EA201590681A1 - Катализатор - Google Patents
КатализаторInfo
- Publication number
- EA201590681A1 EA201590681A1 EA201590681A EA201590681A EA201590681A1 EA 201590681 A1 EA201590681 A1 EA 201590681A1 EA 201590681 A EA201590681 A EA 201590681A EA 201590681 A EA201590681 A EA 201590681A EA 201590681 A1 EA201590681 A1 EA 201590681A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- catalyst
- solid form
- cocatalyst
- metallocene
- boric
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Катализатор, содержащий (i) металлоценовый комплекс металла группы (IV), причем указанный металлоцен содержит по меньшей мере два лиганда циклопентадиенилового типа, (ii) борный сокатализатор и (iii) алюмоксановый сокатализатор, причем указанный катализатор находится в твердой форме, предпочтительно в форме твердых частиц, и не содержит внешнего носителя.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP12189123.8A EP2722345B1 (en) | 2012-10-18 | 2012-10-18 | Catalyst for the polymerisation of olefins |
PCT/EP2013/071760 WO2014060534A1 (en) | 2012-10-18 | 2013-10-17 | Catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201590681A1 true EA201590681A1 (ru) | 2015-10-30 |
EA031952B1 EA031952B1 (ru) | 2019-03-29 |
Family
ID=47044892
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201590681A EA031952B1 (ru) | 2012-10-18 | 2013-10-17 | Катализатор |
Country Status (11)
Country | Link |
---|---|
US (1) | US9475890B2 (ru) |
EP (1) | EP2722345B1 (ru) |
JP (1) | JP6300809B2 (ru) |
KR (1) | KR101900139B1 (ru) |
CN (1) | CN104903361B (ru) |
BR (1) | BR112015008105B1 (ru) |
CA (1) | CA2888385A1 (ru) |
EA (1) | EA031952B1 (ru) |
ES (1) | ES2711081T3 (ru) |
SA (1) | SA515360304B1 (ru) |
WO (1) | WO2014060534A1 (ru) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2722344B1 (en) | 2012-10-18 | 2017-03-22 | Borealis AG | Polymerisation process |
EP2722346A1 (en) | 2012-10-18 | 2014-04-23 | Borealis AG | Polymerisation process and catalyst |
EP2829558B1 (en) | 2013-07-24 | 2016-12-14 | Borealis AG | Process |
BR112020019339A2 (pt) * | 2018-03-30 | 2021-01-05 | Dow Global Technologies Llc | Sistema de catalisador, e, processo de polimerização para produzir polímero à base de etileno |
EP3790909A1 (en) | 2018-05-09 | 2021-03-17 | Borealis AG | Process for preparing propylene polymers |
EP3856794A1 (en) * | 2018-09-28 | 2021-08-04 | Borealis AG | A multi-stage process for producing a c2 to c8 olefin polymer composition |
Family Cites Families (56)
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ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
US5036034A (en) | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
FI89929C (fi) | 1990-12-28 | 1993-12-10 | Neste Oy | Foerfarande foer homo- eller sampolymerisering av eten |
US5416228A (en) | 1991-10-07 | 1995-05-16 | Fina Technology, Inc. | Process and catalyst for producing isotactic polyolefins |
DE4205932A1 (de) | 1992-02-27 | 1993-09-02 | Basf Ag | Verfahren zur herstellung von propenoligomeren |
JP3153000B2 (ja) * | 1992-06-11 | 2001-04-03 | 三菱化学株式会社 | α‐オレフィン重合体の製造法 |
US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
FI96866C (fi) | 1993-11-05 | 1996-09-10 | Borealis As | Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö |
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JP3352555B2 (ja) | 1994-12-01 | 2002-12-03 | 日本ポリオレフィン株式会社 | オレフィン類重合用触媒 |
JP4330176B2 (ja) * | 1995-10-19 | 2009-09-16 | ビーピー・コーポレーション・ノース・アメリカ・インコーポレーテッド | メタロセンを主成分とする高活性均一オレフィン重合系 |
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FI971565A (fi) | 1997-04-14 | 1998-10-15 | Borealis As | Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä |
DE19709866A1 (de) | 1997-03-11 | 1998-09-17 | Basf Ag | Geträgertes Katalysatorsystem zur Polymerisation von Alk-1-enen |
GB9708487D0 (en) | 1997-04-25 | 1997-06-18 | Bp Chem Int Ltd | Novel catalysts for olefin polymerisation |
US6316562B1 (en) | 1997-06-10 | 2001-11-13 | Peroxid-Chemie Gmbh & Co. Kg | Catalyst systems for (co-)polymerization reactions, metallocene amide halogenides, the production and use thereof |
JP3400988B2 (ja) | 1997-09-05 | 2003-04-28 | ビーピー ケミカルズ リミテッド | 重合触媒 |
GB9721559D0 (en) | 1997-10-11 | 1997-12-10 | Bp Chem Int Ltd | Novel polymerisation catalysts |
JP4817209B2 (ja) | 1998-08-11 | 2011-11-16 | ダウ グローバル テクノロジーズ エルエルシー | 触媒活性剤組成物 |
GB9826874D0 (en) | 1998-12-07 | 1999-01-27 | Borealis As | Process |
WO2002002576A1 (en) | 2000-06-30 | 2002-01-10 | Exxonmobil Chemical Patents Inc. | Bridged bis (indenyl) metallocene compounds |
EP1366089A2 (en) * | 2000-11-17 | 2003-12-03 | Univation Technologies LLC | A method for preparing a catalyst composition and its use in a polymerization process |
US6877107B2 (en) | 2001-07-05 | 2005-04-05 | Softwired Ag | Method for ensuring operation during node failures and network partitions in a clustered message passing server |
EP1323747A1 (en) * | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
JP4758650B2 (ja) | 2002-12-04 | 2011-08-31 | バーゼル・ポリオレフィン・ゲーエムベーハー | 1−ブテンポリマーの製造方法 |
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US7169864B2 (en) | 2004-12-01 | 2007-01-30 | Novolen Technology Holdings, C.V. | Metallocene catalysts, their synthesis and their use for the polymerization of olefins |
EA012018B1 (ru) | 2004-12-31 | 2009-06-30 | Бореалис Текнолоджи Ой | Способ получения катализатора полимеризации олефинов |
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JP5355113B2 (ja) | 2009-01-29 | 2013-11-27 | 株式会社Adeka | 一液型シアン酸エステル−エポキシ複合樹脂組成物 |
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EP2545083B1 (en) * | 2010-03-08 | 2016-06-29 | LG Chem, Ltd. | Method for preparing supported metallocene catalyst and method for preparing polyolefin using the same |
US8729206B2 (en) | 2010-04-28 | 2014-05-20 | Borealis Ag | Solid particulate catalysts comprising bridged metallocenes |
EP2383299B1 (en) | 2010-04-28 | 2017-12-20 | Borealis AG | Solid particulate catalysts comprising bridged metallocenes |
US20110294972A1 (en) | 2010-05-27 | 2011-12-01 | Basell Polyolefine Gmbh | Olefin Polymerization Catalysts |
ES2565438T3 (es) | 2010-07-01 | 2016-04-04 | Borealis Ag | Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores |
EP2402353B1 (en) | 2010-07-01 | 2018-04-25 | Borealis AG | Group 4 metallocenes useful as catalysts for the polymerization of olefins |
EP2428526A1 (en) | 2010-09-13 | 2012-03-14 | Borealis AG | Process for producing polyethylene with improved homogeneity |
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US8623974B2 (en) | 2011-03-25 | 2014-01-07 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
ES2572507T3 (es) | 2011-07-08 | 2016-05-31 | Borealis Ag | Copolímeros heterofásicos |
ES2719606T3 (es) | 2012-04-26 | 2019-07-11 | Borealis Ag | Reducción de las impurezas orgánicas en aguas residuales |
EP2722346A1 (en) | 2012-10-18 | 2014-04-23 | Borealis AG | Polymerisation process and catalyst |
EP2722344B1 (en) | 2012-10-18 | 2017-03-22 | Borealis AG | Polymerisation process |
-
2012
- 2012-10-18 EP EP12189123.8A patent/EP2722345B1/en active Active
- 2012-10-18 ES ES12189123T patent/ES2711081T3/es active Active
-
2013
- 2013-10-17 KR KR1020157012495A patent/KR101900139B1/ko active IP Right Grant
- 2013-10-17 BR BR112015008105-3A patent/BR112015008105B1/pt active IP Right Grant
- 2013-10-17 US US14/436,924 patent/US9475890B2/en active Active
- 2013-10-17 CA CA2888385A patent/CA2888385A1/en not_active Abandoned
- 2013-10-17 CN CN201380054664.XA patent/CN104903361B/zh active Active
- 2013-10-17 JP JP2015537258A patent/JP6300809B2/ja active Active
- 2013-10-17 WO PCT/EP2013/071760 patent/WO2014060534A1/en active Application Filing
- 2013-10-17 EA EA201590681A patent/EA031952B1/ru not_active IP Right Cessation
-
2015
- 2015-04-16 SA SA515360304A patent/SA515360304B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
JP6300809B2 (ja) | 2018-03-28 |
KR101900139B1 (ko) | 2018-11-08 |
EP2722345A1 (en) | 2014-04-23 |
EA031952B1 (ru) | 2019-03-29 |
SA515360304B1 (ar) | 2017-07-02 |
KR20150094599A (ko) | 2015-08-19 |
JP2015532346A (ja) | 2015-11-09 |
BR112015008105B1 (pt) | 2021-04-13 |
CA2888385A1 (en) | 2014-04-24 |
US20150266979A1 (en) | 2015-09-24 |
ES2711081T3 (es) | 2019-04-30 |
CN104903361B (zh) | 2017-08-25 |
EP2722345B1 (en) | 2018-12-05 |
BR112015008105A2 (pt) | 2017-07-04 |
CN104903361A (zh) | 2015-09-09 |
WO2014060534A1 (en) | 2014-04-24 |
US9475890B2 (en) | 2016-10-25 |
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