EA201001800A1 - Твёрдый кислый катализатор и способ его приготовления и применения - Google Patents
Твёрдый кислый катализатор и способ его приготовления и примененияInfo
- Publication number
- EA201001800A1 EA201001800A1 EA201001800A EA201001800A EA201001800A1 EA 201001800 A1 EA201001800 A1 EA 201001800A1 EA 201001800 A EA201001800 A EA 201001800A EA 201001800 A EA201001800 A EA 201001800A EA 201001800 A1 EA201001800 A1 EA 201001800A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- acid catalyst
- preparation
- hard acid
- catalyst
- exchange resin
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
- B01J31/10—Ion-exchange resins sulfonated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
- B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D215/00—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems
- C07D215/02—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom
- C07D215/04—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to the ring carbon atoms
- C07D215/06—Heterocyclic compounds containing quinoline or hydrogenated quinoline ring systems having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen atoms or carbon atoms directly attached to the ring nitrogen atom with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to the ring carbon atoms having only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, attached to the ring nitrogen atom
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3437—Six-membered rings condensed with carbocyclic rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
- B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
- B01J2231/342—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
- C08G2261/34—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain
- C08G2261/344—Monomer units or repeat units incorporating structural elements in the main chain incorporating partially-aromatic structural elements in the main chain containing heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G2261/40—Polymerisation processes
- C08G2261/43—Chemical oxidative coupling reactions, e.g. with FeCl3
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Quinoline Compounds (AREA)
- Catalysts (AREA)
Abstract
Твёрдый кислый катализатор, имеющий сильную кислую катионообменную смолу, которая имеет структуру сетки поперечных связей и свободные ароматические сульфоновые кислоты, адсорбированные в сетке. Твёрдый кислый катализатор изготавливают, обрабатывая раствором сильную кислую катионообменную смолу с ароматическими сульфоновыми кислотами. Катализатор полезен при синтезе антиоксиданта резины RD и других катализируемых сильными кислотами реакциях.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200910215840 CN102114432B (zh) | 2009-12-30 | 2009-12-30 | 复合固体酸催化剂及其制备方法和应用 |
CN 201010110589 CN102153511B (zh) | 2010-02-12 | 2010-02-12 | 橡胶防老剂rd的工业合成方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201001800A1 true EA201001800A1 (ru) | 2011-08-30 |
EA018157B1 EA018157B1 (ru) | 2013-05-30 |
Family
ID=43919852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201001800A EA018157B1 (ru) | 2009-12-30 | 2010-12-15 | Твёрдый кислый катализатор и способ его приготовления и применения |
Country Status (11)
Country | Link |
---|---|
US (2) | US8293137B2 (ru) |
EP (1) | EP2354127A3 (ru) |
JP (1) | JP5739140B2 (ru) |
KR (1) | KR101257832B1 (ru) |
AR (1) | AR082362A1 (ru) |
BR (1) | BRPI1005271B1 (ru) |
CA (1) | CA2724338C (ru) |
EA (1) | EA018157B1 (ru) |
MX (2) | MX2010014004A (ru) |
MY (1) | MY158181A (ru) |
TR (1) | TR201010211A2 (ru) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101811712A (zh) * | 2010-04-27 | 2010-08-25 | 中国神华能源股份有限公司 | 一种利用流化床粉煤灰制备冶金级氧化铝的方法 |
RU2609028C1 (ru) * | 2015-07-29 | 2017-01-30 | Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран | Способ получения 2, 2, 4-триметил-1, 2-дигидрохинолина |
CN105503587A (zh) * | 2015-12-10 | 2016-04-20 | 潍坊英雷生物科技有限公司 | 一种固体酸催化剂及其制备方法及应用 |
CN106919725A (zh) * | 2015-12-25 | 2017-07-04 | 中国石油天然气股份有限公司 | 基于智能算法的合成橡胶转化率在线检测方法及装置 |
CN108003095A (zh) * | 2016-10-28 | 2018-05-08 | 中国石油化工股份有限公司 | 一种防老剂tmq及其制备方法 |
CN111039864B (zh) * | 2018-10-15 | 2022-10-18 | 中国石油化工股份有限公司 | 一种防老剂的制备方法 |
CN112657488A (zh) * | 2019-10-15 | 2021-04-16 | 中石化南京化工研究院有限公司 | 一种多酸型固体催化剂 |
CN112755971B (zh) * | 2019-10-21 | 2024-04-02 | 中国石油化工股份有限公司 | 一种用于脱除轻石脑油中微量胺液的吸附剂制备方法 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4811103B1 (ru) * | 1970-04-23 | 1973-04-10 | ||
JPS52116478A (en) * | 1976-03-23 | 1977-09-29 | Mitsubishi Monsanto Chem Co | Synthesis of 2,2,4-trimethyl-1,2-dihydroquinolines |
JPS5540661A (en) | 1978-09-19 | 1980-03-22 | Sumitomo Chem Co Ltd | Preparation of 2,2,4-trimethyl-1,2-dihydroquinoline |
JPS5620026A (en) | 1979-07-26 | 1981-02-25 | Sumitomo Chem Co Ltd | Production of 2,2,4-trimethyl-1,2-dihydroquinoline polymer |
JPS5859970A (ja) * | 1981-10-06 | 1983-04-09 | Sumitomo Chem Co Ltd | 2,2,4−トリメチル−1,2−ジヒドロキノリンの製造法 |
JPS5888363A (ja) | 1981-11-19 | 1983-05-26 | Sumitomo Chem Co Ltd | 2,2,4−トリメチル−1,2−ジヒドロキノリンの製造法 |
US4514570A (en) | 1984-03-02 | 1985-04-30 | Eastman Kodak Company | Process for the preparation of 2,2,4-trimethyl-1,2-dihydroquinoline compounds |
JPH03173851A (ja) * | 1988-12-21 | 1991-07-29 | Nippon Shokubai Kagaku Kogyo Co Ltd | アルキレンアミン類の製造法 |
JPH02306987A (ja) * | 1989-05-19 | 1990-12-20 | Color Chem Kogyo Kk | メチルグルコシドの連続製造装置および方法 |
RU2065456C1 (ru) * | 1992-05-26 | 1996-08-20 | Акционерное общество открытого типа "Химпром" | Способ получения полимеризованного 2,2,4-триметил-1,2-дигидрохинолина |
RU2157387C2 (ru) * | 1998-08-31 | 2000-10-10 | Открытое акционерное общество "Химпром" | Способ получения полимера 1,2-дигидро-2,2,4-триметилхинолина |
RU2163507C2 (ru) * | 1999-04-21 | 2001-02-27 | Общество с ограниченной ответственностью "Нефтехимстарт" | Способ получения термостойких сульфоионитных катализаторов и способ проведения кислотно-катализируемых реакций |
JP4298438B2 (ja) * | 2003-09-01 | 2009-07-22 | 出光興産株式会社 | ビスフェノールa製造用変性触媒の調製方法 |
JP4452058B2 (ja) * | 2003-11-04 | 2010-04-21 | 出光興産株式会社 | ビスフェノールa製造用変性触媒の調製方法 |
CN101730676A (zh) * | 2007-06-28 | 2010-06-09 | 尼科克斯公司 | 1,4-丁二醇单硝酸酯的制备方法 |
RU2357800C2 (ru) * | 2007-08-10 | 2009-06-10 | Общество с ограниченной ответственностью "Научно-технологический центр по химическим технологиям" | Способ получения термостойкого сульфоионитного катализатора |
CN101353447B (zh) * | 2008-08-27 | 2011-09-28 | 河南省开仑化工有限责任公司 | 一种橡胶防老剂rd的合成工艺 |
CN101580602A (zh) * | 2009-03-23 | 2009-11-18 | 天津市科迈化工有限公司 | 球粒状高含量橡胶防老剂rd的生产方法 |
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2010
- 2010-11-10 US US12/943,930 patent/US8293137B2/en active Active
- 2010-11-19 MY MYPI2010005471A patent/MY158181A/en unknown
- 2010-11-25 JP JP2010262798A patent/JP5739140B2/ja active Active
- 2010-11-30 EP EP10193059.2A patent/EP2354127A3/en active Pending
- 2010-12-03 KR KR1020100122542A patent/KR101257832B1/ko active IP Right Grant
- 2010-12-07 CA CA2724338A patent/CA2724338C/en active Active
- 2010-12-08 TR TR2010/10211A patent/TR201010211A2/xx unknown
- 2010-12-15 EA EA201001800A patent/EA018157B1/ru not_active IP Right Cessation
- 2010-12-16 BR BRPI1005271-2A patent/BRPI1005271B1/pt active IP Right Grant
- 2010-12-16 MX MX2010014004A patent/MX2010014004A/es active IP Right Grant
- 2010-12-16 MX MX2013004397A patent/MX367411B/es unknown
- 2010-12-17 AR ARP100104715A patent/AR082362A1/es unknown
-
2012
- 2012-09-19 US US13/623,037 patent/US9186660B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
MY158181A (en) | 2016-09-15 |
TR201010211A2 (tr) | 2011-07-21 |
EP2354127A3 (en) | 2017-09-13 |
CA2724338C (en) | 2014-02-18 |
CA2724338A1 (en) | 2011-06-30 |
KR101257832B1 (ko) | 2013-04-29 |
US8293137B2 (en) | 2012-10-23 |
EA018157B1 (ru) | 2013-05-30 |
MX2010014004A (es) | 2011-06-29 |
AR082362A1 (es) | 2012-12-05 |
EP2354127A2 (en) | 2011-08-10 |
JP2011136330A (ja) | 2011-07-14 |
US9186660B2 (en) | 2015-11-17 |
US20130015407A1 (en) | 2013-01-17 |
BRPI1005271A2 (pt) | 2013-04-02 |
BRPI1005271B1 (pt) | 2021-09-21 |
MX367411B (es) | 2019-08-21 |
KR20110079499A (ko) | 2011-07-07 |
JP5739140B2 (ja) | 2015-06-24 |
US20110155961A1 (en) | 2011-06-30 |
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