EP0500480A1 - Thermofixierter Zwirn aus Kunststoffmonofilen - Google Patents

Thermofixierter Zwirn aus Kunststoffmonofilen Download PDF

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Publication number
EP0500480A1
EP0500480A1 EP92420053A EP92420053A EP0500480A1 EP 0500480 A1 EP0500480 A1 EP 0500480A1 EP 92420053 A EP92420053 A EP 92420053A EP 92420053 A EP92420053 A EP 92420053A EP 0500480 A1 EP0500480 A1 EP 0500480A1
Authority
EP
European Patent Office
Prior art keywords
twisted
monofilaments
twisting
synthetic material
fixing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP92420053A
Other languages
English (en)
French (fr)
Other versions
EP0500480B1 (de
Inventor
Gérard Lagarrigue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc Fibres SA
Original Assignee
Rhone Poulenc Fibres SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Fibres SA filed Critical Rhone Poulenc Fibres SA
Publication of EP0500480A1 publication Critical patent/EP0500480A1/de
Application granted granted Critical
Publication of EP0500480B1 publication Critical patent/EP0500480B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/26Yarns or threads characterised by constructional features, e.g. blending, filament/fibre with characteristics dependent on the amount or direction of twist
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • D02G3/402Yarns in which fibres are united by adhesives; Impregnated yarns or threads the adhesive being one component of the yarn, i.e. thermoplastic yarn
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/447Yarns or threads for specific use in general industrial applications, e.g. as filters or reinforcement
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S57/00Textiles: spinning, twisting, and twining
    • Y10S57/902Reinforcing or tire cords

Definitions

  • the present invention relates to a thermofixed ply produced from monofilaments of synthetic material and a method of manufacturing said ply.
  • a monofilament is by definition a continuous thread made up of a single filament. It is generally used as it is, for example, as a horsehair or a brush, in textile applications such as weaving or knitting of technical fabrics or knits, in the paper industry, for example, as felt loops at the junction of a machine. paper, etc. It can also be used in the form of cords in textile applications such as weaving or knitting of technical fabrics or knits (for example wet felt needling base), in elastomer reinforcement applications (for example tire reinforcement) etc ...
  • a cable is defined as the product resulting from the assembly and twisting of two or more twists of monofilaments; the twist being defined as the product, hitherto an intermediate product, resulting from the assembly and twisting of two or more monofilaments.
  • the intermediate ply may consist of a single filament to which a twist has been applied.
  • the manufacture of a monofilament cable requires several successive operations, in particular the assembly and twisting in one direction (S for example) of the monofilaments then the assembly and twisting in the opposite direction (Z in this case) of several twists , which gives the cable.
  • the opposite twists for the twisted and the cabled are intended to create a mechanical blocking of the cabled by opposition and balancing of the untwisting forces.
  • this mechanical blockage leaves the cable a certain nervousness; there is a twisting of the cable in the free state, which hinders its transformation for example into fabrics or knits.
  • the present invention aims to provide a solution to the above problems.
  • a twisted monofilament for applications such as technical textile use, reinforcements of elastomers, paper industry, etc., characterized in that it consists of at least two monofilaments of synthetic material having a title greater than or equal to 20 tex, assembled, twisted and heat-fixed, and that it is practically free of twisting stress.
  • the synthetic materials which are suitable are all those usually used in the manufacture of monofilaments and in particular polyesters and polyamides in the form of homopolymers, copolymers or mixtures of polymers, where appropriate.
  • the number of monofilaments is not limited, it depends on the characteristics desired for the product produced. However in general this number is between two and nine.
  • each monofilament depends on the use for which the twist is intended.
  • the titer is preferably between 20 and 500 tex.
  • the twisting twist takes the current values in this type of operation, which are to a large extent a function of the unit strength and the number of unit monofilaments.
  • the ply is thermofixed under the conditions defined in the manufacturing process claimed below.
  • the starting monofilaments are produced according to a conventional spinning, stretching in several phases, relaxation process; however, the relaxation rate is lower than that usually practiced.
  • the relaxation rate is advantageously between 0% and 6% instead of 0% to 12%, values usually practiced.
  • the dynamometric characteristics are those common for this type of product and depend on the material.
  • the elongation at break of the starting monofilaments is advantageously between 10% and 20%. Given the rate of relaxation, the material is in a moderately relaxed state, slightly repelotected macromolecules.
  • the assembly of two or more strands is carried out in a known manner continuously; discontinuously, it will be necessary to take the necessary precautions to obtain an assembly with regular thread tension and calculated so as not to generate a winding or twisting fault.
  • Twisting will be done from these monofilaments assembled in a single operation on an appropriate machine.
  • the assembly is placed for example in a single or double twist twisting pot where it receives the desired twist.
  • the assembly is subjected to a tensile stress greater than the elastic limit stress, therefore it undergoes a slight deformation comparable to a further stretching, however with the molecules oriented in the twisted direction. .
  • the product remains very nervous because it is subjected to an internal stress of detorsion.
  • the fixing zone includes a heat treatment oven and it is advantageously delimited by two capstans: an entry capstan (which also marks the exit from the twisting zone) calling the plies at constant speed while keeping torsion blocked, a exit capstan rotating at a speed lower than the entry speed, thus allowing the relaxation of the plied.
  • the reception of the twisted is done for example on a reel with parallel crossing.
  • an additional step of surface treatment for example coating, is integrated between the twisting and the fixing. For this it is necessary to keep the twisted blocked during this operation which can be achieved by means of an additional capstan.
  • the process is carried out at the usual wiring speeds, that is to say generally between 20 and 50 m / min approximately.
  • the method is economically advantageous in that it allows the elimination of a twisting step.
  • it allows the continuous integration of an additional step such as coating, which until now was carried out discontinuously and required a cable recovery.
  • the standard wired control product which the twist according to the invention proposes to replace is produced from shrinked polyamide 66 monofilaments, according to the procedure described below.
  • the monofilaments After extrusion, the monofilaments are cooled in water to 35 ° C, then undergo a series of three phases of hot drawing:
  • the monofilaments After stretching the monofilaments are subjected to relaxation and thermal fixation, relaxation rate 12%, fixing temperature 215 ° C (passage through a hot air oven). The monofilaments are finally wound, winding speed: 180 m / min, weight of the windings: 2 kg.
  • Twist is measured by the method described in French Standard G07 314, it corresponds to the number of loops formed after having unrolled 1 meter of cable or twists and joined the ends.
  • This cable can be used in applications such as a base for stationery felts and in some cases as a weft on the loom to form the felt joining loop, this loop then being in the direction of operation on a paper machine.
  • a twist according to the invention is then produced for comparison.
  • the monofilaments are manufactured by the same process as the control with the same parameters, except for the relaxation rate which is 6% instead of 12% and the assembly by three in this case.
  • a twist according to the invention is produced by the method according to the invention.
  • a modified twisting machine is used for the implementation of the method, it comprises in particular a thermal fixing oven, a first call capstan located upstream of the oven (leaving the twisting area) and a second capstan located downstream from the oven (leaving the fixing area).
  • the spool of triwires is placed in the twisting pot of the machine where the assembly receives a S240 twist. Twisting is carried out with the application of a tension of 400 CN, ie a stress of 2.2 CN / tex, greater than the elastic limit stress. Continuous, twist kept blocked by the capstans, the plied is subjected to a thermal fixing by passage in the oven at the temperature of 200 ° C, higher than the thermal past of the material, with application of a relaxation rate of 8% .
  • the speed of the upstream capstan is 21.6 m / min, that of the downstream capstan 20 m / min, that is to say identical to that of production of the control cable, hence no loss of productivity.
  • the twisted is received on a spool with parallel cross winding, winding weight 2 kg.
  • the plied has the following characteristics:
  • the twist according to example 1 is used for the production of joining loops on felt at the junction of the paper machine, press section. This junction is made by a loop at each end of the felt favoring its mounting during its change, for this a rod is introduced between the loops, thus binding the felt.
  • thermofixed ply according to the invention replaces a 200 tex monofilament, it provides the characteristics of flexibility and longitudinal regularity in section.
  • the coating material consists of a rou water lapping.
  • the product to be applied is a polymerizable silicone with rapid polymerization in the form of a liquid.
  • the heat treatment oven is used both for the thermofixing of the plied (fixing of the twist) and the polymerization of the coating.
  • the speed of the process is between 20 and 50 m / min.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Artificial Filaments (AREA)
  • Paper (AREA)
EP92420053A 1991-02-21 1992-02-18 Thermofixierter Zwirn aus Kunststoffmonofilen Expired - Lifetime EP0500480B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9102309 1991-02-21
FR9102309A FR2673202B1 (fr) 1991-02-21 1991-02-21 Retors thermofixe en monofilaments synthetiques.

Publications (2)

Publication Number Publication Date
EP0500480A1 true EP0500480A1 (de) 1992-08-26
EP0500480B1 EP0500480B1 (de) 1994-12-28

Family

ID=9410128

Family Applications (1)

Application Number Title Priority Date Filing Date
EP92420053A Expired - Lifetime EP0500480B1 (de) 1991-02-21 1992-02-18 Thermofixierter Zwirn aus Kunststoffmonofilen

Country Status (6)

Country Link
US (1) US5442903A (de)
EP (1) EP0500480B1 (de)
CA (1) CA2061428A1 (de)
DE (1) DE69200975T2 (de)
FI (1) FI95288C (de)
FR (1) FR2673202B1 (de)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0741204A3 (de) * 1995-05-04 1997-07-30 Huyck Licensco Inc Presstuch für die Papierherstellung
WO2000075407A1 (de) * 1999-06-07 2000-12-14 Bayer Faser Gmbh Verfahren zur herstellung eines zwirns für technisches gewebe und papiermaschinengewebe
WO2015014574A1 (fr) 2013-07-30 2015-02-05 Compagnie Generale Des Etablissements Michelin Pneu radial à structure de ceinture allégée
WO2016124419A1 (fr) 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Pneu radial ayant une structure de ceinture très fine
WO2016124422A1 (fr) 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Pneu radial ayant une structure de ceinture ameliorée
WO2016124423A1 (fr) 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Pneu radial ayant une structure de ceinture ameliorée
WO2016124417A1 (fr) 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Pneu radial ayant une structure de ceinture améliorée
US10576787B2 (en) 2013-07-30 2020-03-03 Compagnie Generale Des Etablissements Michelin Radial tire having a lightweight belt structure

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040031534A1 (en) * 2001-12-05 2004-02-19 Sun Isle Casual Furniture, Llc Floor covering from synthetic twisted yarns
CN100478509C (zh) * 2001-12-05 2009-04-15 休闲生活世界股份有限公司 用合成的织造材料制造家具的方法
US20040168479A1 (en) * 2003-02-28 2004-09-02 Mcmurray Brian Highly resilient multifilament yarn and products made therefrom
US7472535B2 (en) 2003-11-18 2009-01-06 Casual Living Worldwide, Inc. Coreless synthetic yarns and woven articles therefrom
US7472961B2 (en) * 2003-11-18 2009-01-06 Casual Living Worldwide, Inc. Woven articles from synthetic yarns
US20050161105A1 (en) * 2004-01-22 2005-07-28 Chuen-Jong Tseng Mat
WO2010143017A1 (en) * 2009-06-10 2010-12-16 Kordsa Global Endustriyel Iplik Ve Kord Bezi Sanayi Ve Ticaret A.S Multi-ply synthetic monofilament reinforcing cords
US9447527B2 (en) * 2013-10-21 2016-09-20 Soo Hyun JEON Method for manufacturing heat resistant spun yarn and heat resistant spun yarn manufactured thereby
JP6074634B1 (ja) * 2015-07-16 2017-02-08 パナソニックIpマネジメント株式会社 電気ケーブル

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2509741A (en) * 1942-11-03 1950-05-30 Du Pont Production of filamentous structures
FR2057698A5 (de) * 1969-09-15 1971-05-21 Bobkowicz E
FR2155219A5 (de) * 1971-10-05 1973-05-18 Hollandse Signaalapparaten Bv
GB2051165A (en) * 1979-06-19 1981-01-14 Bobkowicz E Composite Yarns

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2273200A (en) * 1938-11-01 1942-02-17 Du Pont Artificial structure
GB1081089A (en) * 1963-11-19 1967-08-31 Dunlop Rubber Co Improvements in or relating to textile cord material and pneumatic tyres manufacturedtherewith
US3632646A (en) * 1967-05-25 1972-01-04 Uniroyal Inc Succinamides
US3889457A (en) * 1968-10-11 1975-06-17 Ici Ltd Macrofilamentary yarns
JPS6261805A (ja) * 1985-09-13 1987-03-18 Bridgestone Corp 重荷重用ラジアルタイヤ
US5024877A (en) * 1989-04-14 1991-06-18 The Dow Chemical Company Fire resistant materials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2509741A (en) * 1942-11-03 1950-05-30 Du Pont Production of filamentous structures
FR2057698A5 (de) * 1969-09-15 1971-05-21 Bobkowicz E
FR2155219A5 (de) * 1971-10-05 1973-05-18 Hollandse Signaalapparaten Bv
GB2051165A (en) * 1979-06-19 1981-01-14 Bobkowicz E Composite Yarns

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0741204A3 (de) * 1995-05-04 1997-07-30 Huyck Licensco Inc Presstuch für die Papierherstellung
WO2000075407A1 (de) * 1999-06-07 2000-12-14 Bayer Faser Gmbh Verfahren zur herstellung eines zwirns für technisches gewebe und papiermaschinengewebe
AU768703B2 (en) * 1999-06-07 2004-01-08 Bayer Faser Gmbh Method for producing a twisted thread for technical fabric and paper machine fabric
WO2015014574A1 (fr) 2013-07-30 2015-02-05 Compagnie Generale Des Etablissements Michelin Pneu radial à structure de ceinture allégée
US10471774B2 (en) 2013-07-30 2019-11-12 Compagnie Generale Des Etablissements Michelin Radial tire having a lightweight belt structure
US10576787B2 (en) 2013-07-30 2020-03-03 Compagnie Generale Des Etablissements Michelin Radial tire having a lightweight belt structure
WO2016124419A1 (fr) 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Pneu radial ayant une structure de ceinture très fine
WO2016124422A1 (fr) 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Pneu radial ayant une structure de ceinture ameliorée
WO2016124423A1 (fr) 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Pneu radial ayant une structure de ceinture ameliorée
WO2016124417A1 (fr) 2015-02-03 2016-08-11 Compagnie Generale Des Etablissements Michelin Pneu radial ayant une structure de ceinture améliorée
US11433709B2 (en) 2015-02-03 2022-09-06 Compagnie Generale Des Etablissements Michelin Radial tire having a very thin belt structure

Also Published As

Publication number Publication date
FR2673202A1 (fr) 1992-08-28
FR2673202B1 (fr) 1994-01-07
EP0500480B1 (de) 1994-12-28
FI95288C (fi) 1996-01-10
CA2061428A1 (fr) 1992-08-22
FI920741A0 (fi) 1992-02-20
DE69200975D1 (de) 1995-02-09
FI95288B (fi) 1995-09-29
US5442903A (en) 1995-08-22
DE69200975T2 (de) 1995-08-10
FI920741A (fi) 1992-08-22

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