DK142422B - Fremgangsmåde til stereospecifik polymerisation af lavere alfa-olefiner samt katalysator til brug ved fremgangsmåden. - Google Patents
Fremgangsmåde til stereospecifik polymerisation af lavere alfa-olefiner samt katalysator til brug ved fremgangsmåden. Download PDFInfo
- Publication number
- DK142422B DK142422B DK145471AA DK145471A DK142422B DK 142422 B DK142422 B DK 142422B DK 145471A A DK145471A A DK 145471AA DK 145471 A DK145471 A DK 145471A DK 142422 B DK142422 B DK 142422B
- Authority
- DK
- Denmark
- Prior art keywords
- ticl
- catalyst
- brown
- temperature
- violet
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title description 143
- 238000000034 method Methods 0.000 title description 59
- 230000008569 process Effects 0.000 title description 24
- 239000004711 α-olefin Substances 0.000 title description 15
- 238000012721 stereospecific polymerization Methods 0.000 title description 4
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 122
- 238000006243 chemical reaction Methods 0.000 description 62
- 238000006116 polymerization reaction Methods 0.000 description 35
- -1 polypropylene Polymers 0.000 description 31
- 239000007788 liquid Substances 0.000 description 28
- 239000004743 Polypropylene Substances 0.000 description 25
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 25
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 25
- 229920000642 polymer Polymers 0.000 description 24
- 238000006722 reduction reaction Methods 0.000 description 24
- 238000002360 preparation method Methods 0.000 description 23
- 229920001155 polypropylene Polymers 0.000 description 21
- 239000000376 reactant Substances 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 229910010068 TiCl2 Inorganic materials 0.000 description 17
- 230000009467 reduction Effects 0.000 description 16
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 16
- 229910003074 TiCl4 Inorganic materials 0.000 description 15
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 15
- 238000002474 experimental method Methods 0.000 description 14
- 239000002609 medium Substances 0.000 description 14
- 239000012299 nitrogen atmosphere Substances 0.000 description 13
- 238000003756 stirring Methods 0.000 description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 239000011521 glass Substances 0.000 description 12
- 239000000725 suspension Substances 0.000 description 12
- 238000007669 thermal treatment Methods 0.000 description 11
- 150000002902 organometallic compounds Chemical class 0.000 description 10
- 239000012429 reaction media Substances 0.000 description 10
- 238000011282 treatment Methods 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 239000000969 carrier Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 9
- 229910010062 TiCl3 Inorganic materials 0.000 description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 238000001914 filtration Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 125000005234 alkyl aluminium group Chemical group 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 6
- 239000003638 chemical reducing agent Substances 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 230000000707 stereoselective effect Effects 0.000 description 6
- 239000010936 titanium Substances 0.000 description 6
- 230000009466 transformation Effects 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 238000002386 leaching Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000004913 activation Effects 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 239000011261 inert gas Substances 0.000 description 4
- 239000012442 inert solvent Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003701 inert diluent Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229920003299 Eltex® Polymers 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 210000000988 bone and bone Anatomy 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000013256 coordination polymer Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 239000002612 dispersion medium Substances 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 229920001580 isotactic polymer Polymers 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 150000004653 carbonic acids Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000012050 conventional carrier Substances 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229910052587 fluorapatite Inorganic materials 0.000 description 1
- 229940077441 fluorapatite Drugs 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000012245 magnesium oxide Nutrition 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- GBECUEIQVRDUKB-UHFFFAOYSA-M thallium monochloride Chemical compound [Tl]Cl GBECUEIQVRDUKB-UHFFFAOYSA-M 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000009489 vacuum treatment Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/02—Halides of titanium
- C01G23/026—Titanium trichloride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7011085 | 1970-03-26 | ||
| FR7011085A FR2082813A5 (fr) | 1970-03-26 | 1970-03-26 | Procede de preparation d'un catalyseur du type ziegler-natta |
| FR7024087A FR2094681A5 (fr) | 1970-06-29 | 1970-06-29 | Procede de preparation d'un catalyseur du type ziegler-natta |
| FR7024087 | 1970-06-29 | ||
| FR7028300A FR2098923A5 (fr) | 1970-07-30 | 1970-07-30 | Procede de preparation d'un catalyseur du type ziegler-natta |
| FR7028300 | 1970-07-30 | ||
| FR7028663A FR2102436A5 (fr) | 1970-08-03 | 1970-08-03 | Procede de preparation d'un catalyseur du type ziegler-natta |
| FR7028663 | 1970-08-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DK142422B true DK142422B (da) | 1980-10-27 |
| DK142422C DK142422C (en:Method) | 1981-03-30 |
Family
ID=27446055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK145471AA DK142422B (da) | 1970-03-26 | 1971-03-25 | Fremgangsmåde til stereospecifik polymerisation af lavere alfa-olefiner samt katalysator til brug ved fremgangsmåden. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US3769233A (en:Method) |
| JP (2) | JPS53395B1 (en:Method) |
| BE (1) | BE764251A (en:Method) |
| CA (1) | CA962654A (en:Method) |
| CH (1) | CH526989A (en:Method) |
| DE (1) | DE2110380A1 (en:Method) |
| DK (1) | DK142422B (en:Method) |
| FI (1) | FI57355C (en:Method) |
| GB (1) | GB1337764A (en:Method) |
| IE (1) | IE35231B1 (en:Method) |
| NL (1) | NL157317C (en:Method) |
| NO (1) | NO141559C (en:Method) |
| PL (1) | PL72116B1 (en:Method) |
| SE (1) | SE452985B (en:Method) |
| SU (1) | SU410581A3 (en:Method) |
| YU (1) | YU34016B (en:Method) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH543546A (fr) | 1971-03-23 | 1973-10-31 | Solvay | Système catalytique de polymérisation des alpha-oléfines |
| US3905915A (en) * | 1971-07-14 | 1975-09-16 | Exxon Research Engineering Co | Multiple-step procedure for producing a polymerization catalyst |
| BE791441A (fr) * | 1971-11-24 | 1973-05-16 | Solvay | Procede pour la polymerisation des alpha-olefines |
| DE2218361A1 (de) * | 1972-04-15 | 1973-10-31 | Bayer Ag | Verfahren zur kontinuierlichen reinigung von titantetrachlorid |
| GB1467051A (en) * | 1974-01-03 | 1977-03-16 | Shell Int Research | Process for the production of polyolefins and catalyst therefor |
| US4060593A (en) * | 1974-07-31 | 1977-11-29 | Mitsubishi Chemical Industries | Preparation of titanium trichloride |
| JPS527892A (en) * | 1975-07-09 | 1977-01-21 | Toa Nenryo Kogyo Kk | Process for producing catalyst components for polymerization of alpha-olefin |
| JPS527891A (en) * | 1975-07-09 | 1977-01-21 | Toa Nenryo Kogyo Kk | Process for producing catalyst components for polymerization of olefi n |
| US4210736A (en) * | 1975-10-15 | 1980-07-01 | Solvay & Cie. | Particles of titanium trichlorides which can be used for the stereospecific polymerization of alpha-olefines |
| US4207205A (en) * | 1975-10-16 | 1980-06-10 | Exxon Research & Engineering Co. | Reduction of TiCl4 with reducing agents modified with Lewis bases |
| JPS5263981A (en) * | 1975-11-25 | 1977-05-26 | Toa Nenryo Kogyo Kk | Preparation of polymerization catalyst for alpha-olefin |
| US4127504A (en) * | 1975-11-25 | 1978-11-28 | Toa Nenryo Kogyo Kabushiki Kaisha | Process for the production of a catalyst component for use in the polymerization of alphaolefins |
| US4085064A (en) * | 1975-12-12 | 1978-04-18 | Exxon Research & Engineering Co. | Purple TiCl3 by direct low temperature reduction |
| JPS591286B2 (ja) * | 1976-02-05 | 1984-01-11 | 三井東圧化学株式会社 | α−オレフインの重合方法 |
| DE2709857A1 (de) * | 1976-03-08 | 1977-09-15 | Toa Nenryo Kogyo Kk | Verfahren zur herstellung eines titantrichloridkatalysators, der dabei erhaltene katalysator und dessen verwendung zur stereolegulierten polymerisation von alpha-olefinen |
| JPS52110793A (en) * | 1976-03-15 | 1977-09-17 | Sumitomo Chem Co Ltd | Preparation of highly crystalline olefin polymers |
| GB1554574A (en) * | 1976-11-15 | 1979-10-24 | Ici Ltd | Treatment of solid transition metal compound and use of the product in an olefine polymerisation catalyst |
| GB1579725A (en) * | 1976-07-12 | 1980-11-26 | Shell Int Research | Preparation of violet tici3 |
| NL185455C (nl) * | 1976-09-08 | 1990-04-17 | Sumitomo Chemical Co | Werkwijze ter bereiding van een vaste titaantrichloridekatalysator en werkwijze ter bereiding van alkeenpolymeren. |
| US4228262A (en) * | 1976-11-15 | 1980-10-14 | Imperial Chemical Industries Limited | Process for the production of polymer or copolymer of an olefin monomer |
| US4151112A (en) * | 1977-06-30 | 1979-04-24 | Exxon Research & Engineering Co. | Titanium trichloride catalyst complex and process for the production thereof |
| US4267293A (en) * | 1978-05-19 | 1981-05-12 | Phillips Petroleum Company | Method for producing ethylene polymers using treated catalysts containing titanium and vanadium |
| US4208304A (en) * | 1978-05-19 | 1980-06-17 | Phillips Petroleum Company | Catalyst system for producing ethylene polymers |
| DE2962947D1 (en) * | 1978-05-29 | 1982-07-15 | Montedison Spa | Catalysts for stereospecifically polymerizing olefins and process for preparing same |
| CA1121329A (en) * | 1978-07-25 | 1982-04-06 | Andras G.T.G. Kortbeek | Olefin polymerization catalysts |
| IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| US4246134A (en) * | 1978-11-27 | 1981-01-20 | Uvarov Boris A | Catalyst for di-, oligo-, co- and poly- merization of vinyl monomers |
| JPS5846202B2 (ja) * | 1979-01-31 | 1983-10-14 | 住友化学工業株式会社 | オレフィン重合体の製造法 |
| US4284748A (en) * | 1979-09-07 | 1981-08-18 | Phillips Petroleum Company | Olefin polymerization |
| US4405495A (en) * | 1980-06-30 | 1983-09-20 | Union Carbide Corporation | Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization |
| DE3368644D1 (en) * | 1982-07-13 | 1987-02-05 | Mitsubishi Chem Ind | Process for preparing solid titanium trichloride useful for the polymerization of an alpha-olefin |
| US4675368A (en) * | 1982-10-04 | 1987-06-23 | Solvay & Cie. | Process for inhibiting crust formation in reactors during alpha-olefin prepolymerization modification of Ziegler catalyst |
| JPS59137002U (ja) * | 1983-01-31 | 1984-09-12 | 杉谷 栄一 | 木材切断装置 |
| US4900706A (en) * | 1987-03-17 | 1990-02-13 | Sumitomo Chemical Company, Limited | Process for producing olefin polymers and catalyst used therein |
| EP0324835B1 (en) * | 1987-07-10 | 1992-12-02 | Quantum Chemical Corporation | Propylene polymerization catalyst and method |
| US5677256A (en) * | 1990-04-12 | 1997-10-14 | Neste Oy | Method of preparing catalyst composition for polymerizing olefins |
| US5264590A (en) * | 1993-04-01 | 1993-11-23 | Ethyl Corporation | Preparation of titanium (III) coordination complexes |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3141872A (en) * | 1954-12-03 | 1964-07-21 | Montedison Spa | Polymerization catalyst and stereospecific polymerization of propylene therewith |
| DE1292637B (de) * | 1956-08-23 | 1969-04-17 | E H Karl Dr Dr | Verfahren zur Herstellung von Katalysatoren fuer die Polymerisation olefinischer Kohlenwasserstoffe |
| GB898631A (en) * | 1958-11-20 | 1962-06-14 | Hercules Powder Co Ltd | Improvements in or relating to preparation of catalyst for polymerization of 1-olefins |
| US3108973A (en) * | 1961-02-16 | 1963-10-29 | Hercules Powder Co Ltd | Mixed crystal of titanium trichloride, aluminum chloride, and alkylalumi num dichloride |
| BE616930A (en:Method) * | 1961-04-26 | |||
| US3424774A (en) * | 1965-02-10 | 1969-01-28 | Exxon Research Engineering Co | Novel catalyst and process for the cyclotrimerization of conjugated diolefinic materials |
| JPS463717Y1 (en:Method) * | 1966-02-09 | 1971-02-08 | ||
| JPS4611669Y1 (en:Method) * | 1967-06-30 | 1971-04-22 | ||
| FR1550186A (en:Method) * | 1967-08-31 | 1968-12-20 | ||
| JPS4630807Y1 (en:Method) * | 1968-08-02 | 1971-10-25 | ||
| NL141526B (nl) * | 1968-10-08 | 1974-03-15 | Mitsui Petrochemical Ind | Werkwijze voor de bereiding van polyetheen. |
| US3547829A (en) * | 1968-12-27 | 1970-12-15 | Hercules Inc | Preparation of olefin polymerization catalyst |
-
1971
- 1971-01-25 IE IE84/71A patent/IE35231B1/xx unknown
- 1971-02-19 NO NO605/71A patent/NO141559C/no unknown
- 1971-02-26 SU SU1628440A patent/SU410581A3/ru active
- 1971-02-26 CH CH280871A patent/CH526989A/fr not_active IP Right Cessation
- 1971-02-26 NL NL7102587.A patent/NL157317C/xx not_active IP Right Cessation
- 1971-03-04 DE DE19712110380 patent/DE2110380A1/de active Granted
- 1971-03-15 BE BE764251A patent/BE764251A/xx not_active IP Right Cessation
- 1971-03-18 CA CA108,146A patent/CA962654A/en not_active Expired
- 1971-03-24 PL PL1971147114A patent/PL72116B1/pl unknown
- 1971-03-24 US US00127829A patent/US3769233A/en not_active Expired - Lifetime
- 1971-03-25 YU YU756/71A patent/YU34016B/xx unknown
- 1971-03-25 DK DK145471AA patent/DK142422B/da not_active IP Right Cessation
- 1971-03-25 JP JP1693771A patent/JPS53395B1/ja active Pending
- 1971-03-25 SE SE7103901A patent/SE452985B/xx unknown
- 1971-03-26 FI FI871/71A patent/FI57355C/fi active
- 1971-04-19 GB GB2540171*A patent/GB1337764A/en not_active Expired
-
1977
- 1977-06-15 JP JP7005477A patent/JPS537784A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS557442B2 (en:Method) | 1980-02-26 |
| CH526989A (fr) | 1972-08-31 |
| JPS53395B1 (en:Method) | 1978-01-07 |
| IE35231L (en) | 1971-09-26 |
| FI57355B (fi) | 1980-04-30 |
| YU34016B (en) | 1978-10-31 |
| NO141559C (no) | 1980-04-09 |
| JPS537784A (en) | 1978-01-24 |
| YU75671A (en) | 1978-05-15 |
| DE2110380C2 (en:Method) | 1988-02-18 |
| BE764251A (fr) | 1971-09-15 |
| DK142422C (en:Method) | 1981-03-30 |
| PL72116B1 (en) | 1974-06-29 |
| US3769233A (en) | 1973-10-30 |
| NL7102587A (en:Method) | 1971-09-28 |
| GB1337764A (en) | 1973-11-21 |
| FI57355C (fi) | 1980-08-11 |
| DE2110380A1 (de) | 1971-10-07 |
| CA962654A (en) | 1975-02-11 |
| NL157317C (nl) | 1981-11-16 |
| SE452985B (sv) | 1988-01-04 |
| SU410581A3 (en:Method) | 1974-01-05 |
| NL157317B (nl) | 1978-07-17 |
| NO141559B (no) | 1979-12-27 |
| IE35231B1 (en) | 1975-12-24 |
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| PUP | Patent expired |