EP0494920A1 - Matrice de ciment et procede de fabrication. - Google Patents

Matrice de ciment et procede de fabrication.

Info

Publication number
EP0494920A1
EP0494920A1 EP90914728A EP90914728A EP0494920A1 EP 0494920 A1 EP0494920 A1 EP 0494920A1 EP 90914728 A EP90914728 A EP 90914728A EP 90914728 A EP90914728 A EP 90914728A EP 0494920 A1 EP0494920 A1 EP 0494920A1
Authority
EP
European Patent Office
Prior art keywords
cement
additives
silicon dioxide
cement matrix
calcium hydroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP90914728A
Other languages
German (de)
English (en)
Other versions
EP0494920B1 (fr
Inventor
Manfred Pfeifer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DURAPACT GESELLSCHAFT FUER GLASFASERBETONTECHTECHN
Original Assignee
DURAPACT GESELLSCHAFT fur GLASFASERBETONTECHTECHNOLOGIE MBH
DURAPACT GLASFASERBETONTECHN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6390702&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0494920(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by DURAPACT GESELLSCHAFT fur GLASFASERBETONTECHTECHNOLOGIE MBH, DURAPACT GLASFASERBETONTECHN filed Critical DURAPACT GESELLSCHAFT fur GLASFASERBETONTECHTECHNOLOGIE MBH
Publication of EP0494920A1 publication Critical patent/EP0494920A1/fr
Application granted granted Critical
Publication of EP0494920B1 publication Critical patent/EP0494920B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60—Agents for protection against chemical, physical or biological attack
    • C04B2103/606—Agents for neutralising Ca(OH)2 liberated during cement hardening
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Definitions

  • the present invention relates to a cement matrix and its expedient manufacture, in particular for glass fiber-reinforced cement or concrete, consisting of a standard or special cement and additives in solid or liquid form for binding the calcium hydroxide formed during the hydration process.
  • glass fibers are incorporated into a cement matrix in order to increase the mechanical properties and long-term durability of the end product.
  • Cement-bound building materials have a high compressive strength.
  • thin fibers are used in relation to their length; glass fibers have particularly optimal properties.
  • only special alkaline glass fibers can be used, since normal glass fibers are immediately attacked by the cement and a great loss of strength can be determined within a short time.
  • glass fiber reinforced concrete products are exposed to free weathering, especially a warm one. wet environment, this inevitably leads to a short-term decrease in long-term durability and mechanical properties, including a significant reduction in strength properties and an almost complete loss of elongation at break.
  • the decrease in long-term stability in glass fiber reinforced concrete is mainly due to the deposit of calcium hydroxide in the spaces between the glass fiber bundles and on the individual fibers or filaments. Because of the aforementioned problems, the application or use of glass fiber reinforced materials is not possible if long-term durability is extremely important.
  • the glass fibers were also impregnated or coated with polymers and microsilica.
  • Microsilica is reactive, amorphous silicon dioxide, which can be obtained from the exhaust gases or flue gases in the production of silicon or ferrosilicon in the melting furnace. These tests were also unable to solve the problem of long-term stability satisfactorily.
  • Another disadvantage here is the additional coating process, which also leads to an increase in the cost of producing glass fiber reinforced concrete. Attempts have also been made to incorporate a material that will react with or bind to the calcium hydroxide during the hydration process. Some examples of such admixtures were fly ash and microsilica.
  • this object is achieved in that the total amount of additives is at least equivalent to the amount required to bind or react the calcium hydroxide formed during the hydration.
  • the cement matrix also has some other advantages compared to a conventional cement matrix. Due to the lack of Ca ( OH) _, this cement matrix is more resistant to weathering and has a higher efficiency in pigmentation. This means that instead of coating the roof tiles with paint as before, pigmented concrete can now be produced and used with this matrix. Above all, components colored with pigments remain color-intensive and in most cases an additional color coating can be dispensed with.
  • the matrix additive or additives can be admixed in solid and / or liquid form to the basic matrix, so that a premixed matrix is obtained, to which only water and concrete admixtures have to be added for processing.
  • reactive silicon dioxide, metakaolin, diatomaceous earth and / or pozzulan earth are contained as additives, either alone or in combination.
  • the additives can be optimally matched to the given properties of the basic matrix. If you have single or a combination of Ca (0H) ? Binding components used, it is possible to produce a cement matrix that has good processing properties in the fresh state and where all Ca (0H) _ formed is bound by the Ca (OH) binding components or is used for further reaction . Conventional filling material such as sand can also be used in this matrix.
  • the lime-binding additives must be used individually or in Combination is an equivalent to the calcium hydroxide that forms during the hydration of Portland cement, which makes up approx. 25% by weight based on the cement weight.
  • the substances SiO, (reactive), metakaolin, diatomaceous earth and pozzolana alone can achieve the desired effect. All combinations of the aforementioned substances are also possible.
  • the Ca Izi umhydroxi d (Ca (0H) _) binding components have different binding properties.
  • the Ca (0H) ? Binding capacity in% by weight is, for example, approx. 65 for metakaolin, amorphous quartz steam approx. 45, blast furnace slag approx. 6 and fly ash approx. 12.
  • Ca (0H) is formed ? (based on the cement weight).
  • the invention provides for the use of several Ca ( 0H ) 2 binding components.
  • Blast furnace slag has also proven to be a favorable binding component (Ca).
  • the amount of blast furnace slag required is between 35 and 80 % Weight weight (measured by cement weight). It is possible to add this blast furnace slag during the production of the standard cement. This type of cement is called Hoc oven cement and is commercially available.
  • the other Ca (0H) ? Binding component is added in the amount required to bind all of the Ca (0H) _ during the hydration process.
  • reactive silicon dioxide is used in an amount between 50 - 90% (based on port land cement), the other additives form individually or in combination the required residual amount of calcium hydroxide binding substances. This good results have been very achieved and there were excellent results are achieved with al 'len known cements.
  • the object of the invention is achieved in that the reactive silicon dioxide used as an additive is obtained from the flue gases of a melting furnace in the silicon or ferrosilic medium, whereby silicon dioxide is reduced and the reduction product in air during the
  • the main chemical constituent of the amorphous quartz vapor is Si l i c i mdi oxi d, which is generally present at 85% by weight.
  • the material is amorphous and has a density of 2.10 - 2.60 g / cm and the specific surface is 15 - 25 m / g.
  • Particles are highly spherical (spherical) with 90% by weight the main particles are less than 1 micron in size.
  • S i L ici product is commercially available.
  • a blast furnace cement consisting of 50% blast furnace slag and 50% Portland cement was used for this example.
  • the Ca lc i umantei L of the blast furnace cement was about 49% by weight, this corresponds to 12.5% Ca (0H) _ based on the cement weight.
  • the matrix mixture was composed as follows: 20% reactive silicon dioxide from the flue gases in the melting furnace at the silicon or
  • Ferrosi L i ci, 60% fly ash and 100% quartz sand were added to the cement in the dry state. All% figures are based on the weight of the blast furnace cement.
  • the dry ingredients were mixed with a conventional mixer for about 30 seconds.
  • a sulfonated condensate of melamine and methanal with 3% by weight of the cement is added as a drainage agent (water-reducing agent), together with the amount of water required to achieve a water / cement ratio of 0.50.
  • test samples with a Ika li resistant glass fibers were produced according to the following procedure: In a mold with the dimensions length 1000 mm, width 60 mm, height 10 mm was a 0.5 mm poured thick layer of the matrix described above.
  • a spliced glass grate (glass fiber rang) with a width of 60 mm was placed on it.
  • a very thin layer of the matrix was poured onto it, just enough to cover the fibers.
  • a second glass fiber roving was placed.
  • the process was repeated until four fiber optic layers were embedded in the matrix.
  • the total thickness of the four layers of glass fiber could not be more than 1 mm.
  • the mold was then filled with matrix mass.
  • the test samples were removed from the mold after 24 hours and cured in a water bath at 20 degrees Celsius for 28 days.
  • the samples were subjected to an accelerated aging process in a water bath at 80 degrees Celsius for 1, 3, 7 and 14 days. After this process, the test specimens were examined for flexural strength using the conventional four-point flexural strength test. It was clearly shown that there was no reduction in the test.
  • a blast furnace cement consisting of 70% blast furnace paints and 30% Portland cement (weight) was used for this example.
  • the ca lci umante i L of the blast furnace cement was approx. 51%, this corresponds to 6.3% Ca (0H) ? based on the cement weight.
  • the matrix mixture was composed as follows: 20% reactive silicon dioxide from the flue gases in silicon or ferrosilicon production and 150% quartz sand are added to the cement in the dry state. It is also expedient to add 5% metakaolin. All% figures are based on the weight of blast furnace cement.
  • the dry ingredients were mixed with a. conventional mixer mixed for approx. 30 seconds.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Materials For Medical Uses (AREA)
  • Glass Compositions (AREA)
  • Saccharide Compounds (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

L'invention concerne une matrice de ciment et sa fabrication appropriée, particulièrement pour du ciment ou du béton renforcés par fibres de verre, consistant en un ciment standard ou spécial et additifs sous forme solide ou liquide pour lier l'hydroxyde de calcium se formant par processus d'hydratation. Un additif particulièrement avantageux est le dioxyde de silicium réactif, récupéré sur les fumées gazeuses lors de la fabrication de silicium ou de ferro-silicium, où le dioxyde de silicium est d'abord réduit et le produit de réduction est ensuite oxydé à l'air. La quantité totale d'additifs doit être au moins équivalente à la quantité nécessaire et indispensable pour lier l'ensemble de l'hydroxyde de calcium formé par hydratation ou provoquer une réaction. Les autres additifs en-dehors du dioxyde de silicium réactif sont le métakaolin, la terre à diatomées, la pouzzolane, le laitier du haut-fourneau et la suie ou leur combinaison.
EP19900914728 1989-09-30 1990-09-26 Matrice de ciment et procede de fabrication Expired - Lifetime EP0494920B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19893932908 DE3932908C2 (de) 1989-09-30 1989-09-30 Glasfaserverstärkter Zement oder Beton
DE3932908 1989-09-30
PCT/EP1990/001627 WO1991004953A1 (fr) 1989-09-30 1990-09-26 Matrice de ciment et procede de fabrication

Publications (2)

Publication Number Publication Date
EP0494920A1 true EP0494920A1 (fr) 1992-07-22
EP0494920B1 EP0494920B1 (fr) 1994-12-07

Family

ID=6390702

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19900914728 Expired - Lifetime EP0494920B1 (fr) 1989-09-30 1990-09-26 Matrice de ciment et procede de fabrication

Country Status (10)

Country Link
EP (1) EP0494920B1 (fr)
JP (1) JPH05500497A (fr)
KR (1) KR0160943B1 (fr)
AT (1) ATE115100T1 (fr)
AU (1) AU6517390A (fr)
BR (1) BR9007696A (fr)
DE (2) DE3932908C2 (fr)
DK (1) DK0494920T3 (fr)
ES (1) ES2066229T3 (fr)
WO (1) WO1991004953A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4208047C1 (de) * 1992-03-13 1993-11-11 Buderus Guss Gmbh Mörtelmischung zur Umhüllung von metallischen Rohren und Formstücken
DE4433815A1 (de) * 1994-09-22 1996-03-28 Zueblin Ag Verbundwerkstoff
DE19600445A1 (de) * 1996-01-09 1997-07-10 Wester Mineralien Gmbh Homogene ungehärtete Zusammensetzung auf Basis Zement
AT404588B (de) * 1996-07-19 1998-12-28 Wimberger Franz Dämmstoff und verfahren zu seiner herstellung
DE19947302A1 (de) * 1999-09-18 2001-03-22 Zueblin Ag Werkstoff für den konstruktiven Ingenieurbau zur Abschirmung radioaktiver Stra hlung
US6709510B1 (en) 2002-11-19 2004-03-23 Texas Industries, Inc. Process for using mill scale in cement clinker production
DE102005031321B3 (de) * 2005-07-05 2007-03-08 Erlus Aktiengesellschaft Kaminabdeckplatte aus Feinbeton

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3880664A (en) * 1971-08-05 1975-04-29 Herbert C Schulze Method for extrusion
US3834916A (en) * 1972-03-23 1974-09-10 Steel Corp Fiber-reinforced cement composite
GB1421556A (en) * 1973-03-13 1976-01-21 Tac Construction Materials Ltd Board products
DE2634674A1 (de) * 1976-08-02 1978-02-09 Heinz Hoelter Fuellstoff zum verbessern der mechanischen abriebfestigkeit und/oder waermebestaendigkeit, insbesondere der feuerfestigkeit und/oder temperaturwechselbestaendigkeit und/oder der waermedaemmung und/oder der schalldaemmung und/oder der elektrischen isoliereigenschaften und/oder verarbeitbarkeit von massen, insbesondere baumassen, und/oder anstrichen und dergleichen
RO72773B (ro) * 1976-07-09 1984-03-31 Aksjeselskapet Norcem Procedeu de obtinere a unor compozitii de betoane rezistente la coroziune
US4090884A (en) * 1976-07-16 1978-05-23 W. R. Bonsal Company Inhibitors for alkali-glass reactions in glass fiber reinforced cement products
DE2801687A1 (de) * 1978-01-16 1979-07-19 Bautrans Finanz Ag Flugasche enthaltendes bindemittel und daraus hergestellter beton bzw. daraus hergestellte betonfertigteile
WO1981000252A1 (fr) * 1979-07-13 1981-02-05 Aalborg Portland Cement Materiau composite renforce avec des fibres et articles formes
YU43293B (en) * 1983-01-10 1989-06-30 Kemijski Instboris Kidric Process for the manufacture of light-weight insulating and constructional elements from amorphous silica, obtained in the production of ferrosilicium
US4504320A (en) * 1983-09-26 1985-03-12 Research One Limited Partnership Light-weight cementitious product
FR2575744B1 (fr) * 1985-01-10 1991-10-25 Inst Nat Sciences Appliq Lyon Materiau composite pour la construction a base de pouzzolanes de synthese, et procede de fabrication
FR2601356B1 (fr) * 1986-07-10 1992-06-05 Saint Gobain Vetrotex Produit a base de ciment arme de fibres de verre.
US4741777A (en) * 1986-07-15 1988-05-03 Rockwall-Peerless Corp., Stucco And Mortar Products Dry mix for high workability stuccos and mortars
DE3641370A1 (de) * 1986-12-04 1988-06-09 Fraunhofer Ges Forschung Dauerbestaendige baustoff-formteile
DE3818774C2 (de) * 1987-06-04 1993-11-18 Wethmar Herbert Dipl Kaufm Hydraulisch abbindende Baustoffmischung und deren Verwendung
US4842649A (en) * 1987-10-02 1989-06-27 Pyrament, Inc. Cement composition curable at low temperatures

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Title
See references of WO9104953A1 *

Also Published As

Publication number Publication date
WO1991004953A1 (fr) 1991-04-18
JPH05500497A (ja) 1993-02-04
DE3932908A1 (de) 1991-04-11
BR9007696A (pt) 1992-09-01
ATE115100T1 (de) 1994-12-15
DK0494920T3 (da) 1995-05-15
DE3932908C2 (de) 1998-09-10
KR927003469A (ko) 1992-12-18
DE59007956D1 (de) 1995-01-19
ES2066229T3 (es) 1995-03-01
EP0494920B1 (fr) 1994-12-07
AU6517390A (en) 1991-04-28
KR0160943B1 (ko) 1998-11-16

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