EA017068B1 - Каталитическая композиция для получения полиолефинов, имеющих би- или мультимодальное молекулярно-массовое распределение, активная каталитическая система и способ её получения, способ полимеризации олефинов и применение активной каталитической системы для получения линейного полиэтилена - Google Patents
Каталитическая композиция для получения полиолефинов, имеющих би- или мультимодальное молекулярно-массовое распределение, активная каталитическая система и способ её получения, способ полимеризации олефинов и применение активной каталитической системы для получения линейного полиэтилена Download PDFInfo
- Publication number
- EA017068B1 EA017068B1 EA200700679A EA200700679A EA017068B1 EA 017068 B1 EA017068 B1 EA 017068B1 EA 200700679 A EA200700679 A EA 200700679A EA 200700679 A EA200700679 A EA 200700679A EA 017068 B1 EA017068 B1 EA 017068B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- molecular weight
- component
- substituted
- weight distribution
- reactor
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 42
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 30
- 238000009826 distribution Methods 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 title claims abstract description 14
- 238000000034 method Methods 0.000 title claims description 33
- 229920000573 polyethylene Polymers 0.000 title claims description 11
- -1 polyethylene Polymers 0.000 title claims description 11
- 239000004698 Polyethylene Substances 0.000 title claims description 10
- 150000001336 alkenes Chemical class 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title abstract description 13
- 230000000379 polymerizing effect Effects 0.000 title description 3
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 9
- 239000012968 metallocene catalyst Substances 0.000 claims abstract description 5
- 229920000642 polymer Polymers 0.000 claims description 33
- 230000003197 catalytic effect Effects 0.000 claims description 25
- 230000002902 bimodal effect Effects 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 230000003213 activating effect Effects 0.000 claims description 13
- 125000004432 carbon atom Chemical group C* 0.000 claims description 12
- 239000000178 monomer Substances 0.000 claims description 10
- 229910052735 hafnium Inorganic materials 0.000 claims description 9
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 6
- 239000005977 Ethylene Substances 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 6
- 239000002685 polymerization catalyst Substances 0.000 claims description 6
- 125000001424 substituent group Chemical group 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 5
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 239000002879 Lewis base Substances 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 4
- 150000007527 lewis bases Chemical class 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 125000005842 heteroatom Chemical group 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 125000003107 substituted aryl group Chemical group 0.000 claims description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims 2
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical group C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 230000008569 process Effects 0.000 description 20
- 239000000047 product Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000012071 phase Substances 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- 239000001257 hydrogen Substances 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- KOMDZQSPRDYARS-UHFFFAOYSA-N cyclopenta-1,3-diene titanium Chemical compound [Ti].C1C=CC=C1.C1C=CC=C1 KOMDZQSPRDYARS-UHFFFAOYSA-N 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000004700 high-density polyethylene Substances 0.000 description 3
- 229910052809 inorganic oxide Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
- 238000006384 oligomerization reaction Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- 101100324465 Caenorhabditis elegans arr-1 gene Proteins 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 208000012868 Overgrowth Diseases 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000012864 cross contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- ZMMRKRFMSDTOLV-UHFFFAOYSA-N cyclopenta-1,3-diene zirconium Chemical group [Zr].C1C=CC=C1.C1C=CC=C1 ZMMRKRFMSDTOLV-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- IDAPTOGYAAQMGT-UHFFFAOYSA-N diphenylmethylbenzene borate Chemical compound [O-]B([O-])[O-].C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 IDAPTOGYAAQMGT-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 229920006262 high density polyethylene film Polymers 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 210000001724 microfibril Anatomy 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QHLFJSMAWAWVRU-UHFFFAOYSA-N n-(5-chloro-4-methyl-1,3-thiazol-2-yl)propanamide Chemical compound CCC(=O)NC1=NC(C)=C(Cl)S1 QHLFJSMAWAWVRU-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003335 steric effect Effects 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
- C08F4/80—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP04105218A EP1650231A1 (en) | 2004-10-21 | 2004-10-21 | Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor |
| PCT/EP2005/055398 WO2006045738A1 (en) | 2004-10-21 | 2005-10-20 | Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200700679A1 EA200700679A1 (ru) | 2007-10-26 |
| EA017068B1 true EA017068B1 (ru) | 2012-09-28 |
Family
ID=34929742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200700679A EA017068B1 (ru) | 2004-10-21 | 2005-10-20 | Каталитическая композиция для получения полиолефинов, имеющих би- или мультимодальное молекулярно-массовое распределение, активная каталитическая система и способ её получения, способ полимеризации олефинов и применение активной каталитической системы для получения линейного полиэтилена |
Country Status (7)
| Country | Link |
|---|---|
| US (3) | US8178634B2 (enExample) |
| EP (2) | EP1650231A1 (enExample) |
| JP (1) | JP2008517131A (enExample) |
| KR (1) | KR101237261B1 (enExample) |
| CN (1) | CN101044171A (enExample) |
| EA (1) | EA017068B1 (enExample) |
| WO (1) | WO2006045738A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1650236A1 (en) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Activating agents for hafnium based metallocene components |
| KR101092572B1 (ko) | 2006-12-21 | 2011-12-13 | 주식회사 엘지화학 | 담지촉매를 이용한 폴리올레핀의 제조방법 |
| EP2003166A1 (en) * | 2007-06-12 | 2008-12-17 | Repsol Ypf S.A. | Polyethylene compositions and their use in the manufacture of pipes |
| EP2039720A1 (en) * | 2007-09-21 | 2009-03-25 | Total Petrochemicals Research Feluy | Pipes for transporting water containing chlorine. |
| US8436114B2 (en) | 2010-10-21 | 2013-05-07 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| US8431661B2 (en) | 2010-10-21 | 2013-04-30 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| US8507103B2 (en) | 2007-12-18 | 2013-08-13 | Exxonmobil Chemical Patents Inc. | Polyethylene and process for production thereof |
| KR101205473B1 (ko) | 2008-09-18 | 2012-11-27 | 주식회사 엘지화학 | 파이프용 올레핀계 중합체 수지 조성물 및 이로부터 제조되는 파이프 |
| KR101806758B1 (ko) * | 2008-09-25 | 2017-12-07 | 바젤 폴리올레핀 게엠베하 | 내충격성 ｌｌｄｐｅ 조성물 및 이것으로 제조된 필름 |
| MX2012006782A (es) | 2009-12-18 | 2012-10-01 | Total Petrochemicals Res Feluy | Proceso para la preparacion de producto de polietileno bimodal en particulas. |
| PT2382248E (pt) * | 2009-12-18 | 2013-01-23 | Total Res & Technology Feluy | Processo para preparar um produto de polietileno bimodal num reator em anel único |
| ES2975195T3 (es) * | 2010-10-21 | 2024-07-03 | Univation Tech Llc | Polietileno y proceso para la producción del mismo |
| CN104072646B (zh) * | 2013-03-28 | 2016-11-02 | 中国石油天然气股份有限公司 | 一种乙烯气相聚合或共聚合催化剂组合物及其制备和应用 |
| WO2018046567A1 (en) | 2016-09-08 | 2018-03-15 | Total Research & Technology Feluy | Process for preparing polyethylene |
| CA3043011A1 (en) | 2016-11-08 | 2018-05-17 | Univation Technologies, Llc | Bimodal linear low density polyethylene composition |
| EP3538570B1 (en) | 2016-11-08 | 2022-05-18 | Univation Technologies, LLC | Polyethylene composition |
| SG11202002090SA (en) | 2017-09-11 | 2020-04-29 | Univation Tech Llc | Carbon black-containing bimodal polyethylene composition |
| EP3692079B1 (en) | 2017-10-06 | 2024-09-04 | ExxonMobil Chemical Patents Inc. | Polyethylene extrudates and methods of making the same |
| KR102363189B1 (ko) | 2018-01-11 | 2022-02-15 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법 |
| CA3094511A1 (en) | 2018-03-28 | 2019-10-03 | Univation Technologies, Llc | Multimodal polyethylene composition |
| WO2021202483A1 (en) | 2020-04-01 | 2021-10-07 | Dow Global Technologies Llc | Bimodal linear low density polyethylene copolymer |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998038228A1 (de) * | 1997-02-24 | 1998-09-03 | Targor Gmbh | Katalysatorzusammensetzung |
| US6407188B1 (en) * | 1999-09-29 | 2002-06-18 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| WO2004029101A1 (en) * | 2002-09-27 | 2004-04-08 | Total Petrochemicals Research Feluy | Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins in a single reactor |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| EP0485823B1 (de) * | 1990-11-12 | 1995-03-08 | Hoechst Aktiengesellschaft | 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation |
| US5908903A (en) * | 1995-12-27 | 1999-06-01 | Basf Aktiengesellschaft | Metallocene catalyst systems containing lewis bases |
| HU223533B1 (hu) * | 1996-06-17 | 2004-08-30 | Exxonmobil Chemical Patents Inc. | Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására |
| DE19757540A1 (de) * | 1997-12-23 | 1999-06-24 | Hoechst Ag | Geträgertes Katalysatorsystem zur Polymerisation von Olefinen |
| DE69921304T2 (de) * | 1998-03-12 | 2005-02-24 | Bp Chemicals Ltd. | Polymerisationskatalysatoren |
| WO1999050318A1 (en) * | 1998-03-30 | 1999-10-07 | E.I. Du Pont De Nemours And Company | Polymerization of olefins |
| US6297338B1 (en) * | 1998-03-30 | 2001-10-02 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| DE19823871A1 (de) * | 1998-05-28 | 1999-12-02 | Aventis Res & Tech Gmbh & Co | Suspensionsphasenverfahren für die Polymerisation von Ethylen |
| JP2000191719A (ja) * | 1998-12-28 | 2000-07-11 | Mitsui Chemicals Inc | オレフィン重合用触媒並びにオレフィンの重合方法 |
| US6620896B1 (en) * | 1999-02-23 | 2003-09-16 | Eastman Chemical Company | Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom |
| GB9906296D0 (en) * | 1999-03-18 | 1999-05-12 | Bp Chem Int Ltd | Polymerisation catalysts |
| BR0017587B1 (pt) * | 1999-09-29 | 2013-07-16 | misturas de polímeros | |
| WO2001023444A1 (en) | 1999-09-29 | 2001-04-05 | E.I. Du Pont De Nemours And Company | Polymerization of olefins with bimetallic polymerisation catalyst system |
| DE19960123A1 (de) * | 1999-12-13 | 2001-06-21 | Basf Ag | Verfahren zur homogenkatalytischen Herstellung von hochverzweigten amorphen Polyolefinen |
| GB0003363D0 (en) * | 2000-02-14 | 2000-04-05 | Bp Chem Int Ltd | Polymer blends |
| DE10017663A1 (de) * | 2000-04-08 | 2001-10-11 | Basf Ag | Verfahren zur Herstellung eines geträgerten Katalysators zur Polymerisation von Olefinen |
| EP1399491B1 (en) * | 2001-04-30 | 2006-08-23 | W.R. Grace & Co.-Conn. | Supported dual transition metal catalyst systems |
| US6815074B2 (en) * | 2001-05-30 | 2004-11-09 | Novartis Ag | Polymeric materials for making contact lenses |
| US7208559B2 (en) * | 2002-12-27 | 2007-04-24 | Mitsui Chemicals, Inc. | Ethylened polymer and molded object obtained therefrom |
| PL1574525T3 (pl) * | 2004-03-12 | 2007-09-28 | Saudi Basic Ind Corp | Kompozycja katalizatora do polimeryzacji olefin i sposób polimeryzacji z jej zastosowaniem |
| DE102004020524A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| EP1650236A1 (en) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Activating agents for hafnium based metallocene components |
-
2004
- 2004-10-21 EP EP04105218A patent/EP1650231A1/en not_active Withdrawn
-
2005
- 2005-10-20 JP JP2007537275A patent/JP2008517131A/ja not_active Ceased
- 2005-10-20 US US11/665,716 patent/US8178634B2/en not_active Expired - Fee Related
- 2005-10-20 EP EP05799106A patent/EP1809675B1/en not_active Expired - Lifetime
- 2005-10-20 KR KR1020077008279A patent/KR101237261B1/ko not_active Expired - Fee Related
- 2005-10-20 WO PCT/EP2005/055398 patent/WO2006045738A1/en not_active Ceased
- 2005-10-20 EA EA200700679A patent/EA017068B1/ru not_active IP Right Cessation
- 2005-10-20 CN CNA2005800362232A patent/CN101044171A/zh active Pending
-
2012
- 2012-03-28 US US13/433,025 patent/US8455386B2/en not_active Expired - Fee Related
-
2013
- 2013-04-24 US US13/869,528 patent/US8637421B2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998038228A1 (de) * | 1997-02-24 | 1998-09-03 | Targor Gmbh | Katalysatorzusammensetzung |
| US6407188B1 (en) * | 1999-09-29 | 2002-06-18 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| WO2004029101A1 (en) * | 2002-09-27 | 2004-04-08 | Total Petrochemicals Research Feluy | Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins in a single reactor |
Non-Patent Citations (1)
| Title |
|---|
| MECKING S.: "REACTOR BLENDING WITH EARLY/LATE TRANSITION METAL CATALYST COMBINATIONS IN ETHYLENE POLYMERIZATION". MACROMOLECULAR: RAPID COMMUNICATIONS, WILEY VCH, WEINHEIM, DE, vol. 20, no. 3, March 1999 (1999-03), pages 139-143, XP000834998, ISSN: 1022-1336, the whole document * |
Also Published As
| Publication number | Publication date |
|---|---|
| US20120245021A1 (en) | 2012-09-27 |
| EP1809675A1 (en) | 2007-07-25 |
| US20080108766A1 (en) | 2008-05-08 |
| WO2006045738A1 (en) | 2006-05-04 |
| EA200700679A1 (ru) | 2007-10-26 |
| US8637421B2 (en) | 2014-01-28 |
| CN101044171A (zh) | 2007-09-26 |
| EP1650231A1 (en) | 2006-04-26 |
| KR101237261B1 (ko) | 2013-02-27 |
| US8178634B2 (en) | 2012-05-15 |
| KR20070068363A (ko) | 2007-06-29 |
| US20130237405A1 (en) | 2013-09-12 |
| EP1809675B1 (en) | 2013-04-03 |
| JP2008517131A (ja) | 2008-05-22 |
| US8455386B2 (en) | 2013-06-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8455386B2 (en) | Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor | |
| US6403181B1 (en) | Premium pipe resins | |
| US7127853B2 (en) | Process for producing polyethylene pipe resins | |
| JP2002541292A (ja) | ポリオレフィンおよびその使用 | |
| EA005387B1 (ru) | Смолы на основе полиэтилена, применяемые для изготовления труб, и их получение | |
| JP2006500452A (ja) | 二頂ポリオレフィンを単一反応槽内で製造するに適したハフノセン成分含有二部位触媒系 | |
| KR20050057115A (ko) | 개질된 알루미녹산으로부터 미립자 메탈로센 촉매의 제조방법 및 이를 이용한 올레핀 중합방법 | |
| CN101842158A (zh) | 茂金属催化剂及其在聚合工艺中的用途 | |
| CN101835536A (zh) | 具有改进性能的聚乙烯组合物 | |
| JP6281371B2 (ja) | ポリエチレン系樹脂組成物、その製造方法及びそれよりなる樹脂用改質材 | |
| JPWO2007094376A1 (ja) | エチレン系樹脂およびそれからなるブロー成形体 | |
| JP6080708B2 (ja) | ポリエチレン系樹脂からなるチューブ成形体 | |
| KR20000064952A (ko) | 올레핀(공)중합체용 예비활성화 촉매, 올레핀(공)중합용 촉매및 올레핀(공)중합체 조성물 및 그 제조방법 | |
| JPWO1998035997A1 (ja) | オレフィン（共）重合体用予備活性化触媒、オレフィン（共）重合用触媒、並びにオレフィン（共）重合体組成物およびその製造方法 | |
| JP3393631B2 (ja) | エチレン系重合体 | |
| EP1650230A1 (en) | Polyolefins prepared from Ziegler-Natta and metallocene catalyst components in single reactor | |
| US20080214759A1 (en) | Polyolefins Prepared From Two New Single Site Catalyst Components In Single Reactor | |
| EP1598378A1 (en) | Process for the preparation of bimodal polyethylene | |
| CN120476155A (zh) | 基于烯烃的聚合物及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM |
|
| TC4A | Change in name of a patent proprietor in a eurasian patent | ||
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): RU |