EP0199897B1 - Verwendung eines wässrigen, gequollene Makromoleküle enthaltenden Systems als Löschwasser - Google Patents
Verwendung eines wässrigen, gequollene Makromoleküle enthaltenden Systems als Löschwasser Download PDFInfo
- Publication number
- EP0199897B1 EP0199897B1 EP86101157A EP86101157A EP0199897B1 EP 0199897 B1 EP0199897 B1 EP 0199897B1 EP 86101157 A EP86101157 A EP 86101157A EP 86101157 A EP86101157 A EP 86101157A EP 0199897 B1 EP0199897 B1 EP 0199897B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- fire
- extinguishing
- gel particles
- dispersion according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 229920002521 macromolecule Polymers 0.000 title claims abstract description 5
- 239000007863 gel particle Substances 0.000 claims abstract description 18
- 239000006185 dispersion Substances 0.000 claims abstract description 11
- 239000008346 aqueous phase Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 239000012071 phase Substances 0.000 claims abstract description 4
- 229920000642 polymer Polymers 0.000 claims abstract description 4
- 230000036571 hydration Effects 0.000 claims abstract description 3
- 238000006703 hydration reaction Methods 0.000 claims abstract description 3
- 239000000126 substance Substances 0.000 claims abstract description 3
- 150000001253 acrylic acids Chemical class 0.000 claims abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- -1 ammonium ions Chemical class 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 238000009434 installation Methods 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 3
- 239000000499 gel Substances 0.000 description 10
- 230000008961 swelling Effects 0.000 description 9
- 230000000694 effects Effects 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 4
- 230000002745 absorbent Effects 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 235000007575 Calluna vulgaris Nutrition 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000012217 deletion Methods 0.000 description 1
- 230000037430 deletion Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 238000011173 large scale experimental method Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000007717 redox polymerization reaction Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 229920000247 superabsorbent polymer Polymers 0.000 description 1
- 239000004583 superabsorbent polymers (SAPs) Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/005—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0064—Gels; Film-forming compositions
Definitions
- Extinguishing water is mainly used for fighting fires in the form in which it can be found in the mains or in natural water, for example in the case of forest fires.
- the mode of action of the extinguishing water is, on the one hand, that when it comes into contact with burning objects, it achieves very effective cooling due to its high heat capacity and heat of vaporization, so that the combustion temperature or the ignition temperature of the objects may be fallen below, thereby precluding new ignition.
- its effect is that when it hits hot objects, it evaporates and the water vapor that is displaced displaces the air required for combustion, thereby immediately extinguishing the flames.
- a major disadvantage when using water in the usual form is that a large proportion of the water often flows unused into non-burning parts or seeps into the ground. This is particularly disadvantageous in the case of forest fires when a significant proportion of the water, which is often transported at great expense, remains completely unused.
- fighting fires near the ground is an important part of fighting forest fires, because according to a typical form of forest fire, the fire continues to eat in the dry undergrowth (grass, leaves or heather) and causes individual crown fires, which then inevitably combine. So far, it has not been possible to make optimal use of the water that has been brought in, especially since forest fires are often preceded by a longer drying period and the soil is therefore particularly absorbent for water.
- DE-OS 31 14 630 describes the use of gels as a water barrier on surfaces of fire-threatened parts of the building, eg. B. flat roofs, and to protect entire areas from wildfires. This measure is intended to avoid an undesired loss of extinguishing water as a result of running off and seeping away.
- these are real gels with a very high viscosity, which cover the material to be protected as a thick layer. Since such gels do not penetrate the fire-endangered goods, they have a poor extinguishing effect. Their high viscosity makes the use of special devices necessary for their application.
- US-A-3 354 084 also describes the use of a gel made from a water-swellable acrylic polymer, in particular slightly crosslinked acrylamide copolymers, together with finely divided titanium dioxide particles to increase the viscosity and achieve light protection for fighting forest fires.
- US Pat. No. 3,404,089 recommends that the gel be produced only immediately before the fire fighting by reaction of a low-viscosity polyacrylic acid dispersion with aqueous solutions of alkali or ammonium salts. But here too there is the disadvantage that a real gel with very high viscosity is ultimately used to fight the fire, which does not penetrate into the goods to be protected and has a poor extinguishing effect.
- the present invention is therefore based on the object of providing a fire-fighting agent with the objective of reducing the water damage which arises during fire-fighting, reducing the environmental impact, enabling use with generally customary equipment and preventing corrosion damage.
- Water-insoluble, water-swelling polymers are described, for example, in US Pat. Nos. 4017653 and 4018951. In the professional world, these substances are also referred to as superabsorbent polymers or so-called superabsorbers. This applies in particular to the copolymers of acrylic or methacrylic acid with acrylamide, methacrylamide and acrylonitrile, as described in DE-PS 2706135 are.
- All olefinically at least bifunctional monomers are suitable as crosslinking agents, such as. B. methylenebisacrylamide, divinylbenzene, trisallyl cyanurate, trisallyl phosphate, etc.
- crosslinking agents such as. B. methylenebisacrylamide, divinylbenzene, trisallyl cyanurate, trisallyl phosphate, etc.
- the preparation of the suitable crosslinked polymers by radical or redox polymerization is known.
- the dispersion to be used according to the invention is prepared by adding potassium or sodium salts of the dry, slightly crosslinked copolymer based on sodium acrylate and / or acrylic acid with a particle size of 0.02 to 0.5 mm into the corresponding amount of water with stirring or pumping.
- active silica and / or silicates can optionally be added to the unswollen copolymer.
- the optionally added active silicas are products which are known in particular as fillers or absorbers such as the silica xerogels with BET surface areas of '30 m 2 / g, m is usually several 100 2 / g or by flame-hydrolytic cleavage active silicas obtained from silicon tetrachloride with BET surface areas of 50 to 450 m 2 / g (Aerosil).
- active silicas there are also active silicates precipitated from water glass and the corresponding metal salts and possibly mineral acids, in particular calcium, magnesium or aluminum with BET surface areas above 30 m 2 / g in the form of their xerogels for the purposes of the invention in combination with the highly absorbent ones Polymers can be used.
- the aqueous dispersion contains the gel particles in such concentrations that sufficient free water is still available on the one hand to achieve an excellent extinguishing effect with minimal water damage and on the other hand to enable usability with very good wetting properties, such as with pure water.
- 50 to 80% by weight, preferably 60 to 70% by weight, of the total water is present in the gel particles.
- the gel particles arise from the highly absorbent copolymers, the structure of which is such that they quickly absorb 100 to 200 times their weight in water, but do not dissolve in water. If an excess of water is added to the gel particles swollen in this way, the excess water remains as a pure water phase, which acts as a vehicle for the gel particles and largely retains their viscosity, while the gel particles are to be regarded as discrete macromolecules.
- the swelling bodies based on polyacrylic acid in the form of the sodium or potassium salt
- a wetting agent is possible and can be done in special cases, e.g. B. the deletion of cotton bales, be useful.
- the discrete gel particles according to the invention have nothing in common with the known thickeners which are proposed for increasing the adhesion of the water and which cause a great increase in viscosity with the associated disadvantages.
- aqueous system according to the invention By setting the aqueous system according to the invention to a pH of 6-8, corrosion phenomena on used extinguishing devices and on objects sprayed for fire protection can be avoided.
- aqueous system according to the invention as extinguishing water does not require any special pumps or pipes because of the low viscosity.
- it is also possible to work with conventional equipment.
- it can be used in type W fire extinguishers and sprinkler systems.
- the entrained gel particles do not prevent the water from penetrating into the fire material, but do not show any tendency to drain away and, due to their own adherence, remain attached to the fire-prone or burning objects and, on the other hand, give rise to excessive heat the water contained in them is freely released as steam, so that the entire extinguishing water is available for cooling and steam formation. This significantly reduces the amount of extinguishing liquid required compared to conventional agents. In addition, there is very effective protection against fire penetration.
- the swelling bodies can be added in the tank of a fire engine, a “water bomber”, or in special mixing tanks, with gentle stirring or moderate pumping during littering and for a few minutes after the littering has ended.
- the swollen gel particles do not stick together. Although they settle slightly during long periods of inactivity, they can be pumped around or stirred without problems even after weeks, although this is normally not necessary.
- the usual way of using the invention is to spray or spray the aqueous system with already formed gel particles.
- a variant that may be preferred is to add the swelling bodies in an unswollen state shortly before the jet pipe.
- fire blankets which, for. B. in the form of throws to help escape in fire-prone businesses, large buildings such as hotels, etc.
- Such fire blankets contain the swelling body in the swollen state and are to avoid moisture loss, for. B. welded into a film.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Dispersion Chemistry (AREA)
- Fire-Extinguishing Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Revetment (AREA)
- Lift Valve (AREA)
- Insulated Conductors (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Colloid Chemistry (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT86101157T ATE41872T1 (de) | 1985-05-03 | 1986-01-29 | Verwendung eines waessrigen, gequollene makromolekuele enthaltenden systems als loeschwasser. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3515865 | 1985-05-03 | ||
| DE19853515865 DE3515865A1 (de) | 1985-05-03 | 1985-05-03 | Verwendung eines waessrigen, gequollene makromolekuele enthaltenden systems als loeschwasser |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0199897A1 EP0199897A1 (de) | 1986-11-05 |
| EP0199897B1 true EP0199897B1 (de) | 1989-04-05 |
Family
ID=6269692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP86101157A Expired EP0199897B1 (de) | 1985-05-03 | 1986-01-29 | Verwendung eines wässrigen, gequollene Makromoleküle enthaltenden Systems als Löschwasser |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0199897B1 (da) |
| JP (1) | JPH088937B2 (da) |
| AT (1) | ATE41872T1 (da) |
| AU (1) | AU595198B2 (da) |
| CA (1) | CA1276442C (da) |
| DE (2) | DE3515865A1 (da) |
| DK (1) | DK159673C (da) |
| ES (1) | ES8708189A1 (da) |
| FI (1) | FI98271C (da) |
| GR (1) | GR861138B (da) |
| NO (1) | NO166571C (da) |
| PT (1) | PT82441B (da) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3716304A1 (de) * | 1987-05-15 | 1988-11-24 | Bluecher Hubert | Loeschwasserzusatz |
| FR2628976B1 (fr) * | 1988-03-25 | 1991-11-15 | Weber Sa A | Procede de traitement de l'eau pour la lutte contre les incendies |
| DE4336319A1 (de) * | 1993-10-25 | 1995-04-27 | Oeko Tec Umweltschutzsyst Gmbh | Löschmittel und Verfahren zu seiner Herstellung |
| DE4343728C2 (de) * | 1993-12-21 | 1997-04-24 | Gernot Dr Loehnert | Verfahren zur Herstellung von verdicktem Wasser und seine Verwendung |
| AU718417B2 (en) * | 1995-11-14 | 2000-04-13 | Stockhausen Gmbh & Co. Kg | Water additive and method for fire prevention and fire extinguishing |
| GR1002790B (el) * | 1996-07-22 | 1997-10-17 | Μεθοδος και προιοντα κατασβεσης πυρκαιων. | |
| DE19756779A1 (de) * | 1996-12-20 | 1998-07-16 | Dynamit Nobel Ag | Mittel zur Kühlung von heißen Gasen |
| NL1007738C2 (nl) * | 1997-12-08 | 1999-06-09 | Univ Delft Tech | Toepassing van hydrofiele, gelvormende polymeren als brandblusmiddel. |
| DE10041394A1 (de) * | 2000-08-23 | 2002-03-07 | Stockhausen Chem Fab Gmbh | Verwendung von Wasser-in-Wasser-Polymerdispersionen zur Feuerverhütung und -bekämpfung |
| DE10041395A1 (de) | 2000-08-23 | 2002-03-07 | Stockhausen Chem Fab Gmbh | Polymerdispersionen zur Feuerverhütung und -bekämpfung mit verbesserter Umweltverträglichkeit |
| DE102007036902A1 (de) | 2007-08-06 | 2009-02-12 | BLüCHER GMBH | Löschvorrichtung, Löschsystem und Verfahren zur lokalen Brandbekämpfung |
| WO2019068941A1 (es) * | 2017-10-06 | 2019-04-11 | Soriano Azorin Juan Jose | Sistema para extinción de incendios |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3229769A (en) * | 1963-01-28 | 1966-01-18 | Dow Chemical Co | Method for controlling the spread of fire |
| US3354084A (en) * | 1964-06-24 | 1967-11-21 | Dow Chemical Co | Aqueous gel of water-swellable acrylic polymer and non-ionic filler |
| US3404089A (en) * | 1964-08-20 | 1968-10-01 | Mobil Oil Corp | Method of extinguishing fire |
| US3976580A (en) * | 1975-11-07 | 1976-08-24 | Bernard Kaminstein | Gelled fire extinguisher fluid comprising polyacrylamide and bentonite |
| JPS5649167A (en) * | 1979-09-26 | 1981-05-02 | Miyata Ind | Fireeextinguishing substanse |
| US4384988A (en) * | 1980-04-10 | 1983-05-24 | L.M.C. Inc. | Fire protection water barrier which is a gel composition of high water content and high viscosity |
| JPS59189869A (ja) * | 1983-04-11 | 1984-10-27 | 昭和電工株式会社 | 防災用具 |
| EP0212017B1 (en) * | 1983-06-21 | 1990-01-17 | Cease Fire Corporation | Thixotropic fire suppressant composition containing carboxy polymer gelling agent |
-
1985
- 1985-05-03 DE DE19853515865 patent/DE3515865A1/de not_active Withdrawn
-
1986
- 1986-01-29 AT AT86101157T patent/ATE41872T1/de not_active IP Right Cessation
- 1986-01-29 DE DE8686101157T patent/DE3662641D1/de not_active Expired
- 1986-01-29 EP EP86101157A patent/EP0199897B1/de not_active Expired
- 1986-04-14 JP JP61085847A patent/JPH088937B2/ja not_active Expired - Lifetime
- 1986-04-14 FI FI861553A patent/FI98271C/fi not_active IP Right Cessation
- 1986-04-21 CA CA000507177A patent/CA1276442C/en not_active Expired - Lifetime
- 1986-04-22 PT PT82441A patent/PT82441B/pt not_active IP Right Cessation
- 1986-04-29 GR GR861138A patent/GR861138B/el unknown
- 1986-04-30 ES ES554541A patent/ES8708189A1/es not_active Expired
- 1986-05-02 NO NO861750A patent/NO166571C/no unknown
- 1986-05-02 DK DK203786A patent/DK159673C/da not_active IP Right Cessation
- 1986-05-02 AU AU57066/86A patent/AU595198B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| FI98271C (fi) | 1997-05-26 |
| DE3515865A1 (de) | 1986-11-06 |
| DK203786D0 (da) | 1986-05-02 |
| PT82441A (en) | 1986-05-01 |
| ES8708189A1 (es) | 1987-10-01 |
| FI861553A (fi) | 1986-11-04 |
| FI861553A0 (fi) | 1986-04-14 |
| DK203786A (da) | 1986-11-04 |
| EP0199897A1 (de) | 1986-11-05 |
| DK159673B (da) | 1990-11-19 |
| CA1276442C (en) | 1990-11-20 |
| ES554541A0 (es) | 1987-10-01 |
| ATE41872T1 (de) | 1989-04-15 |
| DE3662641D1 (en) | 1989-05-11 |
| NO166571C (no) | 1991-08-14 |
| FI98271B (fi) | 1997-02-14 |
| NO861750L (no) | 1986-11-04 |
| JPS6284779A (ja) | 1987-04-18 |
| AU5706686A (en) | 1986-11-06 |
| PT82441B (pt) | 1988-03-03 |
| JPH088937B2 (ja) | 1996-01-31 |
| DK159673C (da) | 1991-04-15 |
| GR861138B (en) | 1986-08-21 |
| AU595198B2 (en) | 1990-03-29 |
| NO166571B (no) | 1991-05-06 |
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