EA201590681A1 - Катализатор - Google Patents

Катализатор

Info

Publication number
EA201590681A1
EA201590681A1 EA201590681A EA201590681A EA201590681A1 EA 201590681 A1 EA201590681 A1 EA 201590681A1 EA 201590681 A EA201590681 A EA 201590681A EA 201590681 A EA201590681 A EA 201590681A EA 201590681 A1 EA201590681 A1 EA 201590681A1
Authority
EA
Eurasian Patent Office
Prior art keywords
catalyst
solid form
cocatalyst
metallocene
boric
Prior art date
Application number
EA201590681A
Other languages
English (en)
Other versions
EA031952B1 (ru
Inventor
Калле Каллио
Марья Мустонен
Лаури Хухтанен
Йохн Северн
Паскаль Кастро
Вилле Вирккунен
Ану-Леена Хонгелл
Исмо Лехтиниеми
Original Assignee
Бореалис Аг
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бореалис Аг filed Critical Бореалис Аг
Publication of EA201590681A1 publication Critical patent/EA201590681A1/ru
Publication of EA031952B1 publication Critical patent/EA031952B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Катализатор, содержащий (i) металлоценовый комплекс металла группы (IV), причем указанный металлоцен содержит по меньшей мере два лиганда циклопентадиенилового типа, (ii) борный сокатализатор и (iii) алюмоксановый сокатализатор, причем указанный катализатор находится в твердой форме, предпочтительно в форме твердых частиц, и не содержит внешнего носителя.
EA201590681A 2012-10-18 2013-10-17 Катализатор EA031952B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP12189123.8A EP2722345B1 (en) 2012-10-18 2012-10-18 Catalyst for the polymerisation of olefins
PCT/EP2013/071760 WO2014060534A1 (en) 2012-10-18 2013-10-17 Catalyst

Publications (2)

Publication Number Publication Date
EA201590681A1 true EA201590681A1 (ru) 2015-10-30
EA031952B1 EA031952B1 (ru) 2019-03-29

Family

ID=47044892

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201590681A EA031952B1 (ru) 2012-10-18 2013-10-17 Катализатор

Country Status (11)

Country Link
US (1) US9475890B2 (ru)
EP (1) EP2722345B1 (ru)
JP (1) JP6300809B2 (ru)
KR (1) KR101900139B1 (ru)
CN (1) CN104903361B (ru)
BR (1) BR112015008105B1 (ru)
CA (1) CA2888385A1 (ru)
EA (1) EA031952B1 (ru)
ES (1) ES2711081T3 (ru)
SA (1) SA515360304B1 (ru)
WO (1) WO2014060534A1 (ru)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2622627T3 (es) * 2012-10-18 2017-07-06 Borealis Ag Procedimiento de polimerización
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
EP2829558B1 (en) 2013-07-24 2016-12-14 Borealis AG Process
BR112020019339A2 (pt) * 2018-03-30 2021-01-05 Dow Global Technologies Llc Sistema de catalisador, e, processo de polimerização para produzir polímero à base de etileno
CN111902436B (zh) 2018-05-09 2023-06-30 博里利斯股份公司 用于制备丙烯聚合物的方法
EP3856794A1 (en) * 2018-09-28 2021-08-04 Borealis AG A multi-stage process for producing a c2 to c8 olefin polymer composition

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5077255A (en) 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
US5036034A (en) 1989-10-10 1991-07-30 Fina Technology, Inc. Catalyst for producing hemiisotactic polypropylene
FI89929C (fi) 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
US5416228A (en) 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
DE4205932A1 (de) 1992-02-27 1993-09-02 Basf Ag Verfahren zur herstellung von propenoligomeren
JP3153000B2 (ja) 1992-06-11 2001-04-03 三菱化学株式会社 α‐オレフィン重合体の製造法
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
JPH0820606A (ja) * 1994-07-07 1996-01-23 Mitsubishi Chem Corp α‐オレフィン重合用触媒およびそれを用いたα‐オレフィン重合体の製造法
JP3352555B2 (ja) 1994-12-01 2002-12-03 日本ポリオレフィン株式会社 オレフィン類重合用触媒
US5756609A (en) * 1995-10-19 1998-05-26 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
FI104826B (fi) 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
FI971565A (fi) 1997-04-14 1998-10-15 Borealis As Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä
DE19709866A1 (de) 1997-03-11 1998-09-17 Basf Ag Geträgertes Katalysatorsystem zur Polymerisation von Alk-1-enen
GB9708487D0 (en) 1997-04-25 1997-06-18 Bp Chem Int Ltd Novel catalysts for olefin polymerisation
WO1998056831A1 (de) 1997-06-10 1998-12-17 Peroxid-Chemie Gmbh & Co. Kg. Neue katalysatorsysteme für (co-)polymerisationsreaktionen, metallocenamidhalogenide, ihre herstellung und verwendung
BR9811621A (pt) 1997-09-05 2002-02-05 Bp Chem Int Ltd Catalisador de polimerização, sistema catalisador, processo para a polimerização de 1-olefinas, e composto de metal de transição contendo nitrogênio
GB9721559D0 (en) 1997-10-11 1997-12-10 Bp Chem Int Ltd Novel polymerisation catalysts
WO2000009515A1 (en) 1998-08-11 2000-02-24 The Dow Chemical Company Catalyst activator composition
GB9826874D0 (en) 1998-12-07 1999-01-27 Borealis As Process
JP2004502699A (ja) 2000-06-30 2004-01-29 エクソンモービル・ケミカル・パテンツ・インク 架橋ビス（インデニル）メタロセン化合物
JP2004514029A (ja) * 2000-11-17 2004-05-13 ユニベーション・テクノロジーズ・エルエルシー 触媒組成物の製造方法及びそれの重合方法への使用
US6877107B2 (en) 2001-07-05 2005-04-05 Softwired Ag Method for ensuring operation during node failures and network partitions in a clustered message passing server
EP1323747A1 (en) * 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
DE60318616T2 (de) 2002-12-04 2009-01-08 Basell Polyolefine Gmbh Verfahren zur herstellung von1-buten-polymeren
DE10358082A1 (de) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
US7169864B2 (en) 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US8222175B2 (en) 2004-12-31 2012-07-17 Borealis Technology Oy Process for the preparation of an olefin polymerisation catalyst
EP1858907B1 (en) 2005-03-18 2008-10-15 Basell Polyolefine GmbH Metallocene compounds
WO2007116034A1 (en) 2006-04-12 2007-10-18 Basell Polyolefine Gmbh Metallocene compounds
DE602006002512D1 (de) * 2006-07-10 2008-10-09 Borealis Tech Oy Kurzkettig verzweigtes Polypropylen
US7429635B2 (en) * 2006-09-28 2008-09-30 Equistar Chemicals, Lp Preparation of ultra high molecular weight linear low density polyethylene
ATE509967T1 (de) 2007-06-14 2011-06-15 Borealis Tech Oy Verfahren zur herstellung von propylen- copolymeren mit hilfe eines vorpolymerisierten katalysators
KR20100101092A (ko) 2007-10-25 2010-09-16 루머스 노보렌 테크놀로지 게엠베하 메탈로센 화합물, 이를 포함하는 촉매, 이 촉매를 사용한 올레핀 폴리머생산방법, 및 올레핀 호모- 및 코폴리머
EP2853549A3 (en) 2008-08-01 2015-06-03 ExxonMobil Chemical Patents Inc. Process for olefin polymerization
WO2010052263A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
EP2361267B1 (en) 2008-11-07 2015-03-04 Borealis AG Process to prepare a solid catalyst composition
MX2011006667A (es) 2008-12-31 2011-07-20 Lummus Novolen Technology Gmbh Nuevos compuestos de metaloceno, catalizadores que los comprenden, proceso para producir un polimero de olefina por uso de los catalizadores y homo- y copolimeros de olefina.
JP5355113B2 (ja) 2009-01-29 2013-11-27 株式会社Ａｄｅｋａ 一液型シアン酸エステル−エポキシ複合樹脂組成物
US8067652B2 (en) * 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
EP2516486B1 (en) 2009-12-22 2018-02-07 Borealis AG Catalysts
JP5671750B2 (ja) * 2010-03-08 2015-02-18 エルジー・ケム・リミテッド 担持メタロセン触媒の製造方法及びそれを用いたポリオレフィンの製造方法
EP2563821B1 (en) 2010-04-28 2019-08-07 Borealis AG Catalysts
EP2383299B1 (en) 2010-04-28 2017-12-20 Borealis AG Solid particulate catalysts comprising bridged metallocenes
US20110294972A1 (en) 2010-05-27 2011-12-01 Basell Polyolefine Gmbh Olefin Polymerization Catalysts
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
ES2565438T3 (es) 2010-07-01 2016-04-04 Borealis Ag Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores
EP2428526A1 (en) 2010-09-13 2012-03-14 Borealis AG Process for producing polyethylene with improved homogeneity
EP2655431A1 (en) 2010-12-22 2013-10-30 Borealis AG Bridged metallocene catalysts
US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
WO2013007664A1 (en) 2011-07-08 2013-01-17 Borealis Ag Heterophasic copolymers
EP2657192B1 (en) 2012-04-26 2019-03-20 Borealis AG Reducing organic impurities in waste water
ES2622627T3 (es) 2012-10-18 2017-07-06 Borealis Ag Procedimiento de polimerización
EP2722346A1 (en) * 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst

Also Published As

Publication number Publication date
US20150266979A1 (en) 2015-09-24
WO2014060534A1 (en) 2014-04-24
EP2722345A1 (en) 2014-04-23
EA031952B1 (ru) 2019-03-29
ES2711081T3 (es) 2019-04-30
CN104903361A (zh) 2015-09-09
SA515360304B1 (ar) 2017-07-02
KR101900139B1 (ko) 2018-11-08
JP2015532346A (ja) 2015-11-09
BR112015008105B1 (pt) 2021-04-13
CA2888385A1 (en) 2014-04-24
JP6300809B2 (ja) 2018-03-28
BR112015008105A2 (pt) 2017-07-04
KR20150094599A (ko) 2015-08-19
US9475890B2 (en) 2016-10-25
CN104903361B (zh) 2017-08-25
EP2722345B1 (en) 2018-12-05

Similar Documents

Publication Publication Date Title
EA201590682A1 (ru) Способ полимеризации и катализатор
EA201590681A1 (ru) Катализатор
BR112019001111A2 (pt) catalisadores bis-bifenil-fenóxi com pontes de silila para polimerização de olefinas
WO2012122432A3 (en) Automation of business management processes and assets
CA150901S (en) Case for portable computers, documents and other portable items
CA2910375C (en) Catalyst and electrode catalyst layer for fuel cell having the catalyst
IN2014DN05988A (ru)
MX2013010682A (es) Analisis de manejo de servicios con datos de redes sociales.
NZ628314A (en) Cd47 antibodies and methods of use thereof
TWD163518S (zh) 手機的外蓋
CA150902S (en) Case for portable computers, documents and other portable items
MX361985B (es) Producción de polietileno con múltiples reactores de polimerización.
UY33081A (es) Suspensiones de nanopartículas que contienen polímeros de carboxivinilo
IN2013MU02201A (ru)
MX356937B (es) Agregacion de contacto en una red social.
TR201903918T4 (tr) Bir dağıtım ajanı içeren bileşimler ve bunların hazırlanması.
FI20125700A (fi) Yhteisdata suhdetiedolla
GB2522584A (en) Managing performance policies based on workload scalability
BR112019005928A2 (pt) ligantes de bis-fosfosfanidina e de polifosfaganadidina com catalisadores de metal de grupo iv produzidos a partir dos mesmos
WO2014062746A3 (en) Dynamically created links in reports
CN202760525U (zh) 一种防掉物的桌子
GB201205444D0 (en) Composition
CN202992869U (zh) 台灯
GB201213391D0 (en) Social media lifecycle marketing
MD4285B1 (ru) Штамм грибов Trichoderma koningii Oudemans - продуцент кислых, нейтральных и щелочных протеаз

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KG TJ TM