EA201290386A1 - Насыпной катализатор гидропереработки и способы его изготовления - Google Patents

Насыпной катализатор гидропереработки и способы его изготовления

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Publication number
EA201290386A1
EA201290386A1 EA201290386A EA201290386A EA201290386A1 EA 201290386 A1 EA201290386 A1 EA 201290386A1 EA 201290386 A EA201290386 A EA 201290386A EA 201290386 A EA201290386 A EA 201290386A EA 201290386 A1 EA201290386 A1 EA 201290386A1
Authority
EA
Eurasian Patent Office
Prior art keywords
catalyst
hydroprocessing
transition metal
precursor
bulk
Prior art date
Application number
EA201290386A
Other languages
English (en)
Other versions
EA024752B1 (ru
Inventor
Олег МИРОНОВ
Александр И. Куперман
Цзиньи Хань
Original Assignee
Шеврон Ю.Эс.Эй. Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/625,399 external-priority patent/US8431511B2/en
Priority claimed from US12/625,382 external-priority patent/US8372776B2/en
Priority claimed from US12/625,394 external-priority patent/US8420565B2/en
Priority claimed from US12/625,368 external-priority patent/US8389433B2/en
Application filed by Шеврон Ю.Эс.Эй. Инк. filed Critical Шеврон Ю.Эс.Эй. Инк.
Publication of EA201290386A1 publication Critical patent/EA201290386A1/ru
Publication of EA024752B1 publication Critical patent/EA024752B1/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B01J27/0515—Molybdenum with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/10—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles
    • C10G49/12—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 with moving solid particles suspended in the oil, e.g. slurries
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Изобретением обеспечивается насыпной катализатор гидропереработки. Изобретением обеспечивается способ изготовления насыпного катализатора гидропереработки. Катализатор гидропереработки имеет формулу (R)(M)(L)(S)(C)(H)(O)(N), в которой М означает, по меньшей мере, переходный металл; L означает, по меньшей мере, переходный металл, отличный от переходного металла М; t, u, v, w, х, у, z означают общий заряд каждого из компонентов (М, L, S, С, Н, О и N, соответственно); R является необязательным, в одном из вариантов осуществления изобретения R представляет собой лантаноид; 0<=i<=l; pi+ta+ub+vd+we+xf+yg+zh=0; 0<b; 0<b/a=<5; 0,5(a+b)<=d<=5(a+b); 0<е<=11(a+b); 0<f<=7(a+b); 0<g<=5(a+b); 0<h<=2(a+b). Катализатор характеризуется порошковой рентгенограммой по меньшей мере с тремя дифракционными пиками, расположенными под углами 2-θ более 25°. В одном из вариантов осуществления изобретения катализатор получен путем изготовления по меньшей мере одного сульфидированного прекурсора катализатора по меньшей мере из двух переходных металлов; и смешивания прекурсора с углеводородным соединением с целью получения композиции катализатора гидропереработки. В другом варианте осуществления изобретения катализатор получен путем термического разложения диспергируемого в масле серосодержащего органического прекурсора металла в контакте с углеводородным маслом с образованием суспендированного катализатора. Еще в одном из вариантов осуществления изобретения катализатор получен из сульфидированных на месте или вовне металлических прекурсоров переходных металлов в несущем растворителе.
EA201290386A 2009-11-24 2010-11-17 Насыпной катализатор гидропереработки и способы его изготовления EA024752B1 (ru)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US12/625,399 US8431511B2 (en) 2009-11-24 2009-11-24 Hydroprocessing bulk catalyst and methods of making thereof
US12/625,382 US8372776B2 (en) 2009-11-24 2009-11-24 Hydroprocessing bulk catalyst and methods of making thereof
US12/625,394 US8420565B2 (en) 2009-11-24 2009-11-24 Hydroprocessing bulk catalyst and methods of making thereof
US12/625,368 US8389433B2 (en) 2009-11-24 2009-11-24 Hydroprocessing bulk catalyst and methods of making thereof
PCT/US2010/057031 WO2011066150A2 (en) 2009-11-24 2010-11-17 Hydroprocessing bulk catalyst and methods of making thereof

Publications (2)

Publication Number Publication Date
EA201290386A1 true EA201290386A1 (ru) 2013-01-30
EA024752B1 EA024752B1 (ru) 2016-10-31

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Family Applications (1)

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EA201290386A EA024752B1 (ru) 2009-11-24 2010-11-17 Насыпной катализатор гидропереработки и способы его изготовления

Country Status (10)

Country Link
EP (1) EP2504099B1 (ru)
JP (1) JP5871810B2 (ru)
KR (1) KR101804782B1 (ru)
CN (1) CN102665907A (ru)
BR (1) BR112012012495A2 (ru)
CA (1) CA2781530C (ru)
EA (1) EA024752B1 (ru)
ES (1) ES2897562T3 (ru)
MX (1) MX2012005688A (ru)
WO (1) WO2011066150A2 (ru)

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CN103285930B (zh) * 2012-02-22 2015-08-26 中国石油化工股份有限公司 一种含黄铁矿石的重油加氢催化剂及其制备和应用
CN103285928B (zh) * 2012-02-22 2015-08-26 中国石油化工股份有限公司 一种含氧化铁矿石的重油加氢催化剂及其制备和应用
CN108114725B (zh) * 2016-11-28 2021-01-05 中国石油化工股份有限公司 一种臭氧催化氧化催化剂，其制备方法及应用
CN107349948A (zh) * 2017-06-15 2017-11-17 华东理工大学 一种用于煤直接液化的铁碱复合催化剂
CN110038624B (zh) * 2018-01-16 2022-01-04 中国石油化工股份有限公司 加氢裂化催化剂的制法
CN110038580B (zh) * 2018-01-16 2021-11-09 中国石油化工股份有限公司 加氢精制催化剂的制法
CN111514935B (zh) * 2020-04-30 2022-11-15 中国工程物理研究院化工材料研究所 一种面向含能离子液体-双氧水的自点火催化剂及其制备方法
CN112500916B (zh) * 2020-11-12 2022-04-15 中国石油大学(华东) 一种废润滑油临氢预处理提纯方法
CN112500917B (zh) * 2020-11-12 2022-04-26 青岛翌星环保技术有限公司 一种废润滑油加氢循环利用方法
CN117983294A (zh) * 2022-10-27 2024-05-07 中国石油天然气股份有限公司 一种原油低温催化裂解催化剂及其制备方法和应用
CN115845880B (zh) * 2022-12-08 2024-06-14 复旦大学 一种水溶性高分子模板原位构筑过渡金属硫化物/碳复合材料及其制备方法和应用

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Also Published As

Publication number Publication date
CN102665907A (zh) 2012-09-12
KR20120104263A (ko) 2012-09-20
KR101804782B1 (ko) 2017-12-06
EA024752B1 (ru) 2016-10-31
EP2504099A4 (en) 2014-08-27
EP2504099A2 (en) 2012-10-03
CA2781530A1 (en) 2011-06-03
WO2011066150A2 (en) 2011-06-03
ES2897562T3 (es) 2022-03-01
WO2011066150A3 (en) 2011-09-29
JP5871810B2 (ja) 2016-03-01
BR112012012495A2 (pt) 2019-09-24
MX2012005688A (es) 2012-06-13
CA2781530C (en) 2022-08-30
EP2504099B1 (en) 2021-08-11
JP2013512091A (ja) 2013-04-11

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