EP0106334B1 - Pyrotechnische Nebelsätze - Google Patents
Pyrotechnische Nebelsätze Download PDFInfo
- Publication number
- EP0106334B1 EP0106334B1 EP83110260A EP83110260A EP0106334B1 EP 0106334 B1 EP0106334 B1 EP 0106334B1 EP 83110260 A EP83110260 A EP 83110260A EP 83110260 A EP83110260 A EP 83110260A EP 0106334 B1 EP0106334 B1 EP 0106334B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- caesium
- compositions according
- pyrotechnical
- smoke compositions
- smoke
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000779 smoke Substances 0.000 title claims description 19
- 239000000203 mixture Substances 0.000 claims description 26
- NLSCHDZTHVNDCP-UHFFFAOYSA-N caesium nitrate Chemical compound [Cs+].[O-][N+]([O-])=O NLSCHDZTHVNDCP-UHFFFAOYSA-N 0.000 claims description 14
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 7
- 229910052796 boron Inorganic materials 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- 238000007792 addition Methods 0.000 claims description 6
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 claims description 6
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 229910001093 Zr alloy Inorganic materials 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 230000005855 radiation Effects 0.000 claims description 4
- -1 alkali metal salts Chemical class 0.000 claims description 3
- 235000019270 ammonium chloride Nutrition 0.000 claims description 3
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 claims description 3
- 238000002485 combustion reaction Methods 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 150000001664 caesium compounds Chemical class 0.000 claims 7
- 239000004411 aluminium Substances 0.000 claims 3
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- LYQFWZFBNBDLEO-UHFFFAOYSA-M caesium bromide Chemical compound [Br-].[Cs+] LYQFWZFBNBDLEO-UHFFFAOYSA-M 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 238000005275 alloying Methods 0.000 claims 1
- KOPBYBDAPCDYFK-UHFFFAOYSA-N caesium oxide Chemical compound [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 claims 1
- 229910001942 caesium oxide Inorganic materials 0.000 claims 1
- 239000003595 mist Substances 0.000 description 16
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 9
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 230000009102 absorption Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 229910052792 caesium Inorganic materials 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- GDDNTTHUKVNJRA-UHFFFAOYSA-N 3-bromo-3,3-difluoroprop-1-ene Chemical compound FC(F)(Br)C=C GDDNTTHUKVNJRA-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000005062 Polybutadiene Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
- 159000000006 cesium salts Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002663 nebulization Methods 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000011863 silicon-based powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 description 1
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N chlorosulfonic acid Substances OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000005049 silicon tetrachloride Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 238000001931 thermography Methods 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06D—MEANS FOR GENERATING SMOKE OR MIST; GAS-ATTACK COMPOSITIONS; GENERATION OF GAS FOR BLASTING OR PROPULSION (CHEMICAL PART)
- C06D3/00—Generation of smoke or mist (chemical part)
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D5/00—Heat treatments of cast-iron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/08—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes
- C21D9/14—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tubular bodies or pipes wear-resistant or pressure-resistant pipes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F1/00—Cylinders; Cylinder heads
- F02F1/18—Other cylinders
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F1/00—Cylinders; Cylinder heads
- F02F1/18—Other cylinders
- F02F1/20—Other cylinders characterised by constructional features providing for lubrication
Definitions
- the present invention relates to pyrotechnic mist sets which produce impenetrable mists in the visible and infrared range.
- EU-A 0 037 515 it is also known to combine mist from halogen donors / metal powders or phosphor mist with a further secondary mist from organic acids or microballoons in order to produce larger agglomerates which also have a light absorption in the range of> 8 ⁇ m .
- the alkali salts sodium, potassium, lithium nitrate used as oxidizing agents in these mixtures cause, among other things. also a signal effect (coloring of the flame), but are not suitable for changing the infrared absorption.
- cesium salts in the near infrared range up to 12 ⁇ m have no absorptions that can be attributed to vibration in which the cesium ions are involved (cesium halides have none, cesium nitrate only shows the vibration of the nitrate group at 7.2 ⁇ m ), direct absorption of the IR light cannot be considered for the effect. Because the amounts used are based on the total amount Mist rate only correspond to an average of 25%, and correspondingly the other mist-forming components are present in smaller quantities, the increase in the number of particles in the dispersed system cannot be held responsible for the effect.
- the present invention has also set itself the task of increasing the fog yield of phosphorus-containing fog sets.
- the effectiveness can be further increased by adding ammonium chloride.
- the primer has the following components: magnesium powder (1.2 kg) iron blue (0.9 kg), boron amorphous (2.39 kg), powdered chlorinated paraffin (0.8 kg) and black powder (4.71 kg).
- the magnesium powder and iron blue were premixed; the chlorinated paraffin, dissolved in 2 liters of perchlorethylene, was added and mixed.
- the amorphous boron was added and the mixing process repeated for 5 minutes.
- the black powder was added as the last component, mixed with the other components for 10 minutes, dried and pressed at 1500 bar.
- the same mixture as above is additionally mixed with 0.4 kg of cesium nitrate and processed in the same way to form pressed bodies with a weight of approx. 50 g.
- 20 compacts are put together with a primer in a casing to form a charge.
- 3 white plates heated to approx. 40 ° C are set up in the terrain at a distance of 10 m and from a distance of 100 m with infrared and optical viewing devices at wavelengths of 10 Ilm, 3.5 pm and 0.6 ⁇ m observed.
- Fog charges of the above composition are fired with a propellant charge approx. 40-50 m in front of the target, where within 3 seconds a 3-15 m high and 25-40 m wide and deep fog wall forms.
- the coverage ratios listed in the following table are determined.
- a very good coverage of 95-100% is understood, ie the goal can no longer be distinguished from the background.
- a good coverage of 80-95% is understood, ie the goal is almost impossible to identify.
- Moderate is a coverage of 50-80%. Bad means coverage below 50%, where the goal can still be clearly identified.
- the fog effect is determined according to Example 1, the results of Table 2 below being obtained.
- the mists formed have a pH of approx. 5-7.
- the elastomer consisted of butadiene. Polybutadiene can also be used.
- the fog effect is determined according to Example 1, the results of Table 3 below being obtained.
- 0.65 kg of hexachloroethane, 0.2 kg of silicon powder and 0.15 kg of aluminum powder are mixed and pressed into a casing under low pressure, which is connected to a propellant and ignition charge.
- Butadiene (polybutadiene) is used as the binder.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metallurgy (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Botany (AREA)
- Glass Compositions (AREA)
- Air Bags (AREA)
- Fireproofing Substances (AREA)
- Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
- Powder Metallurgy (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT83110260T ATE40101T1 (de) | 1982-10-16 | 1983-10-14 | Pyrotechnische nebelsaetze. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3238444 | 1982-10-16 | ||
| DE3238444A DE3238444C2 (de) | 1982-10-16 | 1982-10-16 | Pyrotechnische Nebelsätze |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0106334A2 EP0106334A2 (de) | 1984-04-25 |
| EP0106334A3 EP0106334A3 (en) | 1985-12-04 |
| EP0106334B1 true EP0106334B1 (de) | 1989-01-18 |
Family
ID=6175923
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP83110260A Expired EP0106334B1 (de) | 1982-10-16 | 1983-10-14 | Pyrotechnische Nebelsätze |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0106334B1 (no) |
| JP (1) | JPS6042194B2 (no) |
| KR (1) | KR910000506B1 (no) |
| AR (1) | AR231962A1 (no) |
| AT (1) | ATE40101T1 (no) |
| CA (1) | CA1237581A (no) |
| DE (2) | DE3238444C2 (no) |
| DK (1) | DK164665C (no) |
| ES (1) | ES526488A0 (no) |
| FI (1) | FI76066C (no) |
| IL (1) | IL69859A (no) |
| NO (1) | NO158375C (no) |
| SG (1) | SG80491G (no) |
| ZA (1) | ZA837647B (no) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8820660D0 (en) * | 1988-09-01 | 1988-11-16 | Astra Holdings Plc | Smoke producing article |
| DE4016854A1 (de) * | 1990-05-25 | 1991-11-28 | Diehl Gmbh & Co | Tarn- und taeusch-einrichtung |
| DE4327976C1 (de) * | 1993-08-19 | 1995-01-05 | Buck Chem Tech Werke | Flaremasse zur Scheinzielerzeugung |
| DE19601506C2 (de) * | 1996-01-17 | 2000-05-18 | Rheinmetall W & M Gmbh | Verfahren und Vorrichtung zur Erzeugung einer Sichtsperre mit Hilfe eines künstlichen Nebels |
| DE19914033A1 (de) | 1999-03-27 | 2000-09-28 | Piepenbrock Pyrotechnik Gmbh | Verfahren zur Erzeugung eines im infraroten Spektralbereich einseitig transparenten Tarnnebels |
| DE19914097A1 (de) | 1999-03-27 | 2000-09-28 | Piepenbrock Pyrotechnik Gmbh | Pyrotechnische Wirkmasse zur Erzeugung eines im Infraroten stark emissiven und im Visuellen undurchdringlichen Aerosols |
| DE10152023B4 (de) * | 2001-10-22 | 2005-06-16 | Buck Neue Technologien Gmbh | Schockunempfindliche Nebelwurfkörper |
| DE10308307B4 (de) * | 2003-02-26 | 2007-01-04 | Buck Neue Technologien Gmbh | Geschoß sowie Submunition mit Vorspannkörper |
| JP4969841B2 (ja) * | 2005-01-19 | 2012-07-04 | 日本工機株式会社 | 赤外線遮蔽発煙組成物 |
| JP4969842B2 (ja) * | 2005-12-09 | 2012-07-04 | 日本工機株式会社 | 赤リン系発煙組成物およびその製造方法 |
| CN107021865A (zh) * | 2017-05-26 | 2017-08-08 | 北京理工大学 | 可干扰可见光、红外及毫米波的宽频段烟幕材料 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE378780C (de) * | 1922-05-03 | 1923-08-01 | Harry James Nichols | Rauchentwickler |
| GB1454258A (en) * | 1972-08-23 | 1976-11-03 | Secr Defence | Smoke generating compositions |
| DE3012405A1 (de) * | 1980-03-29 | 1981-10-01 | Pyrotechnische Fabrik F. Feistel GmbH + Co KG, 6719 Göllheim | Kombinationsnebel |
-
1982
- 1982-10-16 DE DE3238444A patent/DE3238444C2/de not_active Expired
-
1983
- 1983-09-19 DK DK426783A patent/DK164665C/da not_active IP Right Cessation
- 1983-09-28 IL IL69859A patent/IL69859A/xx not_active IP Right Cessation
- 1983-10-04 FI FI833595A patent/FI76066C/fi not_active IP Right Cessation
- 1983-10-07 CA CA000438624A patent/CA1237581A/en not_active Expired
- 1983-10-11 KR KR1019830004813A patent/KR910000506B1/ko not_active IP Right Cessation
- 1983-10-13 AR AR294526A patent/AR231962A1/es active
- 1983-10-14 ZA ZA837647A patent/ZA837647B/xx unknown
- 1983-10-14 DE DE8383110260T patent/DE3378977D1/de not_active Expired
- 1983-10-14 ES ES526488A patent/ES526488A0/es active Granted
- 1983-10-14 AT AT83110260T patent/ATE40101T1/de not_active IP Right Cessation
- 1983-10-14 EP EP83110260A patent/EP0106334B1/de not_active Expired
- 1983-10-14 JP JP58191067A patent/JPS6042194B2/ja not_active Expired
- 1983-10-14 NO NO833739A patent/NO158375C/no unknown
-
1991
- 1991-10-05 SG SG804/91A patent/SG80491G/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK426783D0 (da) | 1983-09-19 |
| ZA837647B (en) | 1984-07-25 |
| KR840006473A (ko) | 1984-11-30 |
| DE3238444C2 (de) | 1986-10-30 |
| EP0106334A3 (en) | 1985-12-04 |
| DE3238444A1 (de) | 1984-08-02 |
| JPS6042194B2 (ja) | 1985-09-20 |
| CA1237581A (en) | 1988-06-07 |
| DK164665C (da) | 1992-12-14 |
| ATE40101T1 (de) | 1989-02-15 |
| SG80491G (en) | 1991-11-15 |
| DK164665B (da) | 1992-07-27 |
| NO158375C (no) | 1988-08-31 |
| NO158375B (no) | 1988-05-24 |
| IL69859A (en) | 1989-01-31 |
| ES8602564A1 (es) | 1985-12-01 |
| DE3378977D1 (en) | 1989-02-23 |
| NO833739L (no) | 1984-04-17 |
| KR910000506B1 (ko) | 1991-01-26 |
| JPS59131592A (ja) | 1984-07-28 |
| FI833595A (fi) | 1984-04-17 |
| FI76066C (fi) | 1988-09-09 |
| FI833595A0 (fi) | 1983-10-04 |
| ES526488A0 (es) | 1985-12-01 |
| FI76066B (fi) | 1988-05-31 |
| AR231962A1 (es) | 1985-04-30 |
| EP0106334A2 (de) | 1984-04-25 |
| DK426783A (da) | 1984-04-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3326884C2 (de) | Verfahren zum Verdecken sichtbarer und infraroter Strahlung und Nebelmunition zur Durchführung dieses Verfahrens | |
| DE4244682B4 (de) | Hochintensive pyrotechnische Infrarot-Leuchtdrohne | |
| EP1173394B9 (de) | Pyrotechnische wirkmasse zur erzeugung eines im infraroten stark emissiven und im visuellen undurchdringlichen aerosols | |
| DE3031369C2 (de) | Pyrotechnische Ladung aus Nebelsatz und Anzündsatz und Verfahren zur Herstellung der Nebelmischung und des Anzündsatzes | |
| EP0106334B1 (de) | Pyrotechnische Nebelsätze | |
| DE3238455A1 (de) | Nebelwurfkoerper | |
| DE4030430C1 (de) | IR-undurchlässigen Nebel erzeugende Zusammensetzung | |
| DE3326883C2 (de) | Pyrotechnische rauch- bzw. nebelbildende Zusammensetzung und deren Verwendung | |
| DE2819850C2 (de) | Pyrotechnischer Nebelsatz | |
| EP2468700B1 (de) | Pyrotechnische Scheinzielwirkmasse für Infrarotscheinziele | |
| WO2000058238A1 (de) | Pyrotechnischer nebelsatz zur erzeugung eines im sichtbaren, infraroten und im millimeterwellen-bereich undurchdringlichen aerosols | |
| DE2754855C2 (de) | Verfahren zur Verbesserung der Druckabhängigkeit des Abbrandverhaltens von Festtreiboder Rohrwaffentreibmittel und Verwendung der nach dem Verfahren hergestellten Treibmittel | |
| EP0639547B1 (de) | IR-undurchlässigen Nebel erzeugende Zusammensetzung | |
| DE10164381B4 (de) | Signaturarmer und schadstoffreduzierter, pyrotechnischer Darstellungskörper | |
| DE102013003172B4 (de) | Sprengstoffwirkmasse, deren Verwendung und Gefechtsmunition | |
| DE3037053C2 (no) | ||
| DE2648308C3 (de) | Verfahren zur Herstellung von direkt zündbaren aluminothermischen Gemischen | |
| DE10138745A1 (de) | Flächenflares | |
| DE2953469C1 (de) | Pyrotechnischer Nebelsatz | |
| DD301407A7 (de) | Gemisch zur Erzeugung von Tarnnebeln, vorzugsweise für den Ir-Bereich | |
| DE1805358C3 (de) | Zündmittelgemisch für Feststofftreibladungen | |
| DE1646280A1 (de) | Wettersprengstoffe mit einem Zusatz von zweiwertigen Metalloxiden | |
| DE102004018861A1 (de) | Pyrotechnischer Satz | |
| DE2831074A1 (de) | Ammonsalpeter-sprengstoff | |
| DE1805358B2 (de) | Zuendmittelgemisch fuer feststofftreibladungen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
| PUAL | Search report despatched |
Free format text: ORIGINAL CODE: 0009013 |
|
| AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
| 17P | Request for examination filed |
Effective date: 19851023 |
|
| 17Q | First examination report despatched |
Effective date: 19860820 |
|
| ITF | It: translation for a ep patent filed | ||
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE CH DE FR GB IT LI LU NL SE |
|
| REF | Corresponds to: |
Ref document number: 40101 Country of ref document: AT Date of ref document: 19890215 Kind code of ref document: T |
|
| GBT | Gb: translation of ep patent filed (gb section 77(6)(a)/1977) | ||
| REF | Corresponds to: |
Ref document number: 3378977 Country of ref document: DE Date of ref document: 19890223 |
|
| ET | Fr: translation filed | ||
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| 26N | No opposition filed | ||
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PFA Free format text: PIEPENBROCK PYROTECHNIK GMBH |
|
| ITPR | It: changes in ownership of a european patent |
Owner name: CESSIONE;PIEPENBROCK PYROTECHNIK GMBH |
|
| NLT1 | Nl: modifications of names registered in virtue of documents presented to the patent office pursuant to art. 16 a, paragraph 1 |
Owner name: FEISTEL PYROTECHNIK GMBH + CO. KG TE GOELLHEIM, BO |
|
| NLS | Nl: assignments of ep-patents |
Owner name: PIEPENBROCK PYROTECHNIK GMBH TE GOELLHEIM, BONDSRE |
|
| ITTA | It: last paid annual fee | ||
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: CD |
|
| EPTA | Lu: last paid annual fee | ||
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LU Payment date: 19941001 Year of fee payment: 12 |
|
| EAL | Se: european patent in force in sweden |
Ref document number: 83110260.3 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19951014 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19960810 Year of fee payment: 14 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19961021 Year of fee payment: 14 Ref country code: BE Payment date: 19961021 Year of fee payment: 14 Ref country code: AT Payment date: 19961021 Year of fee payment: 14 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 19961029 Year of fee payment: 14 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19971014 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19971015 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: THE PATENT HAS BEEN ANNULLED BY A DECISION OF A NATIONAL AUTHORITY Effective date: 19971031 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19971031 |
|
| BERE | Be: lapsed |
Owner name: PIEPENBROCK PYROTECHNIK G.M.B.H. Effective date: 19971031 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19980501 |
|
| NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee |
Effective date: 19980501 |
|
| EUG | Se: european patent has lapsed |
Ref document number: 83110260.3 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: IF02 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20020920 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20021023 Year of fee payment: 20 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20021223 Year of fee payment: 20 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20031013 Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20031013 Ref country code: CH Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20031013 |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: PE20 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |