DK146583C - Fremgangsmaade til ammoxidation eller oxidation af propylen eller isobutylen eller til dehydrogenering af alkener med 4 - 10 carbonatomer og katalysator til brug ved fremgangsmaaden - Google Patents

Fremgangsmaade til ammoxidation eller oxidation af propylen eller isobutylen eller til dehydrogenering af alkener med 4 - 10 carbonatomer og katalysator til brug ved fremgangsmaaden

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Publication number
DK146583C
DK146583C DK465074A DK465074A DK146583C DK 146583 C DK146583 C DK 146583C DK 465074 A DK465074 A DK 465074A DK 465074 A DK465074 A DK 465074A DK 146583 C DK146583 C DK 146583C
Authority
DK
Denmark
Prior art keywords
procedure
dehydrogeneration
ammoxidation
alkenes
isobutylene
Prior art date
Application number
DK465074A
Other languages
Danish (da)
English (en)
Other versions
DK146583B (da
DK465074A (no
Inventor
Robert Karl Grasselli
Arthur Francis Miller
Wilfrid Garside Shaw
Original Assignee
Standard Oil Co Ohio
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Standard Oil Co Ohio filed Critical Standard Oil Co Ohio
Publication of DK465074A publication Critical patent/DK465074A/da
Publication of DK146583B publication Critical patent/DK146583B/da
Application granted granted Critical
Publication of DK146583C publication Critical patent/DK146583C/da

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
    • B01J23/8885Tungsten containing also molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19Molybdenum
    • B01J27/192Molybdenum with bismuth
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/24Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/42Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
    • C07C5/48Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00Chemistry of hydrocarbon compounds
    • Y10S585/8995Catalyst and recycle considerations
    • Y10S585/906Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DK465074A 1973-09-04 1974-09-03 Fremgangsmaade til ammoxidation eller oxidation af propylen eller isobutylen eller til dehydrogenering af alkener med 4 - 10 carbonatomer og katalysator til brug ved fremgangsmaaden DK146583C (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/393,732 US3956181A (en) 1973-09-04 1973-09-04 Oxidation catalyst
US39373273 1973-09-04

Publications (3)

Publication Number Publication Date
DK465074A DK465074A (no) 1975-05-05
DK146583B DK146583B (da) 1983-11-14
DK146583C true DK146583C (da) 1984-04-30

Family

ID=23556013

Family Applications (1)

Application Number Title Priority Date Filing Date
DK465074A DK146583C (da) 1973-09-04 1974-09-03 Fremgangsmaade til ammoxidation eller oxidation af propylen eller isobutylen eller til dehydrogenering af alkener med 4 - 10 carbonatomer og katalysator til brug ved fremgangsmaaden

Country Status (32)

Country Link
US (1) US3956181A (no)
JP (1) JPS5064191A (no)
AR (1) AR205351A1 (no)
BE (1) BE819533A (no)
BG (1) BG36494A3 (no)
BR (1) BR7407285D0 (no)
CA (1) CA1048481A (no)
CH (3) CH605477A5 (no)
CS (1) CS220305B2 (no)
DD (1) DD112906A5 (no)
DE (1) DE2440329C2 (no)
DK (1) DK146583C (no)
EG (1) EG11372A (no)
ES (1) ES429744A1 (no)
FI (1) FI62959C (no)
FR (1) FR2242146B1 (no)
GB (1) GB1473530A (no)
HU (2) HU181732B (no)
IE (1) IE39886B1 (no)
IL (1) IL45503A (no)
IN (1) IN143036B (no)
IT (1) IT1020135B (no)
MY (1) MY7800190A (no)
NL (1) NL186138C (no)
NO (1) NO141830C (no)
PH (1) PH12128A (no)
PL (1) PL108045B1 (no)
RO (1) RO66352A (no)
SE (1) SE403104B (no)
SU (1) SU588906A3 (no)
TR (1) TR18345A (no)
ZA (1) ZA745492B (no)

Families Citing this family (66)

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US4162234A (en) * 1974-07-22 1979-07-24 The Standard Oil Company Oxidation catalysts
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CA1071659A (en) * 1975-09-18 1980-02-12 Goodyear Tire And Rubber Company (The) Oxidative dehydrogenation of olefins to diolefins
US4052332A (en) * 1976-04-20 1977-10-04 E. I. Du Pont De Nemours And Company Catalyst regeneration with impregnation of bismuth and molybdenum
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US4083805A (en) * 1976-06-30 1978-04-11 The Standard Oil Company Preparation of methacrylic acid from methacrolein
US4105586A (en) * 1977-02-10 1978-08-08 Denka Chemical Corporation Oxidation catalysts and process for preparing anhydride from alkanes
US4202826A (en) * 1977-02-10 1980-05-13 Denka Chemical Corporation Process for preparing anhydride from alkanes
US4167516A (en) * 1977-02-10 1979-09-11 Denka Chemical Corporation Preparation of dicarboxylic anhydrides
US4556731A (en) * 1977-07-28 1985-12-03 The Standard Oil Company Process for the oxidation of olefins using catalysts containing various promoter elements
US4322368A (en) * 1979-12-28 1982-03-30 The Standard Oil Co. Copper-promoted antimony phosphate oxide complex catalysts
JPS56140931A (en) * 1980-04-04 1981-11-04 Nippon Zeon Co Ltd Preparation of conjugated diolefin
JPS56150023A (en) * 1980-04-22 1981-11-20 Nippon Zeon Co Ltd Preparation of conjugated diolefin
US4444906A (en) * 1981-06-08 1984-04-24 The Standard Oil Company Method for the preparation of high activity phosphomolybdic acid based catalysts
CA1199905A (en) * 1982-06-07 1986-01-28 William J. Kennelly Catalyst compositions and their use for the preparation of unsaturated carboxylic acids
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
US4777313A (en) * 1983-08-12 1988-10-11 Atlantic Richfield Company Boron-promoted reducible metal oxides and methods of their use
US4855275A (en) * 1988-02-18 1989-08-08 The Standard Oil Company Catalyst performance improvement via separate boron addition
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TR27951A (tr) * 1992-06-23 1995-11-08 Standard Oil Co Ohio Akrilonitrile propilen amoksidasyonu icin gelistirilmis bir islem ve katalizör.
JP3114587B2 (ja) * 1995-10-23 2000-12-04 ヤマハ株式会社 カラオケアンプ
ES2283260T3 (es) * 1999-11-24 2007-11-01 Saudi Basic Industries Corporation Deshidrogenacion oxidante de parafinas.
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
KR100888133B1 (ko) * 2007-10-02 2009-03-13 에스케이에너지 주식회사 4종의 금속성분으로 구성된 다성분계 비스무스몰리브데이트 촉매 제조방법 및 상기촉매를 이용하여1,3-부타디엔을 제조하는 방법
WO2012005837A1 (en) * 2010-07-09 2012-01-12 Sumitomo Chemical Company, Limited Process for producing olefin oxide
JP2013505997A (ja) * 2010-07-09 2013-02-21 住友化学株式会社 酸化オレフィンの製造方法
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JP6138161B2 (ja) 2012-01-30 2017-05-31 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se n−ブタンからのブタジエンおよび/またはブテン類の製造方法
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JP2015530394A (ja) 2012-09-20 2015-10-15 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se C4炭化水素流からの酸素の除去によるブタジエンの製造方法
WO2014086768A1 (de) 2012-12-06 2014-06-12 Basf Se Verfahren zur oxidativen dehydrierung von n-butenen zu butadien
US9399606B2 (en) 2012-12-06 2016-07-26 Basf Se Catalyst and process for the oxidative dehydrogenation of N-butenes to butadiene
WO2014111409A1 (de) 2013-01-15 2014-07-24 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
US10144681B2 (en) 2013-01-15 2018-12-04 Basf Se Process for the oxidative dehydrogenation of N-butenes to butadiene
EP2945921B1 (de) 2013-01-16 2017-03-22 Basf Se Verfahren zur herstellung von butadien durch oxidative dehydrierung von n-butenen mit überwachung des peroxid-gehalts bei der produktaufarbeitung
JP2016526565A (ja) 2013-07-10 2016-09-05 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se n−ブテンをブタジエンへと酸化脱水素化する方法
CN105683136B (zh) 2013-10-30 2018-06-01 巴斯夫欧洲公司 由正丁烯通过氧化脱氢制备1,3-丁二烯的方法
EP3094611A1 (de) 2014-01-13 2016-11-23 Basf Se Verfahren zum anfahren eines reaktors zur oxidativen dehydrierung von n-butenen
DE102014203725A1 (de) 2014-02-28 2015-09-03 Basf Se Oxidationskatalysator mit sattelförmigem Trägerformkörper
JP2017524011A (ja) 2014-08-12 2017-08-24 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 酸化的脱水素反応によりn−ブテン類から1,3−ブタジエンを製造するための方法
JP6608916B2 (ja) 2014-09-26 2019-11-20 ビーエーエスエフ ソシエタス・ヨーロピア 酸化的脱水素化によりn−ブテン類から1,3−ブタジエンを製造するための方法
WO2016071268A1 (en) 2014-11-03 2016-05-12 Basf Se Process for preparing 1,3-butadiene from n-butenes by oxidative dehydrogenation
KR20170084076A (ko) 2014-11-14 2017-07-19 바스프 에스이 부탄 및 2-부텐을 포함하는 스트림의 제공 하에 n-부텐의 탈수소화에 의한 1,3-부타디엔의 제조 방법
EA201792147A1 (ru) 2015-03-26 2018-05-31 Басф Се Способ получения 1,3-бутадиена из н-бутенов путем окислительного дегидрирования
WO2016150940A1 (de) 2015-03-26 2016-09-29 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
WO2016151074A1 (de) 2015-03-26 2016-09-29 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
CN107667084A (zh) 2015-03-26 2018-02-06 巴斯夫欧洲公司 由正丁烯通过氧化脱氢生产1,3‑丁二烯
US20180354872A1 (en) 2015-12-03 2018-12-13 Basf Se Method for producing butadiene by oxidatively dehydrogenating n-butenes
EP3402769B1 (de) 2016-01-13 2020-03-25 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung
CN108884003A (zh) 2016-02-04 2018-11-23 巴斯夫欧洲公司 通过氧化脱氢由n-丁烯制备1,3-丁二烯的方法
CN109843836A (zh) 2016-08-09 2019-06-04 巴斯夫欧洲公司 启动用于正丁烯的氧化脱氢的反应器的方法
WO2018095856A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine methacrolein-abtrennung bei der aufarbeitung
WO2018095840A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine furan-abtrennung bei der aufarbeitung
WO2018095776A1 (de) 2016-11-22 2018-05-31 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wässrige wäsche des c4-produktgasstroms
EP3323797A1 (de) 2016-11-22 2018-05-23 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine saure wäsche des c4-produktgasstroms
WO2018219996A1 (de) 2017-06-02 2018-12-06 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung in kreisgasfahrweise mit co2-angereichertem kreisgas
WO2018234158A1 (de) 2017-06-19 2018-12-27 Basf Se Verfahren zur herstellung von 1,3-butadien aus n-butenen durch oxidative dehydrierung umfassend eine wäsche des c4-produktgasstroms

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Also Published As

Publication number Publication date
BE819533A (fr) 1975-03-04
FI257074A (no) 1975-03-05
BR7407285D0 (pt) 1975-07-01
CH603514A5 (no) 1978-08-15
NO743150L (no) 1975-04-01
RO66352A (fr) 1979-07-15
CS220305B2 (en) 1983-03-25
CH605477A5 (no) 1978-09-29
IN143036B (no) 1977-09-24
IL45503A (en) 1977-06-30
NL186138B (nl) 1990-05-01
SE403104B (sv) 1978-07-31
FI62959C (fi) 1983-04-11
EG11372A (en) 1977-08-15
AR205351A1 (es) 1976-04-30
MY7800190A (en) 1978-12-31
ES429744A1 (es) 1977-06-16
IE39886B1 (en) 1979-01-17
NO141830C (no) 1980-05-21
JPS5064191A (no) 1975-05-31
ZA745492B (en) 1975-09-24
IE39886L (en) 1975-03-04
IL45503A0 (en) 1974-11-29
FR2242146B1 (no) 1980-10-24
NO141830B (no) 1980-02-11
FR2242146A1 (no) 1975-03-28
NL7411580A (nl) 1975-03-06
CA1048481A (en) 1979-02-13
DK146583B (da) 1983-11-14
IT1020135B (it) 1977-12-20
AU7283974A (en) 1976-03-04
DE2440329C2 (de) 1982-10-21
TR18345A (tr) 1977-01-12
HU181732B (en) 1983-11-28
HU181951B (en) 1983-11-28
DD112906A5 (no) 1975-05-12
GB1473530A (en) 1977-05-11
DE2440329A1 (de) 1975-03-13
SU588906A3 (ru) 1978-01-15
FI62959B (fi) 1982-12-31
SE7410289L (no) 1975-03-05
BG36494A3 (en) 1984-11-15
DK465074A (no) 1975-05-05
US3956181A (en) 1976-05-11
CH600946A5 (no) 1978-06-30
PH12128A (en) 1978-11-07
NL186138C (nl) 1990-10-01
PL108045B1 (pl) 1980-03-31

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