EA202192055A1 - Катализаторы, содержащие медь, оксид цинка, оксиды алюминия и кремния - Google Patents
Катализаторы, содержащие медь, оксид цинка, оксиды алюминия и кремнияInfo
- Publication number
- EA202192055A1 EA202192055A1 EA202192055A EA202192055A EA202192055A1 EA 202192055 A1 EA202192055 A1 EA 202192055A1 EA 202192055 A EA202192055 A EA 202192055A EA 202192055 A EA202192055 A EA 202192055A EA 202192055 A1 EA202192055 A1 EA 202192055A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalyst
- aluminum
- zinc oxide
- containing copper
- silicon oxides
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract 2
- 229910052802 copper Inorganic materials 0.000 title abstract 2
- 239000010949 copper Substances 0.000 title abstract 2
- 239000011787 zinc oxide Substances 0.000 title abstract 2
- 229910000611 Zinc aluminium Inorganic materials 0.000 title 1
- 229910052814 silicon oxide Inorganic materials 0.000 title 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 abstract 1
- 239000005751 Copper oxide Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0233—Compounds of Cu, Ag, Au
- B01J20/0237—Compounds of Cu
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/024—Compounds of Zn, Cd, Hg
- B01J20/0244—Compounds of Zn
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0248—Compounds of B, Al, Ga, In, Tl
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0251—Compounds of Si, Ge, Sn, Pb
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
- B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/10—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with water vapour
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1082—Composition of support materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Описан катализатор, пригодный для применения в реакциях конверсии оксида углерода, причем указанный катализатор находится в виде формованных элементов из порошка оксидного катализатора, при этом указанный катализатор включает от 30 до 70 мас.% оксида меди в сочетании с оксидом цинка, оксидами алюминия и кремния, при атомном соотношении Si:Al в диапазоне от 0,005 до 0,15:1, с площадью поверхности по результатам измерения методом БЭТ105 м2/г и площадью поверхности меди > 37 м2/г катализатора. Катализатор получают способом соосаждения с использованием алюмоксидного золя.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB1905293.5A GB201905293D0 (en) | 2019-04-15 | 2019-04-15 | Copper-containing catalysts |
PCT/GB2020/050669 WO2020212681A1 (en) | 2019-04-15 | 2020-03-16 | Catalysts containing copper, zinc oxide, alumina and silica |
Publications (1)
Publication Number | Publication Date |
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EA202192055A1 true EA202192055A1 (ru) | 2021-10-21 |
Family
ID=66809950
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA202192055A EA202192055A1 (ru) | 2019-04-15 | 2020-03-16 | Катализаторы, содержащие медь, оксид цинка, оксиды алюминия и кремния |
Country Status (9)
Country | Link |
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US (1) | US20220152597A1 (ru) |
EP (1) | EP3956058A1 (ru) |
CN (1) | CN113557087B (ru) |
AU (1) | AU2020257578A1 (ru) |
CA (1) | CA3130423A1 (ru) |
CL (1) | CL2021002375A1 (ru) |
EA (1) | EA202192055A1 (ru) |
GB (2) | GB201905293D0 (ru) |
WO (1) | WO2020212681A1 (ru) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB202015634D0 (en) * | 2020-10-02 | 2020-11-18 | Johnson Matthey Plc | Method for making copper-containing catalysts |
GB202015635D0 (en) * | 2020-10-02 | 2020-11-18 | Johnson Matthey Plc | Method for making copper-containing catalysts |
GB2606637B (en) | 2021-05-11 | 2023-07-26 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
CN113877362B (zh) * | 2021-10-12 | 2023-09-12 | 西安近代化学研究所 | 一种氮气和接近气体的选择性吸附和分离的方法 |
WO2023088893A1 (en) | 2021-11-16 | 2023-05-25 | Basf Se | A catalyst for the conversion of co2-rich syngas to methanol and conventional syngas to dimethyl ether |
GB2619796A (en) | 2022-05-09 | 2023-12-20 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
CN116020469A (zh) * | 2022-12-13 | 2023-04-28 | 南京邮电大学 | 一种抗烧结铜基甲醇合成催化剂的制备方法 |
CN116273020A (zh) * | 2023-02-23 | 2023-06-23 | 鄂尔多斯市瀚博科技有限公司 | 一种二氧化碳加氢制甲醇催化剂及合成方法 |
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DE3317725A1 (de) * | 1983-05-16 | 1984-11-22 | Süd-Chemie AG, 8000 München | Katalysator fuer die methanolsynthese |
GB8512684D0 (en) | 1985-05-20 | 1985-06-26 | Ici Plc | Oxidation process |
GB8521650D0 (en) | 1985-08-30 | 1985-10-02 | Ici Plc | Catalyst |
DE4206750A1 (de) * | 1992-03-04 | 1993-09-09 | Hoechst Ag | Verfahren zur herstellung von alkoholen oder aminen |
JP3232326B2 (ja) | 1997-03-11 | 2001-11-26 | 経済産業省産業技術総合研究所長 | 銅系触媒およびその製造法 |
KR100457066B1 (ko) * | 2002-04-22 | 2004-11-12 | 애경유화 주식회사 | 수소화 반응촉매 및 그의 제조방법, 및 이 촉매를이용하여 무수말레인산으로부터 감마-부티로락톤을제조하는 방법 |
DE102005020630A1 (de) * | 2005-05-03 | 2006-11-23 | Süd-Chemie AG | Herstellung von Cu/Zn/Al-Katalysatoren über den Formiatweg |
GB0620793D0 (en) | 2006-10-20 | 2006-11-29 | Johnson Matthey Plc | Process |
US20090149324A1 (en) * | 2007-12-05 | 2009-06-11 | Basf Catalysts Llc | Low temperature water gas shift catalyst |
CN101306369B (zh) | 2008-07-11 | 2010-04-14 | 西南化工研究设计院 | 合成甲醇催化剂及其制备方法 |
GB0816709D0 (en) | 2008-09-12 | 2008-10-22 | Johnson Matthey Plc | Shaped heterogeneneous catalysts |
GB0910364D0 (en) * | 2009-06-17 | 2009-07-29 | Johnson Matthey Plc | Carbon oxides conversion process |
CN102574109B (zh) * | 2009-10-23 | 2014-12-31 | 三菱瓦斯化学株式会社 | 甲醇合成催化剂 |
CN101983765B (zh) * | 2010-11-15 | 2012-12-26 | 大连理工大学 | 一种助剂改性的二氧化碳催化加氢制甲醇的催化剂及制备方法 |
IN2014DN10249A (ru) * | 2012-06-04 | 2015-08-07 | Mitsui Chemicals Inc | |
GB201418475D0 (en) * | 2014-10-17 | 2014-12-03 | Johnson Matthey Plc | Catalyst and process |
CN105833876B (zh) * | 2016-04-15 | 2019-03-26 | 西安向阳航天材料股份有限公司 | 一种高活性铜锌铝低温变换催化剂及其制备方法 |
EP3305404A1 (en) * | 2016-10-10 | 2018-04-11 | National Petrochemical Company | Copper/zinc/aluminium catalyst for the methanol synthesis prepared from a binary zinc-aluminium precursor solution |
-
2019
- 2019-04-15 GB GBGB1905293.5A patent/GB201905293D0/en not_active Ceased
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2020
- 2020-03-16 GB GB2003791.7A patent/GB2583185B/en active Active
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- 2020-03-16 CN CN202080018734.6A patent/CN113557087B/zh active Active
- 2020-03-16 EP EP20715137.4A patent/EP3956058A1/en active Pending
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- 2020-03-16 EA EA202192055A patent/EA202192055A1/ru unknown
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CN113557087A (zh) | 2021-10-26 |
AU2020257578A1 (en) | 2021-09-16 |
CA3130423A1 (en) | 2020-10-22 |
GB2583185B (en) | 2022-04-06 |
GB2583185A (en) | 2020-10-21 |
EP3956058A1 (en) | 2022-02-23 |
CN113557087B (zh) | 2024-03-19 |
JP2022528606A (ja) | 2022-06-15 |
WO2020212681A1 (en) | 2020-10-22 |
CL2021002375A1 (es) | 2022-04-22 |
US20220152597A1 (en) | 2022-05-19 |
GB201905293D0 (en) | 2019-05-29 |
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