US2119876A - Shot - Google Patents
Shot Download PDFInfo
- Publication number
- US2119876A US2119876A US117518A US11751836A US2119876A US 2119876 A US2119876 A US 2119876A US 117518 A US117518 A US 117518A US 11751836 A US11751836 A US 11751836A US 2119876 A US2119876 A US 2119876A
- Authority
- US
- United States
- Prior art keywords
- shot
- aluminum
- zinc
- lead
- spherical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
- C22C18/04—Alloys based on zinc with aluminium as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/02—Making metallic powder or suspensions thereof using physical processes
- B22F9/06—Making metallic powder or suspensions thereof using physical processes starting from liquid material
- B22F9/08—Making metallic powder or suspensions thereof using physical processes starting from liquid material by casting, e.g. through sieves or in water, by atomising or spraying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B7/00—Shotgun ammunition
- F42B7/02—Cartridges, i.e. cases with propellant charge and missile
- F42B7/04—Cartridges, i.e. cases with propellant charge and missile of pellet type
- F42B7/046—Pellets or shot therefor
Definitions
- This invention relates to shot as used primarily in shot shells designed for target shooting and game hunting and in air rifles.
- the present application is a continuation of my prior co-pend- 5 ing application, Serial No. 72,112,1filed April 1, 1936, as to so much of the subject matter as is common to both applications.
- shot have been made essentially of lead, the lead being alloyed with quantities of such ingredients as antimony and arsenic sufficient to control the hardness and likewise control the fluidity and surface tension characteristics of the molten metal in such a manner as to enable the manufacture of shot by the usual method.
- This method comprises the melting of the metal, the pouring of. the molten metal through a suitable screen upon which it is formed into droplets of the desired size, which droplets fall through the air a distance of about 120 feet during which they become solid.
- the falling shot are,-for the purpose of cushioning impact and retaining sphericity, received in a-tank of water; the shot however are fully formed and; substantially hardened prior to impact with the water.
- Lead shot are subject to certain disadvantages, one of which is the poisoning of wild fowl due to the consumption by the wild fowl of shot which has accumulated .in feeding grounds where a substantial amount of shooting has occurred over a considerable period of time. In-recent years this factor in the maintenance of supplies of game birds, particularly wild fowl, has become of suflicient importance to receive the attention of the United States Biological Survey, as well as 4 the manufacturers of shot, and certain efforts have beenmade to render lead shot non-poisonous.
- Another disadvantage of lead shot is that, due to the great density of lead,-the shot are for most purposes undesirably heavy. This is par- 'ticularly true of air rifle shot and shot designed for short range use. With a given load of powder,
- a given number ofpellets of a lighter material may be given a. substantially higher initial velocity, and a charge of such pellets is more effective except at the longer ranges.
- the present invention contemplates the manufacture by dropping of shot ofanon-poisonous and materially lighter metal, and particularly from a relatively light metallic alloy, It has been found that shot may be dropped from a meltof metal consisting of or more per cent of zinc, the remainder being substantially all aluminum. It is. diflicult to drop shot consisting of zinc exclusively, the difiiculties being due to the ready oxidation of zinc causing the formation of an excessive amount of.
- a spherical dropped shot suitable for use in. a: shot shell consisting of an alloy containing from 5%, to 5% of aluminum, the remainder being substantially all zinc.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Catching Or Destruction (AREA)
Description
Patented June 7, 1938 SHOT Michael George Corson, New York, N. Y., as signor to Remington Arms Company, Inc., a corporation of Delaware No Drawing.- Application December 24, 1936, Serial No. 117,518
4 Claims.
This invention relates to shot as used primarily in shot shells designed for target shooting and game hunting and in air rifles. The present application is a continuation of my prior co-pend- 5 ing application, Serial No. 72,112,1filed April 1, 1936, as to so much of the subject matter as is common to both applications.
For a great many years shot have been made essentially of lead, the lead being alloyed with quantities of such ingredients as antimony and arsenic sufficient to control the hardness and likewise control the fluidity and surface tension characteristics of the molten metal in such a manner as to enable the manufacture of shot by the usual method. This method comprises the melting of the metal, the pouring of. the molten metal through a suitable screen upon which it is formed into droplets of the desired size, which droplets fall through the air a distance of about 120 feet during which they become solid. At the bottom of the dropping tower the falling shot are,-for the purpose of cushioning impact and retaining sphericity, received in a-tank of water; the shot however are fully formed and; substantially hardened prior to impact with the water. The
enormous numbers of shot manufactured and? used require a manufacturing method of this character, such methods as casting, swaging and rolling being altogether too expensive.
Lead shot are subject to certain disadvantages, one of which is the poisoning of wild fowl due to the consumption by the wild fowl of shot which has accumulated .in feeding grounds where a substantial amount of shooting has occurred over a considerable period of time. In-recent years this factor in the maintenance of supplies of game birds, particularly wild fowl, has become of suflicient importance to receive the attention of the United States Biological Survey, as well as 4 the manufacturers of shot, and certain efforts have beenmade to render lead shot non-poisonous. Another disadvantage of lead shot is that, due to the great density of lead,-the shot are for most purposes undesirably heavy. This is par- 'ticularly true of air rifle shot and shot designed for short range use. With a given load of powder,
a given number ofpellets of a lighter material may be given a. substantially higher initial velocity, and a charge of such pellets is more effective except at the longer ranges.
The present invention contemplates the manufacture by dropping of shot ofanon-poisonous and materially lighter metal, and particularly from a relatively light metallic alloy, It has been found that shot may be dropped from a meltof metal consisting of or more per cent of zinc, the remainder being substantially all aluminum. It is. diflicult to drop shot consisting of zinc exclusively, the difiiculties being due to the ready oxidation of zinc causing the formation of an excessive amount of. dross in the melting kettle 10 and dropping pans, to the attack of the iron of the melting kettle and dropping pans by the active molten zinc, and to the poor surface tension characteristics of zinc, preventing the formation of spherical pellets or causing the break-up of 15 such pellets as have been formed while falling through the tower. The presence of aluminum in amounts up to about 5% has been found beneficialin contr lling both the formation of dross and the attac on the material of the melt containers. Byv regulating the quantity of aluminum beneficial effects on the dropping char-.- acteristics are likewise secured. While aluminum in any quantity up to 5% is beneficial, the optimumaluminum content has been found, to be 25 about 3%. The minimum practicable quantity is about .5 of 1%, it being difficult to secureuniform distribution of aluminum in a lesser amount.
The present invention is believed to constitute the first discovery of the beneficial effects of 0 aluminum in the manufacture of shot and upon the shot themselves; henceflthe appended claims are to be broadly construed. Q
What, is claimed is: p
1. A spherical dropped shot suitable for use in 35 a shot shell consisting of an alloy of zinc and aluminum.
2. A spherical dropped shot suitable for use in a ,shot shell consisting of an alloy of not less than 95% zinc, the remainder being substantially all aluminum. 4o 3. A spherical dropped shot suitable for use in a shot shell consisting of an alloy of substantially 97% zinc, the balance being substantially all aluminum.
4. A spherical dropped shot suitable for use in. a: shot shell consisting of an alloy containing from 5%, to 5% of aluminum, the remainder being substantially all zinc. v
mcnm GEORGE consort.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US117518A US2119876A (en) | 1936-12-24 | 1936-12-24 | Shot |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US117518A US2119876A (en) | 1936-12-24 | 1936-12-24 | Shot |
Publications (1)
Publication Number | Publication Date |
---|---|
US2119876A true US2119876A (en) | 1938-06-07 |
Family
ID=22373358
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US117518A Expired - Lifetime US2119876A (en) | 1936-12-24 | 1936-12-24 | Shot |
Country Status (1)
Country | Link |
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US (1) | US2119876A (en) |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2356117A1 (en) * | 1976-06-21 | 1978-01-20 | Olin Corp | DEGRADABLE HUNTING LEAD AND ITS CYNEGETIC APPLICATIONS |
WO1991000491A1 (en) * | 1989-06-23 | 1991-01-10 | Brown John E | Non-toxic shot and shot shell containing same |
US5713981A (en) * | 1992-05-05 | 1998-02-03 | Teledyne Industries, Inc. | Composite shot |
EP0838655A1 (en) * | 1996-10-24 | 1998-04-29 | Grillo-Werke AG | Shotgun pellet |
US6248150B1 (en) | 1999-07-20 | 2001-06-19 | Darryl Dean Amick | Method for manufacturing tungsten-based materials and articles by mechanical alloying |
US6270549B1 (en) | 1998-09-04 | 2001-08-07 | Darryl Dean Amick | Ductile, high-density, non-toxic shot and other articles and method for producing same |
US6527880B2 (en) | 1998-09-04 | 2003-03-04 | Darryl D. Amick | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US6749802B2 (en) | 2002-01-30 | 2004-06-15 | Darryl D. Amick | Pressing process for tungsten articles |
US20040112243A1 (en) * | 2002-01-30 | 2004-06-17 | Amick Darryl D. | Tungsten-containing articles and methods for forming the same |
US20040216589A1 (en) * | 2002-10-31 | 2004-11-04 | Amick Darryl D. | Tungsten-containing articles and methods for forming the same |
US20050008522A1 (en) * | 2001-01-09 | 2005-01-13 | Amick Darryl D. | Tungsten-containing articles and methods for forming the same |
US20050034558A1 (en) * | 2003-04-11 | 2005-02-17 | Amick Darryl D. | System and method for processing ferrotungsten and other tungsten alloys, articles formed therefrom and methods for detecting the same |
US6884276B2 (en) | 2000-01-14 | 2005-04-26 | Darryl D. Amick | Methods for producing medium-density articles from high-density tungsten alloys |
US7000547B2 (en) | 2002-10-31 | 2006-02-21 | Amick Darryl D | Tungsten-containing firearm slug |
US20070119523A1 (en) * | 1998-09-04 | 2007-05-31 | Amick Darryl D | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US7399334B1 (en) | 2004-05-10 | 2008-07-15 | Spherical Precision, Inc. | High density nontoxic projectiles and other articles, and methods for making the same |
US20100034686A1 (en) * | 2005-01-28 | 2010-02-11 | Caldera Engineering, Llc | Method for making a non-toxic dense material |
US8122832B1 (en) | 2006-05-11 | 2012-02-28 | Spherical Precision, Inc. | Projectiles for shotgun shells and the like, and methods of manufacturing the same |
US9677860B2 (en) | 2011-12-08 | 2017-06-13 | Environ-Metal, Inc. | Shot shells with performance-enhancing absorbers |
US10260850B2 (en) | 2016-03-18 | 2019-04-16 | Environ-Metal, Inc. | Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same |
US10690465B2 (en) | 2016-03-18 | 2020-06-23 | Environ-Metal, Inc. | Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same |
-
1936
- 1936-12-24 US US117518A patent/US2119876A/en not_active Expired - Lifetime
Cited By (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2356117A1 (en) * | 1976-06-21 | 1978-01-20 | Olin Corp | DEGRADABLE HUNTING LEAD AND ITS CYNEGETIC APPLICATIONS |
WO1991000491A1 (en) * | 1989-06-23 | 1991-01-10 | Brown John E | Non-toxic shot and shot shell containing same |
EP0558161A1 (en) * | 1989-06-23 | 1993-09-01 | BROWN, John E. | Non-toxic shot and shot shell containing same |
AU644370B2 (en) * | 1989-06-23 | 1993-12-09 | John E. Brown | Non-toxic shot and shot shell containing same |
US5713981A (en) * | 1992-05-05 | 1998-02-03 | Teledyne Industries, Inc. | Composite shot |
EP0838655A1 (en) * | 1996-10-24 | 1998-04-29 | Grillo-Werke AG | Shotgun pellet |
US6071359A (en) * | 1996-10-24 | 2000-06-06 | Grillo-Werke Ag | Shot for use as ammunition |
US6270549B1 (en) | 1998-09-04 | 2001-08-07 | Darryl Dean Amick | Ductile, high-density, non-toxic shot and other articles and method for producing same |
US6890480B2 (en) | 1998-09-04 | 2005-05-10 | Darryl D. Amick | Ductile medium- and high-density, non-toxic shot and other articles and method for producing the same |
US6527880B2 (en) | 1998-09-04 | 2003-03-04 | Darryl D. Amick | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US20030172775A1 (en) * | 1998-09-04 | 2003-09-18 | Amick Darryl D. | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US7640861B2 (en) | 1998-09-04 | 2010-01-05 | Amick Darryl D | Ductile medium- and high-density, non-toxic shot and other articles and method for producing the same |
US7267794B2 (en) | 1998-09-04 | 2007-09-11 | Amick Darryl D | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US20070119523A1 (en) * | 1998-09-04 | 2007-05-31 | Amick Darryl D | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US20050211125A1 (en) * | 1998-09-04 | 2005-09-29 | Amick Darryl D | Ductile medium-and high-density, non-toxic shot and other articles and method for producing the same |
US6527824B2 (en) | 1999-07-20 | 2003-03-04 | Darryl D. Amick | Method for manufacturing tungsten-based materials and articles by mechanical alloying |
US6248150B1 (en) | 1999-07-20 | 2001-06-19 | Darryl Dean Amick | Method for manufacturing tungsten-based materials and articles by mechanical alloying |
US20050188790A1 (en) * | 2000-01-14 | 2005-09-01 | Amick Darryl D. | Methods for producing medium-density articles from high-density tungsten alloys |
US6884276B2 (en) | 2000-01-14 | 2005-04-26 | Darryl D. Amick | Methods for producing medium-density articles from high-density tungsten alloys |
US7329382B2 (en) | 2000-01-14 | 2008-02-12 | Amick Darryl D | Methods for producing medium-density articles from high-density tungsten alloys |
US20050008522A1 (en) * | 2001-01-09 | 2005-01-13 | Amick Darryl D. | Tungsten-containing articles and methods for forming the same |
US7217389B2 (en) | 2001-01-09 | 2007-05-15 | Amick Darryl D | Tungsten-containing articles and methods for forming the same |
US6749802B2 (en) | 2002-01-30 | 2004-06-15 | Darryl D. Amick | Pressing process for tungsten articles |
US6823798B2 (en) | 2002-01-30 | 2004-11-30 | Darryl D. Amick | Tungsten-containing articles and methods for forming the same |
US20040112243A1 (en) * | 2002-01-30 | 2004-06-17 | Amick Darryl D. | Tungsten-containing articles and methods for forming the same |
US7000547B2 (en) | 2002-10-31 | 2006-02-21 | Amick Darryl D | Tungsten-containing firearm slug |
US7059233B2 (en) | 2002-10-31 | 2006-06-13 | Amick Darryl D | Tungsten-containing articles and methods for forming the same |
US20040216589A1 (en) * | 2002-10-31 | 2004-11-04 | Amick Darryl D. | Tungsten-containing articles and methods for forming the same |
US7383776B2 (en) | 2003-04-11 | 2008-06-10 | Amick Darryl D | System and method for processing ferrotungsten and other tungsten alloys, articles formed therefrom and methods for detecting the same |
US20050034558A1 (en) * | 2003-04-11 | 2005-02-17 | Amick Darryl D. | System and method for processing ferrotungsten and other tungsten alloys, articles formed therefrom and methods for detecting the same |
US7399334B1 (en) | 2004-05-10 | 2008-07-15 | Spherical Precision, Inc. | High density nontoxic projectiles and other articles, and methods for making the same |
US7422720B1 (en) | 2004-05-10 | 2008-09-09 | Spherical Precision, Inc. | High density nontoxic projectiles and other articles, and methods for making the same |
US20100034686A1 (en) * | 2005-01-28 | 2010-02-11 | Caldera Engineering, Llc | Method for making a non-toxic dense material |
US8122832B1 (en) | 2006-05-11 | 2012-02-28 | Spherical Precision, Inc. | Projectiles for shotgun shells and the like, and methods of manufacturing the same |
US9677860B2 (en) | 2011-12-08 | 2017-06-13 | Environ-Metal, Inc. | Shot shells with performance-enhancing absorbers |
US9897424B2 (en) | 2011-12-08 | 2018-02-20 | Environ-Metal, Inc. | Shot shells with performance-enhancing absorbers |
US10209044B2 (en) | 2011-12-08 | 2019-02-19 | Environ-Metal, Inc. | Shot shells with performance-enhancing absorbers |
US10260850B2 (en) | 2016-03-18 | 2019-04-16 | Environ-Metal, Inc. | Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same |
US10690465B2 (en) | 2016-03-18 | 2020-06-23 | Environ-Metal, Inc. | Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same |
US11280597B2 (en) | 2016-03-18 | 2022-03-22 | Federal Cartridge Company | Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same |
US11359896B2 (en) | 2016-03-18 | 2022-06-14 | Federal Cartridge Company | Frangible firearm projectiles, methods for forming the same, and firearm cartridges containing the same |
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