method is largely replaced by thermal ink jet, also called bubble jet.
- the image signal activates a heating element, which creates a vapor bubble in the aqueous ink. The resulting vapor pressure expels the drop.
- the recording material (image receiving material) used for such recording systems generally consists of a support and an ink-receiving layer and, if appropriate, further auxiliary layers.
- a polyester resin, diacetate or paper can be used as the carrier.
- the ink-receiving layers are mostly hydrophilic coatings which are particularly well suited for the absorption of aqueous inks.
- the ink-receiving layers usually consist of a pigment / binder mixture. In addition to increasing the whiteness of the material, the pigments serve to retain the dyes from the recording liquid on the surface of the sheet.
- Natural or synthetic polymers are used as binders, for example gelatin, starch, pectin, casein, carboxymethyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone and the like.
- cationic substances are often used in the ink receiving layer to fix the ink dyes.
- the backing of which is paper and the ink-receiving layer is a water-soluble binder contains problems such as insufficient water resistance or curling (cockle) of the material.
- JP 61-041585 a recording material known, the one Has polyvinyl alcohol / polyvinyl pyrrolidone mixture and itself in addition to the above-mentioned lack of water resistance due to a bad wet rub resistance.
- a recording material is known from Japanese laid-open publication JP 06-297831, which has a porous layer with a pseudoboehmite / polyvinyl alcohol mixture. This enables fast drying times.
- a disadvantage is the high layer application quantity (35-45 g / m 2 ) required here for rapid absorption of even large amounts of ink.
- the object of the present invention is therefore a recording material to provide the above mentioned Does not have disadvantages, in particular very good water resistance, has a very high resolution and color density.
- the task is carried out by a carrier and a receiving layer containing recording material dissolved, wherein an upper layer is arranged on the receiving layer, the one fine porous inorganic cationic charge centers Contains pigment and / or filler particles according to claim 1.
- Aluminum oxides are particularly well suited for this purpose, pyrrogenic aluminum hydroxides and aluminum oxide hydrates, in particular however, the ⁇ -alumina monohydrate or the metahydroxide ⁇ -AlO (OH) (boehmite) with a pore radius distribution between 1.0 to 3.5 nm.
- the Invention can be a finely divided silica in the upper layer how pyrrogenic silica are used. The amount of finely divided silica can vary between 30 and 70 % By weight, based on the total amount of the pigment.
- a polyvinyl alcohol top layer is used as a binder.
- a partially saponified polyvinyl alcohol is particularly suitable with a degree of saponification between 70 and 90 mol%.
- cationically modified binders such as, for example, are well suited a cationic polyvinyl alcohol or cationic modified starch.
- other water-soluble polymers can be used as binders.
- the amount of binder can be 20 to 90% by weight. The quantitative range is preferred 40 to 90% by weight, but in particular 50 to 80% by weight (based on the dried layer).
- the quantitative ratio of inorganic pigment and / or filler particles to binder can be 1: 0.4 to 1: 100, but especially 1: 2 to 1: 100.
- the Top layer additionally at least one cationic polymer such as for example a cationically modified polyvinyl alcohol, a cationically modified starch, a cationically modified starch Polystyrene, a cationically modified polyvinyl pyrrolidone and similar polymers. Quaternary, Hydroxy- or amino-functional acrylate homo- and / or acrylate copolymers.
- the amount of the cationic polymer is 1 to 30% by weight, in particular 5 to 20% by weight, based on the dried Layer.
- the top layer can be an additional cationic dye fixative Contain agents, for example a quaternary Polyammonium salt from the group of polyvinylbenzyltrimethyl, Polydiallyldimethyl, polymethacryloxyethyldimethylhydroxyethyl, Polyhydroxypropyldimethylammonium chlorides.
- additional dye fixative Contain agents for example a quaternary Polyammonium salt from the group of polyvinylbenzyltrimethyl, Polydiallyldimethyl, polymethacryloxyethyldimethylhydroxyethyl, Polyhydroxypropyldimethylammonium chlorides.
- dye-fixing agents such as cationic cationic Polyamines, cationic polyacrylamides, cationic polyethyleneimines can be used.
- the amount of dye fixative Up to 5% by weight, in particular from 0.5 up to 3% by weight.
- the ink-receiving layer can contain binders, color-fixing compounds, Contain hardening agents and other aids.
- Binders can be modified, for example, polyvinyl alcohol Polyvinyl alcohol, cationically modified polystyrene, carboxymethyl cellulose, Polyvinylpyrrolidone, polyvinyl acetate, Starch, gelatin or mixtures thereof can be used
- a preferred embodiment of the invention is in the ink receiving layer Gelatin used. To be particularly advantageous turned out a pork rind gelatin with a Gelatin strength of 200 to 300 bloom (measured according to BS 757, 1975), but a bovine bone gelatin can also be used become.
- Binder is a modified polyvinyl alcohol, Carboxymethyl cellulose or polyvinyl pyrrolidone. Particularly good ones Results are achieved if in addition to the binder and the in an amount of up to 5% by weight of dye-fixing agents Means additionally a cationic polymer is used.
- the cationic polymer can be a quaternary, hydroxy or amino-functional acrylate homo- and / or acrylate copolymer his. But also other cationic polymers such as a cationic polystyrene or a cationically modified Starch can be used.
- the quantitative ratio cat. Polymer / binder in the receiving layer is 1: 2 to 1:20.
- a plastic film (film) or preferably an uncoated or coated base paper can be used as the carrier.
- Paper that is coated on both sides with synthetic resin and has a weight per unit area of 50 to 250 g / m 2 is particularly suitable.
- Polyolefins or polyester, for example, can be used as the synthetic resin.
- the application amount of the synthetic resin coating, which may also contain pigments, dyes and other auxiliaries, is at least 5 g / m 2 .
- a polyethylene-coated paper is used.
- a coated base paper, in particular a barite-coated paper, is also suitable as a carrier.
- the back of the recording material can also have a functional layer have, for example an anti-curl and / or Antistatic layer.
- Both the ink absorption and the top layer are applied from an aqueous dispersion (coating composition) and dried.
- the coating composition can be applied to the carrier using all customary application and metering methods, such as roller application, engraving or nipping methods and air brushes or roller doctor metering.
- the application amount of the ink-receiving layer can be 1.0 to 20 g / m 2 , preferably 8 to 14 g / m 2 .
- the application amount of the top layer can be 0.5 to 5.0 g / m 2 , preferably 1.0 to 4.0 g / m 2 .
- Tables 1 and 2 below show some of the many possible embodiments of the invention: Components of the ink-receiving layer A A1 A2 A3 A4 A5 A6 A7 Gelatin, 264 Bloom 91.8 81.8 73.6 73.4 82.6 - - Polyvinyl alcohol, degree of saponification: 98 mol% - - 8.2 - 9.2 31.6 41.0 Polyvinylpyrrolidone, Molgew .: 630,000 daltons - - - 18.4 - 31.6 41.0 Vinyl acetate / butyl acrylate cop. - - - - - 31.6 - Aminomethyl methacrylate 5.0 15.0 15.0 5.0 5.0 - 15.0 quat.
- the quantities are expressed in% by weight and relate on dried layers.
- the front side of a base paper neutrally sized with alkyl ketene dimer and coated on both sides with polyethylene 1) of 80 g / m 2 basis weight was first coated with an ink absorption layer according to A1 (Tab. 1) and then with an upper layer according to B1, B2, B6, B7 and B8 ( Tab. 2).
- corresponding aqueous coating compositions were first prepared, which were then applied to the substrate to be coated using a roller doctor blade and dried.
- the back of the base paper was coated with a mixture of LDPE and HDPE (high-density polyethylene).
- the application weight was 20 g / m 2 .
- the recording material obtained was in a so-called. "Thermal Jet” process printed and then analyzed.
- the front of the base paper from Example 1 was first provided with an ink-receiving layer in accordance with A2 (Table 1) and then with an upper layer in accordance with B2, B6 and B8 (Table 2).
- the order weights were: Ink receiving layer 12 g / m 2
- a base paper provided with a baryta layer on the front side (basis weight: 80 g / m 2 ) was first provided with an ink absorption layer in accordance with A7 and then with an upper layer in accordance with B9.
- the barite layer contained 85% by weight of BaSO 4 and 15% by weight of gelatin.
- test conditions were as in Example 1.
- the base paper from Example 1 was coated with an ink absorption layer according to A2 (12 g / m 2 ) and then provided with an upper layer according to B6 (4 g / m 2 ), but without boehmite with a narrow pore radius distribution, instead with aluminum hydroxide with a pore radius distribution of 2.8 to 100.0 nm (V1a) and 2.0 to 14.0 nm (V1b).
- the base paper from Example 1 was only coated with an ink receiving layer in accordance with A2 and A6 without and with the addition of aluminum hydroxide.
- the quantities are expressed in% by weight and relate on dried layers.
- the recording material obtained in the comparative examples was printed in a so-called "thermal jet” process and then analyzed.
- the results are summarized in Table 4.
- the recording material was by means of a Bubble jet principle (thermal jet) working inkjet printer HP Deskjet 550 C from Hewlett Packard printed.
- the density measurements were made using an "original Reflection densitometer SOS-45 "performed. The measurements took place for the basic colors cyan, magenta, yellow and black.
- the recording material was used for the investigation of the water resistance submerged in water. The after 60 s in Water bath 25 ° C remaining density (%) is used as a measure of the Water stability used.
- the gloss values were measured with the laboratory reflectometer RL3 from Dr. Long according to DIN 67530.
- the drying behavior of the recording material becomes as follows determined:
- Black ink (pure black) is placed on a sheet of paper a bar is printed out and after a waiting time of 120 seconds Paper (20 sheets) loaded.
- the color transfer is used as a measure taken for drying.
- the drying time can be ⁇ 120, 120-240 and be> 240 seconds.
- the recording materials produced according to the invention are distinguished by better water resistance, shorter drying times and better bleed behavior. Even if the water resistance and drying times of the papers produced according to V1a and V1b are also good, the bleed behavior is unsatisfactory. With regard to the gloss, too, the values in Example 2.2 are higher than in the corresponding Comparative Examples V1a and V1b.
Landscapes
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Ink Jet (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paper (AREA)
- Particle Formation And Scattering Control In Inkjet Printers (AREA)
Description
Bei der sog. "drop-on-demand"-Methode löst das Bildsignal einen mechanischen Impuls aus, der den Tropfen ausstößt. Die ersten "drop-on-demand"-Drucker benutzten den piezoelektrischen Effekt, um das Ausstoßen der Tropfen zu bewirken. Heute ist die Methode weitgehend durch Thermal Ink Jet, auch Bubble Jet genannt, ersetzt. Hierbei aktiviert das Bildsignal ein Heizelement, wodurch eine Dampfblase in der wässrigen Tinte entsteht. Der resultierende Dampfdruck stößt den Tropfen aus.
- hohe Auflösung,
- hohe Farbdichte,
- genügend Farbabstufungen,
- gute Wischfestigkeit,
- gute Wasserfestigkeit.
- gute Naßriebfestigkeit
- die Tinte muß vom Aufzeichnungsmaterial rasch absorbiert werden,
- die aufgespritzten Tintentröpfchen müssen in möglichst exakter Weise (kreisförmig) und genau begrenzt auseinanderlaufen,
- die Tintendiffusion in dem Aufzeichnungsmaterial darf nicht zu hoch sein, damit der Durchmesser der Tintenpunkte nicht mehr als unbedingt erforderlich vergrößert wird,
- ein Tintenpunkt soll beim Überlappen mit einem vorher aufgebrachten Tintenpunkt diesen nicht beeinträchtigen oder verwischen,
- das Aufzeichnungsmaterial muß eine Oberfläche aufweisen, die eine hohe visuelle Reflexionsdichte und eine hohe Brillanz der Farben ermöglicht,
- das Aufzeichnungsmaterial soll eine hohe Formbeständigkeit aufweisen, ohne daß es sich nach dem Druckvorgang dehnt.
Als Träger kann beispielsweise ein Polyesterharz, Diacetat oder Papier verwendet werden.
Bei den Tintenaufnahmeschichten handelt es sich meistens um hydrophile Beschichtungen, die besonders gut für die Aufnahme der wäßrigen Tinten geeignet sind.
Die Tintenaufnahmeschichten bestehen in der Regel aus einer Pigment/Bindemittel-Mischung. Die Pigmente dienen, neben der Erhöhung des Weißgrades des Materials, zur Retention der Farbstoffe aus der Aufzeichnungsflüssigkeit an die Oberfläche des Blattes. Als Bindemittel werden natürliche oder synthetische Polymere eingesetzt, beispielsweise Gelatine, Stärke, Pektin, Kasein, Carboxymethylcellulose, Polyvinylalkohol, Polyvinylpyrrolidon und ähnliche.
Oft werden in der Tintenaufnahmeschicht zusätzlich kationische Substanzen zur Fixierung der Tintenfarbstoffe eingesetzt.
Die Beschichtungsmasse kann mit allen gebräuchlichen Auftrags- und Dosierverfahren, wie beispielsweise Walzenauftrag-, Gravur oder Nipp-Verfahren und Luftbürsten oder Rollrakeldosierung auf den Träger aufgetragen werden.
Bestandteile der Tintenaufnahmeschicht A | A1 | A2 | A3 | A4 | A5 | A6 | A7 |
Gelatine, 264 Bloom | 91,8 | 81,8 | 73,6 | 73,4 | 82,6 | - | - |
Polyvinylalkohol, Verseifungsgrad: 98 Mol% | - | - | 8,2 | - | 9,2 | 31,6 | 41,0 |
Polyvinylpyrrolidon, Molgew.: 630 000 Dalton | - | - | - | 18,4 | - | 31,6 | 41,0 |
Vinylacetat/Butylacrylat-Cop. | - | - | - | - | - | 31,6 | - |
Aminomethylmethacrylat | 5,0 | 15,0 | 15,0 | 5,0 | 5,0 | - | 15,0 |
quat. Polyammoniumsalz | 3,0 | 3,0 | 3,0 | 3,0 | 3,0 | 5,2 | 3,0 |
TAF/Formaldehyd | 0,2 | 0,2 | 0,2 | 0,2 | 0,2 | - | - |
Bestandteile der Oberschicht B | B1 | B2 | B3 | B4 | B5 | B6 | B7 | B8 | B9 | B10 |
Polyvinylalkohol, Verseifungsgrad: 88 Mol% | 65 | - | - | - | 80 | - | - | - | 36 | - |
Polyvinylalkohol, Verseifungsgrad: 74 Mol% | - | 75 | - | - | - | 62 | 72 | 65 | 36 | - |
Kat. Polyvinylalkohol | - | - | 65 | - | - | - | - | - | - | 72 |
Polyvinylpyrrolidon | - | - | - | 65 | - | - | - | - | - | - |
Al-Hydroxid, 1,0-3,0 nm | - | - | - | 30 | - | - | - | - | - | - |
Boehmit, 1,0-3,5 nm | 30 | 20 | 30 | - | 15 | 20 | 20 | 10 | 10 | 20 |
Kieselsäure | - | - | - | - | - | - | - | 10 | - | - |
Aminomethylmethacrylat | - | - | - | - | - | 15 | - | 10 | - | 5 |
Hydroxyacrylat-Terpolymer | - | - | - | - | - | - | 5 | - | 15 | - |
Quat. Polyammoniumsalz | 5 | 5 | 5 | 5 | 5 | 3 | 3 | 5 | 3 | 3 |
Standard-Drahtrakel/Größe | |||
Tintenaufnahmeschicht | 10 g/m2 | 100 | |
Oberschicht | B1 | 2 g/m2 | 35 |
B2 | 3 g/m2 | 40 | |
B6 | 4 g/m2 | 45 | |
B7 | 4 g/m2 | 45 | |
B8 | 4 g/m2 | 45 |
Beispiele | ||||
1.1 | 1.2 | 1.3 | 1.4 | 1.5 |
A1 + B1 | A1 + B2 | A1 + B6 | A1 + B7 | A1 + B8 |
Maschinengeschwindigkeit | 100 m/min |
Trocknungstemperatur (Luft) | 100°C |
Trocknungszeit | 2-4 min |
Die Beschichtung enthielt außerdem:
- 0,95 Gew.% optischer Aufheller,
- 10 Gew.% Titandioxid,
- 4 Gew.% Gleitmittel,
- 10,8 Gew.% eines Pigmentkonzentrates (10 % Ultramarin, 90 % LDPE).
Tintenaufnahmeschicht | 12 g/m2 | |
Oberschicht | B2 | 4 g/m2 |
B6 | 5 g/m2 | |
B8 | 2 g/m2 |
Beispiele | ||
2.1 | 2.2 | 2.3 |
A2 + B2 | A2 + B6 | A2 + B8 |
Bestandteile | V2a | V2b | V2c |
Gelatine, 264 Bloom | 81,80 | - | - |
Polyvinylalkohol, Verseifungsgrad: 98 Mol% | - | 31,60 | 21,60 |
Polyvinylpyrrolidon, | - | 31,60 | 21,60 |
Molgewicht: 630000 Dalton | |||
Vinylacetat/Butylacrylat-Cop. | - | 31,60 | 21,60 |
Aminomethylmethacrylat | 15,00 | - | - |
quat. Polyammoniumsalz | 3,00 | 5,20 | 5,20 |
Al-Hydroxid, 2,0-14,0 nm | - | - | 30,00 |
TAF/Formaldehyd | 0,20 | - | - |
Auftrag, g/m2 | 15 | 15 | 15 |
Claims (9)
- Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren mit einem Träger und einer Farbempfangsschicht, dadurch gekennzeichnet, daß auf der Farbempfangsschicht eine Oberschicht angeordnet ist, die feinporöse, kationische Ladungszentren aufweisende anorganische Pigment- und/oder Füllstoffpartikeln enthält, deren Porenradiusverteilung 1,0 bis 3,5 nm beträgt.
- Aufzeichnungsmaterial nach Anspruch 1, dadurch gekennzeichnet, daß die anorganischen Pigment- und/oder Füllstoffpartikeln ein Aluminiumhydroxid aufweisen.
- Aufzeichnungsmaterial nach Anspruch 2, dadurch gekennzeichnet, daß das Aluminiumhydroxid ein Böhmit ist.
- Aufzeichnungsmaterial nach Ansprüchen 1 bis 3,
dadurch gekennzeichnet, daß die anorganischen Pigment- und/oder Füllstoffpartikeln ein pyrrogenes Aluminiumoxid sind. - Aufzeichnungsmaterial nach Ansprüchen 1 bis 4,
dadurch gekennzeichnet, daß die Oberschicht mindestens ein kationisches Polymer enthält. - Aufzeichnungsmaterial nach Anspruch 5,
dadurch gekennzeichnet, daß die Menge des kationischen Polymers in der Oberschicht 1 bis 30 Gew.%, insbesondere 5 bis 20 Gew.%, beträgt. - Aufzeichnungsmaterial nach Ansprüchen 1 bis 6,
dadurch gekennzeichnet, daß die Oberschicht ein farbstoffixierendes Mittel in einer Menge von 0,5 bis 3,0 Gew.% enthält. - Aufzeichnungsmaterial nach Ansprüchen 1 bis 7,
dadurch gekennzeichnet, daß der Träger ein polyolefinbeschichtetes Papier ist. - Aufzeichnungsmaterial nach Ansprüchen 1 bis 8,
dadurch gekennzeichnet, daß der Träger ein barythbeschichtetes Papier ist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19618607A DE19618607C2 (de) | 1996-05-09 | 1996-05-09 | Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren |
DE19618607 | 1996-05-09 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0806299A2 EP0806299A2 (de) | 1997-11-12 |
EP0806299A3 EP0806299A3 (de) | 1998-04-08 |
EP0806299B1 true EP0806299B1 (de) | 2001-10-31 |
Family
ID=7793782
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97106976A Expired - Lifetime EP0806299B1 (de) | 1996-05-09 | 1997-04-26 | Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren |
Country Status (8)
Country | Link |
---|---|
US (1) | US5911855A (de) |
EP (1) | EP0806299B1 (de) |
JP (1) | JP4024902B2 (de) |
AT (1) | ATE207816T1 (de) |
DE (2) | DE19618607C2 (de) |
DK (1) | DK0806299T3 (de) |
ES (1) | ES2166931T3 (de) |
PT (1) | PT806299E (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1747901A1 (de) | 2005-07-26 | 2007-01-31 | Kanzan Spezialpapiere GmbH | Tintenstrahlaufzeichnungsmaterial |
Families Citing this family (42)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5681380A (en) | 1995-06-05 | 1997-10-28 | Kimberly-Clark Worldwide, Inc. | Ink for ink jet printers |
US6074761A (en) * | 1997-06-13 | 2000-06-13 | Ppg Industries Ohio, Inc. | Inkjet printing media |
US5880196A (en) * | 1997-06-13 | 1999-03-09 | Ppg Industries, Inc. | Inkjet printing media |
US6524379B2 (en) | 1997-08-15 | 2003-02-25 | Kimberly-Clark Worldwide, Inc. | Colorants, colorant stabilizers, ink compositions, and improved methods of making the same |
PL338379A1 (en) | 1998-06-03 | 2000-10-23 | Kimberly Clark Co | Novel photoinitiators and their application |
BR9906580A (pt) | 1998-06-03 | 2000-09-26 | Kimberly Clark Co | Neonanoplastos e tecnologia de microemulsão para tintas e impressão de jato de tinta |
JP2002520470A (ja) | 1998-07-20 | 2002-07-09 | キンバリー クラーク ワールドワイド インコーポレイテッド | 改良されたインクジェットインク組成物 |
AU1309800A (en) | 1998-09-28 | 2000-04-17 | Kimberly-Clark Worldwide, Inc. | Novel photoinitiators and applications therefor |
US6183844B1 (en) | 1998-12-16 | 2001-02-06 | Hewlett-Packard Company | Inkjet printing medium comprising multiple coatings |
WO2000042110A1 (en) | 1999-01-19 | 2000-07-20 | Kimberly-Clark Worldwide, Inc. | Novel colorants, colorant stabilizers, ink compositions, and improved methods of making the same |
US6331056B1 (en) | 1999-02-25 | 2001-12-18 | Kimberly-Clark Worldwide, Inc. | Printing apparatus and applications therefor |
US6294698B1 (en) | 1999-04-16 | 2001-09-25 | Kimberly-Clark Worldwide, Inc. | Photoinitiators and applications therefor |
PT1048480E (pt) * | 1999-04-30 | 2005-05-31 | Schoeller Felix Jun Foto | Material para gravacao por jacto de tinta compreendendo camadas de pigmentos |
US6368395B1 (en) | 1999-05-24 | 2002-04-09 | Kimberly-Clark Worldwide, Inc. | Subphthalocyanine colorants, ink compositions, and method of making the same |
US6887559B1 (en) * | 1999-10-01 | 2005-05-03 | Cabot Corporation | Recording medium |
GB9930177D0 (en) * | 1999-12-22 | 2000-02-09 | Clariant Int Ltd | Improvements in or relating to organic compounds |
EP1120281B1 (de) * | 2000-01-28 | 2006-05-24 | Oji Paper Company Limited | Tintenstrahlaufzeichnungsmaterial |
JP2001277705A (ja) * | 2000-03-30 | 2001-10-10 | Nippon Paper Industries Co Ltd | 顔料インク用インクジェット記録媒体 |
DE10022529A1 (de) * | 2000-05-09 | 2001-11-15 | Emtec Magnetics Gmbh | Pigmenthaltiges Aufzeichnungsmaterial |
JP3733283B2 (ja) * | 2000-09-07 | 2006-01-11 | キヤノン株式会社 | インクジェット用記録媒体とその製造方法およびそれを用いたインクジェット記録方式による画像形成方法 |
EP1345780B1 (de) | 2000-12-28 | 2005-11-23 | Fuji Photo Film B.V. | Tintenstrahlaufzeichnungsmedium |
DE10103716C5 (de) * | 2001-01-26 | 2005-11-17 | Felix Schoeller Jr. Foto- Und Spezialpapiere Gmbh & Co. Kg | Poröses Tintenstrahlaufzeichnungsmaterial |
DE60209852T3 (de) † | 2001-01-26 | 2011-06-09 | Eastman Kodak Co. | Tintenstrahlaufzeichnungselement und -Druckverfahren |
DE10117504A1 (de) * | 2001-04-07 | 2002-10-17 | Degussa | Injekt-Tinte |
DE10138631A1 (de) * | 2001-08-13 | 2003-02-27 | Basf Ag | Verfahren zur Herstellung von beschichtetem Papier mit hoher Weiße |
EP1285772A1 (de) | 2001-08-15 | 2003-02-26 | Fuji Photo Film B.V. | Mikroporöses Tintenstrahlaufzeichnungsmaterial |
US6843177B2 (en) * | 2001-09-14 | 2005-01-18 | Fine Arts Group Llc | Methods and materials for producing an image, and articles comprising materials for producing an image |
US6979481B2 (en) * | 2002-08-19 | 2005-12-27 | Mohawk Paper Mills, Inc. | Microporous photo glossy inkjet recording media |
EP1567361B1 (de) | 2002-12-04 | 2007-07-18 | FUJIFILM Manufacturing Europe B.V. | Tintenstrahlaufzeichnungsmaterial |
AU2003290446A1 (en) | 2002-12-13 | 2004-07-09 | Fuji Photo Film B.V. | Ink-jet recording medium |
WO2005032834A1 (en) | 2003-10-03 | 2005-04-14 | Fuji Photo Film B.V. | Recording medium |
WO2005032835A1 (en) | 2003-10-03 | 2005-04-14 | Fuji Photo Film B.V. | Recording medium |
DE502005003846D1 (de) | 2005-06-29 | 2008-06-05 | Mitsubishi Hitec Paper Flensbu | Tintenstrahlaufzeichnungsmaterial |
JP2009545664A (ja) * | 2006-08-04 | 2009-12-24 | フジフィルム マニュファクチャリング ユーロプ ビー.ブイ. | 多孔性膜およびこれを含む記録媒体 |
JP2009545662A (ja) * | 2006-08-04 | 2009-12-24 | フジフィルム マニュファクチャリング ユーロプ ビー.ブイ. | 多孔性膜およびこれを含む記録媒体 |
ATE474022T1 (de) * | 2006-08-04 | 2010-07-15 | Fujifilm Mfg Europe Bv | Zusammensetzungen für poröse membranen und aufzeichnungsmedien |
EP2222922B2 (de) | 2007-12-17 | 2020-11-18 | Schoeller Technocell GmbH & Co. KG | Durch das ink-jet-verfahren bedruckbares, verpressfähiges dekorpapierimprägnat |
EP2617580A1 (de) | 2012-01-17 | 2013-07-24 | Mitsubishi HiTec Paper Europe GmbH | Tintenstrahlaufzeichnungsmaterial |
WO2013186367A1 (de) * | 2012-06-15 | 2013-12-19 | Schoeller Technocell Gmbh & Co. Kg | Empfangsschicht für digitale druckverfahren mit nanofibrillierter cellulose |
CN102991175A (zh) * | 2012-12-27 | 2013-03-27 | 天津海华科技发展有限公司 | 一种环保医用喷墨打印胶片 |
CN102991173A (zh) * | 2012-12-27 | 2013-03-27 | 天津海华科技发展有限公司 | 一种环保医用激光打印胶片 |
JP6152279B2 (ja) * | 2013-02-19 | 2017-06-21 | 三菱製紙株式会社 | 化粧シート用原紙およびそれを用いた化粧シートおよび化粧板 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58110287A (ja) * | 1981-12-24 | 1983-06-30 | Mitsubishi Paper Mills Ltd | 記録用シ−ト |
JPS5952689A (ja) * | 1982-09-17 | 1984-03-27 | Mitsubishi Paper Mills Ltd | インクジェット記録用シート |
JPS6011389A (ja) * | 1983-07-01 | 1985-01-21 | Mitsubishi Paper Mills Ltd | インクジエツト記録用紙 |
EP0298424B1 (de) * | 1987-07-07 | 1994-12-07 | Asahi Glass Company Ltd. | Trägermaterial für einen Farbstoff |
CA1337388C (en) * | 1988-03-04 | 1995-10-24 | Mamoru Sakaki | Recording medium and ink jet recording method |
JP2686670B2 (ja) * | 1990-04-02 | 1997-12-08 | キヤノン株式会社 | インクジェット用被記録材 |
US5185213A (en) * | 1990-06-23 | 1993-02-09 | Kanzaki Papper Manufacturing Co., Ltd. | Ink jet recording sheet |
EP0524626B1 (de) * | 1991-07-26 | 1996-12-11 | Asahi Glass Company Ltd. | Aufnahmestreifen für Tintenstrahldrucker |
EP0655346B1 (de) * | 1993-05-13 | 1998-09-09 | Mitsubishi Paper Mills, Ltd. | Tintenstrahl-aufzeichnungsblatt |
JP3302792B2 (ja) * | 1993-07-06 | 2002-07-15 | キヤノン株式会社 | 記録媒体及びそれを用いたインクジェット記録方法 |
EP0634287B1 (de) * | 1993-07-16 | 1997-03-12 | Asahi Glass Company Ltd. | Aufzeichnungsblatt und Verfahren zu seiner Herstellung |
JPH0890900A (ja) * | 1994-09-28 | 1996-04-09 | Asahi Glass Co Ltd | インクジェット記録媒体および記録物 |
JP2887098B2 (ja) * | 1994-10-26 | 1999-04-26 | キヤノン株式会社 | 被記録媒体、その製造方法及び画像形成方法 |
JP3591969B2 (ja) * | 1995-03-15 | 2004-11-24 | キヤノン株式会社 | インクジェット用記録媒体及びこれを用いたカラーインクジェット記録方法 |
DE69729682T2 (de) * | 1996-04-24 | 2005-07-07 | Oji Paper Co., Ltd. | Tintenstrahlaufzeichnungsmaterial und Verfahren zur Herstellung eines Tintenstrahlaufzeichnungsmaterials |
-
1996
- 1996-05-09 DE DE19618607A patent/DE19618607C2/de not_active Expired - Fee Related
-
1997
- 1997-04-26 DK DK97106976T patent/DK0806299T3/da active
- 1997-04-26 EP EP97106976A patent/EP0806299B1/de not_active Expired - Lifetime
- 1997-04-26 PT PT97106976T patent/PT806299E/pt unknown
- 1997-04-26 AT AT97106976T patent/ATE207816T1/de not_active IP Right Cessation
- 1997-04-26 DE DE59705136T patent/DE59705136D1/de not_active Expired - Lifetime
- 1997-04-26 ES ES97106976T patent/ES2166931T3/es not_active Expired - Lifetime
- 1997-05-07 US US08/852,579 patent/US5911855A/en not_active Expired - Lifetime
- 1997-05-09 JP JP13594597A patent/JP4024902B2/ja not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1747901A1 (de) | 2005-07-26 | 2007-01-31 | Kanzan Spezialpapiere GmbH | Tintenstrahlaufzeichnungsmaterial |
Also Published As
Publication number | Publication date |
---|---|
DE19618607A1 (de) | 1997-11-20 |
JPH10100532A (ja) | 1998-04-21 |
DK0806299T3 (da) | 2002-02-18 |
DE19618607C2 (de) | 1999-07-08 |
PT806299E (pt) | 2002-04-29 |
ATE207816T1 (de) | 2001-11-15 |
EP0806299A2 (de) | 1997-11-12 |
US5911855A (en) | 1999-06-15 |
EP0806299A3 (de) | 1998-04-08 |
DE59705136D1 (de) | 2001-12-06 |
ES2166931T3 (es) | 2002-05-01 |
JP4024902B2 (ja) | 2007-12-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0806299B1 (de) | Aufzeichnungsmaterial für Tintenstrahl-Druckverfahren | |
DE69921258T2 (de) | Tintenstrahlaufzeichnungselement, das kolloidales Kieselgel enthält | |
DE69619607T2 (de) | Tintenstrahlaufzeichnungsmaterial und Verfahren zu dessen Herstellung | |
DE69310107T3 (de) | Aufzeichnungsblatt für Tintenstrahlschreiber und Verfahren zu seiner Herstellung | |
DE3886440T2 (de) | Aufzeichnungsmittel. | |
DE69413179T2 (de) | Tintenstrahl-aufzeichnungsblatt | |
DE69428871T2 (de) | Aufzeichnungsmaterial und Bildaufzeichnungsverfahren, das dieses Material benutzt | |
EP0631880B1 (de) | Aufzeichnungsblatt für Ink-Jet-Druckverfahren | |
EP1048480B1 (de) | Ink-Jet-Aufzeichnungspapier mit Pigmentschichten | |
DE69504142T2 (de) | Tintenstrahl-Aufzeichnungsfolie und Aufzeichnungsmethode mittels diesem | |
DE19955081C1 (de) | Basispapier für ein Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren | |
DE69911157T2 (de) | Tintenstrahlaufzeichnungsmaterial, das Polyäthylenglykol und Polyvinylalkohol enthält | |
DE4322178C2 (de) | Aufzeichnungsmaterial für Ink-Jet-Druckverfahren | |
DE19505295C2 (de) | Tintenstrahl-Aufzeichnungsblatt | |
DE60011504T2 (de) | Tintenstrahl-Aufzeichnungsmaterial | |
DE69603214T2 (de) | Druckpapier und Tintenstrahldruckverfahren, das dieses Papier verwendet | |
DE4022008C3 (de) | Tintenstrahl-Aufzeichnungsmedium | |
DE69923114T2 (de) | Tintenstrahlaufzeichnungsmaterial, das kationisches Harz enthält, und Aufzeichnungsverfahren | |
EP0514633B1 (de) | Aufzeichnungsmaterial für das Tintenstrahlaufzeichnungsverfahren | |
DE69507764T2 (de) | Aufzeichnungsmaterial und Bildaufzeichnungsverfahren, das dieses Material verwendet | |
EP0812697B1 (de) | Aufzeichnungsmaterial für das Tintenstrahl-Druckverfahren | |
DE602005002335T2 (de) | Tintenstrahl-Aufzeichnungsmedium und Verfahren zu seiner Herstellung | |
DE69418815T2 (de) | Tintenstrahlaufzeichnungsmaterial | |
DE69607819T2 (de) | Tintenstrahlaufzeichnungsschicht die Kieselerde enthält | |
DE69805470T2 (de) | Aufzeichnungsmaterial für mehrfarbiges Tintenstrahldruckverfahren mit wässerigen Tinten |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE CH DE DK ES FI FR GB GR IT LI LU NL PT SE |
|
PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
AK | Designated contracting states |
Kind code of ref document: A3 Designated state(s): AT BE CH DE DK ES FI FR GB GR IT LI LU NL PT SE |
|
17P | Request for examination filed |
Effective date: 19980527 |
|
17Q | First examination report despatched |
Effective date: 19990728 |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAG | Despatch of communication of intention to grant |
Free format text: ORIGINAL CODE: EPIDOS AGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IT LI LU NL PT SE |
|
REF | Corresponds to: |
Ref document number: 207816 Country of ref document: AT Date of ref document: 20011115 Kind code of ref document: T |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REF | Corresponds to: |
Ref document number: 59705136 Country of ref document: DE Date of ref document: 20011206 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
ET | Fr: translation filed | ||
GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) |
Effective date: 20020106 |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 |
|
REG | Reference to a national code |
Ref country code: PT Ref legal event code: SC4A Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20020115 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2166931 Country of ref document: ES Kind code of ref document: T3 |
|
REG | Reference to a national code |
Ref country code: GR Ref legal event code: EP Ref document number: 20010402477 Country of ref document: GR |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DK Payment date: 20090415 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 20090416 Year of fee payment: 13 Ref country code: PT Payment date: 20090406 Year of fee payment: 13 Ref country code: NL Payment date: 20090415 Year of fee payment: 13 Ref country code: LU Payment date: 20090414 Year of fee payment: 13 Ref country code: FI Payment date: 20090417 Year of fee payment: 13 Ref country code: AT Payment date: 20090416 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 20090528 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GR Payment date: 20090427 Year of fee payment: 13 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20100426 Year of fee payment: 14 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20100426 Year of fee payment: 14 |
|
BERE | Be: lapsed |
Owner name: FELIX *SCHOELLER JR FOTO- UND SPEZIALPAPIERE G.M.B Effective date: 20100430 |
|
REG | Reference to a national code |
Ref country code: PT Ref legal event code: MM4A Free format text: LAPSE DUE TO NON-PAYMENT OF FEES Effective date: 20101026 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: V1 Effective date: 20101101 |
|
EUG | Se: european patent has lapsed | ||
REG | Reference to a national code |
Ref country code: DK Ref legal event code: EBP |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101101 Ref country code: FI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100426 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100426 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101026 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101103 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100430 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100503 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110426 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20120524 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 59705136 Country of ref document: DE Representative=s name: COHAUSZ & FLORACK PATENT- UND RECHTSANWAELTE P, DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110427 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R082 Ref document number: 59705136 Country of ref document: DE Representative=s name: COHAUSZ & FLORACK PATENT- UND RECHTSANWAELTE P, DE Effective date: 20120627 Ref country code: DE Ref legal event code: R081 Ref document number: 59705136 Country of ref document: DE Owner name: SCHOELLER TECHNOCELL GMBH & CO. KG, DE Free format text: FORMER OWNER: FELIX SCHOELLER JR. FOTO- UND SPEZIALPAPIERE GMBH & CO. KG, 49086 OSNABRUECK, DE Effective date: 20120627 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100427 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20100426 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20130422 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20140422 Year of fee payment: 18 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20140418 Year of fee payment: 18 Ref country code: FR Payment date: 20140422 Year of fee payment: 18 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140430 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20140430 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 59705136 Country of ref document: DE |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20150426 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150426 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20151103 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST Effective date: 20151231 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150430 |