Classifications

• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
  • G03C1/00—Photosensitive materials
• • G—PHYSICS
  • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
  • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
  • G03C1/00—Photosensitive materials
  • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
  • G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
  • G03C1/83—Organic dyestuffs therefor

Definitions

• This invention relates in general to photography and specifically to photographic elements that can be handled under a radiation source without requiring packaging in a dark container.
• Photographic elements exhibit sensitivity to a wide variety of light and radiation wavelengths.
• Elements based on silver halides for example have a natural or intrinsic sensitivity to blue light.
• Silver halide can also be sensitive to other wavelengths, ranging from X-rays, ultraviolet, various portions of the visible spectrum, and infrared radiation. This can be accomplished through various known means, such as varying the halide content (e.g., silver chloride is primarily sensitive to ultraviolet radiation) or through the use of various spectral sensitizing dyes.
• dark handling can be satisfied in a number of ways, such as darkroom handling, packaging the element in a light-sealed cassette or other container, and safelight handling, where the wavelength of the safelight is selected so as to not overlap with the sensitivity of the element.
• darkroom handling is cumbersome, time-consuming, expensive, and subject to exposure of the element if the darkroom is dark conditions of the room are compromised.
• Cassettes and containers are expensive, difficult to prepare, require a mechanism for allowing the element to be exposed at the right time and place, and are subject to failure if not properly sealed to light.
• Safelights can also be useful, but their feasibility depends on a photographic element having little or no spectral sensitivity in the range of light emitted by the safelight. Since many sensitizing dyes sensitize silver halide in regions of the spectrum in addition to that for which they are intended, the feasibility of using safelights is often quite limited. Also, safelights must be used in conjunction with a darkroom to be effective.
• the reference discusses the absorbance properties of the dyes and their suitability for antihalation use, but no teaching whatsoever is presented that the dyes might be useful at the levels required for white light or safelight protection nor is there any teaching as to what other dyes might possess the beneficial solubility properties of being aqueous-insoluble at coating pH's and highly aqueous-soluble at processing pH's. There is also no teaching that would enable anyone as to how to choose dyes other than those specifically disclosed in the U.S. Patent 4,092,168 to obtain those properties.
• dye dispersions useful in the invention are the dispersions of prior art dyes and obvious variations thereof known to be used as solid particle dispersions.
• These dyes have the formula: where R1 and R3 each independently represents an alkyl group or an aryl group, R2 and R4 each independently represents an alkyl group, an aryl group, or COOR where R is alkyl or aryl, m is 0 to 3, and the molecule contains at least two carboxyl groups in their free acid form and further contains no solubilizing groups.
• dyes of formula (I) will be substantially insoluble at pH's of 6 or below and substantially soluble at pH's of 8 or above when X has a pKa in a 50/50 mixture (volume basis) of ethanol and water of from 4 to 11 and when the nonionized (neutral) dye has a log partition coefficient (log P) of from 0 to 6.
• Such an element is intended for handling under a first radiation source (e.g., white light or a safe light) and imagewise exposure to a second radiation source (e.g., flash exposure source).
• the element comprises a support having thereon a radiation-sensitive layer that is sensitive to at least a portion of the region of the spectrum of radiation emitted by the first radiation source and a portion of the region of the spectrum of radiation emitted by the second radiation source.
• the element has a layer comprising a vehicle and at least one solid particle dispersion filter dye as described above that absorbs in the wavelength region emitted by the first source and to which the radiation-sensitive layer is sensitive.
• the dye is present in an amount sufficient to prevent formation in the radiation-sensitive layer of a developable latent image from exposure to the first radiation source.
• the elements of the invention utilizing the above-described solid particle dispersion filter dyes provide effective white light or safelight protection, do not suffer from dye wandering, and the filter dyes are removed and/or decolorized during photographic processing.
• the elements of the invention also allow for the use of filter dyes to provide white light or safelight protection in a number of situations or with sensitizing dyes having broad sensitization spectra, e.g., white light handleable infrared-sensitive elements, green safelight-handleable red-sensitive elements, or red or yellow safelight-handleable blue-sensitive elements, where they have not been used before.
• the chromophoric radiation-absorbing moiety, D, of formula (I) can be any of a number of well-known dye compounds. These include cyanines, merocyanines, oxonols, arylidenes (i.e., merostyryls), anthraquinones, triphenylmethanes, azo dye types, azomethines, and others.
• the specific dye used is not critical, as long as all the criteria of formula (I) are met. These dyes are commonly used in the photographic art, and are more fully described in James, The Theory of the Photographic Process , 4th, Macmillan, New York (1977) and Hamer, The Cyanine Dyes and Related Compounds , Interscience (1964).
• the cyanine dyes include, joined by a methine linkage, two basic heterocyclic nuclei, such as those derived from quinolinium, pyridinium, isoquinolinium, 3H-indolium, benzindolium, oxazolium, thiazolium, selenazolinium, imidazolium, benzoxazolinium, benzothiazolium, benzoselenazolium, benzimidazolium, naphthoxazolium, naphthothiazolium, naphthoselenazolium, thiazolinium dihydronaphthothiazolium, pyrylium, and imidazopyrazinium quaternary salts.
• two basic heterocyclic nuclei such as those derived from quinolinium, pyridinium, isoquinolinium, 3H-indolium, benzindolium, oxazolium, thiazolium, selenazo
• the merocyanine dyes include, joined by a methine linkage, a basic heterocyclic nucleus of the cyanine dye type and an acidic nucleus, such as can be derived from barbituric acid, 2-thiobarbituric acid, rhodanine, hydantoin, 2-thiohydantoin, 4-thiohydantoin, 2-pyrazolin-5-one, 2-isoxazolin-­5-one, indan-1,3-dione, cyclohexan-1,3-dione, 1,3-dioxan-4,6-dione, pyrazolin-3,5-dione, pentan-2,4-dione, alkylsulfonyl acetonitrile, malononitrile, isoquinolin-4-one, and chroman-2,4-dione.
• an acidic nucleus such as can be derived from barbituric acid, 2-thiobarbituri
• the oxonol dyes include, joined by a methine or bridged methine linkage, two acidic carbo- or heterocyclic nuclei, such as those described above for merocyanine dyes, with the exclusion of 2-pyrazolin-5-one.
• the arylidene dyes include, joined by a methine or bridged methine linkage, an acidic nucleus as described previously and an aryl group, substituted with electron-donating substituents, such as alkyl- or dialkylamino, methoxy, and the like.
• the anthraquinone dyes include those compounds derived from the anthraquinone nucleus and substituted with electron donating or electron withdrawing groups so as to extend the chromophoric nature of the compound.
• triphenylmethane dyes include those compounds with three aryl groups joined to a single methine linkage and substituted with suitable electron-donating or electron-withdrawing substituents so as to produce an extended chromophoric system.
• the azo dyes include any of a large class of compounds with two nitrogens in the linkage between multiply-substituted aryl groups, as is known in the art.
• the azomethine dyes include, joined by a single nitrogen in the unsaturated linkage, an acidic nucleus as described previously for the merocyanine dyes, and an aryl group substituted with electron-donating substituents such as alkyl- or dialkylamino, methoxy, and the like.
• the aromatic ring (A or an aromatic ring, to which X is attached, that is part of D) of formula (I) can be any aromatic ring capable of bonding with D and X in a manner such that the proper pKa and log P are achieved.
• Examples of such rings include phenyl, naphthyl, anthracenyl, pyridyl, acenaphthyl, dihydronaphthyl, and pyrimidyl.
• the aromatic ring A if present, may be bonded directly to D or indirectly (i.e., through a divalent linking group, such as alkyl, as is known in the art) to D.
• the substituent, X, of formula (I) having an ionizable proton with a pKa in a 50/50 mixture (volume basis) of ethanol and water of from 4 to 11, when attached to the aromatic ring of formula (I), can be easily chosen by one skilled in the art.
• Especially preferred substituents are carboxyl and sulfonamido (e.g., NHSO2R where R is a substituted or unsubstituted alkyl group of from 1 to 6 carbon atoms).
• the pKa of the compounds of formula (I) in a 50/50 mixture (volume basis) of ethanol and water is preferably from 4 to 11.
• the pKa parameter is a well-known measurement of the dissociation constant of an ionizable compound in aqueous environments. It is discussed in most basic chemistry texts and does not require further explanation here.
• the log partition coefficient (log P) of the unionized (i.e., neutral) compounds of formula (I) is preferably from 0 to 6.
• the log P parameter is a well-known measurement of the solubility of a compound in aqueous liquids compared to its solubility in nonpolar organic solvents. The log P parameter is further described, along with log P data for organic compounds, in C. Hansch & T.
• the radiation-sensitive layer of the element of the invention is sensitive to at least a portion of the region of the spectrum of radiation emitted by the first radiation source and a portion of the region of the spectrum of radiation emitted by the second radiation source. In most situations, these will be different regions of the spectrum, although it is contemplated that the invention would cover elements where the two regions overlap to some extent. In such a situation, the second radiation source is preferably of a higher intensity than the first radiation source.
• the intensity of the two radiation sources, the sensitivity of the radiation-sensitive layer, and the amount of dye would be balanced so that the dye would absorb enough radiation to prevent latent image formation caused by the first radiation source but allow latent image formation by the second more intense radiation source to be used for imagewise exposure. Such a balancing is within the skill of the art.
• One such element is an infrared-­sensitive element that is handleable under a first source such as daylight or room light that emits some radiation between 350 and 700 nm, yet can be imagewise exposed by a second radiation source that is an infrared radiation source, such as an infrared laser.
• a first source such as daylight or room light that emits some radiation between 350 and 700 nm
• a second radiation source such as an infrared radiation source
• Such lasers are known in the art and generally utilize diodes that emit somewhere in the region of 700 to 900 nm.
• One common emission wavelength is around 800 nm and other typical emission wavelengths are around 750, 780, 820, and 870 nm.
• a preferred infrared-sensitive element according to the invention has a radiation-sensitive layer that is sensitive to some radiation between 350 and 900 nm.
• the first source emits some radiation between 350 and 700 nm, it need not emit radiation across the entire range of 350 to 700 nm; rather, it need only emit radiation at some point(s) or region(s) within that range.
• the second source need not emit radiation across the entire range of 700 to 900 nm. It only needs to emit radiation at some point(s) or region(s) within that range.
• the radiation-sensitive layer need not be sensitive to all radiation within the 350 to 900 nm range.
• the various elements, sources, and dyes used in accordance with the invention may also have sensitivity, emit, or absorb in regions outside the specified ranges as long as they also have sensitivity, emit, or absorb at some point(s) or region(s) within the specified range so as to fall within the scope of the invention.
• the filter dye absorbs radiation at some point(s) or region(s) in the 350 to 700 nm range, subject to the basic requirement of the invention that it absorb in the wavelength region emitted by the first source and to which the radiation-sensitive layer is sensitive.
• A1, A2, and A3 are each independently a ketomethylene nucleus.
• This class of chemical groups is well-known in the art as described, for example, in the above-referenced Hamer, The Cyanine Dyes and Related Compounds, pp. 469-494, 595-604 (1964).
• ketomethylene residues examples include benzoyl acetonitrile, 2-pyrazolin-5-one, pyrazolindione, a barbituric acid nucleus, rhodanine, indanedione, isoxazolinone, benzofuranone, chromandione, cyclohexanedione, dioxanedione, furanone, isoxazolidindione, pyrandione, and pyrrolinone.
• R1 and R2 are each independently substituted or unsubstituted alkyl, preferably of from 1 to 6 carbon atoms, or substituted or unsubstituted aryl, preferably from 6 to 14 carbon atoms.
• R1 and R2 may also represent the carbon atoms necessary to form a fused ring with the phenyl ring to which the N atom is attached, for example, in a dye having the formula:
• R3 is hydrogen, substituted or unsubstituted alkyl, preferably from 1 to 6 carbon atoms, or substituted or unsubstituted aryl, preferably from 6 to 14 carbon atoms.
• R3 include methyl, ethyl, propyl, butyl, isopropyl, t -butyl, tolyl, and phenyl.
• R4 is substituted or unsubstituted alkyl, preferably of from 1 to 15 carbon atoms.
• R4 include ethyl, propyl, methoxyethyl, benzyl, 4-carboxybenzyl, and ethoxyethoxyethyl.
• R5 is substituted or unsubstituted alkyl, preferably of from 1 to 6 carbon atoms, or substituted or unsubstituted aryl, preferably of from 6 to 12 carbon atoms.
• R5 include methyl, ethyl, propyl, hexyl, phenyl, and tolyl.
• the R groups and the L groups described above may be substituted with any of a number of known substituents, as long as they do not adversely effect the solubility properties of the dye compound.
• the effect on dye solubility can be determined by one of ordinary skill in the art by determining the effect on the log P of the compound, which is preferably between 0 and 6.
• Useful substituents include halogen (e.g., chloro, fluoro), alkoxy (e.g., methoxy, ethoxy), amino (e.g., dimethylamino, diethylamino), alkylcarboxy (e.g., ethoxycarbonyl, isopropoxycarbonyl), and acyl (e.g., carbamoyl, acetyl).
• halogen e.g., chloro, fluoro
• alkoxy e.g., methoxy, ethoxy
• amino e.g., dimethylamino, diethylamino
• alkylcarboxy e.g., ethoxycarbonyl, isopropoxycarbonyl
• acyl e.g., carbamoyl, acetyl
• Z represents the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered heterocyclic nucleus.
• the heterocyclic nucleus is of the type commonly used in cyanine dyes, and is well-known in the art. They are described, for example, in the above-incorporated James and Hamer references.
• Examples of such heterocyclic nuclei include thiazole, selenazole, oxazole, imidazole, indole, benzothiazole, benzoselenazole, benzoxazole, benzimidazole, benzindole, naphthothiazole, naphthoselenazole, naphthoxazole, and naphthimidazole.
• the nucleus may be substituted with known substituents, such as substituted or unsubstituted alkyl of from 1 to 10 carbon atoms (e.g., methyl, ethyl, 3-chloropropyl), alkoxy of from 1 to 8 carbon atoms (e.g. methoxy, ethoxy), halogen (e.g., chloro, fluoro), substituted or unsubstituted aryl of from 6 to 20 carbon atoms (e.g., phenyl), or with carbon atoms form a fused ring system (e.g., with a benzothiazole nucleus or a naphthothiazole nucleus).
• substituents such as substituted or unsubstituted alkyl of from 1 to 10 carbon atoms (e.g., methyl, ethyl, 3-chloropropyl), alkoxy of from 1 to 8 carbon atoms (e.g. methoxy, eth
• dyes according to formula (II) include:
• dyes according to formula (III) include:
• Another element according to the invention is a blue light-sensitive element that is handleable under a first source such as a red safelight that emits some radiation between 560 and 700 nm, yet can be imagewise exposed by a second radiation source that emits somewhere in the region of 400 to 520 nm.
• a second radiation source is an argon ion laser, which emits at around 488 nm.
• the radiation-sensitive layer of this element preferably is sensitive to some radiation from 350 and 700 nm.
• the filter dye absorbs radiation at some point(s) or region(s) in the 540 to 700 nm range, subject to the basic requirement of the invention that it absorb in the wavelength region emitted by the first source and to which the radiation-sensitive layer is sensitive.
• Such a filter dye preferably comprises a solid particle dispersion of a dye according to the formula (V): wherein A4 is a ketomethylene residue, L8, L9, L10, and L11 are each independently a substituted or unsubstituted methine group, R6 is substituted or unsubstituted alkyl, Z′ represents the atoms necessary to complete a substituted or unsubstituted 5- or 6-membered heterocyclic nucleus, at least one of A4, Z′, and R6 is substituted with -X4, and -X4 is -CO2H or -NHSO2R7, wherein R7 is substituted or unsubstituted alkyl or substituted or unsubstituted aryl.
• V solid particle dispersion of a dye according to the formula (V): wherein A4 is a ketomethylene residue, L8, L9, L10, and L11 are each independently a substituted or unsubstituted methine group, R6
• dyes according to formula (IV) include:
• Another element according to the invention is a blue light-sensitive element that is handleable under a first source such as a safelight that emits some radiation between 450 and 570 nm, yet can be imagewise exposed by a second radiation source, such as a helium-neon laser, that emits somewhere in the region of 600 to 700 nm.
• a first source such as a safelight that emits some radiation between 450 and 570 nm
• a second radiation source such as a helium-neon laser
• the filter dye absorbs radiation at some point(s) or region(s) in the 450 to 590 nm range, subject to the basic requirement of the invention that it absorb in the wavelength region emitted by the first source and to which the radiation-sensitive layer is sensitive.
• dyes according to formula (VI) include:
• dyes according to formula (VII) include:
• Another element according to the invention is a photographic element that is sensitive to radiation from 350 to 600 nm and handleable under a first source such as a blue safelight that emits radiation between 400 and 510 nm, yet can be imagewise exposed by a second radiation source that emits in the region of 510 to 600 nm.
• the radiation-sensitive layer of this element preferably sensitive in the range of from 350 and 600 nm.
• the filter dye absorbs radiation at some point(s) or region(s) in the 350 to 500 nm range, subject to the basic requirement of the invention that it absorb in the wavelength region emitted by the first source and to which the radiation-sensitive layer is sensitive.
• Such a filter dye preferably comprises a solid particle dispersion of a dye according to the formula (VIII): or a dye according to the formula (IX): where A8 and A9 are as defined above for A1, A2, and A3, R11, R12, R13, and R14 are as defined above for R4, R1, R2, and R3, respectively, L13, L14, and L15 are as defined above for L1-L7, Z ⁇ is as defined above for Z, at least one of A8, Z ⁇ , and R12 is substituted with -X8 and at least one of A9 and R14 is substituted with -X9, and -X8 and -X9 are as defined above for -X1, -X2, and -X3.
• dyes according to formula (VIII) include:
• Example of dyes according to formula (IX) include:
• the dyes of formula (I) can be prepared by synthetic techniques well-known in the art. Such techniques are further illustrated, for example, in "The Cyanine Dyes and Related Compounds” , Frances Hamer, Interscience Publishers, 1964.
• the dye compounds of formula (I) are utilized in the form of a solid particle dispersion (i.e., the dye is in the form of solid particles of microscopic size).
• the dispersion can be in any vehicle in which the dye is not soluble, such as an aqueous liquid having a pH low enough for the dye to be insoluble (e.g., a gelatin coating solution), an organic solvent in which the dye is insoluble, a monomer, or a polymeric binder.
• the dispersion is useful for incorporation into a layer having a polymeric film-forming binder known in the art (e.g., a hydrophilic colloid binder) a photographic element.
• the dyes may be located in any layer of the element where it will be between the radiation sensitive layer and the first radiation source. Examples of such layer arrangements include:
• layer arrangements are intended to show the relative positions of the support, radiation-sensitive layer, and filter dye layers according to the invention.
• Other layers may, such as antihalation layers, interlayers, protective overcoat layers, subbing layers, and the like may be included anywhere that they are useful in the above-exemplified layer arrangements without disturbing the relative positions of the layers shown.
• the dye should be present in an amount sufficient to prevent formation in the radiation-sensitive layer of a developable latent image from exposure to the first radiation source.
• the formation of a latent image is described in James, The Theory of the Photographic Process , 4th ed., ch. 6, Macmillan Publishing Co, 1977.
• the dye is preferably present in an amount sufficient so that the maximum density of the dye in the wavelength region emitted by the first source and to which the radiation-sensitive layer is sensitive is at least 0.3. This optical density will generally be less than 10 density units for most photographic applications.
• Useful amounts of dye in the present in the filter dye layers of the element of the invention range from 0.1 to 100 mg/ft2.
• the solid particle dispersion can be formed by precipitating or by reprecipitating the dye in the form of a dispersion and/or by well-known milling techniques, e.g., ball-milling, sand-milling, or colloid-milling the solid dye in the presence of a dispersing agent. Reprecipitating techniques by dissolving the dye and precipitating by changing the solvent and/or the pH of the solution in the presence of a surfactant are well-known in the art. Milling techniques are well-known in the art and are described, for example in U.S. Patent 4,006,025.
• the dye particles in the dispersion should have a mean diameter of less than 10 ⁇ m and preferably less than 1 ⁇ m.
• the dye particles can be prepared in sizes ranging down to 0.01 ⁇ m.
• the radiation-sensitive layer of the element of the invention can contain any of the known radiation-sensitive materials, such as silver halide, diazo image-forming systems, light-sensitive tellurium-containing compounds, light-sensitive cobalt-containing compounds, and others described in, for example, J. Kosar, Light-Sensitive Systems: Chemistry and Application of Nonsilver Halide Photographic Processes, J. Wiley & Sons, N.Y. (1965).
• known radiation-sensitive materials such as silver halide, diazo image-forming systems, light-sensitive tellurium-containing compounds, light-sensitive cobalt-containing compounds, and others described in, for example, J. Kosar, Light-Sensitive Systems: Chemistry and Application of Nonsilver Halide Photographic Processes, J. Wiley & Sons, N.Y. (1965).
• Silver halide is especially preferred as a radiation-sensitive material.
• Silver halide emulsions can contain, for example, silver bromide, silver chloride, silver iodide, silver chlorobromide, silver chloroiodide, silver bromoiodide, or mixtures thereof.
• the emulsions can include coarse, medium, or fine silver halide grains bounded by 100, 111, or 110 crystal planes.
• Silver halide emulsions and their preparation are further described in Research Disclosure , Section I. Also useful are tabular grain silver halide emulsions, as described in Research Disclosure , January, 1983, Item 22534 and U.S. Patent 4,425,426.
• the radiation-sensitive materials described above can be sensitized to the desired wavelength range of radiation, such as the red, blue, or green portions of the visible spectrum, or to other wavelength ranges, such as ultraviolet, infrared, X-ray, and the like.
• Sensitization of silver halide can be accomplished with chemical sensitizers such as gold compounds, iridium compounds, or other group VIII metal compounds, or with spectral sensitizing dyes such as cyanine dyes, merocyanine dyes, styryls, or other known spectral sensitizers. Additional information on sensitization of silver halide is described in Research Disclosure , Sections I-IV.
• the element of the invention can advantageously utilize radiation-sensitive silver halide materials that include low intensity reciprocity failure inducers to enhance white-light handleability, as described in U.S. Patent 4,472,497.
• the support of the element of the invention can be any of a number of well-known supports for photographic elements. These include polymeric films such as cellulose esters (e.g., cellulose triacetate and diacetate) and polyesters of dibasic aromatic carboxylic acids with divalent alcohols (e.g., poly(ethylene terephthalate)), paper, and polymer-­coated paper. Such supports are described in further detail in Research Disclosure , December, 1978, Item 17643 [hereinafter referred to as Research Disclosure ], Section XVII.
• the element of the invention can also include any of a number of other well-known additives and layers, as described in Research Disclosure . These include, for example, optical brighteners, antifoggants, image stabilizers, light-absorbing materials such as filter layers or intergrain absorbers, light-scattering materials, gelatin hardeners, coating aids and various surfactants, overcoat layers, interlayers and barrier layers, antistatic layers, plasticizers and lubricants, matting agents, development inhibitor-releasing couplers, bleach accelerator-releasing couplers, and other additives and layers known in the art.
• the layer containing the dye of formula (I) can be located in various locations of the photographic element, as described above.
• the dye is preferably located in a layer where it will be subjected to high pH (i.e., 8 to 12) and/or sulfite during photographic processing, so as to allow the dye to be solubilized and removed or decolorized .
• the photographic elements of the invention when exposed, can be processed to yield an image.
• the dye of formula (I) will generally be decolorized and/or removed.
• the dye of the invention should contribute less than 0.10 density unit, and preferably less than 0.02 density unit to the transmission D-max in the visible region in the minimum density areas of the exposed and processed element.
• Processing can be by any type of known photographic processing, as described in Research Disclosure , Sections XIX-XXIV, although it preferably includes a high pH (i.e., 8 or above) step utilizing an aqueous sulfite solution in order to maximize decolorization and removal of the dye.
• a negative image can be developed by color development with a chromogenic developing agent followed by bleaching and fixing.
• a positive image can be developed by first developing with a non-chromogenic developer, then uniformly fogging the element, and then developing with a chromogenic developer. If the material does not contain a color-forming coupler compound, dye images can be produced by incorporating a coupler in the developer solutions.
• Bleaching and fixing can be performed with any of the materials known to be used for that purpose.
• Bleach baths generally comprise an aqueous solution of an oxidizing agent such as water soluble salts and complexes of iron (III) (e.g., potassium ferricyanide, ferric chloride, ammonium of potassium salts of ferric ethylenediaminetetraacetic acid), water-soluble persulfates (e.g., potassium, sodium, or ammonium persulfate), water-soluble dichromates (e.g., potassium, sodium, and lithium dichromate), and the like.
• an oxidizing agent such as water soluble salts and complexes of iron (III) (e.g., potassium ferricyanide, ferric chloride, ammonium of potassium salts of ferric ethylenediaminetetraacetic acid), water-soluble persulfates (e.g., potassium, sodium, or ammonium persulfate), water-soluble dichromates (e.g., potassium
• Fixing baths generally comprise an aqueous solution of compounds that form soluble salts with silver ions, such as sodium thiosulfate, ammonium thiosulfate, potassium thiocyanate, sodium thiocyanate, thiourea, and the like.
• a pelloid layer comprising 20 mg/ft2 of a soluble green-absorbing filter dye having the formula: 5 mg/ft2 of a soluble infrared-absorbing dye having the formula: 400 mg/ft2 of gel, and 8 mg/ft2 of bis(vinyl sulfone methyl ether) (BVSME) hardener was coated on a poly(ethylene terephthalate) film support.
• a soluble green-absorbing filter dye having the formula: 5 mg/ft2 of a soluble infrared-absorbing dye having the formula: 400 mg/ft2 of gel
• BVSME bis(vinyl sulfone methyl ether)
• the emulsion contained a 0.27 micron rhodium doped cubic AgCl70 Br30 emulsion that was sulfur plus gold sensitized and doctored with 500 mg/mole Ag of 4,4′bis[(4,6-bis-o-chloroanilino-s-triazine-2-yl)­amino]-2,2′stilbene disulfonic acid disodium salt, and spectrally sensitized to infrared radiation with 0.03 millimoles/mole Ag of a dye of the formula:
• emulsions 100 mg/mole Ag of 1-(3-acetamidophenyl)-5-­mercaptotetrazole and 1000 mg/mole Ag of 5-carboxy-4-hydroxy-6-methyl-2-methylmercapto-­1,3,3a,7-tetraazindene.
• This emulsion was coated at a silver coverage level of 400 mg/ft2. and a gel coverage of 400 mg/ft2
• the emulsion layer was overcoated with a solid particle dispersion filter dye layer adjusted to a pH of 5.2 containing a solid particle dispersion having a mean particle size of about 0.5 ⁇ m of dye 16 at a level of 10 mg/ft2.
• the filter dye layer also contained 0.7 mg/ft2 of a soluble infrared-­absorbing dye of the formula: as a sharpness-improving intergrain absorber dye.
• a green light source was constructed by wrapping sheets of dye coatings around a 4ft. cool white fluorescent lamp.
• the dye coatings had optical densities of greater than 3 at wavelengths below 500 nm and between 580nm and 860nm.
• the minimum density of 1.8 was at a wavelength of 540nm.
• the elements were then developed for 30 seconds at 105°F in a developer containing hydroquinone and sulfite and having a pH of 10.35.
• the densities recorded were measured with a densitometer.
• the log speed to infrared at a D-min+1.0 was 1.38 for the comparison element and 1. 41 for the element of the invention, indicating no desensitization from any dye wandering of the solid particle dispersion filter dye.
• the observed neutral density from the fogging test was 1.03 for the comparison element whereas the element of the invention showed no measurable fog over the 0.05 background D-min of the element.
• Most of the solid particle dispersion filter dye was removed or decolorized during processing, leaving a D-min to green light of 0.10 as compared to 0.10 for the undyed comparison element.
• the element of the invention provided effective safelight handleability, with good dye washout and no adverse effects from the solid particle dispersion filter dye from dye wandering.
• a series of elements were prepared by coating a poly(ethylene terephthalate) support with an emulsion as in Example 1, except the sensitizing dye had the formula: and the 5-carboxy-4-hydroxy-6-methyl-2-methylmercapto-­1,3,3a,7-tetraazaindene was coated at a level of 500 mg/mole Ag.
• the emulsion layer was overcoated with with 80 mg/ft2 of gel to which had been added 4.8 mg/ft2 of BVSME.
• Example 2 Another series of supports was then coated with various solid particle filter dye dispersions as described in Example 1.
• the dyes are indicated in Table I below.
• the dispersions were coated at a gelatin level of 150 mg/ft2 of gel, a pH of 5.2, and BVSME at 1.5 mg/ft2.
• Example Filter Dye Fog Density Control (unexposed) none 0.08 Control none 1.72 2 3 0.70 3 4 1.11 4 15 0.11 5 16 0.07 Comparison Wratten 89B filter 0.06

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