EP0636737B1 - Zusammensetzungen zur Entfernung von Silikonöl enthaltenden Avivagen - Google Patents
Zusammensetzungen zur Entfernung von Silikonöl enthaltenden Avivagen Download PDFInfo
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- EP0636737B1 EP0636737B1 EP94110542A EP94110542A EP0636737B1 EP 0636737 B1 EP0636737 B1 EP 0636737B1 EP 94110542 A EP94110542 A EP 94110542A EP 94110542 A EP94110542 A EP 94110542A EP 0636737 B1 EP0636737 B1 EP 0636737B1
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- European Patent Office
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- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 52
- 229920002545 silicone oil Polymers 0.000 title claims abstract description 30
- 238000005282 brightening Methods 0.000 title abstract 2
- 239000004094 surface-active agent Substances 0.000 claims abstract description 36
- 239000006185 dispersion Substances 0.000 claims abstract description 15
- 239000004753 textile Substances 0.000 claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 150000008282 halocarbons Chemical class 0.000 claims abstract description 7
- 125000002091 cationic group Chemical group 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000002280 amphoteric surfactant Substances 0.000 claims abstract description 3
- 229960003237 betaine Drugs 0.000 claims abstract description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 229920006395 saturated elastomer Polymers 0.000 claims description 22
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 16
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 9
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 125000000129 anionic group Chemical group 0.000 claims description 8
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 7
- 229920003169 water-soluble polymer Polymers 0.000 claims description 6
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 claims description 5
- 239000002736 nonionic surfactant Substances 0.000 claims description 5
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 150000007522 mineralic acids Chemical class 0.000 claims description 4
- 150000007524 organic acids Chemical class 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 150000002460 imidazoles Chemical class 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 2
- 239000000872 buffer Substances 0.000 claims description 2
- 239000002552 dosage form Substances 0.000 claims description 2
- IZWSFJTYBVKZNK-UHFFFAOYSA-O N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonic acid Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS(O)(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-O 0.000 claims 1
- 125000003282 alkyl amino group Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 150000004693 imidazolium salts Chemical group 0.000 claims 1
- 229920000831 ionic polymer Polymers 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 11
- 229920002334 Spandex Polymers 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 4
- 150000007513 acids Chemical class 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 239000012141 concentrate Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 33
- 125000000217 alkyl group Chemical group 0.000 description 31
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 22
- 238000005406 washing Methods 0.000 description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 8
- 239000003208 petroleum Substances 0.000 description 8
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000012259 ether extract Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- -1 alkyl radicals Chemical class 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 5
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical compound CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920000609 methyl cellulose Polymers 0.000 description 4
- 239000001923 methylcellulose Substances 0.000 description 4
- 235000010981 methylcellulose Nutrition 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 0 *C(C1*)C(COC(C(*)C2*)OC(*)C2O)C(*)OC1OCC(C(*)C1*)*(*)OC1O Chemical compound *C(C1*)C(COC(C(*)C2*)OC(*)C2O)C(*)OC1OCC(C(*)C1*)*(*)OC1O 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001720 carbohydrates Chemical class 0.000 description 3
- 235000014633 carbohydrates Nutrition 0.000 description 3
- 238000005108 dry cleaning Methods 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005160 1H NMR spectroscopy Methods 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 229920001353 Dextrin Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 2
- 241001076195 Lampsilis ovata Species 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 238000006887 Ullmann reaction Methods 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 229920004482 WACKER® Polymers 0.000 description 2
- 235000011054 acetic acid Nutrition 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 235000015165 citric acid Nutrition 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical compound COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 150000002926 oxygen Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920002401 polyacrylamide Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- WPWHSFAFEBZWBB-UHFFFAOYSA-N 1-butyl radical Chemical compound [CH2]CCC WPWHSFAFEBZWBB-UHFFFAOYSA-N 0.000 description 1
- LHENQXAPVKABON-UHFFFAOYSA-N 1-methoxypropan-1-ol Chemical compound CCC(O)OC LHENQXAPVKABON-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- XPZPBOVIIBHSHV-UHFFFAOYSA-N CC(CCOC(C)=O)(N)N(CCC1)C1=O Chemical compound CC(CCOC(C)=O)(N)N(CCC1)C1=O XPZPBOVIIBHSHV-UHFFFAOYSA-N 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical group 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical compound N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- FYGDTMLNYKFZSV-MRCIVHHJSA-N dextrin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](CO)OC(O[C@@H]2[C@H](O[C@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-MRCIVHHJSA-N 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical group C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012925 reference material Substances 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 210000002023 somite Anatomy 0.000 description 1
- 229920006301 statistical copolymer Polymers 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/382—Aminoaldehydes
Definitions
- the present invention relates to a surfactant system which enables the removal of additives containing silicone oil from textile substrates in an aqueous medium free from halogenated hydrocarbons.
- the silicone oils are removed in the so-called "chemical cleaning".
- the oil is detached from the textile substrate with the help of organic solvents, which usually contain halogenated hydrocarbons.
- the silicone oil remaining on the textile is manifested in the subsequent dyeing process by the levelness and blotchiness of the dyeing (cf. Textile finishing 5, No. 2 (1970), 122 ff. And chemical fibers - Text. Ind. 17, No. 1 (1967), 47 -51).
- Suitable components (1) of the composition according to the invention are those surfactants which, in addition to a hydrophobic fat residue, have a hydrophilic cationic group which is either permanently present or adjusts itself as a function of the pH.
- Other hydrophilic groups can include, for example, hydroxyl, carboxyl, sulfate or sulfonate groups (see Stache, Tensid pocket book, 2nd edition, Vienna, Hanser, 1981 and Lindner, tenside textile auxiliary washing raw materials, Volume III, Stuttgart, scientific publishing company mbH, 1971).
- Compounds of the type described can be found in the classes:
- the invention further relates to the use of the abovementioned composition and the aqueous dispersions which can be prepared therefrom for the removal of additives containing silicone oil from textile substrates.
- the cation activity of which depends on the pH value can be increased by adding acid, component (2) of the composition according to the invention.
- the composition of the agent according to the invention is preferably selected here so that a pH of 2-6, particularly preferably 3-5, results in the application liquor.
- the pH when using the compositions according to the invention can be 0-14.
- the addition of component (2) does not make sense.
- the pH value can be set in the range 0-14 by adding any inorganic or organic base or acid to the application liquor.
- compositions according to the invention examples include: formic acid, acetic acid, lactic acid, citric acid, tartaric acid, oxalic acid, malic acid, oxygen acids of sulfur and phosphorus (in various oxidation states), hydrochloric acid etc. and such other suitable acids are known to the person skilled in the art for this purpose.
- R 7 is preferably C 8 -C 30 alkyl, particularly preferably C 10 -C 18 alkyl.
- compositions according to the invention furthermore contain water-soluble polymers as component (4).
- water-soluble polymers as component (4).
- These are high-molecular, natural or chemically modified natural substances or synthetic polymers (cf. Chwalla / Anger, Handbuch der Textilhilhilstoff, p. 937 ff., Verlag Chemie, Weinheim 1977 and Ullmanns Encycl. Der techn. Chemie, 4th ed., Vol. 24, 102 ff., Verlag Chemie, Weinheim, 1983).
- nonionic types are known which are used with particular preference here.
- n is an integer from approximately 100 to 10,000, preferably 100 to 200
- R 9 is hydrogen, alkyl, hydroxyalkyl or mixed alkyl and hydroxyalkyl.
- Suitable alkyl radicals are the methyl, ethyl, propyl and butyl radical, with the methyl radical being preferred.
- Preferred hydroxyalkyl radicals are the hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl radical, of which the hydroxybutyl radical is preferred. If all hydroxyl groups of the glucose unit are substituted by alkyl or hydroxyalkyl groups, one speaks of a degree of substitution of 3.
- Polyvinyl alcohol is the preferred water-soluble polymer.
- the halohydrocarbon-free solvents, component (5) of the composition according to the invention serve above all to adjust and maintain the desired viscosity of the formulations of components (1) to (4).
- the solvents (5) in question which are also used in a mixture, are, for example Ethanol, isopropanol, 1-methoxypropanol, diethylene glycol, tripropylene glycol and other agents familiar to the person skilled in the art.
- compositions according to the invention thus always contain a cationic surfactant (1) in combination with at least one of components (2), (3), (4) and (5).
- a cationic surfactant (1) in addition to (1), there is a proportion of nonionic surfactant (3), water-soluble nonionic polymer (4) or both, in a particularly preferred manner only one of (3) or (4).
- Compositions containing 3-80% by weight of (1) and 1-60% by weight of (3) and / or 1-60% by weight of (4), 0-20% by weight are preferred.
- of (2) and 0-70% by weight of (5) particularly preferably those with the stated contents of (1), (4), (2) and (5).
- compositions according to the invention can be used as a commercial form. They are then used in the form of an aqueous liquor which is formed by diluting the commercial form with water. Such a dilution is generally easier if the compositions according to the invention additionally contain solvents (5).
- compositions are therefore those with 3-77% by weight of (1) and 1-60% by weight of (3) and / or 1-60% by weight of (4), 0-20% by weight. % of (2) and 3-70% by weight of (5); Particularly preferred compositions contain 3-77% by weight of (1), 1-60% by weight of (4), 0-20% by weight of (2) and 3-70% by weight of (5 ).
- a further advantage for use in the acidic pH range is that the commercial form is adjusted by adding the acid (2) which is required in any case for pH adjustment during use.
- the amount of (2) is therefore preferably 2-8% by weight of the total composition.
- Aqueous dispersions can be produced from the compositions according to the invention, which, due to their additional water content, facilitate simplified dissolution in the wash liquor ultimately used (with contents of 0.1-30 g dispersion / l wash liquor).
- Such aqueous dispersions span the range of high concentrations, for example as a shipping form to be transported, over medium concentrations for dosing into the wash liquor in the stock keeping for the operational practice up to the low concentrations of the actual washing liquors
- These aqueous dispersions thus represent a further aspect of the invention.
- Their water content is therefore generally 1-99.7% by weight, based on the total weight of the aqueous dispersions from the compositions according to the invention.
- Such dispersions contain 3-90% by weight of water as the shipping form or dosage form.
- the aqueous dispersions, including the proportion of (5), are preferably characterized by a total content of 20-90% by weight of water and (5).
- the components can generally be mixed together in any order.
- the manufacturers of such products provide information on the dissolving behavior of these products in individual cases or can be found in the literature.
- the proportions of components (1) to (5) can be selected depending on the desired washing effects or the product viscosity.
- compositions or of the aqueous dispersions which can be prepared therefrom when used to remove silicone-containing additives from textile substrates, in particular elastane fiber mixed articles, in an aqueous medium is a further aspect of the invention and is not tied to a specific technical washing process. You can achieve equally good results using a dwell or a continuous process. Processes have proven to be particularly advantageous in which the goods are treated in a wide, low-tension material guide with as little mechanical stress as possible in order to avoid mechanically caused fiber breaks.
- the silicone oil release ability of the compositions according to the invention was demonstrated when washing knitted stockings made of 100% elastane fiber.
- a statement about the washing effect was obtained from a petroleum ether extract determination of the washed goods compared to the raw goods.
- the washing tests were carried out on two types of elastane fiber that had been treated with different silicone oils.
- the liquor ratio was 1:10 in all tests. In each case it was washed for 30 minutes at 80 ° C. in an AHIBA Polymat washing machine (10 g / l WAS) and then rinsed twice with water at 80 ° C.
- a wash of a commercially available, seasoned and silicone oil-containing mixed article made of polyamide / polyurethane (80:20) was 30 minutes at 80 ° C (liquor ratio 1:10; 1 g / l WAS) each with a composition according to the invention, with a nonionic, with a nonionic / anionic and with an anionic detergent.
- the AHIBA Polymat was washed with approx. 10 g of goods each. After rinsing twice at 80 ° C., the mixture was extracted with petroleum ether and the silicone detachment was determined by means of quantitative 1H-NMR determination of silicone oil in the extract. The unfixed raw material served as reference material.
- Example 3 Analogously to Example 3, the compositions according to the invention were washed at pH 4-4.5.
- the wash liquors obtained had the 1) compositions listed below.
- the specification of the compositions in (g / l) corresponds to current practice in use.
- the percentage composition can be derived from this information.
- the pH was adjusted with glacial acetic acid.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Colloid Chemistry (AREA)
- Fats And Perfumes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4324152 | 1993-07-19 | ||
| DE4324152A DE4324152A1 (de) | 1993-07-19 | 1993-07-19 | Zusammensetzungen zur Entfernung von Silikonöl enthaltenden Avivagen, daraus hergestellte wäßrige Dispersionen und deren Verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0636737A1 EP0636737A1 (de) | 1995-02-01 |
| EP0636737B1 true EP0636737B1 (de) | 1997-10-29 |
Family
ID=6493165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94110542A Expired - Lifetime EP0636737B1 (de) | 1993-07-19 | 1994-07-06 | Zusammensetzungen zur Entfernung von Silikonöl enthaltenden Avivagen |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US5728179A (pt) |
| EP (1) | EP0636737B1 (pt) |
| JP (1) | JP3075925B2 (pt) |
| KR (1) | KR950003554A (pt) |
| CN (2) | CN1075140C (pt) |
| AT (1) | ATE159776T1 (pt) |
| BR (1) | BR9402850A (pt) |
| CA (1) | CA2128159A1 (pt) |
| CZ (1) | CZ285892B6 (pt) |
| DE (2) | DE4324152A1 (pt) |
| DK (1) | DK0636737T3 (pt) |
| ES (1) | ES2108343T3 (pt) |
| PL (1) | PL178204B1 (pt) |
| TW (1) | TW282502B (pt) |
| ZA (1) | ZA945231B (pt) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE59610256D1 (de) * | 1995-05-18 | 2003-04-30 | Ciba Sc Holding Ag | Die Verwendung von Hilfsmittelzubereitungen beim Färben von Wolle |
| DE69719422T2 (de) * | 1996-07-24 | 2003-10-02 | Sunstar Inc., Takatsuki | Waschmittelzusammensetzungen |
| FR2755448B1 (fr) * | 1996-11-07 | 1999-01-29 | G Fargamel Sa | Procede de traitement prealable d'estropes souples textiles a usage en environnement nucleaire |
| DE10022419A1 (de) | 2000-05-09 | 2001-11-22 | Henkel Ecolab Gmbh & Co Ohg | Silikon-Entferner |
| JP3930475B2 (ja) | 2001-07-11 | 2007-06-13 | クラリアント インターナショナル リミティド | テキスタイル繊維脱脂剤、その製造及びその使用 |
| US6818608B2 (en) * | 2002-02-01 | 2004-11-16 | John C. Moore | Cured polymers dissolving compositions |
| JP6006030B2 (ja) * | 2012-07-31 | 2016-10-12 | 株式会社レグルス | シリコーン塗布繊維からシリコーン系の表面処理剤を除去する方法、該方法に好適な剥離剤 |
| JP6082545B2 (ja) * | 2012-08-17 | 2017-02-15 | 松本油脂製薬株式会社 | 精練剤組成物、精練繊維の製造方法及び繊維の精練方法 |
| CN104031757A (zh) * | 2014-06-19 | 2014-09-10 | 宁波市川宁环保科技有限公司 | 一种清洗剂组合物及应用 |
| US10596367B2 (en) | 2016-01-13 | 2020-03-24 | Setpoint Medical Corporation | Systems and methods for establishing a nerve block |
| PL4296340T3 (pl) | 2016-02-18 | 2025-08-04 | Ecolab Usa Inc. | Zastosowanie rozpuszczalnika podczas mycia butelek z wykorzystaniem preparatów na bazie amidyny |
| CN112458769A (zh) * | 2020-11-16 | 2021-03-09 | 五邑大学 | 一种纯棉染色面料复染剂及其制备方法 |
| JP7654912B1 (ja) * | 2023-09-29 | 2025-04-01 | 松本油脂製薬株式会社 | 精練剤組成物、精練繊維の製造方法及び繊維の精練方法 |
| WO2025069894A1 (ja) * | 2023-09-29 | 2025-04-03 | 松本油脂製薬株式会社 | 精練剤組成物、精練繊維の製造方法及び繊維の精練方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL78829C (pt) * | 1951-09-07 | |||
| DE1051439B (de) * | 1956-09-11 | 1959-02-26 | Boehme Fettchemie Gmbh | Loesungsmittel fuer die Trockenreinigung |
| AU416365B2 (en) * | 1966-04-04 | 1971-08-23 | Emery Industries, Inc | Drycleaning method and detergents therefor |
| US3671441A (en) * | 1968-11-04 | 1972-06-20 | Diamond Shamrock Corp | Dry cleaning detergent |
| US3776853A (en) * | 1971-08-19 | 1973-12-04 | Westinghouse Electric Corp | Dry-cleaning composition and method |
| JPS516688B2 (pt) * | 1973-10-17 | 1976-03-01 | ||
| US3985502A (en) * | 1975-05-19 | 1976-10-12 | Boorujy Edward J | Method of cleaning fabrics |
| JPS54108812A (en) * | 1978-02-15 | 1979-08-25 | Kao Corp | Detergent composition for dry cleaning |
| DE3515077C1 (de) * | 1985-04-26 | 1986-06-19 | Hansa Textilchemie GmbH, 2806 Oyten | Verfahren zum Entfernen von auf Fasern,Garnen oder flaechigen textilen Materialien befindlichen Siliconen |
| DE3615544A1 (de) * | 1986-05-09 | 1987-11-12 | Henkel Kgaa | Verfahren zur vorbehandlung verschmutzter textilien |
| GB8804818D0 (en) * | 1988-03-01 | 1988-03-30 | Unilever Plc | Fabric softening composition |
-
1993
- 1993-07-19 DE DE4324152A patent/DE4324152A1/de not_active Withdrawn
-
1994
- 1994-06-09 TW TW083105227A patent/TW282502B/zh active
- 1994-07-06 AT AT94110542T patent/ATE159776T1/de not_active IP Right Cessation
- 1994-07-06 DK DK94110542T patent/DK0636737T3/da active
- 1994-07-06 EP EP94110542A patent/EP0636737B1/de not_active Expired - Lifetime
- 1994-07-06 DE DE59404456T patent/DE59404456D1/de not_active Expired - Fee Related
- 1994-07-06 ES ES94110542T patent/ES2108343T3/es not_active Expired - Lifetime
- 1994-07-14 JP JP06184120A patent/JP3075925B2/ja not_active Expired - Lifetime
- 1994-07-15 CA CA002128159A patent/CA2128159A1/en not_active Abandoned
- 1994-07-18 ZA ZA945231A patent/ZA945231B/xx unknown
- 1994-07-18 CZ CZ941729A patent/CZ285892B6/cs not_active IP Right Cessation
- 1994-07-18 KR KR1019940017237A patent/KR950003554A/ko not_active Abandoned
- 1994-07-18 BR BR9402850A patent/BR9402850A/pt not_active IP Right Cessation
- 1994-07-19 PL PL94304351A patent/PL178204B1/pl unknown
- 1994-07-19 CN CN94108055A patent/CN1075140C/zh not_active Expired - Fee Related
-
1995
- 1995-11-20 US US08/560,567 patent/US5728179A/en not_active Expired - Fee Related
-
2001
- 2001-03-22 CN CN01111891A patent/CN1344789A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CZ172994A3 (en) | 1995-02-15 |
| CN1108326A (zh) | 1995-09-13 |
| KR950003554A (ko) | 1995-02-17 |
| JP3075925B2 (ja) | 2000-08-14 |
| JPH0754264A (ja) | 1995-02-28 |
| BR9402850A (pt) | 1995-04-04 |
| CN1344789A (zh) | 2002-04-17 |
| DK0636737T3 (da) | 1998-07-20 |
| DE4324152A1 (de) | 1995-01-26 |
| ATE159776T1 (de) | 1997-11-15 |
| PL304351A1 (en) | 1995-01-23 |
| CN1075140C (zh) | 2001-11-21 |
| US5728179A (en) | 1998-03-17 |
| ZA945231B (en) | 1995-02-27 |
| PL178204B1 (pl) | 2000-03-31 |
| CZ285892B6 (cs) | 1999-11-17 |
| CA2128159A1 (en) | 1995-01-20 |
| DE59404456D1 (de) | 1997-12-04 |
| TW282502B (pt) | 1996-08-01 |
| EP0636737A1 (de) | 1995-02-01 |
| ES2108343T3 (es) | 1997-12-16 |
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