EP0838655B1 - Plomb pour cartouche de chasse - Google Patents

Plomb pour cartouche de chasse Download PDF

Info

Publication number
EP0838655B1
EP0838655B1 EP97117566A EP97117566A EP0838655B1 EP 0838655 B1 EP0838655 B1 EP 0838655B1 EP 97117566 A EP97117566 A EP 97117566A EP 97117566 A EP97117566 A EP 97117566A EP 0838655 B1 EP0838655 B1 EP 0838655B1
Authority
EP
European Patent Office
Prior art keywords
less
weight
zinc
tin
shot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP97117566A
Other languages
German (de)
English (en)
Other versions
EP0838655A1 (fr
Inventor
Jürgen Wisniewski
Jochen Dr. Spriestersbach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Grillo Werke AG
Original Assignee
Grillo Werke AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Grillo Werke AG filed Critical Grillo Werke AG
Publication of EP0838655A1 publication Critical patent/EP0838655A1/fr
Application granted granted Critical
Publication of EP0838655B1 publication Critical patent/EP0838655B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/04—Making non-ferrous alloys by powder metallurgy
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42—AMMUNITION; BLASTING
    • F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B7/00—Shotgun ammunition
    • F42B7/02—Cartridges, i.e. cases with propellant charge and missile
    • F42B7/04—Cartridges, i.e. cases with propellant charge and missile of pellet type
    • F42B7/046—Pellets or shot therefor

Definitions

  • the present invention relates to shot for ammunition purposes with a diameter of 1.5 to 5.5 mm based of tin and zinc.
  • Steel pellets have been particularly useful in Forests not proven. They are already banned in Denmark since they are too serious in processing the wood Damage to the cutting tools and on top of that lead to rust and discoloration effects. Moreover steel balls tend to ricochet and are therefore extremely dangerous for hunted use because they do not impact Absorb deformation energy (DEVA Altenbeken report June 1992 for German Hunting Protection Association in Bonn).
  • Zinc-based shot for example manufactured in accordance with GB-A-2,211,920 (basis for the preamble of claim 1), has definitely been used in sport and hunting shooting proven (see Die Pirsch, 1995, Issue 10), but they are Shot pellets are still limited to the cutting tools damage to the veneer and wood industry.
  • WO 94/25817 discloses shot ammunition or bullet ammunition to produce from an alloy containing at least 55% zinc and the rest of bismuth and tin, the tin content may not exceed 10%. Alloys are preferred containing 70% zinc and up to 30% by weight bismuth and only small amounts of tin. This ammunition is not for hunting purposes but only suitable as sports ammunition.
  • the invention has therefore set itself the task of grist to provide which is practically lead free and is non-toxic, has good ballistic properties, is easy to work with and similar when it stays in the wood how lead does not damage wood cutting tools. Furthermore, there should be no balls remaining in the wood Discolour the wood. In addition, the shot material may none in the paper and cellulose industry either Operational malfunctions or quality problems cause there the waste from wood processing is recycled.
  • grist Base of tin and zinc which is characterized by that it contains besides tin and the usual inevitable Impurities 12 to 60% by weight zinc and 0 to 5% by weight Aluminum, but less than 0.1 wt% copper, less than 0.1% iron and less than 1% lead.
  • Shot which in addition to tin contains 20 to 40% by weight of zinc and 0.05 contains up to 0.15 wt .-% aluminum.
  • the contain preferably Shot pellets less than 0.05 wt% copper, less than 0.05% by weight iron and less than 0.5% by weight lead.
  • the meal according to the invention can be produced in a conventional manner are made by pouring the liquid alloy into Chill molds in a sufficiently high tower filled with air or in a liquid bath, which leads to a faster cooling leads.
  • Another, albeit more complex, method The manufacture consists in that the alloy becomes one Wire is processed, which by an appropriate Form roller is processed into shot pellets. The remaining one Rest of the wire can be returned to the process become.
  • An alloy of approx. 70% tin and approx. 30% zinc is used, which is easy to cast.
  • Alloys less suitable for casting can be made by Processing into a wire and subsequent pressing Balls are processed into usable grist.
  • zinc types Z1 to Z4 are preferred because they contain significantly less lead, iron and copper.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • General Engineering & Computer Science (AREA)
  • Contacts (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
  • Conductive Materials (AREA)
  • Lifting Devices For Agricultural Implements (AREA)
  • Heat Treatment Of Steel (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Manufacturing Of Electrical Connectors (AREA)
  • Fats And Perfumes (AREA)
  • Train Traffic Observation, Control, And Security (AREA)
  • Catching Or Destruction (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Electrolytic Production Of Metals (AREA)

Claims (4)

  1. Grenaille à des fins de munitions, ayant un diamètre de 1,5 à 5,5 mm, à base d'étain et de zinc, caractérisée en ce qu'elle contient, en plus de l'étain et des impuretés inévitables habituelles, de 12 à 60 % en poids de zinc et de 0 à 5 % en poids d'aluminium, mais moins de 0,1 % en poids de cuivre, moins de 0,1 % de fer et moins de 1 % de plomb.
  2. Grenaille selon la revendication 1, caractérisée en ce qu'elle contient de 20 à 40 % en poids de zinc.
  3. Grenaille selon la revendication 1 ou 2, caractérisée en ce qu'elle contient de 0,05 à 0,15 % en poids d'aluminium.
  4. Grenaille selon l'une des revendications 1 à 3, caractérisée en ce qu'elle contient moins de 0,05 % en poids de cuivre, moins de 0,05 % en poids de fer et moins de 0,5 % en poids de plomb.
EP97117566A 1996-10-24 1997-10-10 Plomb pour cartouche de chasse Expired - Lifetime EP0838655B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19644235 1996-10-24
DE19644235A DE19644235C1 (de) 1996-10-24 1996-10-24 Schrot für Munitionszwecke

Publications (2)

Publication Number Publication Date
EP0838655A1 EP0838655A1 (fr) 1998-04-29
EP0838655B1 true EP0838655B1 (fr) 2000-01-05

Family

ID=7809884

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97117566A Expired - Lifetime EP0838655B1 (fr) 1996-10-24 1997-10-10 Plomb pour cartouche de chasse

Country Status (12)

Country Link
US (1) US6071359A (fr)
EP (1) EP0838655B1 (fr)
AT (1) ATE188545T1 (fr)
AU (1) AU721760B2 (fr)
CA (1) CA2218609C (fr)
DE (2) DE19644235C1 (fr)
DK (1) DK0838655T3 (fr)
ES (1) ES2140941T3 (fr)
GR (1) GR3032627T3 (fr)
HU (1) HU218331B (fr)
NZ (1) NZ328992A (fr)
PT (1) PT838655E (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10045991A1 (de) * 2000-09-16 2002-04-04 Degussa Galvanotechnik Gmbh Ternäre Zinn-Zink-Legierungen, galvanische Bäder und galvanisches Verfahren zur Erzeugung von ternären Zinn-Zink-Legierungsschichten
EP1436436B1 (fr) * 2001-10-16 2005-04-20 International Non-Toxic Composites Corp. Materiau composite contenant du tungstene et du bronze
NZ532694A (en) * 2001-10-16 2005-03-24 Internat Non Toxic Composites High density non-toxic composites comprising tungsten, another metal and polymer powder
WO2004090464A1 (fr) * 2003-04-07 2004-10-21 International Non-Toxic Composites Corporation Projectile en bronze de densite moyenne
US7770521B2 (en) * 2005-06-03 2010-08-10 Newtec Services Group, Inc. Method and apparatus for a projectile incorporating a metastable interstitial composite material
US8393273B2 (en) * 2009-01-14 2013-03-12 Nosler, Inc. Bullets, including lead-free bullets, and associated methods
CN101824557B (zh) * 2010-02-04 2011-05-04 汨罗市鸿昱新材料有限责任公司 一种高效节能生产锻轧锰桃的方法
US9115961B2 (en) 2012-07-19 2015-08-25 Amick Family Revocable Living Trust Corrosion-inhibited projectiles, and shot shells including the same
US9207050B2 (en) 2013-06-28 2015-12-08 Michael Clifford Sorensen Shot shell payloads that include a plurality of large projectiles and shot shells including the same
EP2878917A1 (fr) * 2013-11-29 2015-06-03 Real Federacion Espanola de Caza Composition chimique pour la fabrication de munitions

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2119876A (en) * 1936-12-24 1938-06-07 Remington Arms Co Inc Shot
JPS592747B2 (ja) * 1980-12-26 1984-01-20 三井金属鉱業株式会社 投射メッキ用金属合金粉末および投射メッキ方法
GB8725349D0 (en) * 1987-10-29 1987-12-02 Am & S Europ Ltd Metal shot
JP2825671B2 (ja) * 1991-01-23 1998-11-18 新日本製鐵株式会社 溶融Ｚｎ−Ｍｇ−Ａｌ−Ｓｎめっき鋼板
US5491035A (en) * 1992-03-27 1996-02-13 The Louis Berkman Company Coated metal strip
SE501227C2 (sv) * 1993-04-26 1994-12-12 Leif Persson Material för främst sportskytteammunition
NL9302056A (nl) * 1993-11-26 1995-06-16 Billiton Witmetaal Kogel en het gebruik van een Sn-legering daarvoor.

Also Published As

Publication number Publication date
ATE188545T1 (de) 2000-01-15
HUP9701722A1 (hu) 1998-07-28
DE59700963D1 (de) 2000-02-10
AU721760B2 (en) 2000-07-13
AU4100797A (en) 1998-04-30
NZ328992A (en) 1999-03-29
HU218331B (en) 2000-07-28
ES2140941T3 (es) 2000-03-01
CA2218609C (fr) 2005-04-05
DE19644235C1 (de) 1998-02-12
US6071359A (en) 2000-06-06
HU9701722D0 (en) 1997-12-29
GR3032627T3 (en) 2000-05-31
PT838655E (pt) 2000-04-28
DK0838655T3 (da) 2000-05-08
EP0838655A1 (fr) 1998-04-29
CA2218609A1 (fr) 1998-04-24

Similar Documents

Publication Publication Date Title
DE69831422T2 (de) Bleifreies geschoss aus zinn
DE69824548T3 (de) Zerbrechliches geschoss aus eisenpulver
DE69117191T2 (de) Bleifreie geschosse und kartuschen damit versehen
DE69419581T2 (de) Auf Sn basierter Legierung hergestelltes Kugelgeschoss
EP0838655B1 (fr) Plomb pour cartouche de chasse
DE69321603T2 (de) Verbundgeschoss
DE69833582T2 (de) Automatenlegierung auf Kupferbasis
EP3225707A1 (fr) Composant pour des canalisations d'eau ou de gaz acheminant des milieux comprenant un alliage de cuivre
DE2557676A1 (de) Splittergeschoss
DE69324255T2 (de) Geschossausweichstahl
DE1483324C2 (de) Verwendung von AIZnMg-Leglerungen mit geringer Kerbempfindlichkeit
DE202007019373U1 (de) Verwendung einer Bronzelegierung für ein Schneckenzahnrad
DE102014208457B4 (de) VERSCHLEIßFESTE LEGIERUNG MIT KOMPLEXER MIKROSTRUKTUR
DE2065091A1 (de) Legierung
DE102014208324B4 (de) Verschleißfeste Legierungen mit komplexer Mikrostruktur
EP1980633A1 (fr) Alliage de bronze destiné à la coulée
DE3437516C1 (de) Stahlhelm und Verfahren zu seiner Herstellung
DE102014112126A1 (de) Mikrolegierter Stahl und zusammengesetzte Platinen aus mikrolegiertem Stahl und pressgehärtetem Stahl
DE2422371C3 (de) Aluminiumlegierung mit Antimon und Kupfer für Gleitlager
DE102018119165B3 (de) Vollmantelgeschoß mit Kernen
DE60007799T2 (de) Treibladungshülse aus Metall, die mit einer inneren Erosionsschutzschicht versehen ist
DE2112418C (de) Weichlot
DE763758C (de) Verwendung von Aluminiumlegierungen fuer Press- und Walzerzeugnisse
CH222585A (de) Verfahren zur Herstellung von gleitender Beanspruchung ausgesetzten Maschinenteilen.
DE2040031A1 (de) Kupfer-Zinklegierung fuer druckdichte Gussstuecke

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

AX Request for extension of the european patent

Free format text: AL;LT;LV;RO;SI

17P Request for examination filed

Effective date: 19980619

AKX Designation fees paid

Free format text: AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

RBV Designated contracting states (corrected)

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

17Q First examination report despatched

Effective date: 19990414

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

REF Corresponds to:

Ref document number: 188545

Country of ref document: AT

Date of ref document: 20000115

Kind code of ref document: T

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: SCHMAUDER & PARTNER AG PATENTANWALTSBUERO

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 59700963

Country of ref document: DE

Date of ref document: 20000210

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2140941

Country of ref document: ES

Kind code of ref document: T3

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: GERMAN

ITF It: translation for a ep patent filed
GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20000330

ET Fr: translation filed
REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20000125

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: MC

Payment date: 20001023

Year of fee payment: 4

Ref country code: LU

Payment date: 20001023

Year of fee payment: 4

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20010831

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IE

Payment date: 20010920

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20010924

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GR

Payment date: 20010927

Year of fee payment: 5

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20011010

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20011023

Year of fee payment: 5

Ref country code: BE

Payment date: 20011023

Year of fee payment: 5

Ref country code: AT

Payment date: 20011023

Year of fee payment: 5

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20021010

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20021010

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20021031

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20021031

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20021031

BERE Be: lapsed

Owner name: *GRILLO-WERKE A.G.

Effective date: 20021031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20030430

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20030506

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20051018

Year of fee payment: 9

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070501

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20070501

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20101021

Year of fee payment: 14

Ref country code: IT

Payment date: 20101030

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20111024

Year of fee payment: 15

Ref country code: DK

Payment date: 20111024

Year of fee payment: 15

Ref country code: FI

Payment date: 20111020

Year of fee payment: 15

Ref country code: FR

Payment date: 20111103

Year of fee payment: 15

Ref country code: SE

Payment date: 20111021

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20111215

Year of fee payment: 15

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20121010

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20130628

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121011

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121010

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130501

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 59700963

Country of ref document: DE

Effective date: 20130501

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121010

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121010

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121031

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20140207

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121011