TWI315718B - High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins - Google Patents

High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins

Info

Publication number
TWI315718B
TWI315718B TW092104088A TW92104088A TWI315718B TW I315718 B TWI315718 B TW I315718B TW 092104088 A TW092104088 A TW 092104088A TW 92104088 A TW92104088 A TW 92104088A TW I315718 B TWI315718 B TW I315718B
Authority
TW
Taiwan
Prior art keywords
sub
line
formulae
conversion
olefins
Prior art date
Application number
TW092104088A
Other languages
English (en)
Chinese (zh)
Other versions
TW200304427A (en
Inventor
Karl Gottlieb Strohmaier
Sebastian C Reyes
Doron Levin
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of TW200304427A publication Critical patent/TW200304427A/zh
Application granted granted Critical
Publication of TWI315718B publication Critical patent/TWI315718B/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7015—CHA-type, e.g. Chabazite, LZ-218
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW092104088A 2002-03-15 2003-02-26 High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins TWI315718B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US36445002P 2002-03-15 2002-03-15

Publications (2)

Publication Number Publication Date
TW200304427A TW200304427A (en) 2003-10-01
TWI315718B true TWI315718B (en) 2009-10-11

Family

ID=28041917

Family Applications (1)

Application Number Title Priority Date Filing Date
TW092104088A TWI315718B (en) 2002-03-15 2003-02-26 High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins

Country Status (13)

Country Link
US (2) US7148172B2 (enExample)
EP (1) EP1485323B1 (enExample)
JP (1) JP4508654B2 (enExample)
CN (1) CN100418881C (enExample)
AT (1) ATE350338T1 (enExample)
AU (1) AU2003222228A1 (enExample)
DE (1) DE60310898T2 (enExample)
EA (1) EA007658B1 (enExample)
ES (1) ES2279105T3 (enExample)
MY (1) MY131154A (enExample)
TW (1) TWI315718B (enExample)
WO (1) WO2003078324A1 (enExample)
ZA (1) ZA200407139B (enExample)

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CN1890178B (zh) * 2003-12-23 2011-04-13 埃克森美孚化学专利公司 菱沸石型分子筛、其合成及其在含氧化合物转化成烯烃中的应用
EP1701914B1 (en) * 2003-12-23 2019-02-20 ExxonMobil Chemical Patents Inc. Chabazite-containing molecular sieve, its synthesis and its use in the conversion of oxygenates to olefins
CN1902132B (zh) * 2003-12-30 2010-10-27 埃克森美孚研究工程公司 高固体含量材料处理
CA2589467C (en) * 2004-11-29 2013-07-02 Chevron U.S.A. Inc. High-silica molecular sieve cha
US20060115399A1 (en) * 2004-11-29 2006-06-01 Chevron U.S.A. Inc. Treatment of engine exhaust using high-silica molecular sieve CHA
US20060115403A1 (en) * 2004-11-29 2006-06-01 Chevron U.S.A. Inc. Reduction of oxides of nitrogen in a gas stream using high-silics molecular sieve CHA
US7402297B2 (en) * 2004-11-29 2008-07-22 Chevron U.S.A. Inc. High-silica molecular sieve CHA
US7282082B2 (en) * 2004-11-29 2007-10-16 Chevron Usa, Inc. Gas separation using high-silica molecular sieve CHA
US20060116540A1 (en) * 2004-11-29 2006-06-01 Chevron U.S.A. Inc. Conversion of oxygenates to light olefins using high-silica molecular sieve CHA
CN101065321B (zh) * 2004-11-29 2010-07-28 切夫里昂美国公司 高硅石分子筛cha
US7462744B1 (en) * 2004-11-30 2008-12-09 Chevron U.S.A. Inc. Synthesis of amines using boron-containing molecular sieve CHA
US7226575B2 (en) * 2004-11-30 2007-06-05 Chevron U.S.A. Inc. Boron-containing molecular sieve CHA
US7749471B2 (en) * 2004-11-30 2010-07-06 Chevron U.S.A. Inc. Reduction of oxides of nitrogen in a gas stream using boron-containing molecular sieve CHA
US20060115400A1 (en) * 2004-11-30 2006-06-01 Chevron U.S.A. Inc. Treatment of engine exhaust using boron-containing molecular sieve CHA
EP1838420B1 (en) * 2004-11-30 2021-02-17 Chevron U.S.A., Inc. Boron-containing molecular sieve cha
US7754187B2 (en) * 2005-10-31 2010-07-13 Exxonmobil Chemical Patents Inc. Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
WO2007053239A1 (en) 2005-10-31 2007-05-10 Exxonmobil Chemical Patents Inc. Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins
KR101382804B1 (ko) * 2006-03-30 2014-04-08 미쓰비시 가가꾸 가부시키가이샤 프로필렌의 제조 방법
JP5135839B2 (ja) * 2006-03-30 2013-02-06 三菱化学株式会社 プロピレンの製造方法
US8383080B2 (en) * 2006-06-09 2013-02-26 Exxonmobil Chemical Patents Inc. Treatment of CHA-type molecular sieves and their use in the conversion of oxygenates to olefins
CN101500707B (zh) * 2006-08-03 2014-03-12 埃克森美孚化学专利公司 轻质烯烃的制备
US8415518B2 (en) 2006-08-03 2013-04-09 Exxonmobil Chemical Patents Inc. Production of light olefins
US7507393B2 (en) * 2007-03-20 2009-03-24 Chevron U. S. A. Inc. Boron-containing molecular sieve CHA
US20090131730A1 (en) * 2007-11-16 2009-05-21 Lun-Teh Yuen Oxygenate conversion using boron-containing molecular sieve cha
CN101514022B (zh) * 2008-02-20 2011-08-17 中国石油化工股份有限公司 Zsm-5/zsm-23/mcm-22三相共生分子筛及其合成方法
CN101514013B (zh) * 2008-02-20 2011-05-18 中国石油化工股份有限公司 ZSM-5/Magadiite/丝光沸石共生材料及其合成方法
CN101514023B (zh) * 2008-02-20 2011-11-30 中国石油化工股份有限公司 Zsm-5/zsm-23/y沸石三相共生分子筛及其合成方法
EP2098287A1 (en) 2008-03-03 2009-09-09 ExxonMobil Chemical Patents Inc. Method of formulating a molecular sieve catalyst composition by controlling component addition
US8071071B2 (en) * 2008-05-02 2011-12-06 Exxonmobil Chemical Patents Inc. Treatment of small pore molecular sieves and their use in the conversion of oxygenates to olefins
US8715618B2 (en) 2008-05-21 2014-05-06 Basf Se Process for the direct synthesis of Cu containing zeolites having CHA structure
US7772335B1 (en) 2009-03-27 2010-08-10 Exxonmobil Chemical Patents Inc. Light olefin selective oxygenate conversion process using CHA framework type aluminosilicate
US20100331597A1 (en) * 2009-06-29 2010-12-30 Guang Cao Catalyst And Once-Through Reactor-Regenerator Process For Oxygenate To Olefins Production
JP5668422B2 (ja) * 2009-11-10 2015-02-12 三菱化学株式会社 アルミノシリケートの製造方法
US8409546B2 (en) * 2009-11-24 2013-04-02 Basf Se Process for the preparation of zeolites having B-CHA structure
KR101769564B1 (ko) * 2009-11-24 2017-08-21 바스프 에스이 Ｃｈａ 구조를 갖는 제올라이트의 제조 방법
JP5957828B2 (ja) * 2010-08-26 2016-07-27 三菱化学株式会社 ガス分離用ゼオライト膜複合体
JP5783952B2 (ja) * 2011-05-20 2015-09-24 国立大学法人東京工業大学 オレフィンの製造方法及びオレフィン製造用触媒
US9174849B2 (en) * 2011-08-25 2015-11-03 Basf Corporation Molecular sieve precursors and synthesis of molecular sieves
CA2855572C (en) * 2011-11-11 2020-04-28 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material of the cha-type structure
US9636667B2 (en) 2012-06-04 2017-05-02 Basf Se CHA-type zeolite materials and methods for their preparation using cycloalkyammonium compounds
KR102108057B1 (ko) * 2012-06-04 2020-05-07 바스프 에스이 Cha-형 제올라이트 물질, 및 사이클로알킬암모늄 화합물을 사용하여 이들을 제조하는 방법
US9296620B2 (en) 2013-08-09 2016-03-29 Chevron U.S.A. Inc. Preparation of high-silica cha-type molecular sieves using a mixed template
US10315924B2 (en) * 2014-06-05 2019-06-11 Basf Se CHA type zeolitic materials and methods for their preparation using combinations of cycloalkyl-and tetraalkylammonium compounds
US10173211B2 (en) 2014-10-14 2019-01-08 California Institute Of Technology Organic-free synthesis of small pore zeolite catalysts
JP6442329B2 (ja) * 2015-03-12 2018-12-19 国立大学法人横浜国立大学 高Ｓｉ／Ａｌ比のＣＨＡ型ゼオライトの製法
EP3201161A4 (en) 2015-08-24 2018-08-15 SABIC Global Technologies B.V. Ssz-13 as a catalyst for conversion of chloromethane to olefins
US10179753B2 (en) 2015-10-21 2019-01-15 Exelus, Inc. Process of making olefins or alkylate by reaction of methanol and/or DME or by reaction of methanol and/or DME and butane
MX2019003880A (es) * 2016-10-03 2019-08-05 Basf Corp Composiciones de zeolita de aluminosilicato con gradiente de aluminio.
US10618040B2 (en) 2016-10-25 2020-04-14 Jgc Catalysts And Chemicals Ltd. Chabazite zeolite for substrate coating
ES2698700B2 (es) * 2017-08-04 2019-11-21 Consejo Superior Investigacion Sintesis de la zeolita cha en su forma nanocristalina, procedimiento de sintesis y su uso en aplicaciones cataliticas
US11691933B2 (en) 2019-03-28 2023-07-04 Exxonmobil Chemical Patents Inc. Processes and systems for converting benzene and/or toluene via methylation
CN113574036B (zh) 2019-03-28 2024-10-22 埃克森美孚化学专利公司 经由甲基化转化苯和/或甲苯的方法
CN113574038B (zh) 2019-03-28 2024-10-22 埃克森美孚化学专利公司 经由甲基化转化苯和/或甲苯的方法
CN111547735B (zh) * 2020-04-30 2022-08-09 上海工程技术大学 一种纯硅和高硅cha分子筛的可控合成方法
CN111530302B (zh) * 2020-04-30 2022-08-09 上海工程技术大学 一种全硅和高硅cha分子筛膜的可控合成方法
US20250128999A1 (en) 2021-09-16 2025-04-24 ExxonMobil Technology and Engineering Company Xylene Isomer Separation Processes
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Also Published As

Publication number Publication date
ES2279105T3 (es) 2007-08-16
US7148172B2 (en) 2006-12-12
CN1646427A (zh) 2005-07-27
DE60310898T2 (de) 2007-10-11
EA007658B1 (ru) 2006-12-29
AU2003222228A1 (en) 2003-09-29
US20030176751A1 (en) 2003-09-18
DE60310898D1 (de) 2007-02-15
EP1485323A1 (en) 2004-12-15
US7435863B2 (en) 2008-10-14
ATE350338T1 (de) 2007-01-15
TW200304427A (en) 2003-10-01
EP1485323B1 (en) 2007-01-03
ZA200407139B (enExample) 2006-06-28
EA200401139A1 (ru) 2005-04-28
JP2005520763A (ja) 2005-07-14
JP4508654B2 (ja) 2010-07-21
MY131154A (en) 2007-07-31
WO2003078324A1 (en) 2003-09-25
US20070043251A1 (en) 2007-02-22
CN100418881C (zh) 2008-09-17

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