EP0800857B1 - Tuyau mélangeur pour fluides à faible viscosité - Google Patents
Tuyau mélangeur pour fluides à faible viscosité Download PDFInfo
- Publication number
- EP0800857B1 EP0800857B1 EP96810224A EP96810224A EP0800857B1 EP 0800857 B1 EP0800857 B1 EP 0800857B1 EP 96810224 A EP96810224 A EP 96810224A EP 96810224 A EP96810224 A EP 96810224A EP 0800857 B1 EP0800857 B1 EP 0800857B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tube
- accordance
- mixer
- constriction
- mixing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/431—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
- B01F25/4316—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being flat pieces of material, e.g. intermeshing, fixed to the wall or fixed on a central rod
- B01F25/43161—Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor the baffles being flat pieces of material, e.g. intermeshing, fixed to the wall or fixed on a central rod composed of consecutive sections of flat pieces of material
Definitions
- the invention relates to a mixing tube for low viscosity Fluids, in particular for fluids with suspended contained solids, according to the preamble of claim 1.
- This device includes Mixing elements in a tube, each consisting of two outer segments and at least one inner segment consist. The segments are at one end or sides with the housing gap-free connected while their other ends are at a distance end in front of the pipe wall. Adjacent segments intersect with a gap at each intersection remains. The mixing takes place essentially within the mixing elements by a crosswise deflection individual partial flows.
- the object of the invention is to provide a mixing tube to create static internals in terms of known static mixing device cheaper can be produced.
- This task is claimed by the 1 defined mixing tube solved, in which the mixture due to the bottlenecks mentioned in the claim and the subsequent bottlenecks of mixed routes.
- a Such a mixing device is also for low-viscosity Liquids that do not contain solids can be used.
- the mixing tube according to the invention for low-viscosity fluids contains plate-shaped elements attached to or on individual parts of the tube, its cross section partially cover.
- the bottlenecks left open by the elements each comprise at least one gap-shaped area, with a longitudinal extension of this gap, that of Pipe wall to pipe wall through the pipe axis or from the Pipe wall through the pipe axis to a second section runs.
- the gap closes with the pipe axis Angles in the range between around 20 and 60 °, preferably between 35 and 45 °, a.
- the one Length in the range of 1 to 10 pipe diameters.
- the bottleneck or bottlenecks of the invention Mixing devices are shaped and arranged such that in the flowing fluid as it passes through a Bottleneck two opposite vortices form. While of the flow through the mixing section results in Whirl a partial mixing. Compared to the known mixing device are fewer mixing elements and for each mixing element only two segments are required to create one to achieve largely the same good mixing effect. However, a longer pipe is required. Further causes the mixing device according to the invention lower pressure drop.
- the dependent claims 2 to 11 relate to advantageous Embodiments of the mixing tube according to the invention.
- the Claim 12 relates to the use of Mixing tube.
- Figures 1 and 2 represent an inventive Mixing tube 1 for low-viscosity fluids.
- the tube wall 10 is only indicated by dash-dotted lines.
- the circular Pipe has a diameter D.
- the mixing pipe 1 contains plate-shaped elements 2 as internals, the individual Place the tube 1 partially cover its cross section and create bottlenecks 3.
- the elements 2 are in elliptical surfaces with the main axes d and e arranged.
- the bottleneck 3 released in the elements 2 includes two sections 31 and 32: a wide gap 31, the from the pipe wall 10 through the pipe axis c to the second portion 32 extends along the axis e, and a flow opening 32 adjoining the tube wall 10 of an elongated, here crescent-like shape, the is arranged transversely to the first partial region 31.
- the shape of the second partial area 32 can also be, for example be lenticular.
- the axis e (or the gap 31) closes with the Pipe axis c an angle ⁇ in the range between around 20 and 60 °, preferably between 35 and 45 °.
- the second section 32 is downstream after the gap 31 arranged. After the bottleneck 3 there is a mixed section 4th
- edges these segments essentially include the following Sections: an edge piece a with the shape of a elliptical arc adjacent to tube wall 10; on straight edge piece s, which forms a boundary with the gap 31; and an edge piece b that connects to the second partial area 32 of the bottleneck 3.
- Between the tube wall 10 and the arcuate edge a can be a small gap located at individual points Connecting means, for example welding material, are bridged.
- the elliptical border can, for example be approximated by straight pieces.
- Edge piece s can also be a curved one.
- the flowing fluid is in Fig.1 by arrows 5, 5 ' indicated.
- the bottleneck 3 induces two in the flow opposite vortices that are projected onto a Cross-sectional area are indicated with arrows 6, 6 '.
- the gap 31 is essentially trapezoidal (corner points A, B, B 'and A'); it widens towards the second Subarea 32 of the bottleneck 3. With this slit shape creates an optimal pair of vertebrae 6, 6 '. So that two Bottleneck is 3 mirror-symmetrical; the plane of symmetry lies on the pipe axis c.
- the plate-shaped elements associated with a bottleneck 3 2 are in the embodiment of Figures 1 and 2 in arranged on one level. You can be together with the Manufacture connecting web 23 from a piece of sheet metal. Figure 3 shows how these elements 2 material-saving from one Strips of sheet metal can be cut out.
- the plate-shaped elements 2 can instead of just be curved or kinked.
- bottlenecks 3 in the mixing tube 1 there are at least two bottlenecks 3 in the mixing tube 1 provided, one each to a first bottleneck 3 adjacent, downstream bottleneck 3 ' outside the mixing section 4 at a distance m of around 3 to 5 pipe diameters D is arranged.
- the free space between adjacent bottlenecks 3, 3 ' thus has a length of around 2 to 4 pipe diameters D. on.
- the gaps 31 of adjacent bottlenecks 3, 3 ' are transverse arranged to each other.
- Figures 4 to 8 represent further embodiments possible bottlenecks 3.
- the two are in Fig.4 Segments 21 and 22, which have the same shape, are angular arranged to each other.
- the shape of the segment 21 or 22 can be seen in Fig. 5.
- the segments 21 and 22 can of course also by a web 23 - for example, as shown in dashed lines - connected his.
- Figures 6 and 7 show bottlenecks 3 for Mixing tubes 1 according to the invention, their cross sections are square or rectangular.
- Fig. 6 also shows that a web 23 at a different location than at the Border between the two sections of the bottleneck 3 can be arranged.
- the web 23 can be, for example Be a rod with a circular cross-section.
- the fifth exemplary embodiment according to FIG. 8 shows one Bottleneck 3, which only consists of a gap-shaped area 31 consists.
- the area 31 can be trapezoidal (with two curved sides AA ', BB') and thereby in or against expand the direction of flow.
- the mixing tube 1 according to the invention can mix a Fluids with suspended solids are used become. Especially if the solids are fibrous, this use is advantageous.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Claims (12)
- Tuyau mélangeur (1) pour des fluides à faible viscosité, notamment pour des fluides avec des matières solides en suspension, le tube mélangeur comporte au moins un élément de mélange (2) qui est constitué de deux segments (21, 22) en forme de plaque qui sont reliés le cas échéant par au moins une baguette étroite (23), où est formé par les segments (21, 22) dans le tuyau (1) un passage resserré (3) qui comprend une fente (31) entre les segments, avec une extension longitudinale de cette fente (31) qui s'étend de paroi de tuyau (10) à paroi de tuyau à travers l'axe de tuyau (c) ou de la paroi de tuyau à travers l'axe de tuyau (c) à une seconde zone partielle (32) disposée en aval du passage resserré (3), et la fente (31) forme avec l'axe de tuyau un angle (ϕ) dans la plage entre 20° et 60°, où est disposé en aval de chaque élément de mélange dans la direction d'écoulement un chemin de mélange (4) exempt d'inserts qui a une longueur dans la plage de 1 à 10 diamètres de tuyau (D) et dans lequel un fluide en écoulement forme deux tourbillons contraires.
- Tuyau mélangeur selon la revendication 1, caractérisé en ce que le passage resserré (3) comprend deux zones partielles, à savoir la fente (31) qui s'étend à travers l'axe de tuyau (c) vers la deuxième zone partielle (32) et la deuxième zone partielle qui forme une ouverture d'écoulement avoisinant la paroi de tuyau (10) d'une forme oblongue, par exemple, semblable à une demi-lune ou lenticulaire, où cette ouverture d'écoulement est disposée transversalement à la première zone partielle.
- Tuyau mélangeur selon la revendication 2, caractérisé en ce que les bords de ces segments comprennent sensiblement respectivement les pièces partielles suivantes: une pièce de bord (a), notamment sous la forme d'un arc elliptique qui avoisine étroitement ou avec un petit écart la paroi de tuyau (10), une pièce de bord (s) qui forme une limite à la fente 31 et une pièce de bord (b) qui avoisine la seconde zone partielle (32) du passage resserré.
- Tuyau mélangeur selon la revendication 3, caractérisé en ce que la ou une baguette se situe sur la limite entre les deux zones partielles (31, 32) du passage resserré.
- Tuyau mélangeur selon l'une des revendications 1 à 4, caractérisé en ce que la fente (31) est sensiblement en forme de trapèze et s'élargit dans la direction d'écoulement.
- Tuyau mélangeur selon l'une des revendications 1 à 5, caractérisé en ce que le passage resserré (3) est réalisé d'une manière spéculairement symétrique où le plan de symétrie se situe sur l'axe de tuyau (c).
- Tuyau mélangeur selon l'une des revendications 1 à 6, caractérisé en ce que les segments en forme de plaque (21, 22) associés au passage resserré (3) sont disposés dans un plan.
- Tuyau mélangeur selon les revendications 7 et 4, caractérisé en ce que les segments en forme de plaque disposés dans un plan sont réalisés conjointement avec la baguette de liaison (23) en une pièce de tôle.
- Tuyau mélangeur selon l'une des revendications 1 à 8, caractérisé en ce qu'au moins deux éléments de mélange (2) sont prévus, où respectivement le passage resserré avoisinant (3') situé en aval est disposé à l'extérieur du chemin de mélange (4) à une distance (m) d'environ 3 à 5 diamètres de tuyau (D), où l'espace exempt d'inserts entre les passages resserrés avoisinants présente une longueur d'environ 2 à 4 diamètres de tuyau.
- Tuyau mélangeur selon la revendication 9, caractérisé en ce que les fentes (31) d'éléments de mélange avoisinants (2) sont disposés transversalement l'une à l'autre.
- Tuyau mélangeur selon l'une des revendications 1 à 10, caractérisé en ce que dans la projection normale sur une section transversale de tuyau, la face ouverte du passage resserré (3) représente 50 - 75% de la face en section transversale du tuyau.
- Utilisation d'un tuyau mélangeur (1) selon l'une des revendications 1 à 11 pour le mélange d'un fluide avec des matières solides en suspension, où notamment les matières solides sont fibreuses.
Priority Applications (14)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96810224A EP0800857B1 (fr) | 1996-04-12 | 1996-04-12 | Tuyau mélangeur pour fluides à faible viscosité |
ES96810224T ES2203673T3 (es) | 1996-04-12 | 1996-04-12 | Tubo mezclador para fluidos de baja viscosidad. |
AT96810224T ATE246036T1 (de) | 1996-04-12 | 1996-04-12 | Mischrohr für niedrigviskose fluide |
DE59610627T DE59610627D1 (de) | 1996-04-12 | 1996-04-12 | Mischrohr für niedrigviskose Fluide |
TW086101299A TW358039B (en) | 1996-04-12 | 1997-02-04 | Mixer tube for low viscosity fluids and use thereof |
JP9036291A JPH09276678A (ja) | 1996-04-12 | 1997-02-20 | 低粘度流体のためのミキサー管 |
US08/808,380 US5813762A (en) | 1996-04-12 | 1997-02-28 | Mixer tube for low viscosity fluids |
KR1019970006982A KR100481930B1 (ko) | 1996-04-12 | 1997-03-04 | 저점성유체용믹서튜브 |
CA002199332A CA2199332C (fr) | 1996-04-12 | 1997-03-06 | Tube de melange pour liquides a faible viscosite |
PL97319395A PL182950B1 (pl) | 1996-04-12 | 1997-04-09 | Mieszalnik rurowy do płynów o niskiej lepkości |
MXPA/A/1997/002575A MXPA97002575A (en) | 1996-04-12 | 1997-04-09 | Mixing pipe for viscosity fluids b |
CZ19971091A CZ291563B6 (cs) | 1996-04-12 | 1997-04-10 | Směšovací trubice pro nízkoviskózní kapaliny |
CN97109584A CN1078817C (zh) | 1996-04-12 | 1997-04-11 | 低粘度液体混合管 |
BR9701784-1A BR9701784A (pt) | 1996-04-12 | 1997-04-11 | Tubo de mistura para fluidos de baixa viscosidade |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96810224A EP0800857B1 (fr) | 1996-04-12 | 1996-04-12 | Tuyau mélangeur pour fluides à faible viscosité |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0800857A1 EP0800857A1 (fr) | 1997-10-15 |
EP0800857B1 true EP0800857B1 (fr) | 2003-07-30 |
Family
ID=8225586
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96810224A Expired - Lifetime EP0800857B1 (fr) | 1996-04-12 | 1996-04-12 | Tuyau mélangeur pour fluides à faible viscosité |
Country Status (13)
Country | Link |
---|---|
US (1) | US5813762A (fr) |
EP (1) | EP0800857B1 (fr) |
JP (1) | JPH09276678A (fr) |
KR (1) | KR100481930B1 (fr) |
CN (1) | CN1078817C (fr) |
AT (1) | ATE246036T1 (fr) |
BR (1) | BR9701784A (fr) |
CA (1) | CA2199332C (fr) |
CZ (1) | CZ291563B6 (fr) |
DE (1) | DE59610627D1 (fr) |
ES (1) | ES2203673T3 (fr) |
PL (1) | PL182950B1 (fr) |
TW (1) | TW358039B (fr) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19748383C2 (de) * | 1997-11-03 | 2000-11-23 | U & A Gmbh | Statischer Mischer |
EP0918146A1 (fr) | 1997-11-19 | 1999-05-26 | Sulzer Chemtech AG | Dispositif pour la décomposition de polluants de gaz d'échappement au moyen de catalyseurs |
EP0956906A3 (fr) | 1998-03-25 | 2000-11-08 | Shinyou Technolozies Inc. | Dispositif de mélange et de projection et dispositif de production de neige |
ES2244441T3 (es) * | 1999-04-19 | 2005-12-16 | Sulzer Chemtech Ag | Torbellinos mezcladores estaticos y metodo de empleo para los mismos. |
GB9910738D0 (en) * | 1999-05-11 | 1999-07-07 | Statiflo International Limited | Static miker |
FR2807336B1 (fr) * | 2000-04-07 | 2002-12-13 | Pour Le Dev De L Antipollution | Melangeur statique |
DE60135116D1 (de) * | 2000-06-06 | 2008-09-11 | Trojan Techn Inc | Mischvorrichtung für fluide |
EP1346762A4 (fr) * | 2000-11-28 | 2004-10-20 | Ohr Co Ltd | Dispositif generateur de cavitation et appareil melangeur de fluide utilisant ledit dispositif |
EP1412078B1 (fr) | 2001-08-02 | 2008-10-08 | LG Life Sciences Limited | Methodes de production de derives de 4-aminomethylene-pyrrolidin-3-one proteges, de gemifloxacine ou d'un de leurs sels |
NO318636B1 (no) * | 2002-02-08 | 2005-04-18 | Norsk Hydro As | Anordning for transformasjon av gass-/vaeskestrom til lagdelt strom |
US20060285433A1 (en) * | 2005-06-20 | 2006-12-21 | Jing-Tang Yang | Fluidic mixer of serpentine channel incorporated with staggered sudden-expansion and convergent cross sections |
US7213617B2 (en) * | 2005-07-12 | 2007-05-08 | Deere & Company | Airflow divider with shutoff |
TWI426952B (zh) * | 2006-06-27 | 2014-02-21 | Sulzer Chemtech Ag | 具有在通路流動方向上產生流動漩渦之葉片對的靜態混合器 |
TWI417135B (zh) * | 2007-06-22 | 2013-12-01 | Sulzer Chemtech Ag | 靜態混合元件 |
US8397495B2 (en) * | 2008-06-26 | 2013-03-19 | Tenneco Automotive Operating Company Inc. | Exhaust gas additive/treatment system and mixer for use therein |
US9347355B2 (en) * | 2011-09-08 | 2016-05-24 | Tenneco Automotive Operating Company Inc. | In-line flow diverter |
ES2582321T3 (es) * | 2012-02-03 | 2016-09-12 | General Electric Technology Gmbh | Disposición para inyectar un agente reductor en un gas de combustión |
DE102012008732A1 (de) * | 2012-05-04 | 2013-11-07 | Xylem Water Solutions Herford GmbH | Mischvorrichtung für UV-Wasserbehandlungsanlagen mit offenem Kanal |
CN104560111B (zh) * | 2013-10-25 | 2017-08-25 | 中国石油化工股份有限公司 | 传热管以及使用其的裂解炉 |
JP6382041B2 (ja) * | 2014-09-10 | 2018-08-29 | 旭有機材株式会社 | 流体混合器 |
JP2016107218A (ja) * | 2014-12-08 | 2016-06-20 | 旭有機材工業株式会社 | 流体混合器および流体混合器付き合流継手 |
EP3034159B1 (fr) * | 2014-12-18 | 2020-11-04 | The Procter and Gamble Company | Mélangeur statique et procédé pour mélanger des fluides |
US10729600B2 (en) | 2015-06-30 | 2020-08-04 | The Procter & Gamble Company | Absorbent structure |
HUE057989T2 (hu) | 2015-11-04 | 2022-06-28 | Procter & Gamble | Nedvszívó szerkezetet tartalmazó nedvszívó árucikk |
EP3370673B1 (fr) | 2015-11-04 | 2022-03-30 | The Procter & Gamble Company | Structure absorbante |
US11441521B2 (en) | 2017-08-15 | 2022-09-13 | Volvo Truck Corporation | Vaned valve for exhaust gas recirculation line |
EP3479893A1 (fr) | 2017-11-06 | 2019-05-08 | Sulzer Chemtech AG | Conduit de mélangeur amélioré et son procédé d'utilisation |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
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US3409187A (en) * | 1965-10-11 | 1968-11-05 | Emil C. Socha | Distributing spout |
US4062524A (en) * | 1973-06-06 | 1977-12-13 | Bayer Aktiengesellschaft | Apparatus for the static mixing of fluid streams |
DE2522106C3 (de) * | 1975-05-17 | 1982-04-15 | Bayer Ag, 5090 Leverkusen | Vorrichtung zum kontinuierlichen Mischen fließfähiger Stoffe und Verfahren zum Herstellen eines Mischeinsatzes |
DE2525020C3 (de) * | 1975-06-05 | 1985-11-21 | Basf Ag, 6700 Ludwigshafen | Statischer Mischer für fluide Stoffe |
US4040256A (en) * | 1976-07-14 | 1977-08-09 | The Dow Chemical Company | Flume mixer |
CH669336A5 (fr) * | 1985-12-11 | 1989-03-15 | Sulzer Ag | |
US4813788A (en) * | 1986-01-03 | 1989-03-21 | Union Oil Company Of California | Static, gravity-flow mixing apparatus for particulate matter |
US4765204A (en) * | 1986-09-03 | 1988-08-23 | Koch Engineering Company, Inc. | Method of manufacturing a motionless mixer |
US4936689A (en) * | 1988-07-11 | 1990-06-26 | Koflo Corporation | Static material mixing apparatus |
US4929088A (en) * | 1988-07-27 | 1990-05-29 | Vortab Corporation | Static fluid flow mixing apparatus |
CH678284A5 (en) * | 1988-11-03 | 1991-08-30 | Sulzer Ag | Static mixer assembly requiring no cleaning - in which inner face of tube segments bear ridges which cross each other diagonally with respect to tubular axis |
ATE141827T1 (de) * | 1991-07-30 | 1996-09-15 | Sulzer Chemtech Ag | Einmischvorrichtung |
JP3107877B2 (ja) * | 1991-08-19 | 2000-11-13 | 久夫 小嶋 | 静止型流体混合器の製造方法 |
JPH06182174A (ja) * | 1992-12-22 | 1994-07-05 | Tonen Corp | 流体混合装置 |
EP0655275B1 (fr) * | 1993-11-26 | 1999-10-06 | Sulzer Chemtech AG | Dispositif de mélange statique |
US5378063A (en) * | 1993-12-02 | 1995-01-03 | Tokyo Nisshin Jabara Co., Ltd. | Static mixing module |
JP3003581U (ja) * | 1994-02-16 | 1994-10-25 | 東京日進ジャバラ株式会社 | スタティックミキシングモジュール及び混合装置 |
-
1996
- 1996-04-12 AT AT96810224T patent/ATE246036T1/de not_active IP Right Cessation
- 1996-04-12 ES ES96810224T patent/ES2203673T3/es not_active Expired - Lifetime
- 1996-04-12 EP EP96810224A patent/EP0800857B1/fr not_active Expired - Lifetime
- 1996-04-12 DE DE59610627T patent/DE59610627D1/de not_active Expired - Lifetime
-
1997
- 1997-02-04 TW TW086101299A patent/TW358039B/zh active
- 1997-02-20 JP JP9036291A patent/JPH09276678A/ja active Pending
- 1997-02-28 US US08/808,380 patent/US5813762A/en not_active Expired - Lifetime
- 1997-03-04 KR KR1019970006982A patent/KR100481930B1/ko not_active IP Right Cessation
- 1997-03-06 CA CA002199332A patent/CA2199332C/fr not_active Expired - Fee Related
- 1997-04-09 PL PL97319395A patent/PL182950B1/pl not_active IP Right Cessation
- 1997-04-10 CZ CZ19971091A patent/CZ291563B6/cs not_active IP Right Cessation
- 1997-04-11 BR BR9701784-1A patent/BR9701784A/pt not_active IP Right Cessation
- 1997-04-11 CN CN97109584A patent/CN1078817C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR970069108A (ko) | 1997-11-07 |
US5813762A (en) | 1998-09-29 |
CA2199332A1 (fr) | 1997-10-12 |
KR100481930B1 (ko) | 2005-07-18 |
PL319395A1 (en) | 1997-10-13 |
EP0800857A1 (fr) | 1997-10-15 |
PL182950B1 (pl) | 2002-05-31 |
CN1078817C (zh) | 2002-02-06 |
CZ109197A3 (en) | 1997-10-15 |
BR9701784A (pt) | 1999-10-19 |
DE59610627D1 (de) | 2003-09-04 |
CZ291563B6 (cs) | 2003-04-16 |
JPH09276678A (ja) | 1997-10-28 |
TW358039B (en) | 1999-05-11 |
MX9702575A (es) | 1997-10-31 |
CN1167007A (zh) | 1997-12-10 |
CA2199332C (fr) | 2000-11-21 |
ATE246036T1 (de) | 2003-08-15 |
ES2203673T3 (es) | 2004-04-16 |
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