EP0011814B1 - Procédé de teinture des mélanges de polyester et laine - Google Patents

Procédé de teinture des mélanges de polyester et laine Download PDF

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Publication number
EP0011814B1
EP0011814B1 EP79104617A EP79104617A EP0011814B1 EP 0011814 B1 EP0011814 B1 EP 0011814B1 EP 79104617 A EP79104617 A EP 79104617A EP 79104617 A EP79104617 A EP 79104617A EP 0011814 B1 EP0011814 B1 EP 0011814B1
Authority
EP
European Patent Office
Prior art keywords
polyester
dyeing
wool
alkyl
carriers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP79104617A
Other languages
German (de)
English (en)
Other versions
EP0011814A1 (fr
Inventor
Hans Dr. Schulze
Klaus Dr. Walz
Karlhans Jakobs
Günther Dr. Boehmke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0011814A1 publication Critical patent/EP0011814A1/fr
Application granted granted Critical
Publication of EP0011814B1 publication Critical patent/EP0011814B1/fr
Expired legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/6515—Hydrocarbons
    • D06P1/65156—Halogen-containing hydrocarbons

Definitions

  • the required amounts of the chlorinated alkylbenzenes of the formula (I) to be used according to the invention can easily be determined from case to case by preliminary search. In general, amounts of 1 to 7 g per liter of dyeing liquor have proven themselves in the usual liquor ratios of 1: 5 to 1:40, or 10 to 40 g per liter of padding liquor.
  • chlorinated alkyl benzenes to be used according to the invention are well compatible with other carriers, they can also be used in a mixture with known other carriers.
  • the chlorinated alkyl benzenes of the formula (I) to be used according to the invention are advantageously used together with anionic or nonionic emulsifiers or dispersants.
  • the disperse dyes used in the dyeing process according to the invention are the disperse dyes usually used for dyeing polyesters and cellulose esters, as described, for example, in "Color Index” Vol. 2, pp. 2483-2741, 3rd edition (1971).
  • the dyeing of the structures consisting of polyesters or cellulose esters and wool in the presence of the chlorinated alkylbenzenes to be used according to the invention is carried out by customary continuous or batch processes; The following may be mentioned as such: the customary process operating at 98 ° C., the high temperature and the thermosol process.
  • the isomer mixtures such as those obtained in the industrial chlorination of toluene, have been found to be particularly suitable.
  • Threads, fibers, fabrics, knitted fabrics, films and foils made of polyesters, such as polyterephthalic acid glycol esters, or polyesters made of 1,4-bis (hydroxymethyl) cyclohexane and terephthalic acid, and cellulose esters, e.g. Cellulose triacetate, with disperse dyes in deep shades and excellent to dye evenly.
  • polyesters such as polyterephthalic acid glycol esters, or polyesters made of 1,4-bis (hydroxymethyl) cyclohexane and terephthalic acid
  • cellulose esters e.g. Cellulose triacetate
  • Disperse dyes such as halobenzenes, alkyl phthalimides, aromatic carboxylic acid esters, methyl and methoxynaphthalenes, diphenyl, diphenyl ether, o-, m-up-oxydiphenyls or p-oxydiphenyl ethers.
  • halobenzenes alkyl phthalimides
  • aromatic carboxylic acid esters methyl and methoxynaphthalenes
  • diphenyl diphenyl ether
  • o-, m-up-oxydiphenyls or p-oxydiphenyl ethers o-, m-up-oxydiphenyls or p-oxydiphenyl ethers.
  • Diphenyl has good carrier properties, but it has the disadvantage of causing stains on the textiles because, due to its high melting point, it easily crystallizes out in the dyebaths and emulsifies poorly when the baths are heated.
  • Diphenyl ether has the disadvantage that its carrier activity depends strongly on the constitution of the disperse dye used, and therefore when dyeing with dye combinations, e.g. those for the production of gray and olive tones, no reproducible colorations can be obtained.
  • p-oxy-diphenyl has good carrier properties, it cannot be used as a carrier in the normal dyeing process at 98-100 ° C, since it is still solid at these temperatures. It also affects the lightfastness of the dyeings.
  • chlorinated alkylbenzenes to be used according to the invention have the advantages over these carriers mentioned. that they do not cause stains, that they do not adversely affect the lightfastness of the dyeings, that their effectiveness is independent of the dye constitution, that they can therefore be used to produce reproducible combination dyeings and that the odor nuisance is low.
  • the chlorinated alkyl benzenes have the advantage that they are effective even in lower concentrations. It should also be emphasized that they at least do not impair the build-up capacity of the disperse dyes, if not improve them, as do other carriers which retain the dyes in the dyebath. Another advantage is the excellent compensation for thread structure differences of heat-set polyester material.
  • a combination with 1,2,4-trichlorobenzene has proven to be particularly advantageous. While a pure trichlorobenzene setting already crystallizes at + 10 ° C to + 17 ° C, suitable combinations with dichlorotoluene result in freezing points down to - 20 ° C.
  • the compounds (I) to be used according to the invention are superior in terms of constitution to the closest chlorobenzene even that the wool portion is less soiled when dyeing the polyester portion of polyester-wool blended materials.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Claims (1)

  1. Procédé de teinture de la fraction polyester de matériaux mixtes polyester-laine avec des colorants de dispersion, caractérisé en ce qu'on teint en présence d'alcoylbenzènes chlorés de formule générale:
    Figure imgb0004
    dans laquelle
    n = 1 à 3
    R = H, alcoyle ayant 1 à 4 atomes de carbone.
EP79104617A 1978-12-01 1979-11-21 Procédé de teinture des mélanges de polyester et laine Expired EP0011814B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2852027 1978-12-01
DE19782852027 DE2852027A1 (de) 1978-12-01 1978-12-01 Verfahren zum faerben von polyesterhaltigen materialien

Publications (2)

Publication Number Publication Date
EP0011814A1 EP0011814A1 (fr) 1980-06-11
EP0011814B1 true EP0011814B1 (fr) 1983-02-16

Family

ID=6056083

Family Applications (1)

Application Number Title Priority Date Filing Date
EP79104617A Expired EP0011814B1 (fr) 1978-12-01 1979-11-21 Procédé de teinture des mélanges de polyester et laine

Country Status (5)

Country Link
US (1) US4279614A (fr)
EP (1) EP0011814B1 (fr)
JP (1) JPS5580585A (fr)
BR (1) BR7907800A (fr)
DE (2) DE2852027A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1307482C (fr) * 1987-11-09 1992-09-15 Ronald G. Schoner Vecteurs et sequences d'expression dans la preparation de polypeptides
US5112292A (en) * 1989-01-09 1992-05-12 American Biomed, Inc. Helifoil pump

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1069902A (fr) * 1953-01-16 1954-07-13 Hoechst Ag Procédé de teinture d'articles obtenus à partir de chlorure de polyvinyle ou de copolymères dérivant du chlorure de vinyle et articles ainsi teints
DE1199732B (de) * 1957-01-05 1965-09-02 Kuhlmann Ets Verfahren zum Faerben bzw. Bedrucken von Polyesterfasern
FR2006021A1 (fr) * 1968-04-10 1969-12-19 Ici Ltd Procede de teinture de fibres synthetiques
NL6809649A (fr) * 1968-07-09 1968-11-25
US3644079A (en) * 1969-07-11 1972-02-22 Collins & Aikman Corp Method for improving the dyeability and for heat setting synthetic linear polyesters
US3650663A (en) * 1969-09-15 1972-03-21 Collins & Aikman Corp Method for treating synthetic linear polyesters fibers and film in the vapor phase to improve the dyeability and to heat set said polyesters
US3644080A (en) * 1969-09-15 1972-02-22 Collins & Aikman Co Method of printing synthetic linear polyester sheet materials
US3992143A (en) * 1971-03-23 1976-11-16 Bayer Aktiengesellschaft Exhaust process for the dyeing of synthetic fiber materials
NL7204838A (fr) * 1971-04-14 1972-10-17
US3894842A (en) * 1972-03-10 1975-07-15 Hoechst Ag Process for preparing dyeings and prints fast to light on synthetic fibers
US4013408A (en) * 1973-05-09 1977-03-22 Ciba-Geigy Corporation Exhaust process for the dyeing of synthetic organic textile materials in navy blue to black shades
US4018558A (en) * 1973-05-09 1977-04-19 Ciba-Geigy Corporation Exhaust process for the dyeing of synthetic organic textile material in navy blue to black shades

Also Published As

Publication number Publication date
US4279614A (en) 1981-07-21
DE2852027A1 (de) 1980-06-12
JPS5580585A (en) 1980-06-17
EP0011814A1 (fr) 1980-06-11
BR7907800A (pt) 1980-06-24
DE2964858D1 (en) 1983-03-24

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