EP0142097B1 - Verfahren zur Herstellung von Kohlenmonoxid - Google Patents

Verfahren zur Herstellung von Kohlenmonoxid Download PDF

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Publication number
EP0142097B1
EP0142097B1 EP84113032A EP84113032A EP0142097B1 EP 0142097 B1 EP0142097 B1 EP 0142097B1 EP 84113032 A EP84113032 A EP 84113032A EP 84113032 A EP84113032 A EP 84113032A EP 0142097 B1 EP0142097 B1 EP 0142097B1
Authority
EP
European Patent Office
Prior art keywords
generator
carbon monoxide
carbon
oxygen
nozzles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP84113032A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP0142097A3 (en
EP0142097A2 (de
Inventor
Dieter Dr. Becher
Christian Dr. König
Eckhard Dr. Tiemann
Hans Czwalinna
Wilhelm Hagen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0142097A2 publication Critical patent/EP0142097A2/de
Publication of EP0142097A3 publication Critical patent/EP0142097A3/de
Application granted granted Critical
Publication of EP0142097B1 publication Critical patent/EP0142097B1/de
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/08—Continuous processes with ash-removal in liquid state
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/20—Apparatus; Plants
    • C10J3/30—Fuel charging devices
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/86—Other features combined with waste-heat boilers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0943—Coke
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0959—Oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0969—Carbon dioxide

Definitions

  • the present invention relates to a method for producing carbon monoxide in a carbon-filled, water-cooled generator with a frustoconical longitudinal section by gasifying carbon with a mixed gas of oxygen and carbon dioxide, which is arranged in one or more cooling nozzles arranged on the generator jacket and directed downward in the The generator is blown in and the carbon monoxide formed is drawn off to the side and / or at the top of the generator.
  • the task is to increase the yield with at least the same degree of purity of the carbon monoxide produced.
  • This object is achieved in that oxygen is blown in through at least one additional nozzle above the nozzles for the mixed gas.
  • Coke is preferably used as carbon in this process. If additives are added to the coke, the liquid slag can be drawn off continuously or discontinuously at the bottom of the generator.
  • the process can be carried out particularly effectively by setting a volume ratio of oxygen to carbon dioxide in the mixed gas of up to 1: 1, preferably 0.83 to 0.75. This leads to a significantly improved use of the heat of reaction of the carbon combustion and a further increase in the volume capacity to over 400 m 3 CO / hxm 3 reaction volume.
  • FIG. 1 schematically shows a carbon monoxide generator in which the new method can be carried out. This is just a conceivable embodiment of such a carbon monoxide generator.
  • the carbon 2 is brought into the actual generator 3 through a lock 1. This is surrounded by a cooling water system 4 and has a mixed gas (0 2 / C0 2 ) nozzle 5 and a product gas outlet 6.
  • the slag 7 is removed through a slag discharge 8 at the bottom of the generator.
  • a manhole 9 is used to maintain the generator. Pure oxygen is blown in via a nozzle 10 arranged above the mixed gas nozzle 5.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Hydrogen, Water And Hydrids (AREA)
EP84113032A 1983-11-11 1984-10-30 Verfahren zur Herstellung von Kohlenmonoxid Expired EP0142097B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19833340929 DE3340929A1 (de) 1983-11-11 1983-11-11 Verfahren zur herstellung von kohlenmonoxid
DE3340929 1983-11-11

Publications (3)

Publication Number Publication Date
EP0142097A2 EP0142097A2 (de) 1985-05-22
EP0142097A3 EP0142097A3 (en) 1987-09-30
EP0142097B1 true EP0142097B1 (de) 1989-12-27

Family

ID=6214137

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84113032A Expired EP0142097B1 (de) 1983-11-11 1984-10-30 Verfahren zur Herstellung von Kohlenmonoxid

Country Status (8)

Country Link
US (1) US4564513A (ja)
EP (1) EP0142097B1 (ja)
JP (1) JPS60118619A (ja)
BR (1) BR8405724A (ja)
CA (1) CA1226116A (ja)
DE (2) DE3340929A1 (ja)
ES (1) ES537535A0 (ja)
ZA (1) ZA848768B (ja)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7235056B2 (en) * 1996-05-17 2007-06-26 Amira Medical Body fluid sampling device and methods of use
EP1579814A3 (en) * 1996-05-17 2006-06-14 Roche Diagnostics Operations, Inc. Methods and apparatus for sampling and analyzing body fluid
US7828749B2 (en) 1996-05-17 2010-11-09 Roche Diagnostics Operations, Inc. Blood and interstitial fluid sampling device
US20020010406A1 (en) * 1996-05-17 2002-01-24 Douglas Joel S. Methods and apparatus for expressing body fluid from an incision
US6706000B2 (en) 1997-11-21 2004-03-16 Amira Medical Methods and apparatus for expressing body fluid from an incision
US20020188223A1 (en) 2001-06-08 2002-12-12 Edward Perez Devices and methods for the expression of bodily fluids from an incision
JP2003028577A (ja) * 2001-07-19 2003-01-29 Nippon Soda Co Ltd 酸素吹き込みノズル
JP2005501591A (ja) * 2001-08-29 2005-01-20 エフ ホフマン−ラ ロッシュ アクチェン ゲゼルシャフト 体液をサンプリングする際に使用するための滲出方法および構造体
US20080149524A1 (en) * 2003-03-27 2008-06-26 Rademaker William B Food containers including dental cleaning devices and other personal care items
DE10348116B4 (de) * 2003-10-16 2015-02-19 Bayer Intellectual Property Gmbh CO-Generator und Verfahren zur Herstellung von kohlenmonoxidhaltigem Gas durch Umsetzung eines kohlenstoffhaltigen Brennmaterials
US8372171B2 (en) * 2009-11-23 2013-02-12 Louis Herrington CO generator and process for desulfurizing solid carbon-based fuels
CN103253665B (zh) * 2013-04-15 2015-01-07 内蒙古包钢钢联股份有限公司 实验室利用二氧化碳制备一氧化碳的方法
JP6632123B2 (ja) * 2015-10-30 2020-01-15 藤原　照家 廃棄物ガス化装置

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE387292C (de) * 1921-03-04 1923-12-28 Wilhelm Hoffmann Abstichgaserzeuger
DE916447C (de) * 1942-07-12 1954-08-09 Koppers Gmbh Heinrich Verfahren zur Erzeugung von reinem Kohlenoxydgas
GB1070009A (en) * 1963-01-31 1967-05-24 Gas Council Improvements in and relating to the gasification of solid carbonaceous fuel
US3325253A (en) * 1963-05-29 1967-06-13 Allied Chem Process for producing carbon monoxide
US3635672A (en) * 1969-03-25 1972-01-18 Total Energy Corp Method of gasifying carbonaceous materials to a carbon monoxide fuel gas product
DE1950517A1 (de) * 1969-10-07 1971-04-29 Bamag Verfahrenstechnik Gmbh Verfahren zur Herstellung von Kohlenmonoxid durch Vergasung von Koks
DE2001844B2 (de) * 1970-01-16 1980-01-10 Krupp-Koppers Gmbh, 4300 Essen Verfahren und Vorrichtung zum Erzeugen von Kohlenmonoxyd durch Umsetzung von glühendem Koks mit Sauerstoff und Kohlendioxyd
DE2046172C3 (de) * 1970-09-18 1980-01-17 Dr. C. Otto & Comp. Gmbh, 4630 Bochum Gaserzeuger
GB1569409A (en) * 1975-11-27 1980-06-11 British Gas Corp Slag taps and to coal gasification plants incorporating such slag taps
DE2738932C2 (de) * 1977-08-30 1986-02-06 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zum kontinuierlichen Schlackeabziehen bei dem Vergasen fester Brennstoffe
US4244180A (en) * 1979-03-16 1981-01-13 Rasor Associates, Inc. Process for producing fuel gases from carbonaceous material
US4436530A (en) * 1982-07-02 1984-03-13 Texaco Development Corporation Process for gasifying solid carbon containing materials

Also Published As

Publication number Publication date
ES8507420A1 (es) 1985-09-16
JPH0563407B2 (ja) 1993-09-10
ES537535A0 (es) 1985-09-16
EP0142097A3 (en) 1987-09-30
DE3340929A1 (de) 1985-05-23
ZA848768B (en) 1985-07-31
BR8405724A (pt) 1985-09-17
EP0142097A2 (de) 1985-05-22
CA1226116A (en) 1987-09-01
JPS60118619A (ja) 1985-06-26
US4564513A (en) 1986-01-14
DE3480849D1 (de) 1990-02-01

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