ES2443539B1 - Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39 - Google Patents

Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39 Download PDF

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Publication number
ES2443539B1
ES2443539B1 ES201231138A ES201231138A ES2443539B1 ES 2443539 B1 ES2443539 B1 ES 2443539B1 ES 201231138 A ES201231138 A ES 201231138A ES 201231138 A ES201231138 A ES 201231138A ES 2443539 B1 ES2443539 B1 ES 2443539B1
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Spain
Prior art keywords
itq
oligomerization
alkenes
zeolite
reactor
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Expired - Fee Related
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ES201231138A
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English (en)
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ES2443539A1 (es
Inventor
Avelino Corma Canós
María Cristina MARTÍNEZ SÁNCHEZ
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Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
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Consejo Superior de Investigaciones Cientificas CSIC
Universidad Politecnica de Valencia
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Priority to ES201231138A priority Critical patent/ES2443539B1/es
Priority to PCT/ES2013/000172 priority patent/WO2014013102A1/es
Priority to EP13820279.1A priority patent/EP2876147B1/en
Priority to ES13820279.1T priority patent/ES2613393T3/es
Priority to CN201380048760.3A priority patent/CN104854220B/zh
Publication of ES2443539A1 publication Critical patent/ES2443539A1/es
Application granted granted Critical
Publication of ES2443539B1 publication Critical patent/ES2443539B1/es
Priority to US14/599,544 priority patent/US9550706B2/en
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J35/30—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C10L1/08—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for compression ignition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B01J2229/123—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation in order to deactivate outer surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/34—Reaction with organic or organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/026—Specifically adapted fuels for internal combustion engines for diesel engines, e.g. automobiles, stationary, marine
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

A continuación se describe un proceso heterogéneo de oligomerización de alquenos para producir hidrocarburos dentro de fracción diesel en presencia un catalizador basado en la zeolita ITQ-39. El proceso de oligomerización descrito en la presente invención comprende, al menos:#a. Introducir un catalizador conteniendo al menos el material zeolítico ITQ-39 en el reactor;#b. Alimentar el reactor con una corriente que comprende, al menos, un compuesto olefínico;#c. Permitir que el catalizador conteniendo al menos el material ITQ-39 y el compuesto orgánico permanezcan en contacto el tiempo necesario para que la reacción se lleve a cabo.

Description



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Claims (1)



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ES201231138A 2012-07-19 2012-07-19 Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39 Expired - Fee Related ES2443539B1 (es)

Priority Applications (6)

Application Number Priority Date Filing Date Title
ES201231138A ES2443539B1 (es) 2012-07-19 2012-07-19 Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39
PCT/ES2013/000172 WO2014013102A1 (es) 2012-07-19 2013-07-12 Proceso de oligomerización de alquenos utilizando la zeolita itq-39
EP13820279.1A EP2876147B1 (en) 2012-07-19 2013-07-12 Method for oligomerising alkenes using the itq-39 zeolite
ES13820279.1T ES2613393T3 (es) 2012-07-19 2013-07-12 Método para la oligomerización de alquenos usando la zeolita ITQ-39
CN201380048760.3A CN104854220B (zh) 2012-07-19 2013-07-12 使用itq‑39沸石低聚烯烃的方法
US14/599,544 US9550706B2 (en) 2012-07-19 2015-01-19 Method for oligomerising alkenes using the ITQ-39 zeolite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES201231138A ES2443539B1 (es) 2012-07-19 2012-07-19 Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39

Publications (2)

Publication Number Publication Date
ES2443539A1 ES2443539A1 (es) 2014-02-19
ES2443539B1 true ES2443539B1 (es) 2014-12-04

Family

ID=49948323

Family Applications (2)

Application Number Title Priority Date Filing Date
ES201231138A Expired - Fee Related ES2443539B1 (es) 2012-07-19 2012-07-19 Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39
ES13820279.1T Active ES2613393T3 (es) 2012-07-19 2013-07-12 Método para la oligomerización de alquenos usando la zeolita ITQ-39

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES13820279.1T Active ES2613393T3 (es) 2012-07-19 2013-07-12 Método para la oligomerización de alquenos usando la zeolita ITQ-39

Country Status (5)

Country Link
US (1) US9550706B2 (es)
EP (1) EP2876147B1 (es)
CN (1) CN104854220B (es)
ES (2) ES2443539B1 (es)
WO (1) WO2014013102A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11358912B2 (en) 2017-08-01 2022-06-14 Purdue Research Foundation Increased oligomer selectivity from olefin oligomerization by incorporation of boron
KR102090402B1 (ko) 2018-10-31 2020-03-17 공주대학교 산학협력단 탈실리카된 펜타실구조형 제올라이트 촉매를 이용한 부텐으로부터 고급 알켄 제조방법
RU2709818C1 (ru) * 2019-02-18 2019-12-23 Федеральное государственное бюджетное научное учреждение Уфимский федеральный исследовательский центр Российской академии наук Способ получения олигомеров пент-1-ена в присутствии иерархического цеолита н-y
CN115676849B (zh) * 2021-07-29 2024-03-12 中国石油化工股份有限公司 Svr结构硅锆分子筛及其制备方法

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Also Published As

Publication number Publication date
EP2876147B1 (en) 2016-11-23
ES2443539A1 (es) 2014-02-19
WO2014013102A1 (es) 2014-01-23
WO2014013102A8 (es) 2014-04-03
ES2613393T3 (es) 2017-05-24
US20150197463A1 (en) 2015-07-16
US9550706B2 (en) 2017-01-24
EP2876147A4 (en) 2016-03-30
CN104854220B (zh) 2017-03-22
CN104854220A (zh) 2015-08-19
EP2876147A1 (en) 2015-05-27

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