CN101044171A - 在单一反应器中由金属茂和新型单点催化剂组分制备的聚烯烃 - Google Patents

在单一反应器中由金属茂和新型单点催化剂组分制备的聚烯烃 Download PDF

Info

Publication number
CN101044171A
CN101044171A CNA2005800362232A CN200580036223A CN101044171A CN 101044171 A CN101044171 A CN 101044171A CN A2005800362232 A CNA2005800362232 A CN A2005800362232A CN 200580036223 A CN200580036223 A CN 200580036223A CN 101044171 A CN101044171 A CN 101044171A
Authority
CN
China
Prior art keywords
catalyst
substituted
metallocene
molecular weight
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2005800362232A
Other languages
English (en)
Chinese (zh)
Inventor
阿巴斯·拉扎维
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Total Petrochemicals Research Feluy SA
Original Assignee
Total Petrochemicals Research Feluy SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Petrochemicals Research Feluy SA filed Critical Total Petrochemicals Research Feluy SA
Publication of CN101044171A publication Critical patent/CN101044171A/zh
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70Iron group metals, platinum group metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C08F4/80Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44 selected from iron group metals or platinum group metals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNA2005800362232A 2004-10-21 2005-10-20 在单一反应器中由金属茂和新型单点催化剂组分制备的聚烯烃 Pending CN101044171A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP04105218.4 2004-10-21
EP04105218A EP1650231A1 (en) 2004-10-21 2004-10-21 Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor

Publications (1)

Publication Number Publication Date
CN101044171A true CN101044171A (zh) 2007-09-26

Family

ID=34929742

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2005800362232A Pending CN101044171A (zh) 2004-10-21 2005-10-20 在单一反应器中由金属茂和新型单点催化剂组分制备的聚烯烃

Country Status (7)

Country Link
US (3) US8178634B2 (enExample)
EP (2) EP1650231A1 (enExample)
JP (1) JP2008517131A (enExample)
KR (1) KR101237261B1 (enExample)
CN (1) CN101044171A (enExample)
EA (1) EA017068B1 (enExample)
WO (1) WO2006045738A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102686619A (zh) * 2009-12-18 2012-09-19 道达尔石油化学产品研究弗吕公司 用于在单环流反应器中制备双峰聚乙烯产物的方法
CN104072646A (zh) * 2013-03-28 2014-10-01 中国石油天然气股份有限公司 一种乙烯气相聚合或共聚合催化剂组合物及其制备和应用

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1650236A1 (en) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Activating agents for hafnium based metallocene components
KR101092572B1 (ko) 2006-12-21 2011-12-13 주식회사 엘지화학 담지촉매를 이용한 폴리올레핀의 제조방법
EP2003166A1 (en) * 2007-06-12 2008-12-17 Repsol Ypf S.A. Polyethylene compositions and their use in the manufacture of pipes
EP2039720A1 (en) * 2007-09-21 2009-03-25 Total Petrochemicals Research Feluy Pipes for transporting water containing chlorine.
US8436114B2 (en) 2010-10-21 2013-05-07 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8431661B2 (en) 2010-10-21 2013-04-30 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8507103B2 (en) 2007-12-18 2013-08-13 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
KR101205473B1 (ko) 2008-09-18 2012-11-27 주식회사 엘지화학 파이프용 올레핀계 중합체 수지 조성물 및 이로부터 제조되는 파이프
KR101806758B1 (ko) * 2008-09-25 2017-12-07 바젤 폴리올레핀 게엠베하 내충격성 lldpe 조성물 및 이것으로 제조된 필름
MX2012006782A (es) 2009-12-18 2012-10-01 Total Petrochemicals Res Feluy Proceso para la preparacion de producto de polietileno bimodal en particulas.
ES2975195T3 (es) * 2010-10-21 2024-07-03 Univation Tech Llc Polietileno y proceso para la producción del mismo
WO2018046567A1 (en) 2016-09-08 2018-03-15 Total Research & Technology Feluy Process for preparing polyethylene
CA3043011A1 (en) 2016-11-08 2018-05-17 Univation Technologies, Llc Bimodal linear low density polyethylene composition
EP3538570B1 (en) 2016-11-08 2022-05-18 Univation Technologies, LLC Polyethylene composition
SG11202002090SA (en) 2017-09-11 2020-04-29 Univation Tech Llc Carbon black-containing bimodal polyethylene composition
EP3692079B1 (en) 2017-10-06 2024-09-04 ExxonMobil Chemical Patents Inc. Polyethylene extrudates and methods of making the same
KR102363189B1 (ko) 2018-01-11 2022-02-15 주식회사 엘지화학 혼성 담지 메탈로센 촉매를 이용한 폴리올레핀의 제조 방법
CA3094511A1 (en) 2018-03-28 2019-10-03 Univation Technologies, Llc Multimodal polyethylene composition
WO2021202483A1 (en) 2020-04-01 2021-10-07 Dow Global Technologies Llc Bimodal linear low density polyethylene copolymer

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
EP0485823B1 (de) * 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
US5908903A (en) * 1995-12-27 1999-06-01 Basf Aktiengesellschaft Metallocene catalyst systems containing lewis bases
HU223533B1 (hu) * 1996-06-17 2004-08-30 Exxonmobil Chemical Patents Inc. Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására
DE19707236A1 (de) * 1997-02-24 1998-08-27 Targor Gmbh Katalysatorzusammensetzung
DE19757540A1 (de) * 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
DE69921304T2 (de) * 1998-03-12 2005-02-24 Bp Chemicals Ltd. Polymerisationskatalysatoren
WO1999050318A1 (en) * 1998-03-30 1999-10-07 E.I. Du Pont De Nemours And Company Polymerization of olefins
US6297338B1 (en) * 1998-03-30 2001-10-02 E. I. Du Pont De Nemours And Company Polymerization of olefins
DE19823871A1 (de) * 1998-05-28 1999-12-02 Aventis Res & Tech Gmbh & Co Suspensionsphasenverfahren für die Polymerisation von Ethylen
JP2000191719A (ja) * 1998-12-28 2000-07-11 Mitsui Chemicals Inc オレフィン重合用触媒並びにオレフィンの重合方法
US6620896B1 (en) * 1999-02-23 2003-09-16 Eastman Chemical Company Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom
GB9906296D0 (en) * 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts
US6407188B1 (en) * 1999-09-29 2002-06-18 E. I. Du Pont De Nemours And Company Polymerization of olefins
BR0017587B1 (pt) * 1999-09-29 2013-07-16 misturas de polímeros
WO2001023444A1 (en) 1999-09-29 2001-04-05 E.I. Du Pont De Nemours And Company Polymerization of olefins with bimetallic polymerisation catalyst system
DE19960123A1 (de) * 1999-12-13 2001-06-21 Basf Ag Verfahren zur homogenkatalytischen Herstellung von hochverzweigten amorphen Polyolefinen
GB0003363D0 (en) * 2000-02-14 2000-04-05 Bp Chem Int Ltd Polymer blends
DE10017663A1 (de) * 2000-04-08 2001-10-11 Basf Ag Verfahren zur Herstellung eines geträgerten Katalysators zur Polymerisation von Olefinen
EP1399491B1 (en) * 2001-04-30 2006-08-23 W.R. Grace & Co.-Conn. Supported dual transition metal catalyst systems
US6815074B2 (en) * 2001-05-30 2004-11-09 Novartis Ag Polymeric materials for making contact lenses
EP1403288A1 (en) * 2002-09-27 2004-03-31 ATOFINA Research Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins
US7208559B2 (en) * 2002-12-27 2007-04-24 Mitsui Chemicals, Inc. Ethylened polymer and molded object obtained therefrom
PL1574525T3 (pl) * 2004-03-12 2007-09-28 Saudi Basic Ind Corp Kompozycja katalizatora do polimeryzacji olefin i sposób polimeryzacji z jej zastosowaniem
DE102004020524A1 (de) * 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
EP1650236A1 (en) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Activating agents for hafnium based metallocene components

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102686619A (zh) * 2009-12-18 2012-09-19 道达尔石油化学产品研究弗吕公司 用于在单环流反应器中制备双峰聚乙烯产物的方法
CN102686619B (zh) * 2009-12-18 2015-05-06 道达尔研究技术弗吕公司 用于在单环流反应器中制备双峰聚乙烯产物的方法
CN104072646A (zh) * 2013-03-28 2014-10-01 中国石油天然气股份有限公司 一种乙烯气相聚合或共聚合催化剂组合物及其制备和应用
CN104072646B (zh) * 2013-03-28 2016-11-02 中国石油天然气股份有限公司 一种乙烯气相聚合或共聚合催化剂组合物及其制备和应用

Also Published As

Publication number Publication date
US20120245021A1 (en) 2012-09-27
EP1809675A1 (en) 2007-07-25
US20080108766A1 (en) 2008-05-08
WO2006045738A1 (en) 2006-05-04
EA200700679A1 (ru) 2007-10-26
US8637421B2 (en) 2014-01-28
EA017068B1 (ru) 2012-09-28
EP1650231A1 (en) 2006-04-26
KR101237261B1 (ko) 2013-02-27
US8178634B2 (en) 2012-05-15
KR20070068363A (ko) 2007-06-29
US20130237405A1 (en) 2013-09-12
EP1809675B1 (en) 2013-04-03
JP2008517131A (ja) 2008-05-22
US8455386B2 (en) 2013-06-04

Similar Documents

Publication Publication Date Title
US8455386B2 (en) Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor
US10544245B1 (en) Process for preparing a polyethylene product
CN1476464A (zh) 聚乙烯管树脂及其制备方法
US8445607B2 (en) Process for the preparation of a particulate bimodal polyethylene product
CN1684984A (zh) 单反应器中制双模态聚烯烃的含茂铪组分双位催化剂体系
CN100336876C (zh) 涂料组合物,其制备方法和用其涂布的基底
CN102887967A (zh) 用于生产宽分子量分布聚乙烯的复合催化剂及制法和应用
EP2681249B1 (en) Process for preparing polyethylene blend comprising metallocene produced resins and chromium produced resins
JP2009531502A (ja) 直列に配置された複数の反応装置を用いてエチレンのポリマーを製造する方法
CN101044168A (zh) 包括三种或多种桥接联茚基金属茂组分的催化剂组分
US20080214759A1 (en) Polyolefins Prepared From Two New Single Site Catalyst Components In Single Reactor
CN102686619B (zh) 用于在单环流反应器中制备双峰聚乙烯产物的方法
CN101044170A (zh) 采用具有不同环的联茚基类配体的ldpe系聚合物
CN119529152A (zh) 宽峰分布聚乙烯、其制备方法及其应用

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Open date: 20070926