DK172283B1 - Fremgangsmåde til spaltning i de optisk aktive bestanddele af chirale lactoner, alkoholer eller phenoler samt mellemprodukter - Google Patents

Fremgangsmåde til spaltning i de optisk aktive bestanddele af chirale lactoner, alkoholer eller phenoler samt mellemprodukter Download PDF

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Publication number
DK172283B1
DK172283B1 DK108879A DK108879A DK172283B1 DK 172283 B1 DK172283 B1 DK 172283B1 DK 108879 A DK108879 A DK 108879A DK 108879 A DK108879 A DK 108879A DK 172283 B1 DK172283 B1 DK 172283B1
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DK
Denmark
Prior art keywords
dimethyl
methyl
characteristic
ppm
oxabicyclo
Prior art date
Application number
DK108879A
Other languages
Danish (da)
English (en)
Other versions
DK108879A (da
Inventor
Jacques Martel
Jean Tessier
Andre Teche
Original Assignee
Roussel Uclaf
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Roussel Uclaf filed Critical Roussel Uclaf
Publication of DK108879A publication Critical patent/DK108879A/da
Application granted granted Critical
Publication of DK172283B1 publication Critical patent/DK172283B1/da

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/26—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D307/30—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/32—Oxygen atoms
    • C07D307/33—Oxygen atoms in position 2, the oxygen atom being in its keto or unsubstituted enol form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
    • C07C41/26—Preparation of ethers by reactions not forming ether-oxygen bonds by introduction of hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
    • C07C43/295—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
    • C07D307/93—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems condensed with a ring other than six-membered
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D315/00—Heterocyclic compounds containing rings having one oxygen atom as the only ring hetero atom according to more than one of groups C07D303/00 - C07D313/00
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
DK108879A 1978-03-17 1979-03-16 Fremgangsmåde til spaltning i de optisk aktive bestanddele af chirale lactoner, alkoholer eller phenoler samt mellemprodukter DK172283B1 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7807778A FR2423488A1 (fr) 1978-03-17 1978-03-17 Nouveaux ethers dont les restes organiques comportent des atomes chiraux, leur procede de preparation et leur application au dedoublement des alcools, des phenols ou de certains composes de structure lactonique
FR7807778 1978-03-17

Publications (2)

Publication Number Publication Date
DK108879A DK108879A (da) 1979-09-18
DK172283B1 true DK172283B1 (da) 1998-02-23

Family

ID=9205944

Family Applications (1)

Application Number Title Priority Date Filing Date
DK108879A DK172283B1 (da) 1978-03-17 1979-03-16 Fremgangsmåde til spaltning i de optisk aktive bestanddele af chirale lactoner, alkoholer eller phenoler samt mellemprodukter

Country Status (15)

Country Link
US (5) US4265817A (ja)
EP (1) EP0004493B1 (ja)
JP (2) JPS54130556A (ja)
AT (1) AT368150B (ja)
AU (1) AU531474B2 (ja)
CA (1) CA1128058A (ja)
DD (1) DD143908A5 (ja)
DE (1) DE2960320D1 (ja)
DK (1) DK172283B1 (ja)
ES (1) ES478753A1 (ja)
FR (1) FR2423488A1 (ja)
HU (2) HU184194B (ja)
IL (1) IL56813A (ja)
PT (1) PT69359A (ja)
ZA (1) ZA791186B (ja)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2423488A1 (fr) * 1978-03-17 1979-11-16 Roussel Uclaf Nouveaux ethers dont les restes organiques comportent des atomes chiraux, leur procede de preparation et leur application au dedoublement des alcools, des phenols ou de certains composes de structure lactonique
FR2472570A1 (fr) * 1979-07-31 1981-07-03 Roussel Uclaf Procede de preparation du (1,5) 6,6-dimethyl 4-hydroxy 3-oxa bicylo(3.1.0.)hexan-2-one et de ses ethers en position 4, sous toutes leurs formes stereoisomeres
EP0029092B1 (en) * 1979-09-06 1983-01-05 Sumitomo Chemical Company, Limited Cis-(1r,2s)-3,3-dimethyl-2-((4s)-3-methyl-2-(2-propynyl)cyclopent-2-en-1-on-4-yloxyhydroxymethyl)-cyclopropanecarboxylic lactone and method of producing (s)-4-hydroxy-3-methyl-2-(2-propynyl)-cyclopent-2-en-1-on
US5136050A (en) * 1979-12-10 1992-08-04 Roussel Uclaf Process for resolving amino acids using substituted lactones
FR2471377A1 (fr) * 1979-12-10 1981-06-19 Roussel Uclaf Nouveaux composes comportant un groupement azote, leur procede de preparation et leur application au dedoublement de certains composes organiques
JPS57159777A (en) * 1981-03-27 1982-10-01 Teijin Ltd 4-hydroxycyclopentenone compound and its preparation
US4665174A (en) * 1981-05-12 1987-05-12 Sumitomo Chemical Company, Limited Production of cyclopentenone derivatives
JPS5841836A (ja) * 1981-09-08 1983-03-11 Teijin Ltd 光学活性４−ヒドロキシシクロペンテノン誘導体及びその製造法
FR2517677B1 (fr) * 1981-12-09 1986-05-16 Roussel Uclaf Nouveaux ethers dont les restes organiques comportent des atomes chiraux, leur procede de preparation et leur application au dedoublement des alcools ou de certains composes de structure hemiacetalique.
US4497960A (en) * 1981-12-18 1985-02-05 Christian Noe Chiral, optically active compounds useful as protective groups for hydroxy, thiol and amino compounds
DE3474546D1 (en) * 1983-02-03 1988-11-17 Sumitomo Chemical Co Optically active 4-hydroxy-2-cyclopentenones, and their production
US4499292A (en) * 1983-05-13 1985-02-12 E. R. Squibb & Sons, Inc. 7-Oxabicycloheptane prostaglandin intermediates and method for preparing same
JPS61215342A (ja) * 1985-03-19 1986-09-25 Sumitomo Chem Co Ltd 光学活性４−ヒドロキシ−２−置換−２−シクロペンテノンの製造法
US7857506B2 (en) * 2005-12-05 2010-12-28 Sencal Llc Disposable, pre-calibrated, pre-validated sensors for use in bio-processing applications

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3884966A (en) * 1965-04-23 1975-05-20 Hoffmann La Roche Phenenthrene salts of {60 ,{65 -dihydroxy-{62 -{62 ,dimethylbutyric acid
FR1580474A (ja) * 1968-07-12 1969-09-05
US4014918A (en) * 1968-07-12 1977-03-29 Roussel-Uclaf Process for the preparation of cyclopropane derivatives and compounds produced therein
IL32569A (en) * 1968-07-12 1976-06-30 Roussel Uclaf Process for the preparation of dimethyl cyclopropane carboxylic acid derivatives and some products resulting therefrom
US3775413A (en) * 1972-06-13 1973-11-27 Tanabe Seiyaku Co Diastereoisomeric salts of 3,4-(1',3'-dibenzyl-2'-oxo-imidazolido)-2-oxo-5-hydroxy-tetrahydrofuran
DE2346304A1 (de) * 1973-09-14 1975-04-03 Basf Ag Verfahren zur herstellung von 4-oxa-5hydroxy-polycycloalkenon-(3)-en
US4011211A (en) * 1973-10-16 1977-03-08 Hoffmann-La Roche Inc. Steroid total synthesis process utilizing asymmetric induction
GB1470097A (en) * 1974-04-18 1977-04-14 Int Dev Res Centre Alpha-butyrolactone derivatives as germination factors
DE2510714A1 (de) * 1975-03-12 1976-09-30 Basf Ag Optisch aktive carbamate und diese enthaltende arzneimittel
US4132717A (en) * 1977-08-09 1979-01-02 Shell Oil Company Enol lactone intermediate for the preparation of (1R,cis)-caronaldehydic acid
ZA7911B (en) * 1978-01-31 1980-01-30 Roussel Uclaf Optically-active substituted benzyl alcohol and process for preparing it
FR2419939A1 (fr) * 1978-03-17 1979-10-12 Roussel Uclaf Procede de preparation d'un ether d'alcool a-cyane optiquement actif
FR2423488A1 (fr) * 1978-03-17 1979-11-16 Roussel Uclaf Nouveaux ethers dont les restes organiques comportent des atomes chiraux, leur procede de preparation et leur application au dedoublement des alcools, des phenols ou de certains composes de structure lactonique

Also Published As

Publication number Publication date
US4720556A (en) 1988-01-19
IL56813A (en) 1985-01-31
IL56813A0 (en) 1979-05-31
AU4517979A (en) 1979-09-20
HU184194B (en) 1984-07-30
ATA201679A (de) 1982-01-15
US4540797A (en) 1985-09-10
FR2423488A1 (fr) 1979-11-16
US4265817A (en) 1981-05-05
JPS54130556A (en) 1979-10-09
DK108879A (da) 1979-09-18
ZA791186B (en) 1980-03-26
CA1128058A (fr) 1982-07-20
US4658043A (en) 1987-04-14
HU190500B (en) 1986-09-29
JPH044314B2 (ja) 1992-01-27
AU531474B2 (en) 1983-08-25
EP0004493A1 (fr) 1979-10-03
FR2423488B1 (ja) 1981-12-11
JPH0285273A (ja) 1990-03-26
EP0004493B1 (fr) 1981-05-06
AT368150B (de) 1982-09-10
DE2960320D1 (en) 1981-08-13
ES478753A1 (es) 1980-01-16
JPH0446955B2 (ja) 1992-07-31
PT69359A (fr) 1979-04-01
US4374257A (en) 1983-02-15
DD143908A5 (de) 1980-09-17

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