EP0071124B1 - Fälschungssicheres Dokument und Verfahren zu seiner Herstellung - Google Patents
Fälschungssicheres Dokument und Verfahren zu seiner Herstellung Download PDFInfo
- Publication number
- EP0071124B1 EP0071124B1 EP82106441A EP82106441A EP0071124B1 EP 0071124 B1 EP0071124 B1 EP 0071124B1 EP 82106441 A EP82106441 A EP 82106441A EP 82106441 A EP82106441 A EP 82106441A EP 0071124 B1 EP0071124 B1 EP 0071124B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- poly
- document according
- information carrier
- alkyleneimine
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
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- 238000004519 manufacturing process Methods 0.000 title claims description 5
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- 239000004698 Polyethylene Substances 0.000 claims description 12
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 10
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical group O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 7
- 239000004793 Polystyrene Substances 0.000 claims description 7
- 229920003023 plastic Polymers 0.000 claims description 7
- 239000004033 plastic Substances 0.000 claims description 7
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- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
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- 150000001299 aldehydes Chemical group 0.000 claims description 3
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 2
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- 239000001828 Gelatine Substances 0.000 claims 2
- 150000002576 ketones Chemical group 0.000 claims 2
- JZLWSRCQCPAUDP-UHFFFAOYSA-N 1,3,5-triazine-2,4,6-triamine;urea Chemical compound NC(N)=O.NC1=NC(N)=NC(N)=N1 JZLWSRCQCPAUDP-UHFFFAOYSA-N 0.000 claims 1
- 229920001748 polybutylene Polymers 0.000 claims 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims 1
- 239000011888 foil Substances 0.000 abstract description 19
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical group C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
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- 229940100198 alkylating agent Drugs 0.000 description 2
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- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OZDGMOYKSFPLSE-UHFFFAOYSA-N 2-Methylaziridine Chemical compound CC1CN1 OZDGMOYKSFPLSE-UHFFFAOYSA-N 0.000 description 1
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- CSWPOLMVXVBCSV-UHFFFAOYSA-N 2-ethylaziridine Chemical compound CCC1CN1 CSWPOLMVXVBCSV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910015900 BF3 Inorganic materials 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
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- 229920000299 Nylon 12 Polymers 0.000 description 1
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- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- FYAMXEPQQLNQDM-UHFFFAOYSA-N Tris(1-aziridinyl)phosphine oxide Chemical compound C1CN1P(N1CC1)(=O)N1CC1 FYAMXEPQQLNQDM-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
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- 229920002494 Zein Polymers 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N acryloyl chloride Chemical compound ClC(=O)C=C HFBMWMNUJJDEQZ-UHFFFAOYSA-N 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
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- 239000002518 antifoaming agent Substances 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
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- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
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- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/405—Marking
- B42D25/415—Marking using chemicals
- B42D25/42—Marking using chemicals by photographic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/45—Associating two or more layers
- B42D25/455—Associating two or more layers using heat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/45—Associating two or more layers
- B42D25/46—Associating two or more layers using pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/40—Manufacture
- B42D25/45—Associating two or more layers
- B42D25/465—Associating two or more layers using chemicals or adhesives
- B42D25/47—Associating two or more layers using chemicals or adhesives using adhesives
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C11/00—Auxiliary processes in photography
- G03C11/08—Varnishing, e.g. application of protective layers on finished photographic prints
-
- B42D2033/04—
-
- B42D2033/14—
-
- B42D2033/28—
-
- B42D2033/30—
-
- B42D2035/08—
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S283/00—Printed matter
- Y10S283/904—Credit card
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/916—Fraud or tamper detecting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24843—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] with heat sealable or heat releasable adhesive layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
Definitions
- the invention relates to a tamper-proof document that is laminated on both sides with plastic films, and to a method for producing the tamper-proof document.
- Forgery-proof documents are becoming increasingly important. You will e.g. B. in the form of credit cards from banks, retail stores, oil companies, airlines or credit companies to facilitate cashless payments. Such documents contain information that relates to the owner as well as the body issuing the document and that is in both interests to be protected against counterfeiting. There has been no shortage of attempts to provide information carriers of the type mentioned above in a forgery-proof manner.
- the laminating film is prepared in places so that it does not adhere to the prepared areas on the paper surface of the films.
- An attempt to subsequently peel off the laminating film then has the consequence that when the unprepared areas are reached the tear breaks away from the paper surface due to the lower resistance and tears the paper surface (DE-OS 2511 367).
- a printed information carrier consisting of a paper card and a foil border, a so-called “composite ticking”, is welded between two transparent foils.
- the film border provides for an edge seal that encompasses the edges of the paper card, which makes it difficult to split the welded card (DE-OS 2 756 691).
- a disadvantage of the known lamination processes is that the foils used for this purpose only bond imperfectly to the surface of the information carrier during welding and thus offer only limited protection against counterfeiting. Edge welding also does not mean a significant improvement under these circumstances, since it can be easily removed and replaced again.
- the known lamination processes also have the disadvantage that the laminated film can be separated from the paper backing by heating or by chemical means.
- the card is not sufficiently forgery-proof.
- EP-A-31 521 describes an information carrier which is connected to films on both sides by means of a radically crosslinkable mass and which, after being crosslinked, constitutes a tamper-proof document.
- the manufacturing method is complex and leads to products whose flatness still leaves something to be desired.
- the invention has for its object to provide a forgery-proof document with an information carrier in the form of a photographically and printing-prepared photographic material, in which the entire surface of the information carrier is inextricably linked with a "- transparent film material and which on the Information attached to information carriers can no longer be accessed without destroying the information carrier and are therefore reliably protected against subsequent changes.
- the invention relates to a forgery-proof document, consisting of an information carrier laminated with at least one transparent film made of a photographic material, which contains at least one layer made of a plastic and is characterized in that the photographic material has a layer containing gelatin on its front and back has, on both sides with the transparent film via an adhesive layer containing poly-1,2-alkylenimine, and that the softening point of the plastic of the photographic material is lower than the softening point of the plastic of the transparent film.
- the polyalkyleneimine resins used in the adhesive layer according to the invention are in principle polymerization products of ethyleneimine and its C and N substitution products.
- the reactions leading to such polymerization products which may contain oxygen, sulfur or phosphorus as heteroatoms in addition to nitrogen, are described in “Methods of Organic Chemistry (Houben-Weyl)” Volume XIV / 2, pages 568-579.
- Details of polymerized C-alkyl and N-alkyl derivatives of ethyleneimine can be found in German Patents 888170 and 914 325. Further attention is drawn to G.D. Jones, J. Org. Chem. 9, 484 (1944); L.D. Klapp, Am. Soc. 70, 184 (1948); Y. Minoura, M. Takebayashi and C.C. Price, Am. Soc. 81: 4689 (1959); H. Bestian, Ang. Ch. 62, 451 (1950).
- polyalkyleneimine resins homopolymers or copolymers of ethyleneimine, propyleneimine and butyleneimine have been found, e.g. B. those described in US Pat. No. 3,418,204 and in particular those described in US Pat. No. 3,909,469.
- Polyethyleneimine with a molecular weight of 40,000 to 60,000 is preferred.
- the present adhesive layers are produced from non-gelling aqueous solutions or dispersions which contain polyalkyleneimine, optionally an acid or an alkylating agent and preferably a modifying agent.
- Suitable modifiers are saturated or unsaturated lower aliphatic ketones and aldehydes, preferably with up to 6 carbon atoms, e.g. B. formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, chloral, acetone or acrolein.
- a preferred modifier is formaldehyde.
- Polyfunctional compounds which are able to react with the poly-1,2-alkyleneimine, in particular with its imino groups have also proven to be suitable modifiers.
- Examples are polyhalohydrins, polyisocyanates, polyepoxides and polyaziridinyl compounds, such as. B. epichlorohydrin, hexamethylene diisocyanate, polyvinylcyclohexene dioxide, tris (1-aziridinyl) phosphine oxide, finally unsaturated carboxylic acids and their derivatives such as chlorides and esters, e.g. As acrylic acid, acrylic acid chloride or acrylates.
- acids or alkylating agents are inorganic and organic acids, e.g. B. aliphatic carboxylic acids with up to 6 carbon atoms such. B. acetic acid, propionic acid, butyric acid, malonic acid and succinic acid or their anhydrides. Acetic acid is preferred.
- carboxylic acids can also be used which have only limited solubility in water. In these cases it is possible to increase the solubility of the carboxylic acids by placing them in an organic solvent that is miscible with water, e.g. B. alcohol dissolves.
- hydrohalic acids sulfonic acids
- boron fluoride borofluoride etherate
- diazonium fluoroborates alkyl halides
- dialkyl sulfates carboxylic acid and sulfonic acid chlorides or sulfonic acid esters.
- compounds that split off acids such as. B. ⁇ -chloroethylamine, amine hydrochloride and also certain silver salts, especially silver perchlorates, are effective.
- the composition of the adhesive layer solution can be varied within wide limits.
- An example of a suitable composition is an adhesive layer solution which contains 0.05 to 10% by weight of poly-1,2-alkyleneimine, 0.01 to 2% by weight of modifying agent and optionally 0.01 to 1% by weight a carboxylic acid, based on the carboxyl groups of the carboxylic acid.
- a preferred adhesive layer composition contains 0.1 to 5% by weight of polyethyleneimine, 0.05 to 1% by weight of modifier, optionally 0.05 to 0.2% by weight of a carboxylic acid as defined above and the balance water or others additives necessary for setting certain properties.
- the adhesive layers used in the manner according to the invention develop excellent adhesive properties and a surprising resistance to water during drying.
- a small amount of a thickener can be added to the aqueous adhesive layer solution, or a resin which further improves the water resistance of the adhesive layer after heat treatment, or a defoaming agent in order to prevent foaming, which can have disadvantages for the use of the adhesive solution .
- a thickener, an additional resin or a defoamer can be used individually or together in the following amounts by weight: 0.01 to 1 wt .-% thickener, e.g. B.
- a thickener from the group of hydroxyethyl cellulose, polyvinyl alcohol and methyl cellulose, 0.01 to 2 wt .-% of a resin, such as melamine formaldehyde or urea formaldehyde resin, and 0.01 to 0.1 wt .-% of a defoamer, such as. B. Dimethylpolysiloxane.
- the weight ratio of the thickeners or the resins to the polyalkyleneimine depends on the nature of these additives. In general, ratios of 1: to 1: 100, preferably 1: 3 to 1: 30, are suitable.
- Thermoplastics such as z. B. polyolefins such as polyethylene, polypropylene, cellulose esters, polyvinyl acetate, polystyrene, polyvinyl chloride, polyvinylidene chloride, polyvinyl fluoride, polytetrahalogenethylene, polycarbonate, in particular based on bisphenol A, polyester, in particular based on polyethylene and polybutylene terephthalate, polyamides, e.g. B. polyamide-6 or polyamide-6,6, polyamide-12 or copolyamides.
- polyolefins such as polyethylene, polypropylene, cellulose esters, polyvinyl acetate, polystyrene, polyvinyl chloride, polyvinylidene chloride, polyvinyl fluoride, polytetrahalogenethylene, polycarbonate, in particular based on bisphenol A, polyester, in particular based on polyethylene and polybutylene terephthalate, polyamides, e.
- So-called composite films made of individual films of the same and different chemical composition can of course also be used.
- Examples include: polyethylene / polyamides, polypropylene / polyamides or polyolefin films with other film materials such as polyesters, e.g. B. polyethylene terephthalate.
- Suitable films and composite films are described in Ullmanns Encyklopadie der Technischen Chemie, 4th edition, volume 11, pages 673 ff.
- the individual foils can be connected by customary known, but preferably by the same adhesive layers that also serve to connect the composite foil to the information carrier.
- the thickness of the foils used according to the invention depends on the desired rigidity of the identification document. In general, film thicknesses between 15 and 250 microns will suffice; thicknesses between 50 and 200 ⁇ m are preferred.
- the surface of the film intended to absorb the adhesive layer composition can be subjected to a pretreatment prior to coating to improve the bond between the film and the adhesive layer, which ensures a uniform application of the coating solution and increases its adhesive strength. Good results are obtained e.g. B. with a conventional corona treatment.
- the application of the adhesive layer composition to the film can be carried out using the usual methods in the paint industry, such as. B. spraying, rolling, knife coating, printing, dipping, spinning, flooding, brushing, brushing, etc. take place.
- the dry layer thickness of the adhesive layer depends on the desired requirements and the expected adhesive effect. In general, usable results will be achieved with dry film thicknesses of 0.05 to 10 f.lm. Dry layer thicknesses of 0.05 to 2 f.Lm. Dry layer applications of 0.05-0.5 g per m 2 , based on poly-1,2-alkenyleneimine, are particularly preferred.
- the information carrier will consist of a photographic material containing a light-sensitive silver halide emulsion layer that is constructed in the usual way, that is to say a light-sensitive layer, and contains at least one layer made of a plastic.
- the silver or dye information contained in the photosensitive layer is produced by imagewise exposure and the usual photographic processing.
- Both photographic paper and films containing black and white or color photographic records, image and / or characters and / or other information or other identification features can be used as information carriers.
- the layer support of such photographic information supports can consist of the usual materials used in technical or image photography. Examples include polyolefin-laminated papers and the usual film documents, e.g. B. from cellulose triacetate or polyester, optionally called pigmented, opaque support.
- the photographic emulsion or auxiliary layers of such information carriers have the compositions generally used in photographic materials.
- Examples of light-sensitive photographic layers with which the information carrier can be equipped are layers which are based on non-sensitized silver halide emulsions or spectrally sensitized silver halide emulsions.
- the known gelatin layers used for the various photographic black-and-white and color processes, negative, positive and diffusion transfer processes or printing processes are therefore suitable. Not only gelatin alone can be contained as a binder in the photographic gelatin layers.
- the layers can also contain the usual additives for changing the mechanical properties of photographic layers, such as.
- the information carrier can contain further security or identification features of the most varied types,. which can be created both photographically and by lettering, printing or embossing.
- z. B. can also be attached by machine, magnetically and optically readable data.
- the information carrier according to the invention does not differ in any way from the information carriers used in known documents.
- polyolefin-laminated paper is used as the layer support for the information carrier, it has proven expedient to equip the paper with a polyolefin, the melting point of which is about 10-30 ° C. lower than the melting point of the film of the film material carrying the adhesive layer.
- the film is heated to about 50 to 150 ° C and pressed against the surface of the information carrier, so that a bubble and crease-free laminate is formed.
- the lamination is supported by applying pressures in the range of 1 to 10 kp / cm 3 .
- the lamination, on both sides of the information carrier, which on the front and Back contains gelatin, is advantageously carried out continuously by bringing the individual information carriers together onto the foils running off the supply rolls and provided with the adhesive layer.
- the parts containing the information carriers can then be punched out of the resulting band-shaped laminate, the welded film being separated at a distance of approximately 1 to 2 mm from the edge of the information carrier, depending on the thickness of the information carrier.
- a wrapping of the information carrier which is closed on all sides is obtained, which makes subsequent edge welding unnecessary.
- discontinuous lamination using sheet-shaped pieces of film leads to the same results.
- the documents described are excellent forgery-proof. Just like the foils with the information carrier, the foil parts protruding beyond the information carrier are connected to one another in a practically inseparable manner. Even with the help of heat, the document can no longer be separated without completely destroying the information carrier.
- Conventional photographic paper was used as information carrier, the layer carrier of which consisted of paper laminated on both sides with polyethylene, which had an m 2 weight of approximately 120 g.
- the softening point of the polyethylene of the support was 110 ° C.
- the support was equipped with a light-sensitive silver halide gelatin emulsion layer and with a gelatin-containing protective layer and back layer, both of the same composition.
- a picture of the ID card holder along with the corresponding information was exposed, developed and fixed on the information carrier.
- the information carrier with the photographic and printing technology applied identification features was now placed between 2 of the above-mentioned polyethylene foils, the softening point of which was approximately 122 ° C., so that the adhesive layers of the foils came into contact with the two surfaces of the information carrier and the foils about 1 mm above the Protruding edge of the information carrier.
- the package was then passed between two rolls heated to 90 ° C. and pressed together with a pressure of approximately 1.5 kp / cm 2 .
- the polyethylene films were so firmly connected to the information carrier that when trying to separate the document after cutting the edge bonds while heated (about 100 ° C), the paper support of the information carrier was destroyed, but its remnants were removed from the films were recorded, which were also irreversibly stretched.
- the example was repeated, using a two-component material based on a polyisocyanate and a resin component containing hydroxyl groups (laminating adhesive EPS 71 from Dr. Kurt.) Both for bonding the composite film itself and for bonding the composite film to the information carrier instead of the adhesive layer described in the example Herbert's Wuppertal) existing adhesive layer was used.
- laminate adhesive EPS 71 from Dr. Kurt.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Laminated Bodies (AREA)
- Credit Cards Or The Like (AREA)
- Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Aiming, Guidance, Guns With A Light Source, Armor, Camouflage, And Targets (AREA)
- Forging (AREA)
- Iron Core Of Rotating Electric Machines (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Compounds Of Unknown Constitution (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Printing Methods (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
- Holders For Sensitive Materials And Originals (AREA)
- Document Processing Apparatus (AREA)
- Developing Agents For Electrophotography (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Lubricants (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT82106441T ATE26087T1 (de) | 1981-07-30 | 1982-07-17 | Faelschungssicheres dokument und verfahren zu seiner herstellung. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19813130071 DE3130071A1 (de) | 1981-07-30 | 1981-07-30 | Faelschungssicheres dokument und verfahren zu seiner herstellung |
DE3130071 | 1981-07-30 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0071124A2 EP0071124A2 (de) | 1983-02-09 |
EP0071124A3 EP0071124A3 (en) | 1983-07-27 |
EP0071124B1 true EP0071124B1 (de) | 1987-03-25 |
Family
ID=6138094
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82106441A Expired EP0071124B1 (de) | 1981-07-30 | 1982-07-17 | Fälschungssicheres Dokument und Verfahren zu seiner Herstellung |
Country Status (16)
Country | Link |
---|---|
US (1) | US4456667A (fi) |
EP (1) | EP0071124B1 (fi) |
JP (1) | JPS5825984A (fi) |
AT (1) | ATE26087T1 (fi) |
AU (1) | AU553306B2 (fi) |
CA (1) | CA1191438A (fi) |
DE (2) | DE3130071A1 (fi) |
DK (1) | DK340082A (fi) |
ES (1) | ES514516A0 (fi) |
FI (1) | FI77607C (fi) |
GR (1) | GR76239B (fi) |
IE (1) | IE53072B1 (fi) |
IL (1) | IL66154A (fi) |
NO (1) | NO162803B (fi) |
NZ (1) | NZ201393A (fi) |
PT (1) | PT75291B (fi) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2129371A (en) * | 1982-11-05 | 1984-05-16 | De La Rue Thomas & Co Ltd | Identity cards |
US4749084A (en) * | 1986-11-12 | 1988-06-07 | Minnesota Mining And Manufacturing Co. | Tamper-indicating package with randomly disposed filaments |
US4760919A (en) * | 1987-07-30 | 1988-08-02 | Minnesota Mining And Manufacturing Company | Tamper-indicating package |
US4971646A (en) * | 1989-03-21 | 1990-11-20 | Schell Russell W | Method for forming a hologram film laminate and the hologram laminated product formed thereby |
US5011707A (en) * | 1989-03-21 | 1991-04-30 | Schell Russell W | Method for applying adhesive to a hologram film |
DE4021908C2 (de) * | 1990-07-10 | 2002-04-25 | Gao Ges Automation Org | Verfahren zur Herstellung eines Substrats mit einem optisch variablen Element und Verwendung des Substrats |
US5250348A (en) * | 1991-12-09 | 1993-10-05 | International Paper Company | Improved wrapper paper for use in very low contact pressure applications |
US5261987A (en) * | 1992-06-05 | 1993-11-16 | Eastman Kodak Company | Method of making an identification card |
FR2699109B1 (fr) * | 1992-12-15 | 1995-01-06 | Thomson Csf | Procédé de plastification de documents découpés dans une feuille. |
EP0685079B1 (en) * | 1993-02-16 | 1997-10-22 | Minnesota Mining And Manufacturing Company | Thermal print receptive and frangible retroreflective polymeric sheetings |
GB2321977B (en) * | 1997-02-10 | 2001-10-03 | Andrew Cunnigham Thomson | Mouldable photographic material |
DE19744595A1 (de) * | 1997-10-09 | 1999-04-15 | Hetzel Gmbh & Co Kg | Verfahren zum Herstellen von Laminiertaschen und Laminiertasche |
US6221545B1 (en) | 1999-09-09 | 2001-04-24 | Imation Corp. | Adhesives for preparing a multilayer laminate featuring an ink-bearing surface bonded to a second surface |
US20040161712A1 (en) * | 2002-11-15 | 2004-08-19 | Agfa-Gevaert | Deformable colour photographic silver halide material |
DE102007052947A1 (de) * | 2007-10-31 | 2009-05-07 | Bayer Materialscience Ag | Verfahren zur Herstellung eines Polycarbonat-Schichtverbundes |
AT527110A1 (de) * | 2023-07-27 | 2024-09-15 | Hueck Folien Ges M B H | Sicherheitselement mit Transferfolie und Verfahren zur Herstellung |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0031521A2 (de) * | 1979-12-24 | 1981-07-08 | Agfa-Gevaert AG | Verfahren zur Herstellung fälschungssicherer Dokumente |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3614839A (en) * | 1968-04-01 | 1971-10-26 | Polaroid Corp | Id card laminar structures and processes for making same |
CA981303A (en) * | 1971-07-02 | 1976-01-06 | Shigeharu Matsumoto | Identification card |
US3871119A (en) * | 1972-02-28 | 1975-03-18 | Avant Ind | Laminated identification card |
GB1346960A (en) * | 1972-09-20 | 1974-02-13 | Wiggins Teape Research Dev Ltd | Polymer-coated paper incorporating an antistatic agent |
US3909469A (en) * | 1972-10-20 | 1975-09-30 | Adolph Miller | Polyethylenimine adhesive |
US4152476A (en) * | 1977-03-04 | 1979-05-01 | Champion International Corporation | Laminate bearing a magnetic tape |
US4322461A (en) * | 1980-01-07 | 1982-03-30 | Polaroid Corporation | ID Card laminar structures and a method for preparation thereof using a transfered adhesive |
-
1981
- 1981-07-30 DE DE19813130071 patent/DE3130071A1/de not_active Withdrawn
-
1982
- 1982-06-28 IL IL66154A patent/IL66154A/xx not_active IP Right Cessation
- 1982-07-09 FI FI822465A patent/FI77607C/fi not_active IP Right Cessation
- 1982-07-09 NO NO822394A patent/NO162803B/no unknown
- 1982-07-13 AU AU85953/82A patent/AU553306B2/en not_active Ceased
- 1982-07-17 EP EP82106441A patent/EP0071124B1/de not_active Expired
- 1982-07-17 DE DE8282106441T patent/DE3275824D1/de not_active Expired
- 1982-07-17 AT AT82106441T patent/ATE26087T1/de active
- 1982-07-21 PT PT75291A patent/PT75291B/pt not_active IP Right Cessation
- 1982-07-26 JP JP57129111A patent/JPS5825984A/ja active Granted
- 1982-07-26 US US06/401,655 patent/US4456667A/en not_active Expired - Lifetime
- 1982-07-27 NZ NZ201393A patent/NZ201393A/xx unknown
- 1982-07-28 CA CA000408293A patent/CA1191438A/en not_active Expired
- 1982-07-28 GR GR68888A patent/GR76239B/el unknown
- 1982-07-29 DK DK340082A patent/DK340082A/da not_active Application Discontinuation
- 1982-07-29 IE IE1825/82A patent/IE53072B1/en unknown
- 1982-07-29 ES ES514516A patent/ES514516A0/es active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0031521A2 (de) * | 1979-12-24 | 1981-07-08 | Agfa-Gevaert AG | Verfahren zur Herstellung fälschungssicherer Dokumente |
Also Published As
Publication number | Publication date |
---|---|
FI822465A0 (fi) | 1982-07-09 |
CA1191438A (en) | 1985-08-06 |
JPH0136438B2 (fi) | 1989-07-31 |
ATE26087T1 (de) | 1987-04-15 |
DK340082A (da) | 1983-01-31 |
IE821825L (en) | 1983-01-30 |
IE53072B1 (en) | 1988-05-25 |
ES8305635A1 (es) | 1983-04-16 |
US4456667A (en) | 1984-06-26 |
NO822394L (no) | 1983-01-31 |
FI77607B (fi) | 1988-12-30 |
GR76239B (fi) | 1984-08-04 |
EP0071124A2 (de) | 1983-02-09 |
JPS5825984A (ja) | 1983-02-16 |
AU553306B2 (en) | 1986-07-10 |
PT75291A (en) | 1982-08-01 |
DE3130071A1 (de) | 1983-02-17 |
ES514516A0 (es) | 1983-04-16 |
FI822465L (fi) | 1983-02-01 |
NZ201393A (en) | 1985-08-16 |
DE3275824D1 (en) | 1987-04-30 |
EP0071124A3 (en) | 1983-07-27 |
NO162803B (no) | 1989-11-13 |
FI77607C (fi) | 1989-04-10 |
PT75291B (en) | 1984-07-30 |
AU8595382A (en) | 1983-02-03 |
IL66154A (en) | 1986-10-31 |
IL66154A0 (en) | 1982-09-30 |
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