EA007658B1 - Высококремнеземистый шабазит, его синтез и его применение при превращении кислородсодержащих веществ в олефины - Google Patents

Высококремнеземистый шабазит, его синтез и его применение при превращении кислородсодержащих веществ в олефины Download PDF

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Publication number
EA007658B1
EA007658B1 EA200401139A EA200401139A EA007658B1 EA 007658 B1 EA007658 B1 EA 007658B1 EA 200401139 A EA200401139 A EA 200401139A EA 200401139 A EA200401139 A EA 200401139A EA 007658 B1 EA007658 B1 EA 007658B1
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EA
Eurasian Patent Office
Prior art keywords
crystalline material
porous crystalline
material according
range
oxygen
Prior art date
Application number
EA200401139A
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English (en)
Russian (ru)
Other versions
EA200401139A1 (ru
Inventor
Карл Г. Штромайер
Себастиан С. Рейс
Дорон Левин
Original Assignee
Эксонмобил Кемикэл Пейтентс Инк.
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Application filed by Эксонмобил Кемикэл Пейтентс Инк. filed Critical Эксонмобил Кемикэл Пейтентс Инк.
Publication of EA200401139A1 publication Critical patent/EA200401139A1/ru
Publication of EA007658B1 publication Critical patent/EA007658B1/ru

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015CHA-type, e.g. Chabazite, LZ-218
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/40Ethylene production

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EA200401139A 2002-03-15 2003-02-20 Высококремнеземистый шабазит, его синтез и его применение при превращении кислородсодержащих веществ в олефины EA007658B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US36445002P 2002-03-15 2002-03-15
PCT/US2003/005082 WO2003078324A1 (en) 2002-03-15 2003-02-20 High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins

Publications (2)

Publication Number Publication Date
EA200401139A1 EA200401139A1 (ru) 2005-04-28
EA007658B1 true EA007658B1 (ru) 2006-12-29

Family

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Family Applications (1)

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EA200401139A EA007658B1 (ru) 2002-03-15 2003-02-20 Высококремнеземистый шабазит, его синтез и его применение при превращении кислородсодержащих веществ в олефины

Country Status (13)

Country Link
US (2) US7148172B2 (enExample)
EP (1) EP1485323B1 (enExample)
JP (1) JP4508654B2 (enExample)
CN (1) CN100418881C (enExample)
AT (1) ATE350338T1 (enExample)
AU (1) AU2003222228A1 (enExample)
DE (1) DE60310898T2 (enExample)
EA (1) EA007658B1 (enExample)
ES (1) ES2279105T3 (enExample)
MY (1) MY131154A (enExample)
TW (1) TWI315718B (enExample)
WO (1) WO2003078324A1 (enExample)
ZA (1) ZA200407139B (enExample)

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RU2627399C2 (ru) * 2012-06-04 2017-08-08 Басф Се Цеолитные материалы типа сна и способы их получения с применением циклоалкиламмониевых соединений
RU2678676C2 (ru) * 2014-06-05 2019-01-30 Басф Се Цеолитные материалы типа сна и способы их получения с использованием комбинаций циклоалкил- и тетраалкиламмониевых соединений

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CN1890178B (zh) * 2003-12-23 2011-04-13 埃克森美孚化学专利公司 菱沸石型分子筛、其合成及其在含氧化合物转化成烯烃中的应用
EP1701914B1 (en) * 2003-12-23 2019-02-20 ExxonMobil Chemical Patents Inc. Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins
CN1902132B (zh) * 2003-12-30 2010-10-27 埃克森美孚研究工程公司 高固体含量材料处理
CA2589467C (en) * 2004-11-29 2013-07-02 Chevron U.S.A. Inc. High-silica molecular sieve cha
US20060115399A1 (en) * 2004-11-29 2006-06-01 Chevron U.S.A. Inc. Treatment of engine exhaust using high-silica molecular sieve CHA
US20060115403A1 (en) * 2004-11-29 2006-06-01 Chevron U.S.A. Inc. Reduction of oxides of nitrogen in a gas stream using high-silics molecular sieve CHA
US7402297B2 (en) * 2004-11-29 2008-07-22 Chevron U.S.A. Inc. High-silica molecular sieve CHA
US7282082B2 (en) * 2004-11-29 2007-10-16 Chevron Usa, Inc. Gas separation using high-silica molecular sieve CHA
US20060116540A1 (en) * 2004-11-29 2006-06-01 Chevron U.S.A. Inc. Conversion of oxygenates to light olefins using high-silica molecular sieve CHA
CN101065321B (zh) * 2004-11-29 2010-07-28 切夫里昂美国公司 高硅石分子筛cha
US7462744B1 (en) * 2004-11-30 2008-12-09 Chevron U.S.A. Inc. Synthesis of amines using boron-containing molecular sieve CHA
US7226575B2 (en) * 2004-11-30 2007-06-05 Chevron U.S.A. Inc. Boron-containing molecular sieve CHA
US7749471B2 (en) * 2004-11-30 2010-07-06 Chevron U.S.A. Inc. Reduction of oxides of nitrogen in a gas stream using boron-containing molecular sieve CHA
US20060115400A1 (en) * 2004-11-30 2006-06-01 Chevron U.S.A. Inc. Treatment of engine exhaust using boron-containing molecular sieve CHA
EP1838420B1 (en) * 2004-11-30 2021-02-17 Chevron U.S.A., Inc. Boron-containing molecular sieve cha
US7754187B2 (en) * 2005-10-31 2010-07-13 Exxonmobil Chemical Patents Inc. Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
WO2007053239A1 (en) 2005-10-31 2007-05-10 Exxonmobil Chemical Patents Inc. Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
KR101382804B1 (ko) * 2006-03-30 2014-04-08 미쓰비시 가가꾸 가부시키가이샤 프로필렌의 제조 방법
JP5135839B2 (ja) * 2006-03-30 2013-02-06 三菱化学株式会社 プロピレンの製造方法
US8383080B2 (en) * 2006-06-09 2013-02-26 Exxonmobil Chemical Patents Inc. Treatment of CHA-type molecular sieves and their use in the conversion of oxygenates to olefins
CN101500707B (zh) * 2006-08-03 2014-03-12 埃克森美孚化学专利公司 轻质烯烃的制备
US8415518B2 (en) 2006-08-03 2013-04-09 Exxonmobil Chemical Patents Inc. Production of light olefins
US7507393B2 (en) * 2007-03-20 2009-03-24 Chevron U. S. A. Inc. Boron-containing molecular sieve CHA
US20090131730A1 (en) * 2007-11-16 2009-05-21 Lun-Teh Yuen Oxygenate conversion using boron-containing molecular sieve cha
CN101514022B (zh) * 2008-02-20 2011-08-17 中国石油化工股份有限公司 Zsm-5/zsm-23/mcm-22三相共生分子筛及其合成方法
CN101514013B (zh) * 2008-02-20 2011-05-18 中国石油化工股份有限公司 ZSM-5/Magadiite/丝光沸石共生材料及其合成方法
CN101514023B (zh) * 2008-02-20 2011-11-30 中国石油化工股份有限公司 Zsm-5/zsm-23/y沸石三相共生分子筛及其合成方法
EP2098287A1 (en) 2008-03-03 2009-09-09 ExxonMobil Chemical Patents Inc. Method of formulating a molecular sieve catalyst composition by controlling component addition
US8071071B2 (en) * 2008-05-02 2011-12-06 Exxonmobil Chemical Patents Inc. Treatment of small pore molecular sieves and their use in the conversion of oxygenates to olefins
US8715618B2 (en) 2008-05-21 2014-05-06 Basf Se Process for the direct synthesis of Cu containing zeolites having CHA structure
US7772335B1 (en) 2009-03-27 2010-08-10 Exxonmobil Chemical Patents Inc. Light olefin selective oxygenate conversion process using CHA framework type aluminosilicate
US20100331597A1 (en) * 2009-06-29 2010-12-30 Guang Cao Catalyst And Once-Through Reactor-Regenerator Process For Oxygenate To Olefins Production
JP5668422B2 (ja) * 2009-11-10 2015-02-12 三菱化学株式会社 アルミノシリケートの製造方法
US8409546B2 (en) * 2009-11-24 2013-04-02 Basf Se Process for the preparation of zeolites having B-CHA structure
KR101769564B1 (ko) * 2009-11-24 2017-08-21 바스프 에스이 Cha 구조를 갖는 제올라이트의 제조 방법
JP5957828B2 (ja) * 2010-08-26 2016-07-27 三菱化学株式会社 ガス分離用ゼオライト膜複合体
JP5783952B2 (ja) * 2011-05-20 2015-09-24 国立大学法人東京工業大学 オレフィンの製造方法及びオレフィン製造用触媒
US9174849B2 (en) * 2011-08-25 2015-11-03 Basf Corporation Molecular sieve precursors and synthesis of molecular sieves
CA2855572C (en) * 2011-11-11 2020-04-28 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure
US9636667B2 (en) 2012-06-04 2017-05-02 Basf Se CHA-type zeolite materials and methods for their preparation using cycloalkyammonium compounds
US9296620B2 (en) 2013-08-09 2016-03-29 Chevron U.S.A. Inc. Preparation of high-silica cha-type molecular sieves using a mixed template
US10173211B2 (en) 2014-10-14 2019-01-08 California Institute Of Technology Organic-free synthesis of small pore zeolite catalysts
JP6442329B2 (ja) * 2015-03-12 2018-12-19 国立大学法人横浜国立大学 高Si/Al比のCHA型ゼオライトの製法
EP3201161A4 (en) 2015-08-24 2018-08-15 SABIC Global Technologies B.V. Ssz-13 as a catalyst for conversion of chloromethane to olefins
US10179753B2 (en) 2015-10-21 2019-01-15 Exelus, Inc. Process of making olefins or alkylate by reaction of methanol and/or DME or by reaction of methanol and/or DME and butane
MX2019003880A (es) * 2016-10-03 2019-08-05 Basf Corp Composiciones de zeolita de aluminosilicato con gradiente de aluminio.
US10618040B2 (en) 2016-10-25 2020-04-14 Jgc Catalysts And Chemicals Ltd. Chabazite zeolite for substrate coating
ES2698700B2 (es) * 2017-08-04 2019-11-21 Consejo Superior Investigacion Sintesis de la zeolita cha en su forma nanocristalina, procedimiento de sintesis y su uso en aplicaciones cataliticas
US11691933B2 (en) 2019-03-28 2023-07-04 Exxonmobil Chemical Patents Inc. Processes and systems for converting benzene and/or toluene via methylation
CN113574036B (zh) 2019-03-28 2024-10-22 埃克森美孚化学专利公司 经由甲基化转化苯和/或甲苯的方法
CN113574038B (zh) 2019-03-28 2024-10-22 埃克森美孚化学专利公司 经由甲基化转化苯和/或甲苯的方法
CN111547735B (zh) * 2020-04-30 2022-08-09 上海工程技术大学 一种纯硅和高硅cha分子筛的可控合成方法
CN111530302B (zh) * 2020-04-30 2022-08-09 上海工程技术大学 一种全硅和高硅cha分子筛膜的可控合成方法
US20250128999A1 (en) 2021-09-16 2025-04-24 ExxonMobil Technology and Engineering Company Xylene Isomer Separation Processes
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US12391561B2 (en) 2023-01-10 2025-08-19 Saudi Arabian Oil Company Method to lower structure directing agent content requirement for manufacture of crystalline material having a CHA framework

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Publication number Priority date Publication date Assignee Title
RU2627399C2 (ru) * 2012-06-04 2017-08-08 Басф Се Цеолитные материалы типа сна и способы их получения с применением циклоалкиламмониевых соединений
RU2678676C2 (ru) * 2014-06-05 2019-01-30 Басф Се Цеолитные материалы типа сна и способы их получения с использованием комбинаций циклоалкил- и тетраалкиламмониевых соединений

Also Published As

Publication number Publication date
ES2279105T3 (es) 2007-08-16
US7148172B2 (en) 2006-12-12
CN1646427A (zh) 2005-07-27
DE60310898T2 (de) 2007-10-11
TWI315718B (en) 2009-10-11
AU2003222228A1 (en) 2003-09-29
US20030176751A1 (en) 2003-09-18
DE60310898D1 (de) 2007-02-15
EP1485323A1 (en) 2004-12-15
US7435863B2 (en) 2008-10-14
ATE350338T1 (de) 2007-01-15
TW200304427A (en) 2003-10-01
EP1485323B1 (en) 2007-01-03
ZA200407139B (enExample) 2006-06-28
EA200401139A1 (ru) 2005-04-28
JP2005520763A (ja) 2005-07-14
JP4508654B2 (ja) 2010-07-21
MY131154A (en) 2007-07-31
WO2003078324A1 (en) 2003-09-25
US20070043251A1 (en) 2007-02-22
CN100418881C (zh) 2008-09-17

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