EP0000583A2 - Masse à mouler, de haute résistance aux chocs, à base de polyamide et son utilisation sous forme d'objets moulés - Google Patents

Masse à mouler, de haute résistance aux chocs, à base de polyamide et son utilisation sous forme d'objets moulés Download PDF

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Publication number
EP0000583A2
EP0000583A2 EP78100511A EP78100511A EP0000583A2 EP 0000583 A2 EP0000583 A2 EP 0000583A2 EP 78100511 A EP78100511 A EP 78100511A EP 78100511 A EP78100511 A EP 78100511A EP 0000583 A2 EP0000583 A2 EP 0000583A2
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EP
European Patent Office
Prior art keywords
component
weight
meth
polyamide
acrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP78100511A
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German (de)
English (en)
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EP0000583B1 (fr
EP0000583B2 (fr
EP0000583A3 (en
Inventor
Rolf-Volker Dr. Meyer
Rolf Dr. Dhein
Friedrich Fahnler
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Bayer AG
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Bayer AG
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Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0000583A2 publication Critical patent/EP0000583A2/fr
Publication of EP0000583A3 publication Critical patent/EP0000583A3/xx
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers

Definitions

  • the invention relates to high-impact polymer alloys based on polyamides, which have a rel. Have a viscosity of at least 3; 5 or a k-value of at least 83 (according to Fikentscher).
  • the impact strength of moldings made of polyamide plastics depends considerably on the water content of the moldings.
  • those made from easy-flowing polyamide injection molding compositions with a medium molecular weight, and here again the shaped bodies made from highly crystalline polyamides are relatively sensitive to impact stress.
  • the impact strength of polyamides is improved by adding polymeric substances.
  • Polyethylenes and copolymers of vinyl acetate and ethylene have been used with moderate success.
  • polyamide alloys with particularly high notched impact strength are obtained when freshly sprayed if polyamides, in particular 6-polyamides, with a rel.
  • 6-polyamide is preferably used as the polyamide ven viscosity of at least 3.5 used.
  • using the hydrophobic and non-polar alloy partners mentioned 2) show 6-polyamides with a rel. Viscosity of at least 3.5, preferably at least 3.8, a compared to analog alloys based on 6-polyamides with the viscosity that is common in practice for the injection molding sector ( ⁇ rel approx. 3.0), a drastic improvement in the impact strength, as was previously the case in this ratio only with water, which is known to be partly built into the hydrogen bonds of the polyamide, was possible.
  • the notched impact strength can be doubled under normal conditions using high-molecular 6-polyamide compared to the normally viscous 6-polyamide.
  • Polymers of aliphatic monoolefins with C 2 -C 4 in particular polyethylene or polyethylene / polypropylene copolymers, preferably with melt indices in the range from 5 to 20 cm / 10 min (190 ° C.) are preferably used as polymer component 2a.
  • All or part of the (meth) acrylic acid can be present as a salt, preferably as a sodium or zinc salt.
  • the copolymers 2c) used are preferably copolymers of styrene, (meth) acrylic acid and (meth) acrylic acid esters with C 4 -C 10 , preferably C 4 -C 7 in the alcoholic component, particularly preferably n- or tert-butyl ester.
  • Suitable polymers according to 2d) are preferably high molecular weight polybutadienes and polyisoprenes, as well as copolymers of butadiene and / or isoprene with acrylonitrile, the proportion of acylnitrile preferably being 10-30 mol%.
  • the alloys can be produced by mixing the starting components at temperatures above the melting point of the polyamide used, advantageously at temperatures of 200-320 ° C., in particular at 260-290 ° C.
  • Devices in which the molding compositions according to the invention can be produced are conventional screw machines.
  • thermoplastic molding compositions can also incorporate stabilizers, mold release agents, lubricants, crystallization accelerators, plasticizers, pigments, dyes or fillers, such as glass fibers or asbestos.
  • Moldings made from the polymer alloys according to the invention have a relative to alloys based on 6-polyamides. Viscosity ⁇ 3.5 the same homogeneity and show no tendency to segregate. They show good surface properties and, compared to moldings made from pure polyamides, have a reduced water absorption.
  • the molding compounds are particularly suitable for extruder and injection molding processing for the production of various high-impact molded articles, among others. also Pohren.
  • the relative viscosity of the polyamides is measured on a 1 solution of the polymer in m-cresol at 25 ° C.
  • Example 1 In contrast to Example 1, a 6-polyamide with a rel. Viscosity of 3.0, measured as used in Example 1. The - as described in Example 1 - mixed components are extruded at 26 ° C. The product has a rel. Viscosity ⁇ rel of approx. 3.2, determined according to Example 1. Freshly sprayed test specimens show Alternating bending tests have excellent homogeneity and have a notched impact strength of 12 kJ / m 2 (DIN 53 453).

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
EP78100511A 1977-08-02 1978-07-26 Masse à mouler, de haute résistance aux chocs, à base de polyamide et son utilisation sous forme d'objets moulés Expired - Lifetime EP0000583B2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19772734693 DE2734693A1 (de) 1977-08-02 1977-08-02 Hochschlagzaehe polyamidlegierungen
DE2734693 1977-08-02

Publications (4)

Publication Number Publication Date
EP0000583A2 true EP0000583A2 (fr) 1979-02-07
EP0000583A3 EP0000583A3 (en) 1979-03-07
EP0000583B1 EP0000583B1 (fr) 1981-04-08
EP0000583B2 EP0000583B2 (fr) 1990-08-16

Family

ID=6015399

Family Applications (1)

Application Number Title Priority Date Filing Date
EP78100511A Expired - Lifetime EP0000583B2 (fr) 1977-08-02 1978-07-26 Masse à mouler, de haute résistance aux chocs, à base de polyamide et son utilisation sous forme d'objets moulés

Country Status (5)

Country Link
US (1) US4321336A (fr)
EP (1) EP0000583B2 (fr)
JP (1) JPS5428360A (fr)
DE (2) DE2734693A1 (fr)
IT (1) IT1106620B (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034704B1 (fr) * 1980-01-22 1984-04-11 E.I. Du Pont De Nemours And Company Mélanges à base de polyamide à ténacité améliorée et procédé de préparation
EP0109342A1 (fr) 1982-09-06 1984-05-23 Rhone-Poulenc Chimie Compositions de moulage à base de copolyamides semi-rigides dérivés de dimères d'acides gras, d'élastomères et éventuellement de polyamides conventionnels

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5965666A (en) * 1919-10-19 1999-10-12 Cheil Industries, Inc. Thermoplastic resin composition with high impact strength at low temperatures
US4356286A (en) * 1981-03-23 1982-10-26 The Firestone Tire & Rubber Company Thermoplastic elastomer blends of a nitrile rubber and a crystalline polyamide mixture
US4383084A (en) * 1981-05-14 1983-05-10 Standard Oil Company (Indiana) Polyamide-polyolefin compositions
US4874817A (en) * 1982-05-07 1989-10-17 E. I. Du Pont De Nemours And Company Compositions of imidized acrylic polymers and polyamides
US4415706A (en) * 1982-11-10 1983-11-15 Rohm And Haas Company Compatible blends of polyglutarimides and polyamides
US4525531A (en) * 1983-04-26 1985-06-25 Raychem Corporation Polymeric compositions suitable for use in the medical field and containing a polyolefin, a polysiloxane and an elastomer
GB8317223D0 (en) * 1983-06-24 1983-07-27 Ici Plc Polyamide articles
US4536541A (en) * 1984-02-27 1985-08-20 E. I. Du Pont De Nemours And Company High impact resistant polyamide
EP0154037A3 (fr) * 1984-02-29 1987-02-04 The Dow Chemical Company Mélanges de polyamides aromatiques-aliphatiques et de modificateur d'impact
US4562228A (en) * 1984-02-29 1985-12-31 The Upjohn Company Polymer blends
DE3544761A1 (de) * 1985-12-18 1987-06-19 Basf Ag Thermoplastische formmassen auf der basis von polyamiden und styrolhaltigen polymeren
FR2592388B1 (fr) * 1985-12-30 1988-02-26 Atochem Alliages a base de polyamide, polyetheramide et elastomere thermoplastique
DE3604348A1 (de) * 1986-02-12 1987-08-13 Basf Ag Thermoplastische formmassen
DE3604376A1 (de) * 1986-02-12 1987-08-13 Basf Ag Thermoplastische formmassen
DE3604349A1 (de) * 1986-02-12 1987-08-13 Basf Ag Thermoplastische formmassen
DE3709238A1 (de) * 1986-11-05 1988-05-11 Bayer Ag Silikonhaltige polyamidmassen
DE3637677A1 (de) * 1986-11-05 1988-05-19 Bayer Ag Schlagzaehe, dimensionsstabile polyamid-formmassen
DE3738876A1 (de) * 1986-11-18 1988-05-26 Mitsubishi Monsanto Chem Geformtes amidharz-produkt und verfahren zu dessen herstellung
US5340876A (en) * 1987-03-24 1994-08-23 Bayer Aktiengesellschaft Thermoplastic moulding compounds of polyamides and resin copolymers
US4966941A (en) * 1987-07-14 1990-10-30 E. I. Du Pont De Nemours And Company Nylon compositions for blowmolding
US4885340A (en) * 1988-03-28 1989-12-05 Asahi Kasei Kogyo Kabushiki Kaisha High impact polyamide composition
IT1245603B (it) * 1991-03-29 1994-09-29 Montedipe Srl Composizioni termoplastiche a migliorate caratteristiche meccaniche
US6380289B1 (en) 1993-06-28 2002-04-30 3M Innovative Properties Company Thermoplastic composition comprising fluoroaliphatic radical-containing surface-modifying additive
US5376712A (en) * 1993-09-09 1994-12-27 The University Of Akron High impact strength polyamides
US6685871B2 (en) * 2001-05-15 2004-02-03 Honeywell International Inc. Toughened biaxially oriented film
EP2660372A1 (fr) * 2012-05-04 2013-11-06 LANXESS Deutschland GmbH Fibres thermoplastiques avec une tension de surface réduite
US20150203682A1 (en) * 2012-07-26 2015-07-23 Invista North America S.A.R.L. Thermoplastic composition for use in high impact applications
US9388312B2 (en) * 2012-07-26 2016-07-12 Invista North America S.A.R.L. Thermoplastic composition for use in high impact applications
CN106536632B (zh) 2014-07-25 2019-06-11 帝斯曼知识产权资产管理有限公司 热稳定的聚酰胺组合物
WO2016012558A1 (fr) * 2014-07-25 2016-01-28 Dsm Ip Assets B.V. Récipient moulé par soufflage
TW201728680A (zh) * 2015-10-30 2017-08-16 宇部興產股份有限公司 聚醯胺樹脂組成物及薄膜
US20220169848A1 (en) 2019-03-26 2022-06-02 Dow-Mitsui Polychemicals Co., Ltd. Resin composition and molded body

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1386563A (fr) * 1962-12-31 1965-01-22 Du Pont Mélanges thermoplastiques de polyamides et de polymères d'oléfines contenant des acides
GB990194A (en) * 1961-06-09 1965-04-28 Borg Warner Resin blends
US3218371A (en) * 1961-07-31 1965-11-16 Borg Warner Blends of (1) epsilon caprolactam, (2) rubbery butadiene-acrylonitrile copolymers, and (3) resinous styrene-acrylonitrile copolymers
GB1072635A (en) * 1964-06-22 1967-06-21 Continental Can Co Polyolefin compositions
GB1157569A (en) * 1966-11-04 1969-07-09 Du Pont Polyamide/Polyethylene Blends.
FR2037979A5 (en) * 1969-03-11 1970-12-31 Ici Ltd Mixtures of polyamides with ethylene copol - ymers have improved flexibility and impact
FR2344594A1 (fr) * 1976-03-20 1977-10-14 Bayer Ag Compositions de moulage thermoplastiques a haute resistance au choc
DE2616092A1 (de) * 1976-04-13 1977-11-03 Bayer Ag Verfahren zur herstellung von polymeridispergatoren fuer polymerlegierungen
FR2359179A1 (fr) * 1976-07-22 1978-02-17 Bayer Ag Produits moules en polyamide
FR2372202A1 (fr) * 1976-11-30 1978-06-23 Bayer Ag Matieres a mouler thermoplastiques a base de polyamide-6
FR2372866A1 (fr) * 1976-12-01 1978-06-30 Bayer Ag Matieres a mouler thermoplastiques a base de polyamides

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA740501A (en) * 1966-08-09 E.I. Du Pont De Nemours And Company Thermoplastic blends of polyamides and acid-containing olefin polymers
CH441742A (de) * 1964-01-31 1967-08-15 Igo Plast Faigle & Co Kunststoffmaterial, vorzugsweise für Lager und ähnliche Maschinenelemente, sowie Verfahren zu dessen Herstellung
FR1570562A (fr) * 1968-03-22 1969-06-13
DE1908468B2 (de) 1969-02-20 1976-10-28 Bayer Ag, 5090 Leverkusen Homogene spritzfaehige mischungen von polyamiden und polyolefinen
GB1241361A (en) * 1969-03-11 1971-08-04 Ici Ltd Thermoplastic polymer blends
US3668274A (en) * 1970-09-10 1972-06-06 Rohm & Haas Acrylic modifiers for polycarbonamides
US3796771A (en) * 1970-09-10 1974-03-12 Rohm & Haas Acrylic modifiers for polycarbonamides
JPS5710144B2 (fr) * 1974-03-11 1982-02-25
JPS51125451A (en) * 1975-04-03 1976-11-01 Asahi Chem Ind Co Ltd Polyamide composition
JPS51143061A (en) * 1975-05-23 1976-12-09 Du Pont Reinforced multiiphase thermoplastic compound
JPS5280352A (en) * 1975-12-27 1977-07-06 Asahi Chem Ind Co Ltd Polyamide compositions
JPS5321252A (en) * 1976-08-10 1978-02-27 Toray Ind Inc High impact polyamide composition
US4086295A (en) * 1976-12-16 1978-04-25 Asahi Kasei Kogyo Kabushiki Kaisha Polyamide composition
JPH04310366A (ja) * 1991-04-09 1992-11-02 Seiko Epson Corp 研磨方法

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB990194A (en) * 1961-06-09 1965-04-28 Borg Warner Resin blends
US3218371A (en) * 1961-07-31 1965-11-16 Borg Warner Blends of (1) epsilon caprolactam, (2) rubbery butadiene-acrylonitrile copolymers, and (3) resinous styrene-acrylonitrile copolymers
FR1386563A (fr) * 1962-12-31 1965-01-22 Du Pont Mélanges thermoplastiques de polyamides et de polymères d'oléfines contenant des acides
GB1072635A (en) * 1964-06-22 1967-06-21 Continental Can Co Polyolefin compositions
GB1157569A (en) * 1966-11-04 1969-07-09 Du Pont Polyamide/Polyethylene Blends.
FR2037979A5 (en) * 1969-03-11 1970-12-31 Ici Ltd Mixtures of polyamides with ethylene copol - ymers have improved flexibility and impact
FR2344594A1 (fr) * 1976-03-20 1977-10-14 Bayer Ag Compositions de moulage thermoplastiques a haute resistance au choc
DE2616092A1 (de) * 1976-04-13 1977-11-03 Bayer Ag Verfahren zur herstellung von polymeridispergatoren fuer polymerlegierungen
FR2359179A1 (fr) * 1976-07-22 1978-02-17 Bayer Ag Produits moules en polyamide
FR2372202A1 (fr) * 1976-11-30 1978-06-23 Bayer Ag Matieres a mouler thermoplastiques a base de polyamide-6
FR2372866A1 (fr) * 1976-12-01 1978-06-30 Bayer Ag Matieres a mouler thermoplastiques a base de polyamides

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0034704B1 (fr) * 1980-01-22 1984-04-11 E.I. Du Pont De Nemours And Company Mélanges à base de polyamide à ténacité améliorée et procédé de préparation
EP0109342A1 (fr) 1982-09-06 1984-05-23 Rhone-Poulenc Chimie Compositions de moulage à base de copolyamides semi-rigides dérivés de dimères d'acides gras, d'élastomères et éventuellement de polyamides conventionnels

Also Published As

Publication number Publication date
DE2860599D1 (en) 1981-04-30
JPS5428360A (en) 1979-03-02
JPS6232220B2 (fr) 1987-07-13
IT1106620B (it) 1985-11-11
EP0000583B1 (fr) 1981-04-08
EP0000583B2 (fr) 1990-08-16
US4321336A (en) 1982-03-23
EP0000583A3 (en) 1979-03-07
IT7850521A0 (it) 1978-07-28
DE2734693A1 (de) 1979-02-15

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